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    • 2. 发明专利
    • Thermosetting resin composition, and prepreg, laminate and printed wiring board using the same
    • 热固性树脂组合物和PREPREG,层压板和印刷线路板
    • JP2012236909A
    • 2012-12-06
    • JP2011106671
    • 2011-05-11
    • Hitachi Chemical Co Ltd日立化成工業株式会社
    • NAGAI SHUNSUKEMIYATAKE MASATOKOTAKE TOMOHIKOTAKANEZAWA SHINMURAI AKIRA
    • C08G59/40B32B15/08B32B27/04B32B27/38C08G59/68C08J5/24H05K1/03
    • PROBLEM TO BE SOLVED: To provide a resin composition excellent in low thermal expansion, heat resistance, and adhesion, and a prepreg and a laminate and a printed wiring board excellent in warpage characteristics and resistance to desmearing, which use the resin composition.SOLUTION: A thermosetting resin composition includes: a compound (A) having an acidic substituent and an N-substituted maleimide group in molecular structure produced by the reaction of a maleimide compound (a) having at least two N-substituted maleimide groups in one molecule with an amine compound (b) having an acidic substituent represented by general formula (I); and a bisphenol F novolak type epoxy resin (B) having an average molecular weight of 500-10,000. The prepreg, the laminate, and the printed wiring board use the thermosetting resin composition. In formula, when a plurality of Rs are present, Rs are each independently an acidic substituent selected from a hydroxyl group, a carboxy group, and a sulfonic acid group; when a plurality of Rs are present, Rs are each independently a hydrogen atom, a 1-5C aliphatic hydrocarbon group, or a halogen atom; and x is an integer of 1-5, y is an integer of 0-4, and the sum of x and y is 5.
    • 要解决的问题:提供使用该树脂组合物的低热膨胀性,耐热性和粘合性优异的树脂组合物以及具有优异的翘曲特性和耐干燥性的预浸料和层压体以及印刷线路板 。 解决方案:热固性树脂组合物包括:具有酸性取代基的化合物(A)和通过具有至少两个N-取代的马来酰亚胺基团的马来酰亚胺化合物(a)的反应制备的分子结构中的N-取代的马来酰亚胺基团 在具有由通式(I)表示的酸性取代基的胺化合物(b)的一个分子中; 和平均分子量为500〜10000的双酚F酚醛清漆型环氧树脂(B)。 预浸料,层压体和印刷布线板使用热固性树脂组合物。 在式中,当存在多个R 1 时,R“SB POS =”POST“> 1 各自独立地为选自羟基的酸性取代基 基,羧基和磺酸基; 当存在多个R 2 时,R 2 各自独立地为氢原子,1-5C脂族烃 基团或卤素原子; x为1〜5的整数,y为0〜4的整数,x与y的和为5.(C)2013,JPO&INPIT
    • 4. 发明专利
    • Prepreg, laminated plate, and printed wiring board using thermocurable resin composition
    • PREPREG,层压板和使用可热固化树脂组合物的印刷线路板
    • JP2012246395A
    • 2012-12-13
    • JP2011119505
    • 2011-05-27
    • Hitachi Chemical Co Ltd日立化成工業株式会社
    • MIYATAKE MASATOKOTAKE TOMOHIKONAGAI SHUNSUKETAKANEZAWA SHINMURAI AKIRAUCHIMURA RYOICHITAKAHARA NAOKI
    • C08J5/24C08G59/50C08K5/18C08K7/14C08K9/06C08L79/00C08L101/00H05K1/03
    • PROBLEM TO BE SOLVED: To provide a laminated plate and a printed wiring board which are excellent in heat resistance and insulation reliability and in which impregnating ability of a thermocurable resin and adhesion of a thermocurable resin with a glass cloth are good.SOLUTION: This prepreg for a printed wiring board is obtained by a method including: impregnating a glass cloth treated with (C) a silane coupling agent represented by General Formula (I) (where Rrepresents a 1-5C divalent hydrocarbon group, Rrepresents hydrogen or a 1-10C monovalent hydrocarbon group, X represents OCH, OCH, or OCH, m represents an integer of 0 to 5, and plural Xs and Rs when present in plurality may be the same as or different from each other) with a thermocurable resin composition containing (A) a compound containing an unsaturated maleimide group obtained by reacting (a) a maleimide compound having at least two N-substituted maleimide groups in the molecule with (b) an amine compound having at least two primary amino groups in the molecule and (B) a thermocurable resin; heating-drying the glass cloth; and converting the glass cloth into a B-stage.
    • 要解决的问题:提供耐热性和绝缘可靠性优异,并且其中耐热树脂的浸渍能力和耐热树脂与玻璃布的粘附性良好的层压板和印刷线路板。 解决方案:用于印刷线路板的该预浸料通过以下方法获得:浸渍用(C)由通式(I)表示的硅烷偶联剂(其中R 1 表示1-5C的二价烃基,R表示氢或1-10C一价烃基,X表示OCH 3 ,OC 2 H 5 或OC 3 H 7 ,m表示0〜5的整数,多个X和R 2 相同或不同)与含有(A)含有不饱和马来酰亚胺基团的化合物的热固性树脂组合物通过使(a)在分子中具有至少两个N-取代马来酰亚胺基团的马来酰亚胺化合物与(b) 分子中具有至少两个伯氨基的胺化合物和(B)热固性树脂; 加热干燥玻璃布; 并将玻璃布转换成B级。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Thermosetting resin composition, prepreg using the same, and laminate using the prepreg
    • 热固性树脂组合物,使用相同的PREPREG和使用PREPREG的层压板
    • JP2012021098A
    • 2012-02-02
    • JP2010160982
    • 2010-07-15
    • Hitachi Chem Co Ltd日立化成工業株式会社
    • MIYATAKE MASATOKOTAKE TOMOHIKONAGAI SHUNSUKETAKANEZAWA SHINMURAI AKIRA
    • C08G59/50C08J5/24C08K3/00C08L63/04H05K1/03
    • PROBLEM TO BE SOLVED: To provide a resin composition excellent in adhesiveness, heat resistance, moisture resistance, flame retardancy, dielectric property and the like, and particularly having a characteristic such that the warpage amount of the substrate thereof when heated is extremely small; and to provide a prepreg using the composition and also a laminate using the prepreg.SOLUTION: The thermosetting resin composition contains a setting agent (A) having the N-substituted maleimide groups and acidic substituent, produced by reacting a maleimide compound (a) having at least two N-substituted maleimide groups in one molecule with an amino compound (b) having the acidic substituent represented by general formula (I), and a bisphenol F type phenol novolac epoxy resin (B) (wherein Rs are each independently hydroxyl being an acidic substituent, carboxyl or sulfonic acid; Rs are each independently 1-5C aliphatic hydrocarbon or halogen; and x is an integer of 1 to 5, y is an integer of 0 to 4 and x+y=5). The invention further provides a prepreg using the composition and a laminate using the prepreg.
    • 要解决的问题:提供粘合性,耐热性,耐湿性,阻燃性,介电性等优异的树脂组合物,特别是具有使其加热时的基材的翘曲量极其特性的特性 小; 并提供使用该组合物的预浸料,以及使用该预浸料的层压体。 解决方案:热固性树脂组合物含有具有N-取代的马来酰亚胺基和酸性取代基的固化剂(A),其通过使一分子中具有至少两个N-取代的马来酰亚胺基团的马来酰亚胺化合物(a)与一 具有由通式(I)表示的酸性取代基的氨基化合物(b)和双酚F型酚醛清漆环氧树脂(B)(其中R 1 作为酸性取代基,羧基或磺酸; R 2各自独立地为1-5C脂族烃或卤素; x为1〜5的整数,y为整数 0〜4,x + y = 5)。 本发明还提供使用该组合物的预浸料坯和使用该预浸料的层压材料。 版权所有(C)2012,JPO&INPIT