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1. 发明申请

US20070167318A1 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US20070167318A1
公开(公告)日：2007-07-19
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
IPC分类号： B01J23/00
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

2. 发明授权

US07495132B2 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
IPC分类号： C07C45/65 , B01J23/42
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

3. 发明申请

US20070032681A1 Method for dehydrogenation of carbonyl compounds 失效
标题翻译：羰基化合物脱氢方法
公开(公告)号：US20070032681A1
公开(公告)日：2007-02-08
申请号：US10565730
申请日：2004-07-22
申请人： Christian Walsdorff , Beatrice Robler , Gotz-Peter Schindler , Joaquim Teles , Klaus Harth
发明人： Christian Walsdorff , Beatrice Robler , Gotz-Peter Schindler , Joaquim Teles , Klaus Harth
IPC分类号： C07C45/72
CPC分类号： C07C45/65 , B01J23/626 , B01J23/96 , B01J38/14 , Y02P20/584 , C07C49/597
摘要： Process for preparing alpha, beta-unsaturated acyclic or cyclic carbonyl compounds by dehydrogenation of the corresponding saturated carbonyl compounds in the gas phase over a heterogeneous dehydrogenation catalyst comprising platinum and/or palladium and tin on an oxidic support.
摘要翻译：通过相对于气相中的饱和羰基化合物在氧化载体上包含铂和/或钯和锡的异相脱氢催化剂脱氢来制备α，β-不饱和非环或环状羰基化合物的方法。

4. 发明授权

US07034195B2 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US07034195B2
公开(公告)日：2006-04-25
申请号：US10516920
申请日：2003-07-10
申请人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/333
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

5. 发明申请

US20050171311A1 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US20050171311A1
公开(公告)日：2005-08-04
申请号：US10516920
申请日：2003-07-10
申请人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： B01J23/62 , C07B61/00 , C07C5/333 , C07C11/167 , C08F36/00
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

6. 发明授权

US07193121B2 Method for producing 4-vinylcyclohexene, ethyl benzole and styrene 失效
标题翻译：制备4-乙烯基环己烯，乙基苯和苯乙烯的方法
公开(公告)号：US07193121B2
公开(公告)日：2007-03-20
申请号：US10501876
申请日：2003-02-17
申请人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
发明人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/32
CPC分类号： C07C5/367 , C07C2/52 , C07C13/20 , C07C15/073 , C07C15/46
摘要： The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.
摘要翻译：本发明涉及一种制备4-乙烯基环己烯的方法，其包括步骤（A）提供含正丁烷的进料气流，（B）将含正丁烷的进料气流进料至至少一个脱氢区和将正丁醇脱氢成丁二烯，得到包含丁二烯，正丁烷，可能的1-丁烯和2-丁烯以及可能的水蒸气和其他二次成分的产物流，（C）如果适当，将脱离后的产物流从分离出来水蒸气和次要成分，进入二聚化区域并催化二聚丁二烯，得到包含4-乙烯基环己烯，正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流，和（D）将4-乙烯基环己烯从来自二聚和再循环的正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流到脱氢区。

7. 发明授权

US07468463B2 Method for producing optically active carbonyl compounds 有权
标题翻译：光学活性羰基化合物的制造方法
公开(公告)号：US07468463B2
公开(公告)日：2008-12-23
申请号：US10591925
申请日：2005-03-04
申请人： Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人： Thorsten Johann , Oliver Löber , Eike Johannes Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
IPC分类号： C07C45/65
CPC分类号： C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要： The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译：本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心，通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢。

8. 发明申请

US20070191644A1 Method for producing optically active carbonyl compounds 有权
标题翻译：光学活性羰基化合物的制造方法
公开(公告)号：US20070191644A1
公开(公告)日：2007-08-16
申请号：US10591925
申请日：2005-03-04
申请人： Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
发明人： Thorsten Johann , Oliver Lober , Eike Bergner , Klaus Ebel , Klaus Harth , Christian Walsdorff
IPC分类号： C07C35/12 , C07C45/37
CPC分类号： C07C45/002 , C07B2200/07 , C07C2601/08 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C49/403 , C07C49/395 , C07C47/02 , C07C49/647
摘要： The present invention relates to a process for preparing optically active aldehydes or ketones which have from 3 to 25 carbon atoms and at least one racemizable stereocenter by catalytic dehydrogenation of the corresponding optically active primary or secondary alcohols in the gas phase in the presence of a catalyst.
摘要翻译：本发明涉及一种制备具有3至25个碳原子的光学活性醛或酮的方法和至少一种可消化的立体中心，通过在催化剂存在下在气相中相应的光学活性伯或仲醇的催化脱氢。

9. 发明申请

US20080008877A1 Catalytic Bulk Material Having Catalytically Inactive Shaped Bodies that are Rounded Off On the External Friction Surfaces 审中-公开
标题翻译：催化散装材料具有在外摩擦表面上圆化的催化非活性成形体
公开(公告)号：US20080008877A1
公开(公告)日：2008-01-10
申请号：US10574973
申请日：2004-10-08
申请人： Klaus Harth , Thorsten Johann , Christian Walsdorff , Otto Hofstadt , Michael Baier , Wolfgang Jürgen Pöpel , Karin Pöpel
发明人： Klaus Harth , Thorsten Johann , Christian Walsdorff , Otto Hofstadt , Michael Baier , Wolfgang Jürgen Pöpel , Karin Pöpel
IPC分类号： B01J35/08 , B01J37/00 , B32B5/02
CPC分类号： B01J19/30 , B01J23/002 , B01J35/0006 , B01J35/026 , B01J2208/0069 , B01J2208/025 , B01J2219/30203 , B01J2219/30211 , B01J2219/30215 , B01J2219/30223 , B01J2219/30475 , B01J2523/00 , Y10T428/268 , B01J2523/51 , B01J2523/55
摘要： Novel catalyst beds comprising a physical mixture of catalytically active and catalytically inactive shaped bodies, in which the catalytically inactive shaped bodies have rounded edges on the external rubbing surfaces.
摘要翻译：新型催化剂床包含催化活性和催化活性成形体的物理混合物，其中催化无活性成形体在外部摩擦表面上具有圆形边缘。

10. 发明申请

US20080200739A1 Catalyst For the Dehydrogenation or Hydrogenation of Hydrocarbons Containing Secondary Catalyst 失效
标题翻译：用于含二级催化剂的烃脱氢或氢化的催化剂
公开(公告)号：US20080200739A1
公开(公告)日：2008-08-21
申请号：US11996372
申请日：2006-07-13
申请人： Christian Walsdorff , Christophe Houssin , Gerald Vorberg , Reinhard Korner , Otto Hofstadt
发明人： Christian Walsdorff , Christophe Houssin , Gerald Vorberg , Reinhard Korner , Otto Hofstadt
IPC分类号： C07C5/00 , B01J23/58 , C07C5/327
CPC分类号： B01J37/0036 , B01J23/745 , B01J23/8872 , B01J37/04 , B01J38/02 , C07C5/3332 , C07C2523/745 , Y02P20/584 , C07C15/46
摘要： Catalysts comprising: a ground, spent (de)hydrogenation catalyst material present in an amount of 10 to 70% by weight based on the catalyst, the ground, spent catalyst material comprising iron oxide; and a fresh catalyst material present in an amount of 30 to 90% by weight based on the catalyst, the fresh catalyst material comprising iron oxide, wherein at least a portion of the iron oxide in the fresh catalyst material comprises a phase selected from the group consisting of hematite, potassium ferrite, and mixtures thereof are described along with processes for preparing and using the same.
摘要翻译：催化剂包括：基于催化剂的研磨，废催化剂材料，包含氧化铁的研磨，废（de）氢化催化剂材料，其量为10-70重量％和新鲜催化剂材料，其以基于催化剂的30至90重量％的量存在，新鲜催化剂材料包含氧化铁，其中新鲜催化剂材料中的至少一部分氧化铁包含选自以下的相：由赤铁矿，铁酸钾及其混合物组成，以及制备和使用它们的方法。

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