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1. 发明申请

US20110062426A1 SUBSTITUTED OLIGO- OR POLYTHIOPHENES 有权
标题翻译：取代的寡糖或聚乙二醇
公开(公告)号：US20110062426A1
公开(公告)日：2011-03-17
申请号：US12921176
申请日：2009-03-06
申请人： Hans Jurg Kirner , Frank Bienewald , Jean Charles Flores , Oliver Frédéric Aebischer
发明人： Hans Jurg Kirner , Frank Bienewald , Jean Charles Flores , Oliver Frédéric Aebischer
IPC分类号： H01L51/30 , C07D409/04 , C07D495/04 , C07F7/10 , C07D495/14 , C07F7/12 , C08G75/06 , H01L51/40
CPC分类号： C07D333/28 , C07D495/04 , C07D495/14 , C07F7/0814 , C07F9/6578 , C08G61/12 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/141 , C08G2261/3223 , C08G2261/3244 , C08G2261/3247 , C08G2261/364 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0094 , Y02E10/549
摘要： A process for the preparation of a substituted 2,2′-dithiophene is described, which process comprises the steps (a), (c) and optional steps (b) and (d): a reaction of a compound of the formula: with a suitable lithium organic compound, preferably Li-alkyl or Li-alkylamide; b) optional exchange of lithium against another metal selected from Mg1 Zn and Cu; c) reaction of the metallated intermediate obtained in step (a) or (b) with a suitable electrophil, which is CO2 or an aldehyde (addition reaction), or a compound Y′—R17 or Y′—R18-Z (substitution reaction), where R17 and R18 are as defined in claim 1; and optionally d) modification of the product obtained in step (c), e.g. by introducing one or more conjugating moieties Y ring closure between suitable monovalent residues R17, exchange or extension of functional groups or substituents such as addition to carbonyl or substitution of carbonyl in R17 or R18. The products, including or corresponding polymers, are excellent conducting materials
摘要翻译：描述了制备取代的2,2'-二噻吩的方法，该方法包括步骤（a），（c）和任选步骤（b）和（d）：下式化合物与合适的锂有机化合物，优选为Li-烷基或Li-烷基酰胺; b）任选地将锂与另一种选自Mg1 Zn和Cu的金属交换; c）将步骤（a）或（b）中获得的金属化中间体与合适的亲电体（其为CO 2或醛（加成反应））或化合物Y'-R17或Y'-R18-Z（取代反应），其中R 17和R 18如权利要求1所定义; 和任选地d）修饰步骤（c）中获得的产物，例如，通过在合适的单价残基R17之间引入一个或多个缀合部分Y闭环，官能团或取代基的交换或延伸，例如加成羰基或在R17或R18中取代羰基。包括或相应的聚合物的产品是优良的导电材料

2. 发明申请

US20100297405A1 KETOPYRROLES AS ORGANIC SEMICONDUCTORS 有权
标题翻译：作为有机半导体的KETOPYRROLOL
公开(公告)号：US20100297405A1
公开(公告)日：2010-11-25
申请号：US12680920
申请日：2008-10-16
申请人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
发明人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jurg Kirner , Mathieu G.R. Turbiez
IPC分类号： C07D403/04 , C08F226/06 , B32B3/10
CPC分类号： H01L51/0036 , C08G61/123 , C08G61/124 , H01L51/0043 , H01L51/0545 , Y02E10/549 , Y10T428/24802
摘要： Monomeric or polymeric compounds comprising at least one moiety of the formula (Ia) wherein X is CR, where R is H or a substituent as defined in claim 1, or is another ketopyrrole moiety e.g. of the formula (1b) or (1c) with this moiety and all other symbols are as defined in claim 1, show good solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：包含至少一个式（Ia）部分的单体或聚合化合物，其中X是CR，其中R是H或如权利要求1所定义的取代基，或者是另一个酮基吡咯部分。的式（1b）或（1c）与所有其它符号如权利要求1中所定义，在有机溶剂中表现出良好的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于半导体器件或有机光伏（PV）器件时，可以观察到高的能量转换效率，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性太阳能电池）。

3. 发明申请

US20090101890A1 Azaperylenes as organic semiconductors 有权
标题翻译：亚萘基作为有机半导体
公开(公告)号：US20090101890A1
公开(公告)日：2009-04-23
申请号：US11919605
申请日：2006-05-03
申请人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jurg Kirner
发明人： Frank Bienewald , Beat Schmidhalter , Ulrich Berens , Hans Jurg Kirner
IPC分类号： H01L51/00 , C07D471/04 , H01L51/40 , C07D409/14
CPC分类号： C09B5/028 , C07D471/06 , H01L51/0067 , H01L51/0069 , H01L51/0071 , H01L51/0072 , H01L51/0512 , H01L51/0541 , H01L51/5012 , Y10S428/93
摘要： A novel semiconductor device comprises an azaperylene organic semiconductor of the formula I (I) wherein each of R1, R2, R3 and R4 independently is selected from H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, halogen, Si(RH)3, XR6; or one or more of R1 and R2, R2 and R3, R3 and R4, together with the carbon atoms they are bonding to, form a saturated or unsaturated, unsubstituted or substituted carbocyclic or heterocyclic ring; R5 is OR7, SR7, NR7R8, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, or unsubstituted or substituted aryl; R6 is Si(R11)3, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; R7 is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl; X is O, S, NR8; Rδ is H, unsubstituted or substituted alkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl, unsubstituted or substituted aryl, R11 being C1-C20-alkyl or -alkoxy.
摘要翻译：一种新颖的半导体器件包括式I（I）的氮杂伯有机半导体，其中R1，R2，R3和R4各自独立地选自H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，卤素，Si（RH）3，XR6; 或R 1和R 2，R 2和R 3，R 3和R 4中的一个或多个与它们键合的碳原子一起形成饱和或不饱和的未取代或取代的碳环或杂环; R5是OR7，SR7，NR7R8，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，或未取代或取代的芳基; R6是Si（R11）3，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; R 7为H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基; X是O，S，NR8; Rdelta是H，未取代或取代的烷基，未取代或取代的烯基，未取代或取代的炔基，未取代或取代的芳基，R11为C1-C20烷基或 - 烷氧基。

4. 发明授权

US08404864B2 Pyrrolopyrrole derivatives, their manufacture and use 有权
标题翻译：吡咯并吡咯衍生物，其制造和使用
公开(公告)号：US08404864B2
公开(公告)日：2013-03-26
申请号：US12680904
申请日：2008-09-22
申请人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Mathieu Turbiez , Frank Bienewald , Mathias Düggeli , Oliver Frédéric Aebischer , Pascal Hayoz , Marta Fonrodona Turon
发明人： Zhimin Hao , Beat Schmidhalter , Jean-Luc Budry , Margherita Fontana , Mathieu Turbiez , Frank Bienewald , Mathias Düggeli , Oliver Frédéric Aebischer , Pascal Hayoz , Marta Fonrodona Turon
IPC分类号： C07D487/02
CPC分类号： H01L51/0071 , C07D487/04 , C09B57/004 , H01L51/0053 , H01L51/0058 , H01L51/0068 , H01L51/0095 , Y02E10/549
摘要： The present invention relates to compounds of the formula (I) wherein the substituents are as defined in claim 1, and their use as organic semiconductor in organic devices, like diodes, organic field effect transistors and/or a solar cells. The compounds of the formula I have excellent solubility in organic solvents. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when said compounds are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：本发明涉及式（I）化合物，其中取代基如权利要求1中所定义，及其作为有机半导体在有机器件中的用途，如二极管，有机场效应晶体管和/或太阳能电池。式I的化合物在有机溶剂中具有优异的溶解性。当所述化合物用于半导体器件或有机光伏（PV）器件（太阳能电池））时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性。

5. 发明申请

US20070142662A1 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US20070142662A1
公开(公告)日：2007-06-21
申请号：US11657808
申请日：2007-01-24
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Jurg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Jurg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C227/04
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group.
摘要翻译：本发明涉及用于制备适于制备他汀类衍生物的中间体的新型合成方法，特别涉及式VI中间体的新型合成方法，其中R a a， C 1各自独立地为另一个氢或羟基保护基团，或者一起是桥接羟基保护基团，并且R b是羧基保护基团，该方法进行通过其中R a a和R c C分别独立于另一个氢或羟基保护基的式XIX的中间体的转化，并且R b' SUB>是羧基保护基。

6. 发明授权

US08436208B2 Substituted oligo- or polythiophenes 有权
标题翻译：取代的寡聚或聚噻吩
公开(公告)号：US08436208B2
公开(公告)日：2013-05-07
申请号：US12921176
申请日：2009-03-06
申请人： Hans Jürg Kirner , Frank Bienewald , Jean-Charles Flores , Olivier Frédéric Aebischer
发明人： Hans Jürg Kirner , Frank Bienewald , Jean-Charles Flores , Olivier Frédéric Aebischer
IPC分类号： C07C233/00 , C07C235/00 , C07C237/00 , C07C239/00
CPC分类号： C07D333/28 , C07D495/04 , C07D495/14 , C07F7/0814 , C07F9/6578 , C08G61/12 , C08G61/122 , C08G61/123 , C08G61/126 , C08G2261/124 , C08G2261/141 , C08G2261/3223 , C08G2261/3244 , C08G2261/3247 , C08G2261/364 , C08G2261/92 , H01L51/0036 , H01L51/0043 , H01L51/0094 , Y02E10/549
摘要： A process for the preparation of a substituted 2,2′-dithiophene is described, which process comprises the steps (a), (c) and optional steps (b) and (d): a reaction of a compound of the formula: with a suitable lithium organic compound, preferably Li-alkyl or Li-alkylamide; b) optional exchange of lithium against another metal selected from Mg1 Zn and Cu; c) reaction of the metallated intermediate obtained in step (a) or (b) with a suitable electrophil, which is CO2 or an aldehyde (addition reaction), or a compound Y′—R17 or Y′—R18-Z (substitution reaction), where R17 and R18 are as defined in claim 1; and optionally d) modification of the product obtained in step (c), e.g. by introducing one or more conjugating moieties Y ring closure between suitable monovalent residues R17, exchange or extension of functional groups or substituents such as addition to carbonyl or substitution of carbonyl in R17 or R18. The products, including or corresponding polymers, are excellent conducting materials
摘要翻译：描述了制备取代的2,2'-二噻吩的方法，该方法包括步骤（a），（c）和任选步骤（b）和（d）：下式化合物与合适的锂有机化合物，优选为Li-烷基或Li-烷基酰胺; b）任选地将锂与另一种选自Mg1 Zn和Cu的金属交换; c）将步骤（a）或（b）中获得的金属化中间体与合适的亲电体（其为CO 2或醛（加成反应））或化合物Y'-R17或Y'-R18-Z（取代反应），其中R 17和R 18如权利要求1所定义; 和任选地d）修饰步骤（c）中获得的产物，例如，通过在合适的单价残基R17之间引入一个或多个缀合部分Y闭环，官能团或取代基的交换或延伸，例如加成羰基或在R17或R18中取代羰基。包括或相应的聚合物的产品是优良的导电材料

7. 发明授权

US08758880B2 Ketopyrroles as organic semiconductors 有权
标题翻译：酮基吡咯酮作为有机半导体
公开(公告)号：US08758880B2
公开(公告)日：2014-06-24
申请号：US12680920
申请日：2008-10-16
申请人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jürg Kirner , Mathieu G. R. Turbiez
发明人： Jean-Charles Flores , Ulrich Berens , Frank Bienewald , Hans Jürg Kirner , Mathieu G. R. Turbiez
IPC分类号： H01L35/24
CPC分类号： H01L51/0036 , C08G61/123 , C08G61/124 , H01L51/0043 , H01L51/0545 , Y02E10/549 , Y10T428/24802
摘要： Monomeric or polymeric compounds comprising at least one moiety of the formula (Ia) wherein X is CR, where R is H or a substituent as defined in claim 1, or is another ketopyrrole moiety e.g. of the formula (Ib) or (Ic) with this moiety and all other symbols are as defined in claim 1, show good solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in semiconductor devices or organic photovoltaic (PV) devices (solar cells).
摘要翻译：包含至少一个式（Ia）部分的单体或聚合化合物，其中X是CR，其中R是H或如权利要求1所定义的取代基，或者是另一个酮基吡咯部分。式（Ib）或（Ic）与该部分和所有其它符号如权利要求1中所定义，在有机溶剂中表现出良好的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于半导体器件或有机光伏（PV）器件时，可以观察到高的能量转换效率，优异的场效应迁移率，良好的导通/截止电流比和/或优异的稳定性太阳能电池）。

8. 发明申请

US20070172624A1 Optical recording materials writable using blue lasers 审中-公开
标题翻译：光学记录材料可使用蓝色激光器写入
公开(公告)号：US20070172624A1
公开(公告)日：2007-07-26
申请号：US10590021
申请日：2005-02-16
申请人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
发明人： Heinz Wolleb , Annemarie Wolleb , Frank Bienewald , Beat Schmidhalter , Jean-Luc Budry , Heinz Spahni
IPC分类号： B32B3/02
CPC分类号： G11B7/2492 , C09B47/045 , G11B7/2472 , G11B7/2475 , G11B7/2478 , G11B7/248 , G11B7/2534 , G11B7/259 , G11B2007/2571 , G11B2007/25713 , G11B2007/25715
摘要： The invention relates to an optical recording medium comprising a substrate, a recording layer and optionally one or more reflecting layers, wherein the recording layer comprises a compound of formula (I) or a tautomeric or mesomeric form thereof, wherein G1 and G2 are each independently of the other C(R5) or N; M1 is a lanthanide or transition metal of groups 4 to 10; P is a phthalocyanino diradical; and R1 to R5 are substituents as defined in the description and the claims. Recording and playback are effected especially at a wavelength of from 350 to 500 nm, for example using a blue laser. The recording and playback quality is excellent and allows a high storage density.
摘要翻译：本发明涉及一种包括基底，记录层和任选的一个或多个反射层的光学记录介质，其中记录层包含式（I）化合物或其互变异构体或介导体形式，其中G 1， / SUB和G 2各自独立地为C（R 5 N）或N; M 1是第4至10族的镧系元素或过渡金属; P是酞菁双基; 和R 1至R 5是如说明书和权利要求书中所定义的取代基。记录和回放特别是在350至500nm的波长下进行，例如使用蓝色激光。录制和播放质量非常好，可以保持较高的存储密度。

9. 发明授权

US08471019B2 Quinoid systems as organic semiconductors 有权
标题翻译：醌类系统作为有机半导体
公开(公告)号：US08471019B2
公开(公告)日：2013-06-25
申请号：US12226182
申请日：2007-04-04
申请人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
发明人： Ulrich Berens , Arno Stassen , Beat Schmidhalter , Wolfgang Kalb , Frank Bienewald
IPC分类号： H01L51/00 , C07D409/14 , C07D211/18 , C07D319/00 , C07D413/14
CPC分类号： H01L51/0074 , C07D493/04 , C07D493/22 , C07D495/04 , H01L51/0055 , H01L51/0073 , H01L51/0529 , H01L51/0533 , H01L51/0545 , Y02E10/549
摘要： A semiconducting layer comprising a non-polymeric quinoid heteroacene compound of the formula (I) wherein X stands for O, S or NR, each of R, R1, R2, R3, R4, R5, R6, R7, R8 being independently selected from hydrogen and an organic residue, or 2 or more thereof together forming one or more annealed rings, which may be substituted or unsubstituted, carbocyclic or helerocyclic, aromatic, quinoid or aliphatic, may be used e.g. for the manufacture of a diode, an organic field effect transistor, an organic thin film transistor, or a device containing a diode and/or an organic field effect transistor and/or organic thin film transistor.
摘要翻译：一种半导体层，其包含式（I）的非聚合醌型杂炔化合物，其中X代表O，S或NR，R，R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8中的每一个独立地选自氢和有机残基，或其中2个或更多个一起形成可以是取代或未取代的碳环或环丙基，芳族，醌型或脂族的一个或多个退火环，例如用于制造二极管，有机场效应晶体管，有机薄膜晶体管或包含二极管和/或有机场效应晶体管和/或有机薄膜晶体管的器件。

10. 发明授权

US08044058B2 Merocyanine derivatives 有权
标题翻译：梅花菁衍生物
公开(公告)号：US08044058B2
公开(公告)日：2011-10-25
申请号：US12715839
申请日：2010-03-02
申请人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
发明人： Barbara Wagner , Frank Bienewald , Heinz Wolleb , Olof Wallquist , Bernd Herzog , Thomas Ehlis , Jürg Haase
IPC分类号： A61K31/517 , A61K31/445 , A61K31/16
CPC分类号： A61K8/498 , A61K8/4913 , A61K8/494 , A61Q17/04
摘要： Disclosed is the use of merocyanine derivatives of formula Q is hydrogen; C1-C22alkyl; —OH; —OR7; —NR7R8; or —N═R9; R1 is hydrogen; C1-C22alkyl; —OR7, —SR7; —NR7R8; C1-C22alkyl; C2-C12 alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12heteroalkyl, C2-C11heteroaralkyl; C6-C10aryl; or C1-C9heteroaryl; R4 is cyano; COR7, COOR7; CONR7R8; SO2(C6-C12)aryl; C2-C12alk-1-enyl; C3-C12cycloalk-1-enyl; C2-C12alk-1-inyl; C2-C12heteroalkyl; C3-C5heterocycloalkyl; C6-C10aryl; or C1-C9heteroaryl; R5 is —COR7; —COOR7; —OR7; —SR7, —NHR7, —NR7R8; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; C7-C12aralkyl; C1-C12alkylphenyl; C1-C12alkoxy-C6-C10aryl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C3-C12cycloheteroalkyl; C6-C10aryl; C1-C12alkoxy-C6-C10aryl; or C1-C9heteroaryl; R6 is hydrogen; C1-C22alkyl; C1-C22alkoxy; or COR7; R7 and R8 independently from each other are hydrogen; C1-C22alkyl; C2-C12alkenyl; C2-C12alkinyl; C3-C12cycloalkyl; C3-C12cycloalkenyl; —(CH2)tCOOH; C7-C12aralkyl; C1-C12heteroalkyl; C2-C11heteroaralkyl; C6-C10aryl; C1-C9heteroaryl; Si—R10R11R12; Si(OR10)(OR11)(OR12); SiR10(OR11)(OR12); SiR10R11(OR12); —(CH2)u—O—(CH2)v—SiR10R11R12; or a radical X-Sil; t, u and v, independently from each other are a number from 1 to 5; R9 is a (C1-C6)alkylidene radical; R10, R11, R12 independently form each other are C1-C22alkyl; X is a linker; for protecting of human hair and skin against the damaging effect of UV radiation.
摘要翻译：披露式Q的部花青衍生物的用途是氢; C 1 -C 22烷基; -哦; -OR7; -NR7R8; 或-N = R9; R1是氢; C 1 -C 22烷基; -OR7，-SR7; -NR7R8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12杂烷基，C 2 -C 11杂芳烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R4是氰基; COR7，COOR7; CONR7R8; SO2（C6-C12）芳基; C2-C12烷-1-烯基; C 3 -C 12环烯-1-烯基; C2-C12alk-1-inyl; C 2 -C 12杂烷基; C3-C5杂环烷基; C6-C10芳基; 或C 1 -C 9杂芳基; R5为-COR7; -COOR7; -OR7; -SR 7，-NHR 7，-NR 7 R 8; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; C7-C12芳烷基; C 1 -C 12烷基苯基; C 1 -C 12烷氧基-C 6 -C 10芳基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C 3 -C 12环杂烷基; C6-C10芳基; C 1 -C 12烷氧基-C 6 -C 10芳基; 或C 1 -C 9杂芳基; R6是氢; C 1 -C 22烷基; C1-C22烷氧基; 或COR7; R 7和R 8彼此独立地是氢; C 1 -C 22烷基; C 2 -C 12烯基; C 2 -C 12炔基; C 3 -C 12环烷基; C3-C12环烯基; - （CH 2）t COOH; C7-C12芳烷基; C 1 -C 12杂烷基; C 2 -C 11杂芳烷基; C6-C10芳基; C1-C9杂芳基; Si-R10R11R12; Si（OR10）（OR11）（OR12）; SiR10（OR11）（OR12）; SiR10R11（OR12）; - （CH 2）u -O-（CH 2）v -SiR 10 R 11 R 12; 或基团X-Sil; t，u和v彼此独立地为1至5的数; R9是（C1-C6）亚烷基; R 10，R 11，R 12彼此独立地为C 1 -C 22烷基; X是一个连接子; 用于保护人的头发和皮肤免受紫外线辐射的破坏作用。

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