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    • 2. 发明专利
    • Ceramic carrier, ceramic catalytic body and methods for manufacturing them
    • 陶瓷载体,陶瓷催化体及其制备方法
    • JP2007244993A
    • 2007-09-27
    • JP2006071840
    • 2006-03-15
    • Denso CorpNational Institute Of Advanced Industrial & TechnologyNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所独立行政法人産業技術総合研究所
    • YOSHIDA KATSUMIDANIEL DONI JAYASEELANKITA HIDENORIKONDO NAOKIHIUGA HIDEKIKOIKE KAZUHIKONAKANISHI TOMOHIKO
    • B01J35/04B01D53/86B01J35/06B01J35/10B01J37/08C04B38/00
    • PROBLEM TO BE SOLVED: To provide a ceramic carrier having a cordierite porous body, which is stable at high temperature and has high specific surface area, as a base material and a granular agglomerate in which fibrous ceramics are intertwined with one another and to provide a ceramic catalytic body. SOLUTION: The cordierite-based porous ceramic carrier has the granular agglomerate in which fibrous ceramics are intermingled with one another. The ceramic catalytic body is manufactured by depositing a catalyst component on the porous ceramic carrier and has fibrous ceramics. A method for manufacturing the porous ceramic carrier comprises a step of reacting a part of a raw material with a porogen to produce the granular agglomerate of fibrous ceramics intermingled with one another on the surface of a sintered compact at a firing step. As a result, a catalyst-deposited honeycomb structure can be obtained, which has large specific surface area, the decrease of whose specific surface area due to the sintering is restrained, which has a small heat capacity and consequently is activated in early stages and has a small pressure loss, the cordierite porous body as the base material and the granular agglomerate of fibrous ceramics intermingled with one another. COPYRIGHT: (C)2007,JPO&INPIT
    • 待解决的问题:提供一种陶瓷载体,其具有堇青石多孔体,其在高温下稳定并具有高比表面积,作为基体材料和颗粒团聚体,其中纤维状陶瓷彼此缠结, 以提供陶瓷催化体。 解决方案:堇青石基多孔陶瓷载体具有其中纤维状陶瓷彼此混合的颗粒聚集体。 陶瓷催化剂体通过在多孔陶瓷载体上沉积催化剂组分并具有纤维状陶瓷来制造。 制造多孔陶瓷载体的方法包括使一部分原料与致孔剂反应的步骤,以在煅烧步骤中在烧结体的表面上形成相互混合的纤维状陶瓷的颗粒团聚体。 结果,可以获得具有大的比表面积的催化剂沉积的蜂窝结构体,抑制烧结时的比表面积的减小,其热容量小,因此在早期阶段被激活, 小的压力损失,堇青石多孔体作为基础材料和相互混合的纤维状陶瓷颗粒团聚物。 版权所有(C)2007,JPO&INPIT
    • 5. 发明专利
    • Ceramic filter with catalyst
    • 陶瓷过滤器与催化剂
    • JP2009248011A
    • 2009-10-29
    • JP2008100154
    • 2008-04-08
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • OYAMA NAOHISANAKANISHI TOMOHIKOOMICHI SHIGEKI
    • B01J23/652B01D53/94B01J35/04B01J35/10C04B35/195F01N3/02
    • PROBLEM TO BE SOLVED: To provide a ceramic filter with a catalyst which is excellent in heat resistance, has sufficient catalytic performance, and can reduce the number of times of combustion removal. SOLUTION: The ceramic filter has a honeycomb structure 2 made of a cordierite base material with a large number of cells formed by arranging a porous bulkhead in the shape of a honeycomb. Among the cells of the honeycomb structure 2, the downstream end of a cell to be an introduction passage introducing exhaust gas and the upstream end of a cell to be a discharge passage discharging the exhaust gas which passed through the porous bulkhead are blocked by plug parts. In the honeycomb structure 2, the volume of pores not exceeding 5 μm measured by a mercury porosimeter method is ≤0.05 mL/g. The cordierite base material has a cordierite phase 3, a TiO 2 phase 4, and a MgWO 4 phase 5. When the whole cordierite base material is 100 mass%, Ti is at least 5.8 mass%, and W is at least 4.5 mass%. The cordierite base material supports a catalytic metal 6 made of platinum, or platinum and rhodium. COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:为了提供具有耐热性优异的催化剂的陶瓷过滤器,具有足够的催化性能,并且可以减少燃烧除去的次数。 解决方案:陶瓷过滤器具有由堇青石基材制成的蜂窝结构体2,其具有通过将蜂窝状的多孔隔壁设置而形成的多个单元。 在蜂窝结构体2的电池中,作为引入排气的导入通道的电池的下游端和排出通过多孔隔板的废气的排出通道的电池的上游端被插塞部件 。 在蜂窝结构体2中,通过水银孔率计法测定的不超过5μm的孔的体积≤0.05mL/ g。 堇青石基材具有堇青石相3,TiO 2 SB 3相4,MgWO 4 SB 4相。当整个堇青石基材为100质量%时,Ti为 至少5.8质量%,W为4.5质量%以上。 堇青石基材支持由铂或铂和铑制成的催化金属6。 版权所有(C)2010,JPO&INPIT
    • 6. 发明专利
    • Method for preparing ceramic catalyst body
    • 制备陶瓷催化剂体的方法
    • JP2006136845A
    • 2006-06-01
    • JP2004330358
    • 2004-11-15
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • MIZUTANI KEISUKENAKANISHI TOMOHIKOKOIKE KAZUHIKO
    • B01J23/46B01D53/86B01D53/94B01J37/02F01N3/10F01N3/28
    • PROBLEM TO BE SOLVED: To provide a method for preparing a ceramic catalyst body of high catalytic performances with a proper distribution of nano particles on a ceramic carrier of Pt and Rh catalysts even under existence of impurities. SOLUTION: This method for preparing the ceramic catalyst body allows Pt and Rh to be carried on the ceramic carrier by immersing the ceramic carrier into a solution containing Pt ions and Rh ions. The amount of Ir components in the solution into which the ceramic carrier is immersed is W1×0.35≤W0 and W2×10 -4 ≤W0, wherein W0 is the weight of the Ir components contained in the solution into which the ceramic carrier is immersed, W1 is the weight of the Pb components contained as impurities in the solution and W2 is the weight of the Pt components contained in the solution. COPYRIGHT: (C)2006,JPO&NCIPI
    • 待解决的问题:提供一种制备具有高催化性能的陶瓷催化剂体的方法,即使在存在杂质的情况下,也能在Pt和Rh催化剂的陶瓷载体上适当分布纳米颗粒。

      解决方案:制备陶瓷催化剂体的方法允许通过将陶瓷载体浸入含有Pt离子和Rh离子的溶液中来将Pt和Rh载带在陶瓷载体上。 浸渍陶瓷载体的溶液中的Ir成分的量为W1×0.35≤W0,W2×10 -4 ≤W0,其中W0是溶液中所含的Ir成分的重量 陶瓷载体浸入其中,W1是溶液中作为杂质含有的Pb成分的重量,W2是溶液中所含的Pt成分的重量。 版权所有(C)2006,JPO&NCIPI

    • 7. 发明专利
    • Method for producing ceramic catalyst body
    • 生产陶瓷催化剂体的方法
    • JP2004290956A
    • 2004-10-21
    • JP2004013406
    • 2004-01-21
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • KOIKE KAZUHIKOTANAKA MASAICHISUZAWA TAKUMIHASE TOMOMINAKANISHI TOMOHIKO
    • F01N3/10B01D53/86B01D53/94B01J23/30B01J23/40B01J23/652B01J32/00B01J35/04B01J35/10B01J37/02C04B41/85F01N3/28
    • B01J35/04B01J23/40
    • PROBLEM TO BE SOLVED: To provide a method for producing a ceramic catalyst body capable of making a catalyst carried directly on a ceramic carrier without forming a coating layer on the ceramic carrier. SOLUTION: A catalyst carrying solution containing a catalyst component composed of a negative complex ion produced from a catalyst precursor is prepared. when a surface potential of a parent phase of the ceramic carrier containing a parent phase composed of a cordierite-W complex for the pH of the catalyst carrying solution and hetero-facies composed of a compound except the cordierite-W complex is E1 and a surface potential of hetero-facies of the ceramic carrier is E2, the pH of the catalyst carrying solution is adjusted so as to be E1>E2 and E1>0 to make the ceramic carrier contact with the catalyst carrying solution to be carried. Thereafter, a heat treatment is carried out to carry the catalyst on the ceramic carrier by bonding the parent phase composed of the cordierite-W complex with the catalyst component. COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种能够制造直接在陶瓷载体上载持的催化剂而不在陶瓷载体上形成涂层的陶瓷催化剂体的制造方法。 解决方案:制备含有由催化剂前体产生的负配位离子组成的催化剂组分的催化剂载体溶液。 当含有由堇青石-W络合物构成的催化剂载体溶液的pH和由堇青石-W络合物以外的化合物构成的异相的母相的母体相的表面电位为E1,表面 陶瓷载体的异质相的电位为E2,调节催化剂载体溶液的pH以使E1> E2和E1> 0,使陶瓷载体与携带催化剂的溶液接触。 此后,通过将由堇青石-W络合物组成的母相与催化剂组分接合,进行催化剂载体在陶瓷载体上。 版权所有(C)2005,JPO&NCIPI
    • 9. 发明专利
    • Honeycomb structure body with high strength and its manufacturing method
    • 蜂窝结构体高强度及其制造方法
    • JP2009226301A
    • 2009-10-08
    • JP2008074052
    • 2008-03-21
    • Denso CorpNippon Soken Inc株式会社デンソー株式会社日本自動車部品総合研究所
    • MAKINO KENTAROSEGAWA YOSHIHIDENAKANISHI TOMOHIKO
    • B01J35/04B01D53/86B01J35/10C04B35/195
    • PROBLEM TO BE SOLVED: To provide a honeycomb structure body with high strength which has large substrate strength and to provide a manufacturing method thereof. SOLUTION: The manufacturing method of the honeycomb structure body is related to a manufacturing method of the honeycomb structure 1 with high strength. The honeycomb structure consists of cordierite and has a cell wall 11 arranged in a honeycomb shape and a number of cells 12 divided within the cell wall 11. The total pore volume that is a total volume per unit weight of the pore that the cell wall 11 has is 0.2 (cc/g) or less. The method comprises the raw material preparation step of preparing the raw material for making cordierite including talc, the extrusion step of conducting the extrusionof the raw material for making cordierite to obtain the honeycomb formed body, the drying step of drying the honeycomb formed body, and the calcining step of calcining the honeycomb formed body. Talc as a raw material for making cordierite uses microcrystalline talc of which the ratio (111/006) of the strength of orientation (111) and the strength of orientation (006) among diffraction peaks by X-ray diffraction is 0.1 or more. It is preferable that the average particle size of talc is 20 μm or less. COPYRIGHT: (C)2010,JPO&INPIT
    • 解决的问题:提供一种具有大的基板强度的高强度的蜂窝结构体,并提供其制造方法。 解决方案:蜂窝结构体的制造方法与具有高强度的蜂窝结构体1的制造方法有关。 蜂窝状结构体由堇青石构成,具有以蜂窝状形成的细胞壁11和分隔在细胞壁11内的多个细胞12.作为细胞壁11的细孔总体积的总孔容积 的浓度为0.2(cc / g)以下。 该方法包括制备用于制造包含滑石的堇青石原料的原料制备步骤,用于制造堇青石原料的挤出以获得蜂窝成形体的挤出步骤,干燥蜂窝成形体的干燥步骤,以及 煅烧蜂窝成形体的煅烧步骤。 作为制造堇青石的原料的滑石使用通过X射线衍射测定的衍射峰的取向强度(111)和取向强度(006)的比(111/006)的微晶滑石为0.1以上。 滑石的平均粒径优选为20μm以下。 版权所有(C)2010,JPO&INPIT