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    • 2. 发明专利
    • Prepreg, laminated plate, and printed wiring board using thermocurable resin composition
    • PREPREG,层压板和使用可热固化树脂组合物的印刷线路板
    • JP2012246395A
    • 2012-12-13
    • JP2011119505
    • 2011-05-27
    • Hitachi Chemical Co Ltd日立化成工業株式会社
    • MIYATAKE MASATOKOTAKE TOMOHIKONAGAI SHUNSUKETAKANEZAWA SHINMURAI AKIRAUCHIMURA RYOICHITAKAHARA NAOKI
    • C08J5/24C08G59/50C08K5/18C08K7/14C08K9/06C08L79/00C08L101/00H05K1/03
    • PROBLEM TO BE SOLVED: To provide a laminated plate and a printed wiring board which are excellent in heat resistance and insulation reliability and in which impregnating ability of a thermocurable resin and adhesion of a thermocurable resin with a glass cloth are good.SOLUTION: This prepreg for a printed wiring board is obtained by a method including: impregnating a glass cloth treated with (C) a silane coupling agent represented by General Formula (I) (where Rrepresents a 1-5C divalent hydrocarbon group, Rrepresents hydrogen or a 1-10C monovalent hydrocarbon group, X represents OCH, OCH, or OCH, m represents an integer of 0 to 5, and plural Xs and Rs when present in plurality may be the same as or different from each other) with a thermocurable resin composition containing (A) a compound containing an unsaturated maleimide group obtained by reacting (a) a maleimide compound having at least two N-substituted maleimide groups in the molecule with (b) an amine compound having at least two primary amino groups in the molecule and (B) a thermocurable resin; heating-drying the glass cloth; and converting the glass cloth into a B-stage.
    • 要解决的问题:提供耐热性和绝缘可靠性优异,并且其中耐热树脂的浸渍能力和耐热树脂与玻璃布的粘附性良好的层压板和印刷线路板。 解决方案:用于印刷线路板的该预浸料通过以下方法获得:浸渍用(C)由通式(I)表示的硅烷偶联剂(其中R 1 表示1-5C的二价烃基,R表示氢或1-10C一价烃基,X表示OCH 3 ,OC 2 H 5 或OC 3 H 7 ,m表示0〜5的整数,多个X和R 2 相同或不同)与含有(A)含有不饱和马来酰亚胺基团的化合物的热固性树脂组合物通过使(a)在分子中具有至少两个N-取代马来酰亚胺基团的马来酰亚胺化合物与(b) 分子中具有至少两个伯氨基的胺化合物和(B)热固性树脂; 加热干燥玻璃布; 并将玻璃布转换成B级。 版权所有(C)2013,JPO&INPIT
    • 3. 发明专利
    • Flame retardant resin compound, thermosetting resin composition using the same, prepreg, and laminate
    • 阻燃树脂化合物,使用它们的热固性树脂组合物,PREPREG和层压体
    • JP2012153896A
    • 2012-08-16
    • JP2012069195
    • 2012-03-26
    • Hitachi Chemical Co Ltd日立化成工業株式会社
    • UCHIMURA RYOICHITSUCHIKAWA SHINJIMIYATAKE MASATO
    • C08G59/18B32B15/08C08J5/24C08K3/00C08K5/3492C08L35/00C08L63/00H05K1/03
    • PROBLEM TO BE SOLVED: To provide: a non-halogen flame retardant resin compound having a good balance between all of flame retardancy, metal foil adhesivity, heat resistance, moisture resistance and dielectric characteristics, and suitably usable for electronic parts or the like; a thermosetting resin composition and a prepreg and a laminate using the non-halogen flame retardant resin compound.SOLUTION: The flame retardant resin compound is produced by reacting a compound (a), which is obtained from an N-substituted maleimide compound and an amine compound having an acid substituent, with a phosphorus-containing epoxy resin (b) in an organic solvent. The thermosetting resin composition includes: a solution (A) of the flame retardant resin compound; a 6-substituted guanamine compound (B); a copolymer resin (C) from a styrene compound or a vinyl compound and a maleic anhydride; an epoxy resin (D); a hardener (E) for an epoxy resin having an acid substituent; and an inorganic filler (F). The prepreg and a laminate are produced using the thermosetting resin composition.
    • 要解决的问题:提供:阻燃性,金属箔粘合性,耐热性,耐湿性和介电特性之间具有良好平衡的非卤素阻燃树脂化合物,并且适用于电子部件或 喜欢; 热固性树脂组合物和预浸料以及使用非卤素阻燃树脂化合物的层压体。 解决方案:阻燃树脂化合物通过使由N-取代的马来酰亚胺化合物获得的化合物(a)和具有酸取代基的胺化合物与含磷环氧树脂(b)在 有机溶剂。 热固性树脂组合物包括:阻燃树脂化合物的溶液(A); 6-取代胍胺化合物(B); 来自苯乙烯化合物或乙烯基化合物的共聚物树脂(C)和马来酸酐; 环氧树脂(D); 具有酸取代基的环氧树脂的固化剂(E); 和无机填料(F)。 使用热固性树脂组合物制备预浸料和层压材料。 版权所有(C)2012,JPO&INPIT
    • 4. 发明专利
    • Thermocurable resin composition, prepreg using the thermocurable resin composition, laminated plate, and printed wiring board
    • 可热固性树脂组合物,使用可热固化树脂组合物,层压板和印刷线路板
    • JP2012111930A
    • 2012-06-14
    • JP2011117322
    • 2011-05-25
    • Hitachi Chemical Co Ltd日立化成工業株式会社
    • TAKAHARA NAOKIOSE MASAHISAUCHIMURA RYOICHIKATO IKUHIKOMIYATAKE MASATOKOTAKE TOMOHIKO
    • C08G59/40C08J5/24C08K3/22C08L63/00H05K1/03
    • PROBLEM TO BE SOLVED: To provide a thermocurable resin composition satisfying moisture resistance and adhesion and imparting heat resistance relative to a temperature condition in a lead-free soldering or a reflow soldering and an advantageous thermal coefficient of linear expansion.SOLUTION: This thermocurable resin composition is a thermocurable resin composition containing: a compound (A) obtained by reacting a maleimide compound (a) having in one molecule thereof, at least two N-substituted maleimide group with an amine compound (b) having an acidic substituent represented by General Formula (1) (where, when Rexists in a plurality, Rs represent each independently any one of a hydroxy group, a carboxy group, and a sulfonic acid group which are an acidic substituent; when Rexists in a plurality, Rs represent independently any one of a hydrogen atom, a 1C-5C aliphatic hydrocarbon group, a halogen atom, a hydroxy group, a carboxy group, and a sulfonic acid group; and x and y are each an integer of 1 to 4) and having in the molecule structure thereof, an acidic substituent and an N-substituted maleimide group; an epoxy resin (B); a metal hydrate (C) having a thermal decomposition temperature of 300°C or higher; and a modified imidazole compound (D).
    • 要解决的问题:提供一种满足耐湿性和粘合性并且在无铅焊接或回流焊接中相对于温度条件赋予耐热性和有利的线性膨胀热系数的热固性树脂组合物。 解决方案:该热固性树脂组合物是含有下列化合物的热固性树脂组合物:通过使具有1分子的马来酰亚胺化合物(a),至少2个N-取代马来酰亚胺基与胺化合物(b )具有由通式(1)表示的酸性取代基(其中当R 1 存在于多个时,R 1 独立地表示作为酸性取代基的羟基,羧基和磺酸基中的任一个;当多个R 2 时,R SB SB = “POST”> 2 独立地表示氢原子,1C-5C脂族烃基,卤素原子,羟基,羧基和磺酸基中的任何一个; x和y分别为 每个为1至4的整数),并且在其分子结构中具有酸性取代基和N-取代的马来酰亚胺基团; 环氧树脂(B); 热分解温度为300℃以上的金属水合物(C) 和改性咪唑化合物(D)。 版权所有(C)2012,JPO&INPIT
    • 7. 发明专利
    • Metal foil clad laminated sheet and manufactured method of multilayered printed wiring board
    • 金属箔层压板和多层印刷线路板的制造方法
    • JP2006297613A
    • 2006-11-02
    • JP2005118191
    • 2005-04-15
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • NAKAMURA YUKIOISHIGAMI FUMIOUCHIMURA RYOICHI
    • B32B15/08B32B17/04H05K3/38H05K3/46
    • PROBLEM TO BE SOLVED: To provide a metal foil clad laminated sheet excellent in withstand voltage characteristics and heat resistance constituted by using a specific metal foil in the metal foil clad laminated sheet, and a multilayered printed wiring board. SOLUTION: In the metal foil clad laminated sheet, which has an insulating layer with a thickness of 0.06 mm or below, manufactured by laminating the metal foil on plain weave glass cloth impregnated with a thermosetting resin composition and subsequently heating and pressing the formed laminate, the untreated surface (glossy surface) of the metal foil is smoothed by plating treatment so that its surface roughness (Rz) becomes 2.0 μm or below. The manufacturing method of the metal foil clad laminated sheet is characterized by using the metal foil of which the surface is subjected to roughening treatment so as to have a surface roughness (Rz) of 2.0-3.5 mm. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种在金属箔包覆层压片中使用特定金属箔构成的耐电压特性和耐热性优异的金属箔复合层叠片和多层印刷线路板。 解决方案:在通过将金属箔层压在浸渍有热固性树脂组合物的平纹玻璃织物上并随后加热和压制的情况下,将厚度为0.06mm或更小的绝缘层的金属箔包覆层压片 通过电镀处理使金属箔的未处理面(光泽面)平滑化,使得其表面粗糙度(Rz)为2.0μm以下。 金属箔复合层叠片的制造方法的特征在于,使用表面经过粗糙化处理的金属箔,使其表面粗糙度(Rz)为2.0〜3.5mm。 版权所有(C)2007,JPO&INPIT
    • 8. 发明专利
    • Resin composition, production method of resin composition, and prepreg and laminate each using the same
    • 树脂组合物,树脂组合物的生产方法,以及使用它们的PREPREG和层压板
    • JP2010260955A
    • 2010-11-18
    • JP2009112750
    • 2009-05-07
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • TAKAHASHI YOSHIHIROKAMIGATA YASUOMIYATAKE MASATOUCHIMURA RYOICHI
    • C08L101/00C08J5/24C08K3/36C08K9/00
    • PROBLEM TO BE SOLVED: To provide a resin composition having good drillability, low heat expansibility, and excellent heat resistance and suited for semiconductor packages and printed wiring boards and to provide a prepreg and a laminate each using the same.
      SOLUTION: What are provided are a resin composition comprising a thermosetting resin, a silica filler, and a core/shell resin particles having a primary particle diameter of 0.01-1 μm, wherein the secondary particle diameter of the core/shell resin particles is 0.01-1 μm and a method for producing a resin composition comprising the step of dispersing a silica filler in an organic solvent under agitation to prepare a silica filler dispersion, the step of adding core/shell resin particles to the silica filler dispersion and dispersing the particles in the dispersion under agitation till the secondary particle diameter of the core/shell resin particles reaches 0.01-1 μm, and the step of further adding a thermosetting resin to the resultant dispersion under agitation.
      COPYRIGHT: (C)2011,JPO&INPIT
    • 要解决的问题:提供一种具有良好的可钻性,低热膨胀性和优异的耐热性并且适用于半导体封装和印刷线路板的树脂组合物,并提供使用该树脂组合物的预浸料和层压材料。 解决方案:提供一种包含热固性树脂,二氧化硅填料和一次粒径为0.01-1μm的核/壳树脂颗粒的树脂组合物,其中芯/壳树脂的二次粒径 颗粒为0.01-1μm的树脂组合物的制造方法和包括在搅拌下将二氧化硅填料分散在有机溶剂中以制备二氧化硅填料分散体的步骤的方法,将核/壳树脂颗粒添加到二氧化硅填料分散体中的步骤和 在搅拌下将颗粒分散在分散体中直到核/壳树脂颗粒的二次粒径达到0.01-1μm,并且在搅拌下向所得分散体中进一步加入热固性树脂的步骤。 版权所有(C)2011,JPO&INPIT
    • 9. 发明专利
    • Flame retardant resin compound, and thermosetting resin composition, prepreg and laminated plate using the same
    • 阻燃树脂化合物和热固性树脂组合物,使用它们的PREPREG和层压板
    • JP2008163305A
    • 2008-07-17
    • JP2007205709
    • 2007-08-07
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • UCHIMURA RYOICHITSUCHIKAWA SHINJIMIYATAKE MASATO
    • C08G59/14B32B15/08C08G59/58C08J5/24
    • PROBLEM TO BE SOLVED: To provide a non-halogen flame retardant resin compound that has a good balance between all of flame retargency, metal foil adhesion, heat resistance, moisture resistance and dielectric characteristics, and can be suitably used for electronic parts, and to provide a thermosetting resin composition using the resin compound as well as a prepreg and a laminated plate.
      SOLUTION: The flame retardant resin compound is produced by reacting a compound (a) obtained from an N-substituted maleimide compound and an amine compound having an acidic substituent with a phosphorus-containing epoxy resin (b) in an organic solvent. The thermosetting resin composition comprises a solution (A) of the flame retardant resin compound, a 6-substituted guanamine compound (B), a copolymer resin (C) from a styrene compound or a vinyl compound and a maleic anhydride, an epoxy resin (D), and an acidic substituent-containing hardener (E) for the epoxy resin. The prepreg and the laminated plate using the composition are also disclosed.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供在所有的火焰恢复性,金属箔粘附性,耐热性,耐湿性和介电特性之间具有良好平衡的非卤素阻燃树脂化合物,并且可以适用于电子部件 并且提供使用该树脂化合物的热固性树脂组合物以及预浸料和层压板。 解决方案:通过使由N-取代的马来酰亚胺化合物获得的化合物(a)和具有酸性取代基的胺化合物与含磷环氧树脂(b)在有机溶剂中反应来制备阻燃树脂化合物。 热固性树脂组合物包含阻燃树脂化合物的溶液(A),6-取代的胍胺化合物(B),来自苯乙烯化合物或乙烯基化合物的共聚物树脂(C)和马来酸酐,环氧树脂 D)和用于环氧树脂的酸性取代基的固化剂(E)。 还公开了使用该组合物的预浸料坯和层压板。 版权所有(C)2008,JPO&INPIT