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1. 发明授权

US07193121B2 Method for producing 4-vinylcyclohexene, ethyl benzole and styrene 失效
标题翻译：制备4-乙烯基环己烯，乙基苯和苯乙烯的方法
公开(公告)号：US07193121B2
公开(公告)日：2007-03-20
申请号：US10501876
申请日：2003-02-17
申请人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
发明人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/32
CPC分类号： C07C5/367 , C07C2/52 , C07C13/20 , C07C15/073 , C07C15/46
摘要： The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.
摘要翻译：本发明涉及一种制备4-乙烯基环己烯的方法，其包括步骤（A）提供含正丁烷的进料气流，（B）将含正丁烷的进料气流进料至至少一个脱氢区和将正丁醇脱氢成丁二烯，得到包含丁二烯，正丁烷，可能的1-丁烯和2-丁烯以及可能的水蒸气和其他二次成分的产物流，（C）如果适当，将脱离后的产物流从分离出来水蒸气和次要成分，进入二聚化区域并催化二聚丁二烯，得到包含4-乙烯基环己烯，正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流，和（D）将4-乙烯基环己烯从来自二聚和再循环的正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流到脱氢区。

2. 发明授权

US07034195B2 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US07034195B2
公开(公告)日：2006-04-25
申请号：US10516920
申请日：2003-07-10
申请人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/333
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

3. 发明申请

US20050171311A1 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US20050171311A1
公开(公告)日：2005-08-04
申请号：US10516920
申请日：2003-07-10
申请人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Goetz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： B01J23/62 , C07B61/00 , C07C5/333 , C07C11/167 , C08F36/00
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

4. 发明授权

US07495132B2 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US07495132B2
公开(公告)日：2009-02-24
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Roessler , Hartmut Hibst , Joaquim Henrique Teles , Sebastian Storck , Jens Klein
IPC分类号： C07C45/65 , B01J23/42
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

5. 发明申请

US20070167318A1 Catalytically active composition and the use thereof in dehydration methods 失效
标题翻译：催化活性组合物及其在脱水方法中的应用
公开(公告)号：US20070167318A1
公开(公告)日：2007-07-19
申请号：US10587191
申请日：2005-01-28
申请人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
发明人： Christian Walsdorff , Thorsten Johann , Beatrice Rossler , Hartmut Hibst , Joaquim Teles , Sebastian Storck , Jens Klein
IPC分类号： B01J23/00
CPC分类号： C07C45/65 , B01J23/6445 , B01J23/6447 , B01J23/6522 , B01J23/681 , B01J23/8973 , B01J35/008 , B01J37/0201 , B01J37/0221 , B01J37/03 , C07C47/21 , C07C49/603
摘要： The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.
摘要翻译：本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

6. 发明授权

US5693340A Delayed-release form for pharmaceutical active compounds 失效
标题翻译：药物活性化合物的延迟释放形式
公开(公告)号：US5693340A
公开(公告)日：1997-12-02
申请号：US727314
申请日：1996-10-08
申请人： Klaus Harth , Hartmut Hibst , Juergen Dembowski , Reinhard Spengler , Ernst Flaig
发明人： Klaus Harth , Hartmut Hibst , Juergen Dembowski , Reinhard Spengler , Ernst Flaig
IPC分类号： A61K9/32 , A61K9/22 , A61K9/28 , A61K9/50 , A61K9/52 , A61K47/34 , A61K9/16 , A61K9/30
CPC分类号： A61K9/5031 , A61K9/5089
摘要： A novel delayed-release form for pharmaceutical active compounds, characterized by a core containing the active compound and a diffusion-inhibiting, adhesive coating layer having a thickness in the range from 0.01 to 10 .mu.m, consisting of a chemical network which has been applied to the support in a plasma-assisted chemical deposition process, and a process for its production are described.
摘要翻译：一种用于药物活性化合物的新型延迟释放形式，其特征在于含有活性化合物的核心和具有0.01至10μm的厚度的扩散抑制性粘合剂涂层，其由已应用的化学网络组成涉及等离子体辅助化学沉积工艺中的载体，并描述了其生产方法。

7. 发明授权

US5620743A Coating or surface treatment of solid particles by means of a plasma fluidized bed 失效
标题翻译：通过等离子体流化床涂覆或表面处理固体颗粒
公开(公告)号：US5620743A
公开(公告)日：1997-04-15
申请号：US348866
申请日：1994-11-29
申请人： Klaus Harth , Hartmut Hibst , Wolfgang Mattmann
发明人： Klaus Harth , Hartmut Hibst , Wolfgang Mattmann
IPC分类号： B01J19/08 , B01J2/00 , C23C16/44 , C23C16/442 , C23C16/452 , C23C16/50 , C23C16/511 , B05D7/00
CPC分类号： C23C16/50 , C23C16/4417 , C23C16/442 , C23C16/452
摘要： Solid particles are coated in a fluidized bed by application of a gaseous coating agent from a plasma, wherein the plasma is generated outside the fluidized bed under 0.01-500 mbar, and the plasma-activated gas is passed into the fluidized bed, which is operated under 0.1-500 mbar, wherea. the plasma is generated from the total amount of gaseous coating agent with or without another gas, orb. the plasma is generated from a portion of the gaseous coating agent with or without another gas, and the remaining portion is introduced directly into the fluidized bed, orc. the plasma is generated from another gas, and the total amount of gaseous coating agent is introduced directly into the fluidized bed.
摘要翻译：通过施加来自等离子体的气态涂层剂将固体颗粒涂覆在流化床中，其中在0.01-500毫巴下在流化床外部产生等离子体，并且等离子体活化气体进入流化床，其被操作低于0.1-500毫巴，其中a。等离子体由具有或不具有另外气体的气体涂覆剂的总量产生，或b。等离子体由具有或不具有另一种气体的一部分气态涂覆剂产生，并且剩余部分直接引入流化床，或c。等离子体由另一种气体产生，气态涂料的总量直接引入到流化床中。

8. 发明授权

US5559065A Coated catalysts 失效
标题翻译：涂层催化剂
公开(公告)号：US5559065A
公开(公告)日：1996-09-24
申请号：US305817
申请日：1994-09-14
申请人： Guenter Lauth , Wolfgang Hoelderich , Klaus Harth , Hartmut Hibst
发明人： Guenter Lauth , Wolfgang Hoelderich , Klaus Harth , Hartmut Hibst
IPC分类号： B01J23/38 , B01J23/42 , B01J23/44 , B01J23/70 , B01J23/72 , B01J25/00 , B01J37/02 , B01J37/34 , B01J23/40
CPC分类号： B01J23/72 , B01J23/42 , B01J23/44 , B01J37/0238 , B01J37/347 , B01J23/38 , B01J23/70 , B01J25/00 , B01J37/0221
摘要： A coated catalyst is prepared by depositing an alloy by physical vapor deposition and/or chemical vapor deposition on a molding, at least one alloy component being a metal selected from the group consisting of aluminum, gallium, silicon, germanium, tin, lead, bismuth, yttrium, titanium, zirconium, vanadium, niobium, tantalum, chromium, molybdenum, tungsten, iron, cobalt, ruthenium, rhodium, palladium, osmium, iridium, platinum, copper, silver, gold and zinc.
摘要翻译：通过将物理气相沉积和/或化学气相沉积在合金上沉积合金来制备涂覆的催化剂，至少一种合金成分是选自铝，镓，硅，锗，锡，铅，铋的金属，钇，钛，锆，钒，铌，钽，铬，钼，钨，铁，钴，钌，铑，钯，锇，铱，铂，铜，银，金和锌。

9. 发明授权

US5667861A Magneto-optical disk 失效
标题翻译：磁光盘
公开(公告)号：US5667861A
公开(公告)日：1997-09-16
申请号：US663516
申请日：1991-03-04
申请人： Klaus Harth , Hartmut Hibst
发明人： Klaus Harth , Hartmut Hibst
IPC分类号： G11B11/10 , G11B11/105 , G11B5/66
CPC分类号： G11B11/10586 , Y10S428/90 , Y10T428/12458
摘要： A magneto-optical disk having at least one optically transparent, dimensionally stable substrate and at least one magneto-optical recording layer of a chromium-containing lanthanide/transition metal alloy, wherein the chromium concentration changes in the horizontal direction, and a process for the producton of the magneto-optical disks.
摘要翻译：一种磁光盘，其具有至少一个光学透明的尺寸稳定的基底和含铬的镧系元素/过渡金属合金的至少一个磁光记录层，其中铬浓度在水平方向上变化，磁光盘的产品。

10. 发明授权

US5193085A Magneto-optical recording medium with exchange-coupled reproducing layer containing platinum 失效
标题翻译：具有交换耦合复合层的MAGNETO-OPTICAL记录介质
公开(公告)号：US5193085A
公开(公告)日：1993-03-09
申请号：US761131
申请日：1991-09-17
申请人： Klaus Harth , Hartmut Hibst
发明人： Klaus Harth , Hartmut Hibst
IPC分类号： G11B5/66 , G11B11/10 , G11B11/105
CPC分类号： G11B5/66 , G11B11/10586
摘要： In a magnetooptical computer disk having one or more optically transparent dimensionally stable substrates and one or more double layer systems consisting of two exchange-coupled magnetic layers which consist of alloys of rare earth metals with transition metals and have vertical magnetic anisotropy, the first magnetic layer adjacent to the substrate has a composition corresponding to the formula IRE.sub.x TM.sub.100-x-y-a Pt.sub.y A.sub.a Iand the second magnetic layer, which is arranged on that side of the first magnetic layer which faces away from the substrate, has a composition corresponding to the formula IIRE.sub.u TM.sub.100-u-b B.sub.b IIwhereRE is one or more elements from the group consisting of Gd, Tb, Dy and Ho,TM is one or more elements from the group consisting of Fe and Co,A and B independently of one another are elements from the group consisting of Cr, Nb, Ta, Al, Si, Ni and Mo,and5.ltoreq.x.ltoreq.30,0.5.ltoreq.y.ltoreq.20,15.ltoreq.u.ltoreq.30,0.ltoreq.a.ltoreq.25 and0.5.ltoreq.b.ltoreq.25.
摘要翻译：在具有一个或多个光学透明的尺寸稳定的基板和一个或多个双层系统的磁光计算机盘中，所述双层系统由由稀土金属与过渡金属的合金构成并且具有垂直的磁各向异性的两个交换耦合磁性层组成，第一磁性层与基板相邻的具有对应于式I的组成RExTM100-xy-aPtyAa和布置在第一磁性层背离基板的那侧的第二磁性层具有对应于式II的组成 REuTM100-u-bBb II其中RE是由Gd，Tb，Dy和Ho组成的组中的一种或多种元素，TM是由Fe和Co组成的组中的一种或多种元素，A和B彼此独立地是元素来自由Cr，Nb，Ta，Al，Si，Ni和Mo组成的组，5≤x≤30,0.5≤y≤20,15 30， 0

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