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1. 发明授权

US5408017A High temperature polymerization process using ionic catalysts to produce polyolefins 失效
标题翻译：使用离子催化剂生产聚烯烃的高温聚合方法
公开(公告)号：US5408017A
公开(公告)日：1995-04-18
申请号：US77479
申请日：1993-06-14
申请人： Howard W. Turner , Jo Ann M. Canich , Bernard J. Folie
发明人： Howard W. Turner , Jo Ann M. Canich , Bernard J. Folie
IPC分类号： C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/643
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/65908 , C08F4/6592 , C08F4/65922
摘要： This invention relates to a process for polymerizing olefins at high pressures in a polymerization medium at high temperature utilizing an ionic olefin polymerization catalyst derived from the reaction of a cyclopentadienyl-containing transition metal compound having a hydrolyzable alkyl or hydride ligand with an ion exchange activator. The ionic catalyst system has been found to be highly active at temperatures of 160.degree. C. or greater, to provide a process capable of producing polymer products of desired chemical and physical properties at high production rates.
摘要翻译：本发明涉及使用衍生自具有可水解的烷基或氢化物配体的含环戊二烯基的过渡金属化合物与离子交换活化剂的反应的离子型烯烃聚合催化剂，在高温聚合介质中在高压下聚合烯烃的方法。已经发现离子催化剂体系在160℃或更高的温度下具有高活性，以提供能够以高生产率生产具有所需化学和物理性质的聚合物产物的方法。

2. 发明授权

US5502124A Transition metal olefin polymerization processes 失效
标题翻译：过渡金属烯烃聚合方法
公开(公告)号：US5502124A
公开(公告)日：1996-03-26
申请号：US445062
申请日：1995-05-19
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to processes using non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及使用可用作烯烃聚合催化剂的非4族过渡金属组合物的方法，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

3. 发明授权

US5318935A Amido transition metal compound and a catalyst system for the production of isotatic polypropylene 失效
标题翻译：酰胺过渡金属化合物和用于生产等压聚丙烯的催化剂体系
公开(公告)号：US5318935A
公开(公告)日：1994-06-07
申请号：US922646
申请日：1992-07-30
申请人： Jo Ann M. Canich , Howard W. Turner
发明人： Jo Ann M. Canich , Howard W. Turner
IPC分类号： C07F7/00 , C07F7/10 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F110/00 , C08F110/06 , C08F210/00 , C08F210/02
CPC分类号： C07F7/10 , C08F110/06 , Y10S526/943
摘要： Certain bridged and unbridged amido transition metal compounds of the Group IV-B metals are disclosed. These compounds may be used in a catalyst system comprising the amido transition metal compound and an alumoxane. Also disclosed is a process using the catalyst system for the production of high molecular weight polyolefins and, particularly, high molecular weight isotactic polypropylene.
摘要翻译：公开了IV-B族金属的某些桥连和未桥连的酰氨基过渡金属化合物。这些化合物可以用于包含酰氨基过渡金属化合物和铝氧烷的催化剂体系中。还公开了使用催化剂体系制备高分子量聚烯烃，特别是高分子量全同立构聚丙烯的方法。

4. 发明授权

US5504049A Transition metal olefin polymerization catalysts 失效
标题翻译：过渡金属烯烃聚合催化剂
公开(公告)号：US5504049A
公开(公告)日：1996-04-02
申请号：US86772
申请日：1993-07-01
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及可用作烯烃聚合催化剂的非4族过渡金属组合物，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

5. 发明授权

US5621126A Monocyclopentadienyl metal compounds for ethylene-.alpha.-olefin-copolymer production catalysts 失效
标题翻译：用于乙烯-α-烯烃共聚物制备催化剂的单环戊二烯基金属化合物
公开(公告)号：US5621126A
公开(公告)日：1997-04-15
申请号：US138169
申请日：1993-10-15
申请人： Jo Ann M. Canich , Howard W. Turner , Gregory G. Hlatky
发明人： Jo Ann M. Canich , Howard W. Turner , Gregory G. Hlatky
IPC分类号： C07F7/10 , C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C07F7/00
CPC分类号： C07F7/10 , C07F17/00 , C08F10/00 , C08F10/06 , C08F210/16 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65922 , Y10S526/943
摘要： Described are certain mono(cyclopentadienyl) Group IV B metal compounds, catalyst systems comprising such mono(cyclopentadienyl) metal compounds and an activator, and to a process using such catalyst systems for the production of polyolefins, particularly ethylene-.alpha.-olefin copolymers having a high molecular weight and high level of .alpha.-olefin incorporation.
摘要翻译：描述了某些单（环戊二烯基）ⅣB族金属化合物，包含这种单（环戊二烯基）金属化合物和活化剂的催化剂体系，以及使用这种催化剂体系制备聚烯烃，特别是乙烯-α-烯烃共聚物的方法，高分子量和高水平的α-烯烃结合。

6. 发明授权

US08058461B2 Mono-indenyl transition metal compounds and polymerization therewith 有权
标题翻译：单茚基过渡金属化合物及其聚合反应
公开(公告)号：US08058461B2
公开(公告)日：2011-11-15
申请号：US12715068
申请日：2010-03-01
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Aleksey A. Tsarev , Andrey F. Asachenko , Alexander V. Babkin , Garth R. Giesbrecht , Jo Ann M. Canich
IPC分类号： C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/943
摘要： This invention relates to transition metal compounds, catalyst systems comprising said compounds and polymerization processes using such catalyst systems, where the transition metal compound is represented by the formula: This invention also relates to process to produce such compounds.
摘要翻译：本发明涉及过渡金属化合物，包含所述化合物的催化剂体系和使用这种催化剂体系的聚合方法，其中过渡金属化合物由下式表示：本发明还涉及制备这些化合物的方法。

7. 发明授权

US07868197B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US07868197B2
公开(公告)日：2011-01-11
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

8. 发明授权

US07763562B2 Heteroatom bridged metallocene compounds for olefin polymerization 有权
标题翻译：异质桥接金属茂化合物用于烯烃聚合
公开(公告)号：US07763562B2
公开(公告)日：2010-07-27
申请号：US11302998
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/6392 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2231/12 , B01J2531/48 , C08F4/65912 , C08F10/06 , C08F110/02 , C08F210/16 , C08F2420/06 , Y10S526/943 , C08F2500/03 , C08F210/14 , C08F2500/01 , C08F110/06 , C08F2500/20 , C08F210/06 , C08F10/00 , C08F4/65927
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

9. 发明申请

US20100113717A1 Process For Producing Substituted Metallocene Compounds For Olefin Polymerization 有权
标题翻译：用于生产用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US20100113717A1
公开(公告)日：2010-05-06
申请号：US12641123
申请日：2009-12-17
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/16 , C07F17/00 , B01J31/12 , B01J31/14
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

10. 发明授权

US07709670B2 Process for producing substituted metallocene compounds for olefin polymerization 失效
标题翻译：制备用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US07709670B2
公开(公告)日：2010-05-04
申请号：US11302997
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C07F7/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

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