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1. 发明授权

US07193121B2 Method for producing 4-vinylcyclohexene, ethyl benzole and styrene 失效
标题翻译：制备4-乙烯基环己烯，乙基苯和苯乙烯的方法
公开(公告)号：US07193121B2
公开(公告)日：2007-03-20
申请号：US10501876
申请日：2003-02-17
申请人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
发明人： Christian Walsdorff , Götz-Peter Schindler , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/32
CPC分类号： C07C5/367 , C07C2/52 , C07C13/20 , C07C15/073 , C07C15/46
摘要： The invention relates to a process for preparing 4-vinylcyclohexene, which comprises the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into at least one dehydrogenation zone and dehydrogenating n-butane to butadiene to give a product stream comprising butadiene, n-butane, possibly 1-butene and 2-butene and possibly water vapor and other secondary constituents, (C) feeding the product stream from dehydrogenation, if appropriate after separating off water vapor and secondary constituents, into a dimerization zone and catalytically dimerizing butadiene to give a product stream comprising 4-vinylcyclohexene, n-butane and possibly 1-butene, 2-butene and unreacted butadiene, and (D) separating off 4-vinylcyclohexene from the product stream from the dimerization and recirculating n-butane and possibly 1-butene, 2-butene and unreacted butadiene to the dehydrogenation zone.
摘要翻译：本发明涉及一种制备4-乙烯基环己烯的方法，其包括步骤（A）提供含正丁烷的进料气流，（B）将含正丁烷的进料气流进料至至少一个脱氢区和将正丁醇脱氢成丁二烯，得到包含丁二烯，正丁烷，可能的1-丁烯和2-丁烯以及可能的水蒸气和其他二次成分的产物流，（C）如果适当，将脱离后的产物流从分离出来水蒸气和次要成分，进入二聚化区域并催化二聚丁二烯，得到包含4-乙烯基环己烯，正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流，和（D）将4-乙烯基环己烯从来自二聚和再循环的正丁烷和可能的1-丁烯，2-丁烯和未反应的丁二烯的产物流到脱氢区。

2. 发明授权

US07034195B2 Method for the production of butadiene from n-butane 失效
标题翻译：从正丁烷生产丁二烯的方法
公开(公告)号：US07034195B2
公开(公告)日：2006-04-25
申请号：US10516920
申请日：2003-07-10
申请人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
发明人： Götz-Peter Schindler , Christian Walsdorff , Klaus Harth , Hartmut Hibst
IPC分类号： C07C5/333
CPC分类号： C07C5/3335 , C07C5/3337 , C07C11/167
摘要： The invention relates to a process for preparing butadiene from n-butane comprising the steps (A) providing an n-butane-containing feed gas stream, (B) feeding the n-butane-containing feed gas stream into a first dehydrogenation zone and nonoxidatively catalytically dehydrogenating n-butane to 1-butene, 2-butene and optionally butadiene to obtain a first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, (C) feeding the first product gas stream comprising n-butane, 1-butene and 2-butene, with or without butadiene and secondary components, into a second dehydrogenation zone and oxidatively dehydrogenating 1-butene and 2-butene to butadiene to give a second product gas stream comprising butadiene, n-butane and steam, with or without secondary components, (D) recovering butadiene from the second product gas stream.
摘要翻译：本发明涉及一种从正丁烷制备丁二烯的方法，包括步骤（A）提供含正丁烷的原料气流，（B）将含正丁烷的进料气流进料到第一脱氢区和非氧化反应将正丁烷催化脱氢为1-丁烯，2-丁烯和任选的丁二烯以获得含有或不具有丁二烯和二级组分的正丁烷，1-丁烯和2-丁烯的第一产物气流，（C）将包含或不具有丁二烯和次要组分的正丁烷，1-丁烯和2-丁烯的产物气流转化为第二脱氢区并将1-丁烯和2-丁烯氧化脱氢成丁二烯，得到包含丁二烯的第二产物气流正丁烷和蒸汽，具有或没有二级组分，（D）从第二产物气流回收丁二烯。

3. 发明授权

US07285685B2 Method for dehydrogenation of carbonyl compounds 失效
公开(公告)号：US07285685B2
公开(公告)日：2007-10-23
申请号：US10565730
申请日：2004-07-22
申请人： Christian Walsdorff , Beatrice Rössler , Götz-Peter Schindler , Joaquim H. Teles , Klaus Harth
发明人： Christian Walsdorff , Beatrice Rössler , Götz-Peter Schindler , Joaquim H. Teles , Klaus Harth
IPC分类号： C07C45/65
CPC分类号： C07C45/65 , B01J23/626 , B01J23/96 , B01J38/14 , Y02P20/584 , C07C49/597
摘要： Process for preparing alpha, beta-unsaturated acyclic or cyclic carbonyl compounds by dehydrogenation of the corresponding saturated carbonyl compounds in the gas phase over a heterogeneous dehydrogenation catalyst comprising platinum and/or palladium and tin on an oxidic support.

4. 发明授权

US06900363B2 Method for the production of 1,2-dichloroethane 失效
标题翻译：生产1,2-二氯乙烷的方法
公开(公告)号：US06900363B2
公开(公告)日：2005-05-31
申请号：US10497598
申请日：2002-12-04
申请人： Klaus Harth , Götz-Peter Schindler , Christian Walsdorff , Christian Kuhrs , Falk Simon
发明人： Klaus Harth , Götz-Peter Schindler , Christian Walsdorff , Christian Kuhrs , Falk Simon
IPC分类号： C07C17/02 , C07C17/15 , C07C17/152 , C07C17/156 , C07C17/158 , C07C17/25 , C07C17/38 , C07C19/045 , C07C21/06
CPC分类号： C07C17/02 , C07C17/156 , C07C19/045
摘要： A process for preparing 1,2-dichloroethane which comprises (A) feeding an ethane-containing feed gas stream into a dehydrogenation zone and dehydrogenating ethane to ethane to give a product gas stream comprising ethane, ethane and secondary constituents, (B) feeding the ethan- and ethene-containing dehydrogenation product gas stream as a single stream or a plurality of substreams, optionally after having separated off secondary constituents, into one or more chlorination zones, chlorinating ethene to 1,2-dichloroethane to give one or more product gas streams comprising 1,2-dichloroethane, ethane and possibly further secondary constituents, isolating 1,2-dichloroethane and one or more ethane-containing circulating gas streams and recirculating the ethane-containing circulating gas stream or streams to the ethane dehydrogenation.
摘要翻译：一种制备1,2-二氯乙烷的方法，其包括（A）将含乙烷的原料气流送入脱氢区并将乙烷脱氢为乙烷，得到包含乙烷，乙烷和第二组分的产物气流，（B）含有乙烯和乙烯的脱氢产物气流作为单一流或多个子流，任选地在分离出次级成分后，形成一个或多个氯化区，将乙烯氯化成1,2-二氯乙烷，得到一种或多种产物气体包含1,2-二氯乙烷，乙烷和可能的其它二级成分的物流，分离1,2-二氯乙烷和一种或多种含乙烷的循环气流，并将含乙烷的循环气流或物流再循环到乙烷脱氢。

5. 发明授权

US07038098B2 Method for dehydrogenating C2-C30-alkanes 失效
标题翻译： C2-C30-烷烃脱氢方法
公开(公告)号：US07038098B2
公开(公告)日：2006-05-02
申请号：US10491906
申请日：2002-10-14
申请人： Christian Walsdorff , Götz-Peter Schindler , Otto Machhammer , Klaus Harth
发明人： Christian Walsdorff , Götz-Peter Schindler , Otto Machhammer , Klaus Harth
IPC分类号： C07C5/333 , C07C5/367
CPC分类号： C07C5/48 , C07C5/327 , C07C5/333 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/42 , C07C2523/44 , C07C2523/74 , C07C15/46
摘要： C2–C30-alkanes are dehydrogenated in a process in which (i) ethylbenzene is dehydrogenated to styrene in a first part process to give a hydrogen-containing offgas stream, and (ii) one or more C2–C30-alkanes are dehydrogenated in the presence of a heterogeneous catalyst in one or more reaction zones in a second part process to give the corresponding olefins, with a hydrogen-containing gas stream being mixed into the reaction gas mixture of the dehydrogenation in at least one reaction zone, wherein at least part of the hydrogen-containing offgas stream obtained in the dehydrogenation of ethylbenzene is mixed into the reaction gas mixture of the alkane dehydrogenation.
摘要翻译：在第一部分方法中，（ⅰ）乙苯脱氢成苯乙烯的方法中，将C 2 -C 30烷基脱氢，得到含氢废气流，和（ii）一种或多种C 2 -C 30 - 烷烃在非均相催化剂存在下在一个或多个反应区中在第二部分方法中脱氢，得到将相应的烯烃与含氢气流混合到至少一个反应区中的脱氢反应气体混合物中，其中在乙苯脱氢中获得的至少部分含氢废气流混合到反应器烷烃脱气的气体混合物。

6. 发明授权

US07850842B2 Zr02-base catalyst carrier and method for the production thereof 有权
标题翻译： ZrO 2 - 基催化剂载体及其制备方法
公开(公告)号：US07850842B2
公开(公告)日：2010-12-14
申请号：US10513041
申请日：2003-05-02
申请人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
发明人： Otto Hofstadt , Michael Hesse , Götz-Peter Schindler , Klaus Harth , Falk Simon
IPC分类号： C10G35/06 , B01J23/00 , B01J21/00 , B01J20/00
CPC分类号： C07C5/3332 , B01J21/066 , B01J23/002 , B01J23/63 , B01J35/002 , B01J35/10 , B01J35/109 , B01J37/0009 , B01J37/0018 , B01J2523/00 , C07C2521/06 , Y02P20/52 , C07C11/06 , B01J2523/13 , B01J2523/15 , B01J2523/3706 , B01J2523/41 , B01J2523/43 , B01J2523/48 , B01J2523/828
摘要： The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.
摘要翻译：本发明涉及制备催化剂载体的方法，其中如果需要，二氧化锆粉末与粘合剂混合，如果需要，成孔剂如果需要，可以使用酸，水，并且如果需要，可提供另外的添加剂以得到可捏合组合物和组合物均化，成型以产生成形体，干燥和煅烧，其中粘合剂是单体，低聚或聚合的有机硅化合物。合适的粘合剂是单体，低聚或聚合硅烷，烷氧基硅烷，芳氧基硅烷，丙烯酰氧硅烷，肟基硅烷，卤代硅烷，氨基硅烷，氨基硅烷，酰胺基硅烷，硅氮烷或硅氧烷。本发明还提供了以这种方式制备的催化剂载体，包含载体的催化剂及其作为脱氢催化剂的用途。

7. 发明申请

US20060122436A1 Method for producing aldehydes from alkanes 审中-公开
标题翻译：从烷烃生产醛的方法
公开(公告)号：US20060122436A1
公开(公告)日：2006-06-08
申请号：US10533959
申请日：2003-11-03
申请人： Götz-Peter Schindler , Rocco Paciello , Klaus Harth
发明人： Götz-Peter Schindler , Rocco Paciello , Klaus Harth
IPC分类号： C07C45/50
CPC分类号： C07C45/72 , C07C5/42 , C07C29/141 , C07C45/50 , Y02P20/125 , C07C31/125 , C07C47/02 , C07C11/06 , C07C11/08
摘要： Process for preparing saturated aliphatic Cn-aldehydes and Cn-1-alkanes, where n is from 4 to 20, which comprises a) providing a feed gas stream comprising one or more Cn-1-alkanes, b) subjecting the Cn-1-alkanes to a catalytic dehydrogenation to give a product gas stream comprising unreacted Cn-1-alkanes, one or more Cn-1-alkenes and secondary constituents, c) at least partly hydroformylating the Cn-1-alkenes in the presence of the Cn-1-alkanes and possibly the secondary constituents by means of carbon monoxide and hydrogen in the presence of a hydroformylation catalyst to give the Cn-aldehydes, d) separating the product mixture obtained to give a stream comprising the Cn-aldehydes and a stream comprising Cn-1-alkanes and possibly secondary constituents, e) recirculating at least part of the gas stream comprising the Cn-1-alkanes and possibly the secondary constituents as recycle gas stream to the catalytic alkane dehydrogenation (step b)).
摘要翻译：制备饱和脂肪族C n - 醛和C n-1-N烷烃的方法，其中n为4至20，其包括a）提供包含一种或更多的C 1〜n烷烃，b）使C 1 -C 12烷烃进行催化脱氢，得到包含未反应的C n的产物气流 -1个 - 烷烃，一个或多个C n-1 - 烯烃和第二组分，c）至少部分地将C 1 -C 6 - 亚烷基在加氢甲酰化催化剂存在下，通过一氧化碳和氢气存在C n-1 - 烷烃并且可能存在第二成分，得到C 1 -C 6烷基，d）将得到的产物混合物分离得到包含C 1 -C 4烷基的物流和包含C 1〜N 2烷烃的物流，并且可能是二级成分，e）循环气流的至少一部分包含C n-1 - 烷烃，并且可能是二级的 y成分作为催化烷烃脱氢的再循环气流（步骤b））。

8. 发明申请

US20120091068A1 METHOD FOR PHOTOCATALYTIC WATER PURIFICATION 审中-公开
标题翻译：光化学水净化方法
公开(公告)号：US20120091068A1
公开(公告)日：2012-04-19
申请号：US13378100
申请日：2010-06-23
申请人： Florina Corina Patcas , Grigorios Kolios , Götz-Peter Schindler , Peter Pfab , Reinhard Hess
发明人： Florina Corina Patcas , Grigorios Kolios , Götz-Peter Schindler , Peter Pfab , Reinhard Hess
IPC分类号： C02F1/32
CPC分类号： C02F1/32 , C02F1/725 , C02F2103/10 , C02F2103/28 , C02F2103/36 , C02F2103/365
摘要： The present invention relates to a process for the purification of a contaminant-containing stream by bringing the stream to be purified into contact with a heterogeneous photocatalyst with irradiation with light, where the bringing into contact takes place in the presence of at least one compound dissolved in the stream and comprising at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese and mixtures thereof, and to the use of a heterogeneous photocatalyst for the purification of a contaminant-containing stream, where, in the stream to be purified, at least one compound comprising at least one metal selected from the group consisting of iron, chromium, nickel, cobalt, manganese and mixtures thereof is present in dissolved form.
摘要翻译：本发明涉及一种通过使待纯化物流与异质光催化剂接触的方法，该方法是用光照射进行，其中在存在至少一种溶解的化合物的情况下进行接触并且包含至少一种选自铁，铬，镍，钴，锰及其混合物的金属，以及使用异相光催化剂来净化含污染物流，其中在要纯化的物流，至少一种包含至少一种选自铁，铬，镍，钴，锰及其混合物的金属的化合物以溶解的形式存在。

9. 发明授权

US07482500B2 Preparation of butadiene 有权
标题翻译：丁二烯的制备
公开(公告)号：US07482500B2
公开(公告)日：2009-01-27
申请号：US10584758
申请日：2004-12-30
申请人： Thorsten Johann , Götz-Peter Schindler , Andreas Brodhagen , Sven Crone , Regina Benfer , Thomas Hill , Mark Duda
发明人： Thorsten Johann , Götz-Peter Schindler , Andreas Brodhagen , Sven Crone , Regina Benfer , Thomas Hill , Mark Duda
IPC分类号： C07C5/327 , C07C5/32
CPC分类号： C07C5/333 , C07C5/48 , C07C11/167
摘要： The disclosure relates to a process for preparing butadiene. The process involves nonoxidatively catalytically dehydrogenating butane to obtain a product gas stream containing butane, 1-butene, 2-butene, butadiene, hydrogen and secondary constituents. The 1-butene and 2-butene of the product gas stream is then oxidatively dehydrogenated to give a second gas stream containing butane,2-butene, butadiene, hydrogen, steam and secondary constituents. Next, the butane,2-butene and butadiene are separated from the second gas stream and the butane and 2-butene are then separated from the butadiene product. The butane and 2-butene are then recycled into the nonoxidative catalytic dehydrogenating zone.
摘要翻译：本公开涉及一种制备丁二烯的方法。该方法涉及非氧化催化脱氢丁烷，以获得含有丁烷，1-丁烯，2-丁烯，丁二烯，氢和二次成分的产物气流。然后将产物气流的1-丁烯和2-丁烯氧化脱氢，得到含有丁烷，2-丁烯，丁二烯，氢气，蒸汽和二级成分的第二气流。接下来，将丁烷，2-丁烯和丁二烯与第二气流分离，然后从丁二烯产物中分离丁烷和2-丁烯。然后将丁烷和2-丁烯循环到非氧化催化脱氢区。

10. 发明申请

US20100304143A1 PRODUCTION OF Si02-COATED TITANIUM DIOXIDE PARTICLES WITH AN ADJUSTABLE COATING 审中-公开
标题翻译：用可调涂层生产二氧化硅 - 二氧化钛二氧化硅颗粒
公开(公告)号：US20100304143A1
公开(公告)日：2010-12-02
申请号：US12675432
申请日：2008-08-27
申请人： Alexandra Seeber , Götz-Peter Schindler , Katrin Freitag , Frank Jäger , Dirk Klingler , Frieder Borgmeier
发明人： Alexandra Seeber , Götz-Peter Schindler , Katrin Freitag , Frank Jäger , Dirk Klingler , Frieder Borgmeier
IPC分类号： B32B1/00 , B05D7/00 , C23C16/44
CPC分类号： B01J35/004 , B01J2/003 , B01J2/04 , B01J19/24 , B01J19/26 , B01J21/08 , B01J35/0013 , B01J37/349 , B01J2219/00123 , B01J2219/00157 , B01J2219/00166 , B82Y30/00 , C01G23/07 , C01P2002/85 , C01P2004/04 , C01P2004/64 , C01P2004/84 , C01P2004/86 , C09C1/3661 , C09C1/3684 , Y10T428/2991 , Y10T428/2993
摘要： The present invention relates to a process for producing coated nanoparticles comprising a core comprising at least one first substance and at least one envelope at least partly surrounding the core and composed of at least one further substance, in a streaming system, to nanoparticles which can be produced according to this process, to nanoparticles comprising a nonporous core comprising at least one first substance and at least one porous envelope at least partly surrounding the core and composed of at least one further substance, the nanoparticles having a narrow particle size distribution, to the use of such nanoparticles in photocatalysis and to apparatus for carrying out the process.
摘要翻译：本发明涉及一种制备包覆纳米颗粒的方法，其包括核心，其包含至少一种第一物质和至少一个包膜，所述至少一个包膜至少部分地围绕所述核心，并且由流系统中的至少一种其它物质组成，所述纳米颗粒可以是根据该方法制备的纳米颗粒包含至少一种第一物质的至少一种第一物质和至少一部分包围核心的至少一个多孔包膜的纳米颗粒，所述至少一个多孔包膜由至少一种另外的物质构成，该纳米颗粒具有窄的粒度分布，在光催化中使用这种纳米颗粒以及用于进行该方法的设备。

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