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1. 发明授权

US08546595B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US08546595B2
公开(公告)日：2013-10-01
申请号：US13424782
申请日：2012-03-20
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

2. 发明授权

US08541522B2 Catalyst compounds and use thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US08541522B2
公开(公告)日：2013-09-24
申请号：US12908268
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可用于或不使用活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

3. 发明申请

US20110098430A1 Catalyst Compounds and Use Thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US20110098430A1
公开(公告)日：2011-04-28
申请号：US12908550
申请日：2010-10-20
申请人： Garth R. GIESBRECHT , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. GIESBRECHT , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C07F7/00 , C07D213/30 , B01J31/12
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物在有或没有活化剂的情况下可用于聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

4. 发明授权

US07910783B2 Preparation of substituted bridged indenyl and related ligands 失效
标题翻译：取代的桥连茚基和相关配体的制备
公开(公告)号：US07910783B2
公开(公告)日：2011-03-22
申请号：US11302846
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07C13/28 , C07C13/32 , C07C13/465 , C07C13/567
CPC分类号： C07F17/00
摘要： A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp2-sp2 or sp2-sp3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L1 and L2 in formula (I) and to L3 and L4 in formula (II); L1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp2 carbon atom of the ring structure of the ligand; L2 is a monoanionic ligand; or L2 may, independently, be defined as L1; L3 is the same group as L1, but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L4 is the same group as L2, though, when L2 is defined as L1, L4 may be the same as L3 or L1; R1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X2, if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r+t corresponds to the oxidation number of M1.
摘要翻译：通过与式（III）的有机金属化合物的sp2-sp2或sp2-sp3偶联反应从式（I）的螯合配体制备式（II）的螯合配体的方法。其中B是与式（I）中的L1和L2键合并且在式（II）中与L3和L4键合的桥连基团; L1是取代的单环或多环配体，其包含直接键合到配体的环结构的sp2碳原子上的至少一个氯，溴，碘或磺酸盐取代基; L2是单阴离子配体; 或L2可以独立地定义为L1; L3是与L1相同的基团，但是所述至少一个氯，溴，碘或磺酸酯取代基被烃基取代的烃基，卤代烃基或取代的卤代烃基片段代替; L4与L2相同，但当L2定义为L1时，L4可以与L3或L1相同; R 1是烃基，取代的烃基，卤代烃基或取代的卤代烃基; M1是元素周期表第1,2,12,13或14族的元素; 每个X 2如果存在，独立地选自卤素原子，羟基，烷氧基，芳氧基，甲磺酸酯，甲苯磺酸酯和三氟甲磺酸酯; r为1,2或3，t为0,1或2，其中r + t对应于M1的氧化数。

5. 发明授权

US07812104B2 Production of propylene-based polymers 有权
标题翻译：丙烯基聚合物的生产
公开(公告)号：US07812104B2
公开(公告)日：2010-10-12
申请号：US12016346
申请日：2008-01-18
申请人： Jo Ann M. Canich , Peijun Jiang , Gary L. Casty , Gabor Kiss , Alexander Z. Voskoboynikov
发明人： Jo Ann M. Canich , Peijun Jiang , Gary L. Casty , Gabor Kiss , Alexander Z. Voskoboynikov
IPC分类号： C08F4/64 , C08F4/642 , C08F4/6592 , C08F10/06 , B01J31/22 , B01J31/18
CPC分类号： C08F10/06 , C08F4/65908 , C08F4/65912 , C08F210/06 , Y02P20/544 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/03 , C08F2500/17 , C08F2500/20
摘要： In a process for producing a propylene-based olefin homopolymer or copolymer, a monomer composition comprising propylene is contacted with a polymerization catalyst system under homogeneous polymerization conditions (such as solution, supersolution or supercritical conditions), wherein the polymerization catalyst system includes an activator and a bridged bis-indenyl transition metal (group 4) compound substituted with a carbazole (unsubstituted or substituted) at the 4 position.
摘要翻译：在制备丙烯类烯烃均聚物或共聚物的方法中，包含丙烯的单体组合物在均相聚合条件（例如溶液，超溶剂或超临界条件）下与聚合催化剂体系接触，其中聚合催化剂体系包括活化剂和在4位被咔唑（未取代或取代的）取代的桥连双茚基过渡金属（4族）化合物。

6. 发明授权

US07550544B2 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07550544B2
公开(公告)日：2009-06-23
申请号：US11302821
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/76 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
摘要翻译：金属茂化合物由式（1）表示：其中：M是第3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子，优选选自钛的第4族过渡金属原子，锆或铪; E是与M键合的取代或未取代的单环或多环的烷基配体; A是取代或未取代的与M配体结合并具有不同于E配体的环结构的多环烷基配体; A和E配体中的至少一个配体包括至少一个卤素取代基，直接键合到可结合的环位置上的sp2碳; Y是含有至少一个第13,14,15或16族元素和A的环结构的任何单个位置和E的环结构的任何单个位置的桥连基团; y为0或1，表示Y不存在（y = 0）或存在（y = 1）; 并且每个X是一价阴离子配体，或两个X连接并结合到金属原子以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当E是未取代的环戊二烯基配体时，y是1或A不是2-溴芴基或2,7-二溴芴基。

7. 发明授权

US09163046B2 Process for producing substituted metallocene compounds for olefin polymerization 有权
标题翻译：制备用于烯烃聚合的取代茂金属化合物的方法
公开(公告)号：US09163046B2
公开(公告)日：2015-10-20
申请号：US12641123
申请日：2009-12-17
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6592 , C08F4/642 , C08F4/643 , C08F10/00 , C08F4/659 , C08F210/16
CPC分类号： C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F210/16 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F4/65925 , C08F210/14 , C08F2500/03 , C08F2500/01 , C08F2500/20 , C08F210/06
摘要： A process for producing a substituted metallocene compound comprises reacting a first compound with a transfer-agent, wherein the first compound comprises a complex of a transition metal atom selected from Group 3, 4, 5 or 6 of the Periodic Table of Elements, or a lanthanide metal atom, or actinide metal atom and at least one monocyclic or polycyclic ligand that is pi-bonded to M and is substituted with at least one halogen or sulfonate substituent and the transfer-agent comprises a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, or germylcarbyl radical capable of replacing said at least one halogen or sulfonate substituent of said first compound under reaction conditions.
摘要翻译：制备取代的茂金属化合物的方法包括使第一化合物与转移剂反应，其中第一化合物包含选自元素周期表第3,4,5或6族的过渡金属原子的络合物，或镧系元素金属原子或锕系金属原子和至少一个单键或多环配体，其与M键合并被至少一个卤素或磺酸盐取代基取代，并且转移剂包含烃基，取代的烃基，卤代烃基，取代的卤代烃基，甲硅烷基或甲锗烷基，其能够在反应条件下替代所述第一化合物的所述至少一个卤素或磺酸盐取代基。

8. 发明授权

US09079985B2 Bridged metallocene catalysts 有权
标题翻译：桥接金属茂催化剂
公开(公告)号：US09079985B2
公开(公告)日：2015-07-14
申请号：US13996831
申请日：2011-12-20
申请人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
发明人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
IPC分类号： C08F4/6592 , C08F4/642 , C08F4/643 , C08F10/00 , C08F4/76 , C08F4/659 , B01J31/22 , C07F17/00 , C08F4/52 , C08F110/06 , C08F210/06
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and each R7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

9. 发明授权

US08541521B2 Catalyst compounds and use thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US08541521B2
公开(公告)日：2013-09-24
申请号：US12908257
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00
摘要： Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：提供了含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可用于或不使用活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

10. 发明授权

US08530593B2 Catalyst compounds and use thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US08530593B2
公开(公告)日：2013-09-10
申请号：US12908615
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00 , C07F7/003
摘要： This invention relates to Group 4 dialkyl compounds supported by a pyridyl-amido-aryl (“PAA”), an anisole-amido-aryl (“AAA”), a phenoxy-amido-pyridyl (“PAPY”), an anisole-amido-phenoxy (“AAP”) or a anisole-amido-phenoxy (“AAP”) tridentate ligand. Such compounds can polymerize olefins, such as ethylene.
摘要翻译：本发明涉及由吡啶基 - 酰氨基 - 芳基（“PAA”），苯甲醚 - 酰氨基 - 芳基（“AAA”），苯氧基 - 酰胺基 - 吡啶基（“PAPY”），苯甲醚 - 酰氨基 - 苯氧基（“AAP”）或苯甲醚 - 酰氨基 - 苯氧基（“AAP”）三齿配体。这样的化合物可以聚合烯烃，如乙烯。

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