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1. 发明授权

US5408017A High temperature polymerization process using ionic catalysts to produce polyolefins 失效
标题翻译：使用离子催化剂生产聚烯烃的高温聚合方法
公开(公告)号：US5408017A
公开(公告)日：1995-04-18
申请号：US77479
申请日：1993-06-14
申请人： Howard W. Turner , Jo Ann M. Canich , Bernard J. Folie
发明人： Howard W. Turner , Jo Ann M. Canich , Bernard J. Folie
IPC分类号： C07F17/00 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/643
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/65908 , C08F4/6592 , C08F4/65922
摘要： This invention relates to a process for polymerizing olefins at high pressures in a polymerization medium at high temperature utilizing an ionic olefin polymerization catalyst derived from the reaction of a cyclopentadienyl-containing transition metal compound having a hydrolyzable alkyl or hydride ligand with an ion exchange activator. The ionic catalyst system has been found to be highly active at temperatures of 160.degree. C. or greater, to provide a process capable of producing polymer products of desired chemical and physical properties at high production rates.
摘要翻译：本发明涉及使用衍生自具有可水解的烷基或氢化物配体的含环戊二烯基的过渡金属化合物与离子交换活化剂的反应的离子型烯烃聚合催化剂，在高温聚合介质中在高压下聚合烯烃的方法。已经发现离子催化剂体系在160℃或更高的温度下具有高活性，以提供能够以高生产率生产具有所需化学和物理性质的聚合物产物的方法。

2. 发明授权

US5502124A Transition metal olefin polymerization processes 失效
标题翻译：过渡金属烯烃聚合方法
公开(公告)号：US5502124A
公开(公告)日：1996-03-26
申请号：US445062
申请日：1995-05-19
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to processes using non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及使用可用作烯烃聚合催化剂的非4族过渡金属组合物的方法，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

3. 发明授权

US5504049A Transition metal olefin polymerization catalysts 失效
标题翻译：过渡金属烯烃聚合催化剂
公开(公告)号：US5504049A
公开(公告)日：1996-04-02
申请号：US86772
申请日：1993-07-01
申请人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
发明人： Donna J. Crowther , Richard A. Fisher , Jo Ann M. Canich , Gregory G. Hlatky , Howard W. Turner
IPC分类号： C08F4/642 , B01J31/12 , B01J31/14 , B01J31/16 , B01J31/18 , B01J31/22 , C07F9/00 , C07F11/00 , C07F17/00 , C08F4/60 , C08F4/602 , C08F4/622 , C08F4/639 , C08F4/6592 , C08F4/69 , C08F4/72 , C08F4/74 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00 , B01J31/122 , B01J31/146 , B01J31/1805 , B01J31/2295 , C07F11/00 , C07F11/005 , C07F17/00 , C07F9/005 , C08F10/02 , B01J2531/0227 , B01J2531/57 , B01J2531/58 , B01J2531/66 , C08F2420/04 , C08F4/639 , C08F4/63908 , C08F4/63912 , Y10S526/904
摘要： This invention relates to non-Group 4 transition metal compositions useful as olefin polymerization catalysts, wherein the transition metal is in a high oxidation state. The invention further relates to design of new ligand systems and methods of preparing and using the same. Compositions useful as catalyst precursors are neutral transition metal complexes comprising the unique ligand systems of the invention. The inventive compositions may be activated to a catalytic state by ion-exchange reagents or by Lewis acids.
摘要翻译：本发明涉及可用作烯烃聚合催化剂的非4族过渡金属组合物，其中过渡金属处于高氧化态。本发明还涉及新的配体体系的设计及其制备和使用方法。可用作催化剂前体的组合物是包含本发明独特配体体系的中性过渡金属配合物。本发明的组合物可以通过离子交换试剂或路易斯酸活化至催化状态。

4. 发明授权

US5318935A Amido transition metal compound and a catalyst system for the production of isotatic polypropylene 失效
标题翻译：酰胺过渡金属化合物和用于生产等压聚丙烯的催化剂体系
公开(公告)号：US5318935A
公开(公告)日：1994-06-07
申请号：US922646
申请日：1992-07-30
申请人： Jo Ann M. Canich , Howard W. Turner
发明人： Jo Ann M. Canich , Howard W. Turner
IPC分类号： C07F7/00 , C07F7/10 , C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F110/00 , C08F110/06 , C08F210/00 , C08F210/02
CPC分类号： C07F7/10 , C08F110/06 , Y10S526/943
摘要： Certain bridged and unbridged amido transition metal compounds of the Group IV-B metals are disclosed. These compounds may be used in a catalyst system comprising the amido transition metal compound and an alumoxane. Also disclosed is a process using the catalyst system for the production of high molecular weight polyolefins and, particularly, high molecular weight isotactic polypropylene.
摘要翻译：公开了IV-B族金属的某些桥连和未桥连的酰氨基过渡金属化合物。这些化合物可以用于包含酰氨基过渡金属化合物和铝氧烷的催化剂体系中。还公开了使用催化剂体系制备高分子量聚烯烃，特别是高分子量全同立构聚丙烯的方法。

5. 发明授权

US5621126A Monocyclopentadienyl metal compounds for ethylene-.alpha.-olefin-copolymer production catalysts 失效
标题翻译：用于乙烯-α-烯烃共聚物制备催化剂的单环戊二烯基金属化合物
公开(公告)号：US5621126A
公开(公告)日：1997-04-15
申请号：US138169
申请日：1993-10-15
申请人： Jo Ann M. Canich , Howard W. Turner , Gregory G. Hlatky
发明人： Jo Ann M. Canich , Howard W. Turner , Gregory G. Hlatky
IPC分类号： C07F7/10 , C07F17/00 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C07F7/00
CPC分类号： C07F7/10 , C07F17/00 , C08F10/00 , C08F10/06 , C08F210/16 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F4/65922 , Y10S526/943
摘要： Described are certain mono(cyclopentadienyl) Group IV B metal compounds, catalyst systems comprising such mono(cyclopentadienyl) metal compounds and an activator, and to a process using such catalyst systems for the production of polyolefins, particularly ethylene-.alpha.-olefin copolymers having a high molecular weight and high level of .alpha.-olefin incorporation.
摘要翻译：描述了某些单（环戊二烯基）ⅣB族金属化合物，包含这种单（环戊二烯基）金属化合物和活化剂的催化剂体系，以及使用这种催化剂体系制备聚烯烃，特别是乙烯-α-烯烃共聚物的方法，高分子量和高水平的α-烯烃结合。

6. 发明授权

US5759967A Ethylene .alpha.-olefin/diene interpolymer-substituted carboxylic acid dispersant additives 失效
标题翻译：乙烯α-烯烃/二烯互聚物取代的羧酸分散剂添加剂
公开(公告)号：US5759967A
公开(公告)日：1998-06-02
申请号：US876789
申请日：1997-06-16
申请人： Won R. Song , Albert Rossi , Howard W. Turner , Howard C. Welborn, deceased , Robert D. Lundberg , Antonio Gutierrez , Robert A. Kleist
发明人： Won R. Song , Albert Rossi , Howard W. Turner , Howard C. Welborn, deceased , Robert D. Lundberg , Antonio Gutierrez , Robert A. Kleist
IPC分类号： C08F8/00 , C08F210/16 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/238 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10M129/93 , C10M129/95 , C10M133/52 , C10M133/56
CPC分类号： C10M133/56 , C08F8/00 , C10L1/198 , C10L1/238 , C10L10/04 , C10M129/93 , C10M129/95 , C10M133/52 , C08F210/16 , C10L1/143 , C10L1/1608 , C10L1/1616 , C10L1/1817 , C10L1/1832 , C10L1/201 , C10L1/221 , C10L1/2493 , C10L1/2641 , C10L1/2691 , C10L1/303 , C10L1/306 , C10M2205/00 , C10M2207/123 , C10M2207/129 , C10M2207/22 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/288 , C10M2207/289 , C10M2207/34 , C10M2209/00 , C10M2209/02 , C10M2209/10 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/26 , C10M2215/28 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2221/00 , C10M2223/045 , C10N2210/02 , C10N2220/02 , C10N2240/00 , C10N2240/02 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02
摘要： The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene/alpha-olefin/diene interpolymer of 300 to 20,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted interpolymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such s amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.
摘要翻译：本发明涉及一种油溶性润滑油添加剂，其包含至少一种具有300至20,000个数均分子量的末端不饱和的乙烯/α-烯烃/二烯互聚物，其数均分子量被单或二羧酸生产部分（优选二羧酸或酸酐部分），其中末端不饱和基团包含末端亚乙烯基不饱和基团。本发明的单羧酸或二羧酸或酐取代的互聚物本身可用作润滑油的添加剂，并且还可以与亲核试剂如胺，醇，氨基醇和反应性金属化合物反应，形成产物，也是有用的润滑油添加剂，例如分散剂。

7. 发明授权

US5427991A Polyionic transition metal catalyst composition 失效
标题翻译：聚阴离子过渡金属催化剂组合物
公开(公告)号：US5427991A
公开(公告)日：1995-06-27
申请号：US31004
申请日：1993-03-12
申请人： Howard W. Turner
发明人： Howard W. Turner
IPC分类号： C08F4/642 , C07F17/00 , C08F4/60 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/645 , C08F4/6592 , C08F10/00 , B01J31/00
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65925 , C08F4/65927
摘要： Ionically activated metallocene catalyst compositions which are useful in the polymerization of olefins comprise transition metal cationic components associated with and stabilized by a polyanionic moleties constituted of non-coordinating anionic groups chemically bonded to core components. The transition metal cationic components typically are cyclopentadienyl-group containing Group 4, 5, and 6 metal compounds having a hydrolyzable ligand such that they react with the activator compounds so as to form the cationic components in non-coordinating association with bulky, labile anions derived from the activator compound which in turn is chemically bound to the core component, such as a polymeric or metal oxide support.
摘要翻译：可用于烯烃聚合的离子活化的茂金属催化剂组合物包含与通过化学键合到核心组分的非配位阴离子基团构成的聚阴离子摩擦相关联并由其稳定的过渡金属阳离子组分。过渡金属阳离子组分通常是含有第4,5和6族的具有可水解配体的金属化合物的环戊二烯基，使得它们与活化剂化合物反应，以便形成阳离子组分，其与引发的大体积不稳定阴离子非配位缔合来自活化剂化合物，其又与核组分化学键合，例如聚合物或金属氧化物载体。

8. 发明授权

US5407884A Catalysts, method of preparing these catalysts, and polymerization processes wherein these catalysts are used 失效
标题翻译：催化剂，制备这些催化剂的方法和使用这些催化剂的聚合方法
公开(公告)号：US5407884A
公开(公告)日：1995-04-18
申请号：US104226
申请日：1993-08-09
申请人： Howard W. Turner , Gregory G. Hlatky
发明人： Howard W. Turner , Gregory G. Hlatky
IPC分类号： B01J31/14 , C07F17/00 , C08F20060101 , C08F4/14 , C08F4/16 , C08F4/42 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F10/00 , C08F10/02 , C08F36/00 , C08F36/02 , C08F38/00 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C07F17/00 , C08F4/65908 , C08F4/65922 , Y10S526/943
摘要： An ionic catalyst useful for the polymerization of olefins, diolefins and/or acetylenically unsaturated monomers is described. The catalyst comprises cyclopentadienyl derivatives of Group IV-B metals as cation and a compatible non-coordinating anion containing a plurality of boron atoms. Borate, carborate, borane, carborane, metallaborane and metallacarborane compounds exemplify anion sources and dihydrocarbyl-substituted bis(cyclopentadienyl) zirconium compounds exemplify the Group IV-B metal cation sources. Utility is illustrated for olefin polymerization.
摘要翻译：描述了可用于烯烃，二烯烃和/或炔属不饱和单体的聚合的离子催化剂。该催化剂包含作为阳离子的IV-B族金属的环戊二烯基衍生物和含有多个硼原子的相容的非配位阴离子。硼酸盐，碳硼酸盐，硼烷，碳硼烷，金属硼烷和金属硼烷化合物举例说明阴离子源和二烃基取代的双（环戊二烯基）锆化合物，例示IV-B族金属阳离子源。用于烯烃聚合的实用性。

9. 发明授权

US5277833A Ethylene alpha-olefin polymer substituted mono-and dicarboxylic acid lubricant dispersant additives 失效
标题翻译：乙烯α-烯烃聚合物取代的单和二羧酸润滑剂添加剂
公开(公告)号：US5277833A
公开(公告)日：1994-01-11
申请号：US928624
申请日：1992-08-12
申请人： Won R. Song , Albert Rossi , Howard W. Turner , Howard C. Welborn , Robert D. Lungberg , Antonio Gutierrez , Robert A. Kleist
发明人： Won R. Song , Albert Rossi , Howard W. Turner , Howard C. Welborn , Robert D. Lungberg , Antonio Gutierrez , Robert A. Kleist
IPC分类号： C08F8/00 , C08F210/16 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/238 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10M129/93 , C10M129/95 , C10M133/52 , C10M133/56 , C10M143/02 , C10M171/00 , C10M145/00
CPC分类号： C10M171/00 , C08F8/00 , C10L1/143 , C10L1/198 , C10L1/238 , C10L10/04 , C10M129/93 , C10M129/95 , C10M133/52 , C10M133/56 , C10M143/02 , C08F210/16 , C10L1/1608 , C10L1/1616 , C10L1/1817 , C10L1/1832 , C10L1/201 , C10L1/221 , C10L1/2493 , C10L1/2641 , C10L1/2691 , C10L1/303 , C10L1/306 , C10M2205/00 , C10M2207/123 , C10M2207/129 , C10M2207/22 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2207/288 , C10M2207/289 , C10M2207/34 , C10M2215/04 , C10M2215/042 , C10M2215/08 , C10M2215/082 , C10M2215/086 , C10M2215/26 , C10M2215/28 , C10M2217/042 , C10M2217/043 , C10M2217/046 , C10M2217/06 , C10M2221/00 , C10M2223/045 , C10N2210/02 , C10N2220/02 , C10N2240/00 , C10N2240/02 , C10N2240/08 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/106 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , C10N2270/02 , Y10S526/943
摘要： The present invention is directed to an oil-soluble lubricating oil additive comprising at least one terminally unsaturated ethylene alpha-olefin polymer of 300 to 10,000 number average molecular weight substituted with mono- or dicarboxylic acid producing moieties (preferably dicarboxylic acid or anhydride moieties), wherein the terminal unsaturation comprises terminal ethenylidene unsaturation. The mono- and dicarboxylic acid or anhydride substituted polymers of this invention are useful per se as additives to lubricating oils, and can also be reacted with a nucleophilic reagent, such as amines, alcohols, amino alcohols and reactive metal compounds, to form products which are also useful lubricating oil additives, e.g., as dispersants.
摘要翻译：本发明涉及一种油溶性润滑油添加剂，其包含至少一种由单或二羧酸产生部分（优选二羧酸或酸酐部分）取代的数均分子量为300至10,000的末端不饱和乙烯α-烯烃聚合物，其中末端不饱和键包含末端亚乙烯基不饱和键。本发明的单羧酸或二羧酸或酐取代的聚合物本身可用作润滑油的添加剂，并且还可以与亲核试剂如胺，醇，氨基醇和反应性金属化合物反应，形成产物，也是有用的润滑油添加剂，例如分散剂。

10. 发明授权

US5198401A Ionic metallocene catalyst compositions 失效
标题翻译：离子金属茂催化剂组合物
公开(公告)号：US5198401A
公开(公告)日：1993-03-30
申请号：US737611
申请日：1991-07-30
申请人： Howard W. Turner , Gregory G. Hlatky , Richard R. Eckman
发明人： Howard W. Turner , Gregory G. Hlatky , Richard R. Eckman
IPC分类号： C07F17/00 , C08F4/643 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18
CPC分类号： C08F10/00 , C07F17/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/18 , C08F4/65925 , Y10S526/943
摘要： Ionic catalyst compositions can be prepared by combining two components. The first component is a bis(cyclopentadienyl) Group IV-B metal complex containing at least one ligand which will combine irreversibly with the second component or at least a portion thereof such as a cation portion thereof. The second component comprises a cation which will irreversibly react with at least one ligand on the Group IV-B metal complex and a non-coordinating anion. The combination of the two components produces an ionic catalyst composition comprising a cationic bis(cyclopentadienyl) Group IV-B metal complex which has a formal coordination number of 3 and a 4+ valence charge and the aforementioned non-coordinating anion. The anion is (i) labile and can be displaced by an olefin, diolefin or acetylenically unsaturated monomer; (ii) has a molecular diameter about or greater than 4 angstroms; (iii) forms stable salts with reducible Lewis acids and protonated Lewis bases; (v) has a negative charge delocalized over the framework on the anion or within the core thereof; (v) is not a reducing or oxidizing agent; and (vi) is a relatively poor nucleophile. These ionic catalyst compositions can be used to polymerize .alpha.-olefins, diolefins and/or acetylenically unsaturated monomers, either alone or in combination, to polymers and copolymers.
摘要翻译：离子催化剂组合物可以通过组合两种组分来制备。第一组分是含有至少一种将不可逆地与第二组分或其至少一部分如其阳离子部分结合的配体的双（环戊二烯基）Ⅳ-B族金属络合物。第二组分包含将与第IV-B族金属络合物上的至少一种配体和非配位阴离子不可逆地反应的阳离子。两种组分的组合产生离子催化剂组合物，其包含阳离子双（环戊二烯基）IV-B族金属络合物，其形式配位数为3，4+价电荷和上述非配位阴离子。阴离子是（i）不稳定并且可以被烯烃，二烯烃或炔属不饱和单体置换; （ii）具有大约或大于4埃的分子直径; （iii）与可还原的路易斯酸和质子化的路易斯碱形成稳定的盐; （v）在阴离子或其核心中具有在骨架上离域的负电荷; （v）不是还原或氧化剂; 和（vi）是相对较差的亲核试剂。这些离子催化剂组合物可用于将α-烯烃，二烯烃和/或炔属不饱和单体单独或组合聚合到聚合物和共聚物中。

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