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    • 6. 发明授权
    • Comonomer compositions for production of imide-containing polyamino acids
    • 用于生产含酰亚胺的聚氨基酸的共聚单体组合物
    • US06720405B2
    • 2004-04-13
    • US10307377
    • 2002-12-02
    • Graham SwiftGeorge H. Redlich
    • Graham SwiftGeorge H. Redlich
    • C08G6344
    • A61Q19/00A61K8/88A61Q5/02A61Q5/12C07C227/40C08G73/1092C07C229/24
    • Described are monomer compositions containing aspartic acid and other comonomers, such as monosodium aspartate, and methods for their production. The monomer compositions can be polymerized, particularly by thermal polymerization, to obtain useful and novel imide-containing polyamino acids, i.e., copolymers containing polymerized aspartate units and succinimide units. The invention is also directed to the resulting polymeric materials, their methods of production, and their uses and the derivatized polymeric materials by nucleophilic or electrophilic addition. Uses of the imide-containing polyamino acids include, for example, dispersants in detergents and cleansers, water-treatment chemicals as anti-scalants and corrosion inhibitors, personal-care additives for softening and moisturizing, and many others.
    • 描述了含有天冬氨酸和其它共聚单体如天冬氨酸单钠的单体组合物及其生产方法。 单体组合物可以特别通过热聚合来聚合,以获得有用和新颖的含酰亚胺的聚氨基酸,即含有聚合天冬氨酸酯单元和琥珀酰亚胺单元的共聚物。 本发明还涉及通过亲核或亲电子加成得到的聚合物材料,其制备方法及其用途和衍生的聚合物材料。 含酰亚胺的聚氨基酸的用途包括例如在洗涤剂和清洁剂中的分散剂,作为抗鳞屑剂和防腐剂的水处理化学品,用于软化和保湿的个人护理添加剂等。
    • 8. 发明授权
    • Method of inhibiting corrosion in aqueous systems using poly(amino acids)
    • 使用聚(氨基酸)在含水体系中抑制腐蚀的方法
    • US5531934A
    • 1996-07-02
    • US304063
    • 1994-09-12
    • Michael B. FreemanWilliam M. HannYi H. PaikGraham Swift
    • Michael B. FreemanWilliam M. HannYi H. PaikGraham Swift
    • C23G5/02C09K8/54C11D3/37C23F11/08C23F11/173C11D3/06
    • C09K8/54C11D3/3719C23F11/08C23F11/173
    • The present invention provides a method of inhibiting corrosion of ferrous metals in aqueous systems. The corrosion is inhibited by adding an effective amount of one or more poly(amino acids) to the aqueous system. Aqueous systems include for example water treatment systems and equipment used for detergent applications. The poly(amino acids) comprise a reaction product of at least one compound selected from amino acids, amic acids, ammonium salts of monoethylenically unsaturated dicarboxylic acids, ammonium salts of hydroxypolycarboxylic acids and combinations thereof.In one embodiment the poly(amino acids) are added to detergent solutions to inhibit corrosion in equipment for detergent applications. In another embodiment, corrosion inhibitors comprising one or more homopolymers of amino acids and one or more pyrophosphates are added to aqueous systems to inhibit corrosion.
    • 本发明提供一种抑制含水体系中黑色金属腐蚀的方法。 通过向水性体系中加入有效量的一种或多种聚(氨基酸)来抑制腐蚀。 水系统包括例如用于洗涤剂应用的水处理系统和设备。 聚(氨基酸)包含至少一种选自氨基酸,酰胺酸,单烯属不饱和二羧酸的铵盐,羟基多羧酸的铵盐及其组合的化合物的反应产物。 在一个实施方案中,将聚(氨基酸)加入到洗涤剂溶液中以抑制用于洗涤剂应用的设备中的腐蚀。 在另一个实施方案中,包含一种或多种氨基酸均聚物和一种或多种焦磷酸盐的腐蚀抑制剂被加入到含水体系中以抑制腐蚀。