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1. 发明授权

US6034169A Mixtures of aqueous polymer dispersions 失效
标题翻译：水性聚合物分散体的混合物
公开(公告)号：US6034169A
公开(公告)日：2000-03-07
申请号：US939180
申请日：1992-09-02
申请人： Reiner Witkowski , Otto Ganster , Heinrich Konigshofen , Ralph Ostarek
发明人： Reiner Witkowski , Otto Ganster , Heinrich Konigshofen , Ralph Ostarek
IPC分类号： B32B7/12 , B32B27/08 , C08G18/08 , C08G18/10 , C08G18/70 , C08J3/21 , C08J5/12 , C08L25/08 , C08L75/00 , C08L75/04 , C08L101/00 , C09J5/06 , C09J7/00 , C09J125/02 , C09J175/04 , C09J201/00
CPC分类号： C09J175/04 , C08G18/0828 , C08G18/10 , C08G18/706 , C09J125/02 , C09J5/06 , C09J7/00 , C08G2170/40 , C08G2170/80 , C08L25/08 , C08L75/04 , C09J2425/00 , C09J2475/00
摘要： The present invention is directed to a novel adhesive which is a mixture ofA) at least one aqueous dispersion of a polymer which has a softening point below 70.degree. C., said dispersion containing 5 to 70% by weight solids and having a film-forming temperature below 70.degree. C., andB) at least one aqueous dispersion of a polymer based on olefinically unsaturated monomers having a softening point is above 70.degree. C., said dispersion containing 5 to 70% by weight solids,wherein the weight ratio of dispersion A) to dispersion B) is from 97:3 to 60:40, based on the solids content of said dispersions.
摘要翻译：本发明涉及一种新型粘合剂，其是A）至少一种具有软化点低于70℃的聚合物的水分散体的混合物，所述分散体含有5至70重量％的固体并具有膜 - 成型温度低于70℃，和B）至少一种基于软化点的烯属不饱和单体的聚合物水分散体高于70℃，所述分散体含有5-70重量％的固体，其中重量比的分散体A）与分散体B）的摩尔比为97:3至60:40，基于所述分散体的固体含量。

2. 发明授权

US06417256B1 Polycarbonate-ABS moulding materials 有权
标题翻译：聚碳酸酯ABS成型材料
公开(公告)号：US06417256B1
公开(公告)日：2002-07-09
申请号：US09509161
申请日：2000-03-22
申请人： Thomas Eckel , Dieter Wittmann , Ralph Ostarek , Richard Weider , Gisbert Michels
发明人： Thomas Eckel , Dieter Wittmann , Ralph Ostarek , Richard Weider , Gisbert Michels
IPC分类号： C08L6900
CPC分类号： C08L51/04 , C08K5/523 , C08L69/00 , C08L69/005 , C08L2666/14 , C08L51/00
摘要： A thermoplastic molding composition containing 1 to 99 parts by weight of aromatic polycarbonate or polyester carbonate and 1 to 99 parts by weight of at least one graft polymer prepared by solution polymerization is disclosed. The graft polymer is characterized in having rubber content of 20 to 50 wt. % and in that the average particle size of its rubber phase is 80 to 600 nm. The composition, which optionally contains additives, flameproofing agents and reinforcing agents, is characterized by its improved mechanical properties.
摘要翻译：公开了一种含有1-99重量份芳族聚碳酸酯或聚酯碳酸酯和1-99重量份至少一种通过溶液聚合制备的接枝聚合物的热塑性模塑组合物。接枝聚合物的特征在于橡胶含量为20〜50wt。％，其橡胶相的平均粒径为80〜600nm。任选地含有添加剂，防火剂和增强剂的组合物的特征在于其改进的机械性能。

3. 发明授权

US4626579A Process for the quasi-ionic polymerization of acrylic acid derivatives 失效
标题翻译：丙烯酸衍生物的准离子聚合方法
公开(公告)号：US4626579A
公开(公告)日：1986-12-02
申请号：US825822
申请日：1986-02-04
申请人： Manfred T. Reetz , Ralph Ostarek , Karl-Erwin Piejko
发明人： Manfred T. Reetz , Ralph Ostarek , Karl-Erwin Piejko
IPC分类号： C08F4/00 , C08F4/08 , C08F4/42 , C08F4/58 , C08F4/72 , C08F20/00 , C08F20/10 , C08F20/12 , C08F20/44 , C08F2/00
CPC分类号： C08F20/12 , C08F4/42
摘要： The invention relates to a process for the quasi-ionic polymerization of acrylic acid derivatives, in which the polymerization is initiated by using special mercaptosilanes as initiators in the presence of nucleophilic or electrophilic catalysts.
摘要翻译：本发明涉及丙烯酸衍生物的准离子聚合方法，其中通过在亲核或亲电催化剂存在下使用特殊的巯基硅烷作为引发剂引发聚合反应。

4. 发明授权

US5981644A Method of producing ABS moulding compositions 失效
标题翻译：生产ABS成型组合物的方法
公开(公告)号：US5981644A
公开(公告)日：1999-11-09
申请号：US814988
申请日：1997-03-14
申请人： Ralph Ostarek , Herbert Eichenauer , Karl-Erwin Piejko , Frank Wingler , Claus Wulff
发明人： Ralph Ostarek , Herbert Eichenauer , Karl-Erwin Piejko , Frank Wingler , Claus Wulff
IPC分类号： C08L25/08 , C08F2/44 , C08F279/00 , C08F279/02 , C08F279/04 , C08L55/00 , C08L55/02 , C08L69/00 , C08J3/11
CPC分类号： C08F279/02 , C08F279/04
摘要： A method of producing ABS moulding compositions wherein a solution of polymers in group (A) solvents is gradually supplied to a polymerizing mixture of previously-formed soluble rubber, aromatic mono-alkenyl compounds, ethylenically unsaturated nitrites, optional other copolymerizable compounds and optionally a group (B) solvent or a mixture of group (A) and group (B) solvents, the gradual addition of the polymer solution to the polymerizing mixture being started before the beginning of phase inversion and at a monomer conversion rate of 5 to 15% and a viscosity of the polymerizing mixture of less than 20 Pa.sec with simultaneous continuation of polymerization, the group (A) solvent is an aliphatic (C.sub.1 -C.sub.8) or cycloaliphatic alcohol, ketone, ether, ester and/or nitrile, and the group (B) solvent is an aliphatic (C.sub.4 -C.sub.10), cycloaliphatic and/or aromatic hydrocarbon.
摘要翻译：一种制备ABS模塑组合物的方法，其中将（A）组溶剂中的聚合物溶液逐渐供应到预先形成的可溶性橡胶，芳族单链烯基化合物，烯属不饱和亚硝酸盐，任选的其它可共聚化合物和任选的基团（B）溶剂或（A）组和（B）组溶剂的混合物中，聚合溶液逐渐加入到聚合混合物中，在相转变开始之前开始，单体转化率为5〜15％，聚合混合物的粘度小于20Pa·s，同时持续聚合，基团（A）溶剂是脂族（C1-C8）或脂环族醇，酮，醚，酯和/或腈，基团（B）溶剂是脂族（C 4 -C 10），脂环族和/或芳族烃。

5. 发明授权

US5266642A Process for the preparation of alpha-methylstyrene polymers 失效
标题翻译：制备α-甲基苯乙烯聚合物的方法
公开(公告)号：US5266642A
公开(公告)日：1993-11-30
申请号：US859056
申请日：1992-03-27
申请人： Karl-Erwin Piejko , Ralph Ostarek , Christian Lindner
发明人： Karl-Erwin Piejko , Ralph Ostarek , Christian Lindner
IPC分类号： C08F2/22 , C08F2/24 , C08F2/44 , C08F4/40 , C08F212/10 , C08F212/12 , C08F220/42 , C08F220/44 , C08F257/02 , C08F285/00 , C08F265/04 , C08F283/12
CPC分类号： C08F257/02 , C08F285/00
摘要： An improved process for the preparation of .alpha.-methylstyrene polymers by aqueous emulsion polymerization in which a styrene monomer mixture is first polymerized in a quantity of from 0.5 to 8% by weight of the total quantity of monomers and thereafter an .alpha.-methylstyrene monomer mixture is polymerized batchwise or semi-continuously.
摘要翻译：一种用于通过水乳液聚合制备α-甲基苯乙烯聚合物的改进方法，其中苯乙烯单体混合物首先以占单体总量的0.5至8重量％的量聚合，然后α-甲基苯乙烯单体混合物为分批或半连续聚合。

6. 发明授权

US06239225B1 Process for the manufacture of impact resistant modified polymers 有权
标题翻译：用于制造抗冲击改性聚合物的方法
公开(公告)号：US06239225B1
公开(公告)日：2001-05-29
申请号：US09350228
申请日：1999-07-08
申请人： Gisbert Michels , Bernd Klinksiek , Otto Schmid , Ralph Ostarek , Richard Weider , Raymond D. Burk , Joong-In Kim
发明人： Gisbert Michels , Bernd Klinksiek , Otto Schmid , Ralph Ostarek , Richard Weider , Raymond D. Burk , Joong-In Kim
IPC分类号： C08F2502
CPC分类号： C08F279/02 , C08F279/04 , C08F212/00 , C08F2/02
摘要： A continuous process for the manufacture of impact resistant polymers is disclosed. The process comprise polymerization of a reaction mixture containing vinylaromatic monomers in the presence of soluble rubber and entails shearing at least some of said mixture at a rate of more than 30000 1/s using a device having no rotating parts. The resulting product is characterized in its low gloss and improved impact properties.
摘要翻译：公开了制造抗冲击聚合物的连续方法。该方法包括在可溶性橡胶存在下聚合含有乙烯基芳族单体的反应混合物，并且使用不具有旋转部分的装置，以至少一些所述混合物以大于30000l / s的速率剪切。所得产品的特征在于其低光泽和改善的冲击性能。

7. 发明授权

US5225465A Process for working up stabilized ABS polymers with recovery of unreacted monomers 失效
标题翻译：加工稳定的ABS聚合物与回收单体的工艺
公开(公告)号：US5225465A
公开(公告)日：1993-07-06
申请号：US864302
申请日：1992-04-06
申请人： Herbert Eichenauer , Ulrich Jansen , Ralph Ostarek , Otto Koch , Karl-Heinz Ott
发明人： Herbert Eichenauer , Ulrich Jansen , Ralph Ostarek , Otto Koch , Karl-Heinz Ott
IPC分类号： C08F6/16 , C08F6/00 , C08F6/06 , C08F279/00 , C08F279/04 , C08J11/02 , C08K5/13 , C08K5/36 , C08L55/00 , C08L55/02
CPC分类号： C08F6/003 , C08F279/04
摘要： A process for processing polymers of the ABS type present in emulsion form and effectively stabilized against oxidative attack with optionally continuous recovery and direct reuse of untreated monomers, wherein a combination of at least one phenolic antioxidant having a molecular weight above 300 without ester groups in the molecule and at least one sulfur-containing co-stabilizer having a molecular weight above 500 without ester groups in the molecule is added to the ABS polymer emulsion for stabilization against oxidative degradation.
摘要翻译：一种用于处理以乳液形式存在的ABS型聚合物的方法，并有效稳定的抗氧化攻击，可任选地连续回收和直接再利用未处理的单体，其中至少一种分子量大于300的酚类抗氧化剂在没有酯基的组合中分子和至少一种分子量大于500的含硫共聚稳定剂，而不分子中的酯基被加入到ABS聚合物乳液中，以防止氧化降解。

8. 发明授权

US5112910A Mixtures of thermoplastic polymers in powder form 失效
标题翻译：粉末形式的热塑性聚合物的混合物
公开(公告)号：US5112910A
公开(公告)日：1992-05-12
申请号：US743678
申请日：1991-08-12
申请人： Karl-Erwin Piejko , Christian Lindner , Ralph Ostarek , Hans-Eberhard Braese , Karl-Heinz Ott
发明人： Karl-Erwin Piejko , Christian Lindner , Ralph Ostarek , Hans-Eberhard Braese , Karl-Heinz Ott
IPC分类号： C08J3/00 , C08L21/00 , C08L25/12 , C08L33/06 , C08L33/12 , C08L51/04
CPC分类号： C08L33/06 , C08J3/005 , C08L21/00 , C08L25/12 , C08L33/12 , C08L51/04
摘要： Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.
摘要翻译：制备粉末形式的热塑性聚合物的混合物的方法，该方法由以下混合物的水性乳液制备：a）丙烯酸C 2 -C 8烷基酯和/或丁二烯与（基于共聚物）的至少40重量％的颗粒部分交联的橡胶状共聚物。丙烯腈，苯乙烯或甲基丙烯酸C 1 -C 4烷基酯，b）热塑性树脂，如果合适，c）在二烯或烷基上的苯乙烯，α-甲基苯乙烯，丙烯腈，甲基丙烯酸甲酯和/或丙烯酸烷基酯的富含橡胶的接枝聚合物丙烯酸酯橡胶，其橡胶含量为50〜95重量％％，其中a）和b）和如果合适的水性乳液c）具有15至50重量％的聚合物含量。％与凝固溶液同时混合，但在单独的流中，在20℃至100℃连续或半连续，聚合物a）和b），如果合适，c）凝结，将流合并，聚合物混合物然后分离出来。

9. 发明授权

US4801669A Process for the quasi-ionic polymerization of acrylic acid derivatives 失效
标题翻译：丙烯酸衍生物的准离子聚合方法
公开(公告)号：US4801669A
公开(公告)日：1989-01-31
申请号：US132525
申请日：1987-12-14
申请人： Karl-Erwin Piejko , Ralph Ostarek , Manfred T. Reetz
发明人： Karl-Erwin Piejko , Ralph Ostarek , Manfred T. Reetz
IPC分类号： C08F2/06 , C08F4/00 , C08F4/06 , C08F4/10 , C08F20/00 , C08F20/02 , C08F20/12 , C08F4/14
CPC分类号： C08F20/12
摘要： In the process according to the invention for the quasi-ionic polymerization of acrylic acid derivatives in organic solvents with initiators and zinc halides, the zinc halides are dissolved in the acrylic acid derivatives to be polymerized and the other components of the polymerization mixture are combined with this solution.
摘要翻译：在根据本发明的丙烯酸衍生物在有机溶剂中与引发剂和卤化锌进行准离子聚合的方法中，将卤化锌溶解在丙烯酸衍生物中以进行聚合，并将聚合混合物的其它组分与这个解决方案。

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