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1. 发明申请

US20070032681A1 Method for dehydrogenation of carbonyl compounds 失效
标题翻译：羰基化合物脱氢方法
公开(公告)号：US20070032681A1
公开(公告)日：2007-02-08
申请号：US10565730
申请日：2004-07-22
申请人： Christian Walsdorff , Beatrice Robler , Gotz-Peter Schindler , Joaquim Teles , Klaus Harth
发明人： Christian Walsdorff , Beatrice Robler , Gotz-Peter Schindler , Joaquim Teles , Klaus Harth
IPC分类号： C07C45/72
CPC分类号： C07C45/65 , B01J23/626 , B01J23/96 , B01J38/14 , Y02P20/584 , C07C49/597
摘要： Process for preparing alpha, beta-unsaturated acyclic or cyclic carbonyl compounds by dehydrogenation of the corresponding saturated carbonyl compounds in the gas phase over a heterogeneous dehydrogenation catalyst comprising platinum and/or palladium and tin on an oxidic support.
摘要翻译：通过相对于气相中的饱和羰基化合物在氧化载体上包含铂和/或钯和锡的异相脱氢催化剂脱氢来制备α，β-不饱和非环或环状羰基化合物的方法。

2. 发明申请

US20050124837A1 Preparation of alkenylaromatic compounds 审中-公开
标题翻译：烯基芳族化合物的制备
公开(公告)号：US20050124837A1
公开(公告)日：2005-06-09
申请号：US10501878
申请日：2003-01-20
申请人： Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
发明人： Christian Walsdorff , Michael Baier , Klaus Harth , Susanne Weber , Wilhelm Ruppel , Gotz-Peter Schindler
IPC分类号： C07B35/04 , C07C2/68 , C07C5/333 , C07C15/46 , C07D233/04
CPC分类号： C07C5/3332 , B01J23/83 , B01J37/0009 , B01J2523/00 , C07C2523/02 , C07C2523/10 , C07C2523/28 , C07C2523/745 , C07C15/46 , C07C15/52 , C07C15/44 , B01J2523/13 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/842
摘要： A process for preparing alkenylaromatic compounds by reacting alkylaromatic compounds in the presence of steam and natural gas or methane over a suitable catalyst at a temperature of from 400 to 800° C. and a pressure of from 0.01 to 10 bar, wherein the molar ratio of steam to alkylaromatic compound is from 6.9:1 to 1:1 or the molar ratio of methane to alkylaromatic compound is from 0.1:1 to 8:1.
摘要翻译：在蒸气和天然气或甲烷的存在下，在合适的催化剂上，在400-800℃的温度和0.01至10巴的压力下使烷基芳族化合物反应制备链烯基芳族化合物的方法，其中摩尔比蒸汽至烷基芳族化合物的摩尔比为6.9:1至1:1，或甲烷与烷基芳族化合物的摩尔比为0.1:1至8:1。

3. 发明申请

US20080262281A1 Catalyst Used for the Oxidation of Hydrogen, and Method for the Dehydrogenation of Hydrocarbons 审中-公开
标题翻译：用于氧化氢的催化剂和烃脱氢方法
公开(公告)号：US20080262281A1
公开(公告)日：2008-10-23
申请号：US11547500
申请日：2005-03-22
申请人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
发明人： Christian Walsdorff , Falk Simon , Gerald Vorberg , Gotz-Peter Schindler , Michael Hesse
IPC分类号： C07C5/327 , B01J23/42
CPC分类号： B01J23/626 , B01J21/04 , B01J35/1009 , B01J35/1014 , B01J37/0009 , C07C5/3337 , C07C2523/60 , C07C15/46
摘要： A catalyst for the oxidation of hydrogen in a process for the dehydrogenation of hydrocarbons, wherein the catalyst comprises, supported on α-aluminum oxide, from 0.01 to 0.1% by weight of platinum and from 0.01 to 0.1% by weight of tin, based on the total weight of the catalyst, a process for the oxidation of hydrogen and a process for the dehydrogenation of hydrocarbons with an integrated oxidation process using the catalyst described.
摘要翻译：一种在烃脱氢方法中氧化氢气的催化剂，其中催化剂包含负载在α-氧化铝上的0.01至0.1重量％的铂和0.01至0.1重量％的锡，基于催化剂的总重量，氢氧化的方法和使用所述催化剂的使用一体化氧化方法使烃脱氢的方法。

4. 发明申请

US20080167484A1 Process For Producing Propylene Oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US20080167484A1
公开(公告)日：2008-07-10
申请号：US11994129
申请日：2006-06-20
申请人： Gotz-Peter Schindler , Christian Walsdorff , Reinhard Korner , Hans-Georg Gobbel
发明人： Gotz-Peter Schindler , Christian Walsdorff , Reinhard Korner , Hans-Georg Gobbel
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention relates to a process for producing propylene oxide comprising (I) reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (GI) comprising propylene oxide, unreacted propene, and oxygen; (II) separating propylene oxide from mixture (GI) to give a mixture (GII) comprising propene and oxygen; (III) reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising Sn and at least one noble metal.
摘要翻译：本发明涉及一种生产环氧丙烷的方法，其包括（I）在催化剂存在下使丙烯与过氧化氢反应，得到包含环氧丙烷，未反应的丙烯和氧的混合物（GI）（II）将环氧丙烷与混合物（GI）分离，得到包含丙烯和氧的混合物（GII）; （III）在包含Sn和至少一种贵金属的催化剂的存在下至少部分地通过与氢反应来还原混合物（GII）中包含的氧。

5. 发明申请

US20070004926A1 Process for producing propylene oxide 审中-公开
标题翻译：生产环氧丙烷的方法
公开(公告)号：US20070004926A1
公开(公告)日：2007-01-04
申请号：US11168454
申请日：2005-06-29
申请人： Gotz-Peter Schindler , Christian Walsdorff , Reinhard Korner , Hans-Georg Gobbel
发明人： Gotz-Peter Schindler , Christian Walsdorff , Reinhard Korner , Hans-Georg Gobbel
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention relates to a process for producing propylene oxide comprising (I) reacting propene with hydrogen peroxide in the presence of a catalyst to give a mixture (GI) comprising propylene oxide, unreacted propene, and oxygen; (II) separating propylene oxide from mixture (GI) to give a mixture (GII) comprising propene and oxygen; (III) reducing the oxygen comprised in mixture (GII) at least partially by reaction with hydrogen in the presence of a catalyst comprising Sn and at least one noble metal.
摘要翻译：本发明涉及一种生产环氧丙烷的方法，其包括（I）在催化剂存在下使丙烯与过氧化氢反应，得到包含环氧丙烷，未反应的丙烯和氧的混合物（GI）（II）将环氧丙烷与混合物（GI）分离，得到包含丙烯和氧的混合物（GII）; （III）在包含Sn和至少一种贵金属的催化剂的存在下至少部分地通过与氢反应来还原混合物（GII）中包含的氧。

6. 发明申请

US20060046929A1 Zr02-base catalyst carrier and method for the production thereof 有权
标题翻译： ZrO 2 - 基催化剂载体及其制备方法
公开(公告)号：US20060046929A1
公开(公告)日：2006-03-02
申请号：US10513041
申请日：2003-05-02
申请人： Otto Hofstadt , Michael Hesse , Gotz-Peter Schindler , Klaus Harth , Falk Simon
发明人： Otto Hofstadt , Michael Hesse , Gotz-Peter Schindler , Klaus Harth , Falk Simon
IPC分类号： B01J31/00
CPC分类号： C07C5/3332 , B01J21/066 , B01J23/002 , B01J23/63 , B01J35/002 , B01J35/10 , B01J35/109 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C2521/06 , Y02P20/52 , C07C11/06 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
摘要翻译：本发明涉及制备催化剂载体的方法，其中如果需要，二氧化锆粉末与粘合剂混合，如果需要，成孔剂如果需要，可以使用酸，水，并且如果需要，可提供另外的添加剂以得到可捏合组合物和组合物均化，成型以产生成形体，干燥和煅烧，其中粘合剂是单体，低聚或聚合的有机硅化合物。合适的粘合剂是单体，低聚或聚合硅烷，烷氧基硅烷，芳氧基硅烷，丙烯酰氧硅烷，肟基硅烷，卤代硅烷，氨基硅烷，氨基硅烷，酰胺基硅烷，硅氮烷或硅氧烷。本发明还提供了以这种方式制备的催化剂载体，包含载体的催化剂及其作为脱氢催化剂的用途。

7. 发明申请

US20050245751A1 Integrated method for synthesis propylene oxide 有权
标题翻译：合成环氧丙烷的综合方法
公开(公告)号：US20050245751A1
公开(公告)日：2005-11-03
申请号：US10526045
申请日：2003-08-29
申请人： Michael Bender , Peter Zehner , Otto Machhammer , Ulrich Muller , Klaus Harth , Gotz-Peter Schindler , Henrik Junicke
发明人： Michael Bender , Peter Zehner , Otto Machhammer , Ulrich Muller , Klaus Harth , Gotz-Peter Schindler , Henrik Junicke
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/125 , Y02P20/582
摘要： The present invention relates to an integrated process for the synthesis of propylene oxide, which comprises at least the following steps: (i) dehydrogenation of propane to give a substream T (0) comprising at least propane, propene and hydrogen; (ii) fractionation of the substream T (0) to give at least one gaseous hydrogen-rich substream T (2) and a substream T (1) comprising at least propene and propane; (iii) synthesis of hydrogen peroxide using the substream T (2), giving a substream T (4) which is rich in hydrogen peroxide and a gaseous substream T (6); (iv) fractionation of the substream T (1) to give at least one propane-rich substream T (5) and at least one propene-rich substream T (3); (v) reaction of the at least one substream T (3) with substream T (4) to give propylene oxide.
摘要翻译：本发明涉及一种用于合成环氧丙烷的综合方法，其包括至少以下步骤：（i）丙烷脱氢得到至少包含丙烷，丙烯和氢的分支T（O）; （ii）分流T（0）以产生至少一个富含气体的气流T（2）和至少包含丙烯和丙烷的子流T（1）; （iii）使用子流T（2）合成过氧化氢，得到富含过氧化氢的气流T（4）和气态分支T（6）; （iv）分流T（1）以产生至少一个富含丙烷的子流T（5）和至少一个富含丙烯的子流T（3）; （v）至少一个子流T（3）与子流T（4）的反应，得到环氧丙烷。

8. 发明申请

US20050119515A1 Partial dehydrogenation method using continuous heterogeneous catalysis 有权
标题翻译：使用连续多相催化的部分脱氢方法
公开(公告)号：US20050119515A1
公开(公告)日：2005-06-02
申请号：US10507001
申请日：2003-03-04
申请人： Otto Machhammer , Gotz-Peter Schindler , Klaus Harth , Peter Zehner
发明人： Otto Machhammer , Gotz-Peter Schindler , Klaus Harth , Peter Zehner
IPC分类号： B01J23/62 , B01J8/02 , B01J19/26 , B01J27/199 , C07B61/00 , C07C5/333 , C07C11/06 , C07C11/08 , C07C11/09 , C07C45/33 , C07C45/35 , C07C5/327
CPC分类号： B01J19/26 , B01J8/025 , B01J8/0278 , B01J23/002 , B01J27/199 , B01J2523/00 , C07C45/33 , C07C45/35 , Y02P20/582 , C07C47/22 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： A process for the continuous heterogeneously catalyzed partial dehydrogenation of a hydrocarbon in the gas phase and in the presence of molecular oxygen, in which part of the product gas is recirculated to the reaction zone, and a reactor for carrying out such a process.
摘要翻译：在气相和分子氧存在下，烃的连续不均匀催化部分脱氢的方法，其中部分产物气体再循环到反应区，以及用于进行这种方法的反应器。

9. 发明申请

US20070244349A1 Method for Producing Butadiene From N-Butane 有权
标题翻译：从丁烷生产丁二烯的方法
公开(公告)号：US20070244349A1
公开(公告)日：2007-10-18
申请号：US11718814
申请日：2005-11-11
申请人： Sven Crone , Catharina Klanner , Gotz-Peter Schindler , Mark Duda , Frieder Borgmeier
发明人： Sven Crone , Catharina Klanner , Gotz-Peter Schindler , Mark Duda , Frieder Borgmeier
IPC分类号： C07C5/333 , C07C11/167
CPC分类号： C07C7/09 , C07C5/333 , C07C11/167
摘要： Processes for producing butadiene from n-butane comprising: (a) providing a feed gas stream comprising n-butane; (b) non-oxidatively dehydrogenating the feed gas stream in the presence of a catalyst in a first dehydrogenation zone to form a first intermediate gas stream comprising n-butane, 1-butene, 2-butene, butadiene and hydrogen; (c) oxidatively dehydrogenating the first intermediate gas stream in the presence of an oxygenous gas having an oxygen content of at least 75% by volume in a second dehydrogenation zone to form a second intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (d) compressing and cooling the second intermediate gas to form a first condensate stream comprising water and a third intermediate gas stream comprising n-butane, butadiene, hydrogen, carbon dioxide and steam; (e) compressing and cooling the third intermediate gas to form a second condensate stream comprising n-butane, butadiene and water and a fourth intermediate gas stream comprising n-butane, butadiene, hydrogen and carbon dioxide; (f) cooling the fourth intermediate gas stream to form a third condensate stream comprising n-butane and butadiene, and an offgas stream comprising carbon dioxide and hydrogen; (g) removing water from the second condensate stream and combining the second condensate stream and third condensate stream to form a C4 hydrocarbon stream comprising n-butane and butadiene; and (h) separating the C4 hydrocarbon stream to form a recycle stream comprising n-butane and a product stream comprising butadiene; wherein at least a portion of the recycle stream is fed to the first dehydrogenation zone.
摘要翻译：用于从正丁烷生产丁二烯的方法包括：（a）提供包含正丁烷的进料气流; （b）在催化剂存在下在第一脱氢区中使进料气流非氧化脱氢，以形成包含正丁烷，1-丁烯，2-丁烯，丁二烯和氢的第一中间气流; （c）在第二脱氢区中在氧含量至少为75体积％的氧气存在下，使第一中间气流氧化脱氢以形成包含正丁烷，丁二烯，氢，碳的第二中间气流二氧化碳和蒸汽; （d）压缩和冷却第二中间气体以形成包含水的第一冷凝物流和包含正丁烷，丁二烯，氢气，二氧化碳和蒸汽的第三中间气流; （e）压缩和冷却第三中间气体以形成包含正丁烷，丁二烯和水的第二冷凝物流和包含正丁烷，丁二烯，氢气和二氧化碳的第四中间气流; （f）冷却第四中间气流以形成包含正丁烷和丁二烯的第三冷凝物流和包含二氧化碳和氢气的废气流; （g）从第二冷凝物流中除去水并将第二冷凝物流和第三冷凝物流合并以形成包含正丁烷和丁二烯的C 4烃流; 和（h）分离C 4 O 4烃流以形成包含正丁烷和包含丁二烯的产物流的再循环料流; 其中所述再循环流的至少一部分被供给到所述第一脱氢区。

10. 发明申请

US20050107628A1 Modified method for producing surfactant alcohols and surfactant alcohol ethers, the products of said method and use of the same 审中-公开
标题翻译：用于生产表面活性剂醇和表面活性剂醇醚的改性方法，所述方法的用途和使用方法相同
公开(公告)号：US20050107628A1
公开(公告)日：2005-05-19
申请号：US10503213
申请日：2003-02-19
申请人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
发明人： Michael Roper , Jurgen Stephan , Gotz-Peter Schindler , Jurgen Tropsch , Thomas Heidemann , Martina Prinz , Soeren Zimdahl
IPC分类号： C07B61/00 , C07C2/00 , C07C2/06 , C07C2/10 , C07C6/04 , C07C11/02 , C07C11/107 , C07C29/141 , C07C29/16 , C07C31/125 , C07C41/03 , C07C45/50 , C07C47/21 , C07C9/00 , C07C27/12 , C07F9/02 , C07H13/02
CPC分类号： C07C29/141 , C07C2/06 , C07C6/04 , C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： A process for preparing surfactant alcohols and surfactant alcohol ethers by derivatization of olefins having about 10 to 20 carbon atoms or of mixtures of such olefins and optional subsequent alkoxylation is described. As features, the process involves (a) subjecting a C4-olefin mixture with a 1-butene/2-butene ratio of ≧1.2 to a metathesis, (b) separating off olefins having 5 to 8 carbon atoms from the metathesis mixture, (c) subjecting the separated-off olefins individually or in a mixture to a dimerization to give olefin mixtures having 10 to 16 carbon atoms, (d) subjecting the resulting olefin mixture, optionally after a fractionation, to derivatization to give a mixture of surfactant alcohols and (e) optionally alkoxylating the surfactant alcohols. The olefin mixture obtained in the dimerization comprises a high content of branched components and less than 10% by weight of compounds which contain a vinylidene group. Also described is the use of surfactant alcohols and surfactant alcohol ethers to give surfactans by glycosidation or polyglycosidation, sulfation or phosphation.
摘要翻译：描述了通过衍生具有约10至20个碳原子的烯烃或这种烯烃的混合物和任选的随后的烷氧基化来制备表面活性剂醇和表面活性剂醇醚的方法。作为特征，该方法包括（a）使具有> = 1.2的1-丁烯/ 2-丁烯比的C 4 - 4 - 烯烃混合物复分解，（b）将具有5至（c）将单独或混合物中的分离的烯烃进行二聚，得到具有10至16个碳原子的烯烃混合物，（d）任选地在分馏之后对所得烯烃混合物进行处理，衍生化得到表面活性剂醇的混合物和（e）任选地使表面活性剂醇烷氧基化。在二聚中获得的烯烃混合物包含高含量的支链组分和小于10重量％的含有亚乙烯基的化合物。还描述了表面活性剂醇和表面活性剂醇醚通过糖基化或多糖苷化，硫酸化或磷酸化来提供表面活性剂的用途。

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