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    • 3. 发明授权
    • Reactive systems and a process for the preparation of polyurethane
plastics
    • 反应体系和制备聚氨酯塑料的方法
    • US5173559A
    • 1992-12-22
    • US429264
    • 1989-10-20
    • Hanns-Peter MullerOtto GansterBruno Luckas
    • Hanns-Peter MullerOtto GansterBruno Luckas
    • C08G18/30C08G18/00C08G18/08C08G18/09C08G18/58C08G18/70C08G101/00
    • C08G18/003C08G18/089C08G18/092C08G18/58C08G18/70C08G2101/00
    • The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.The present invention also relates to a process for the preparation of optionally foamed polyurethane plastics containing isocyanurate groups comprising (1) mixing the components of such reactive systems at a temperature less than 60.degree. C. and (2) heating said reactive system to a temperature of at least 60.degree. C.
    • 本发明涉及反应体系,其包括(a)(i)包含至少一种有机多异氰酸酯的多异氰酸酯组分和(ii)在烷基化剂存在下通过加热稳定的环氧化物组分的可储存混合物,其中所述加热为 任选地在部分多异氰酸酯组分(i)的另外存在下进行,(b)含有至少两个异氰酸酯反应性基团的异氰酸酯反应性组分,其量使得每个异氰酸酯存在0.1至0.9个异氰酸酯反应性基团 组分(a)中的组,其中至少10重量%的组分(b)包含分子量大于约2000的化合物,(c)任选的叔胺,其量使得总可储存混合物含有至少0.005 每100g存储混合物的总量的叔胺氮原子摩尔数,和任选的(d)其它助剂和添加剂。 本发明还涉及一种制备含有异氰脲酸酯基团的任选发泡聚氨酯塑料的方法,包括(1)在低于60℃的温度下混合这些反应体系的组分,和(2)将所述反应体系加热至 至少60℃
    • 9. 发明授权
    • Process for the production of molded articles having integral skin
    • 用于生产具有整体皮肤的模制品的方法
    • US4576970A
    • 1986-03-18
    • US703844
    • 1985-02-21
    • Otto GansterUlrich KnippBruno Luckas
    • Otto GansterUlrich KnippBruno Luckas
    • C08G18/00C08G18/08C08G18/30C08G18/42C08G18/48C08G18/66C08G18/76C08G18/14C08G18/79
    • C08G18/6603C08G18/302C08G2120/00Y10T428/249989
    • The present invention is directed to a process for the production of a molded article having a compact surface layer and a gross density above 900 kg/m.sup.3 via the reaction injection molding technique, comprising introducing a reaction mixture into a closed mold, said reaction mixture comprising:(a) a polyisocyanate component consisting of at least one polyisocyanate in which all the isocyanate groups are aromatically bound,(b) compounds having molecular weights of from 400 to 12,000 and having at least two isocyanate reactive hydrogen atoms,(c) water, in a quantity of at least 0.15 mol per mol of isocyanate groups of component (a), and(d) optionally compounds having molecular weights of from 60 to 399 and having at least two isocyanate reactive hydrogen atoms,wherein the isocyanate index, based on all the reactants taking part in the reaction is from 70 to 125, and wherein a pressure of above 40 bar is maintained in the reaction mixture during the reaction so that the carbon dioxide formed in the course of the reaction remains completely or predominantly in solution in the reaction mixture and in the molded article produced.
    • 本发明涉及通过反应注射成型技术生产具有紧密表面层和总密度高于900kg / m 3的模塑制品的方法,包括将反应混合物引入封闭模具中,所述反应混合物包含 (a)由至少一种多异氰酸酯组成的多异氰酸酯组分,其中所有异氰酸酯基团都被芳族结合,(b)分子量为400至12,000并具有至少两个异氰酸酯反应性氢原子的化合物,(c)水, 每摩尔组分(a)的异氰酸酯基团至少为0.15摩尔的量,和(d)任选分子量为60至399的具有至少两个异氰酸酯反应性氢原子的化合物,其中异氰酸酯指数基于 参与反应的所有反应物均为70〜125,在反应中反应混合物中保持40巴以上的压力,使二氧化碳 在反应过程中形成的反应完全或主要存在于反应混合物和所制备的模制品中的溶液中。