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1. 发明授权

US08546595B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US08546595B2
公开(公告)日：2013-10-01
申请号：US13424782
申请日：2012-03-20
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

2. 发明授权

US07868197B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US07868197B2
公开(公告)日：2011-01-11
申请号：US11300240
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

3. 发明申请

US20120202956A1 Halogen Substituted Heteroatom-Containing Metallocene Compounds for Olefin Polymerization 有权
标题翻译：用于烯烃聚合的卤素取代杂原子茂金属化合物
公开(公告)号：US20120202956A1
公开(公告)日：2012-08-09
申请号：US13424782
申请日：2012-03-20
申请人： Alexander Z. VOSKOBOYNIKOV , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. VOSKOBOYNIKOV , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/76 , C07F7/28 , B01J21/06 , C07F7/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

4. 发明授权

US08173828B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US08173828B2
公开(公告)日：2012-05-08
申请号：US12951814
申请日：2010-11-22
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6192 , C08F4/6592 , B01J31/22
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

5. 发明申请

US20110288249A1 Halogen Substituted Heteroatom-Containing Metallocene Compounds for Olefin Polymerization 有权
标题翻译：用于烯烃聚合的卤素取代杂原子茂金属化合物
公开(公告)号：US20110288249A1
公开(公告)日：2011-11-24
申请号：US12951814
申请日：2010-11-22
申请人： Alexander Z. VOSKOBOYNIKOV , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina I. Coker , Jo Ann M. Canich
发明人： Alexander Z. VOSKOBOYNIKOV , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina I. Coker , Jo Ann M. Canich
IPC分类号： C08F4/76 , C08F10/00 , C07F17/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

6. 发明授权

US07910783B2 Preparation of substituted bridged indenyl and related ligands 失效
标题翻译：取代的桥连茚基和相关配体的制备
公开(公告)号：US07910783B2
公开(公告)日：2011-03-22
申请号：US11302846
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07C13/28 , C07C13/32 , C07C13/465 , C07C13/567
CPC分类号： C07F17/00
摘要： A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp2-sp2 or sp2-sp3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L1 and L2 in formula (I) and to L3 and L4 in formula (II); L1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp2 carbon atom of the ring structure of the ligand; L2 is a monoanionic ligand; or L2 may, independently, be defined as L1; L3 is the same group as L1, but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L4 is the same group as L2, though, when L2 is defined as L1, L4 may be the same as L3 or L1; R1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X2, if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r+t corresponds to the oxidation number of M1.
摘要翻译：通过与式（III）的有机金属化合物的sp2-sp2或sp2-sp3偶联反应从式（I）的螯合配体制备式（II）的螯合配体的方法。其中B是与式（I）中的L1和L2键合并且在式（II）中与L3和L4键合的桥连基团; L1是取代的单环或多环配体，其包含直接键合到配体的环结构的sp2碳原子上的至少一个氯，溴，碘或磺酸盐取代基; L2是单阴离子配体; 或L2可以独立地定义为L1; L3是与L1相同的基团，但是所述至少一个氯，溴，碘或磺酸酯取代基被烃基取代的烃基，卤代烃基或取代的卤代烃基片段代替; L4与L2相同，但当L2定义为L1时，L4可以与L3或L1相同; R 1是烃基，取代的烃基，卤代烃基或取代的卤代烃基; M1是元素周期表第1,2,12,13或14族的元素; 每个X 2如果存在，独立地选自卤素原子，羟基，烷氧基，芳氧基，甲磺酸酯，甲苯磺酸酯和三氟甲磺酸酯; r为1,2或3，t为0,1或2，其中r + t对应于M1的氧化数。

7. 发明授权

US07550544B2 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07550544B2
公开(公告)日：2009-06-23
申请号：US11302821
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/76 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
摘要翻译：金属茂化合物由式（1）表示：其中：M是第3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子，优选选自钛的第4族过渡金属原子，锆或铪; E是与M键合的取代或未取代的单环或多环的烷基配体; A是取代或未取代的与M配体结合并具有不同于E配体的环结构的多环烷基配体; A和E配体中的至少一个配体包括至少一个卤素取代基，直接键合到可结合的环位置上的sp2碳; Y是含有至少一个第13,14,15或16族元素和A的环结构的任何单个位置和E的环结构的任何单个位置的桥连基团; y为0或1，表示Y不存在（y = 0）或存在（y = 1）; 并且每个X是一价阴离子配体，或两个X连接并结合到金属原子以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当E是未取代的环戊二烯基配体时，y是1或A不是2-溴芴基或2,7-二溴芴基。

8. 发明授权

US07538168B2 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07538168B2
公开(公告)日：2009-05-26
申请号：US11300002
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/72 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound comprises a transition metal and at least one substituted monocyclic or polycyclic arene ligand bonded to the transition metal, wherein said arene ligand comprises at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of an aromatic five-membered ring of said arene ligand.
摘要翻译：金属茂化合物包含过渡金属和至少一个与过渡金属键合的取代的单环或多环芳族配体，其中所述芳族配体包括至少一个卤素取代基，其直接键合到芳族五元环的可键合环位上的sp2碳原子上，所述芳族配体的多元环。

9. 发明授权

US07763562B2 Heteroatom bridged metallocene compounds for olefin polymerization 有权
标题翻译：异质桥接金属茂化合物用于烯烃聚合
公开(公告)号：US07763562B2
公开(公告)日：2010-07-27
申请号：US11302998
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey N. Ryabov , Artyom Y. Lebedev , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/6392 , C08F4/6592 , B01J31/22 , C07F17/00
CPC分类号： C07F17/00 , B01J31/2295 , B01J2231/12 , B01J2531/48 , C08F4/65912 , C08F10/06 , C08F110/02 , C08F210/16 , C08F2420/06 , Y10S526/943 , C08F2500/03 , C08F210/14 , C08F2500/01 , C08F110/06 , C08F2500/20 , C08F210/06 , C08F10/00 , C08F4/65927
摘要： This invention relates to a transition metal compound represented by the formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is: 1) a substituted or unsubstituted indenyl ligand that is bonded to Y through the four, five, six or seven position of the indenyl ring, or 2) a substituted or unsubstituted heteroindenyl ligand that is bonded to Y through the four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom, or 3) a substituted or unsubstituted fluorenyl ligand that is bonded to Y through the one, two, three, four, five, six, seven or eight position of the fluorenyl ring, or 4) a substituted or unsubstituted heterofluorenyl ligand that is bonded to Y through the one, two, three, four, five or six position of the heteroindenyl ring, provided that the bonding position is not the same as the position of the ring heteroatom; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand; Y is a Group 15 or 16 bridging heteroatom substituent that is bonded via the heteroatom to E and A; and X are, independently, univalent anionic ligands, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.
摘要翻译：本发明涉及由下式表示的过渡金属化合物：其中M是3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子; E是：1）通过茚基环的4,5,6或7位与Y键合的取代或未取代的茚基配体，或2）通过四个，五个键连接到Y上的取代或未取代的杂茚基配体或六位的杂茚基环，条件是键合位置不同于环杂原子的位置，或3）取代或未取代的芴基配体，其通过一个，两个，三个，四个，五个六，七或八位的芴基环，或者4）取代或未取代的异芴基配体，其通过杂烯基环的一个，二个，三个，四个，五个或六个位置与Y键合，条件是键合位置与环杂原子的位置不同; A是取代或未取代的环戊二烯基配体，取代或未取代的杂环戊二烯基配体，取代或未取代的茚基配体，取代或未取代的杂烯基配体，取代或未取代的芴基配体，取代或未取代的杂芴基配体或其它单阴离子配体 ; Y是通过杂原子与E和A键合的15或16位桥连杂原子取代基; X独立地为一价阴离子配体，或两者X连接并结合到金属原子以形成金属环，或两者X连接形成螯合配体，二烯配体或亚烷基配体。

10. 发明授权

US07557171B2 Halogen substituted metallocene compounds for olefin polymerization 失效
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07557171B2
公开(公告)日：2009-07-07
申请号：US11300032
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Vyatcheslav V. Izmer , Andrey F. Asachenko , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/76 , C07F17/00
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A metallocene compound comprising a transition metal, a first substituted or unsubstituted indenyl or fluorenyl ligand pi—bonded to the transition metal, a second monoanionic ligand bonded to the transition metal, and a divalent bridging group bonded to the indenyl ligand and said second monoanionic ligand, wherein said bridging group is connected to the four, five, six or seven position of the indenyl ligand or to the one, two, three, four, five, six, seven or eight position of the fluorenyl ligand, and wherein at least one of one of the first and second ligands comprises at least one halogen substituent directly bonded to any sp2 carbon atom at a bondable ring position of the ligand.
摘要翻译：包含过渡金属，与过渡金属键合的第一取代或未取代的茚基或芴基配体的金属茂化合物，与过渡金属键合的第二单离子配体和键合到茚基配体和所述第二单离子配体的二价桥连基团其中所述桥连基团连接到茚基配体的四，五，六或七位，或连接到芴基配体的一个，二个，三个，四个，五个，六个，七个或八个位置，并且其中至少一个第一和第二配体之一包括至少一个与配体的可键合环位置上的任何sp 2碳原子键合的卤素取代基。

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