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1. 发明申请

US20100073847A1 TETHER-CONTAINING CONDUCTING POLYMERS 有权
标题翻译：包含导电聚合物
公开(公告)号：US20100073847A1
公开(公告)日：2010-03-25
申请号：US12564270
申请日：2009-09-22
申请人： Brett D. Martin , Banahalli R. Ratna , Jawad Naciri , Michael A. Markowitz
发明人： Brett D. Martin , Banahalli R. Ratna , Jawad Naciri , Michael A. Markowitz
IPC分类号： H01G9/00 , C07D333/04 , C08G75/06 , H01G9/016
CPC分类号： H01G9/028 , C07D333/38 , C08G61/126 , C08G65/3324 , C08G65/3344 , C08G65/3346 , C08G2261/1424 , C08G2261/1432 , C08G2261/1452 , C08G2261/44 , C08G2650/50 , Y10T29/41 , Y10T29/417
摘要： A compound having the formula below. X is hydroxyl, a sulfonic ester or salt thereof, a phosphonate or salt thereof, a carboxylate or salt thereof, or a boronic ester or salt thereof. The value n is an integer greater than or equal to 2. A polymer made by polymerizing the compound. A method of: reacting NH2—(CH2—CH2—O)n—CH2—CH2—OH with thiophene acid chloride to form a (SC4H3)—CO—NH—(CH2—CH2—O)n—CH2—CH2—OH amide; reacting the amide with a vinyl sulfonic ester, a vinyl phosphonate, a vinyl carboxylate, or a vinyl boronic ester to form an intermediate; and converting the intermediate to a salt form.
摘要翻译：具有下式的化合物。 X是羟基，磺酸酯或其盐，膦酸盐或其盐，羧酸盐或其盐，或硼酸酯或其盐。值n是大于或等于2的整数。通过聚合该化合物制成的聚合物。一种使NH2-（CH2-CH2-O）n-CH2-CH2-OH与噻吩酰氯反应形成（SC4H3）-CO-NH-（CH2-CH2-O）n-CH2-CH2-OH 酰胺; 使酰胺与乙烯基磺酸酯，乙烯基膦酸酯，羧酸乙烯酯或乙烯基硼酸酯反应形成中间体; 并将中间体转化成盐形式。

2. 发明授权

US06713416B2 Molecularly-imprinted material made by template-directed synthesis 失效
标题翻译：通过模板指导合成制备的分子印迹材料
公开(公告)号：US06713416B2
公开(公告)日：2004-03-30
申请号：US10337723
申请日：2003-01-08
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C03C100
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.
摘要翻译：制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。

3. 发明授权

US06310110B1 Molecularly-imprinted material made by template-directed synthesis 失效
标题翻译：通过模板指导合成制备的分子印迹材料
公开(公告)号：US06310110B1
公开(公告)日：2001-10-30
申请号：US09363819
申请日：1999-07-30
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C01B3312
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.
摘要翻译：制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。

4. 发明授权

US06660780B2 Molecularly-imprinted material made by template-directed synthesis 失效
公开(公告)号：US06660780B2
公开(公告)日：2003-12-09
申请号：US10307536
申请日：2002-11-27
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C01B3312
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.

5. 发明授权

US06583191B2 Molecularly-imprinted material made by template-directed synthesis 失效
公开(公告)号：US06583191B2
公开(公告)日：2003-06-24
申请号：US09955032
申请日：2001-09-19
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C01B3312
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.

6. 发明申请

US20110223331A1 Mesoporous Monoliths Containing Conducting Polymers 审中-公开
标题翻译：包含导电聚合物的介孔整体
公开(公告)号：US20110223331A1
公开(公告)日：2011-09-15
申请号：US12884278
申请日：2010-09-17
申请人： Brett D. Martin , Michael A. Markowitz , Brian Melde
发明人： Brett D. Martin , Michael A. Markowitz , Brian Melde
IPC分类号： B05D7/14 , B05D7/00
CPC分类号： H01B1/20 , H01L51/0037 , Y10T428/249953
摘要： The present invention relates to a mesoporous monolith containing a conducting polymer such as poly(3,4-ethylenedioxythiophene) and methods for making the monolith. The mesoporous monolith is electroactive, at least semi-transparent and has one or more of a large internal pore surface area, pore size and pore volume. It can be used for various applications in photovoltaics, sensing electrochromics, separations, reversible ion exchange and control of protein activity. The method employs hydrothermal treatment and/or substantially complete drying to obtain the desirable properties of the monolith. Conducting polymer can be covalently bound to the internal pore surfaces and polymerized in situ to partially or completely fill the pores producing increased mechanical strength and a high conductivity per unit area.
摘要翻译：本发明涉及一种含有聚（3,4-亚乙二氧基噻吩）等导电性聚合物的中孔整料及其制造方法。中孔整料是电活性的，至少是半透明的并且具有一个或多个大的内孔表面积，孔径和孔体积。它可用于各种光伏应用，感测电致变色，分离，可逆离子交换和蛋白质活性的控制。该方法采用水热处理和/或基本上完全干燥以获得整料的理想特性。导电聚合物可以共价结合到内孔表面，并原位聚合以部分或完全填充孔隙，产生增加的机械强度和每单位面积的高导电率。

7. 发明申请

US20090130422A1 MESOPOROUS MONOLITHS CONTAINING CONDUCTING POLYMERS 审中-公开
标题翻译：包含导电聚合物的多孔单体
公开(公告)号：US20090130422A1
公开(公告)日：2009-05-21
申请号：US11942542
申请日：2007-11-19
申请人： Brett D. Martin , Michael A. Markowitz , Brian Melde
发明人： Brett D. Martin , Michael A. Markowitz , Brian Melde
IPC分类号： B32B3/26 , B05D7/22
CPC分类号： H01B1/20 , H01L51/0037 , Y10T428/249953
摘要： The present invention relates to a mesoporous monolith containing a conducting polymer such as poly(3,4-ethylenedioxythiophene) and methods for making the monolith. The mesoporous monolith is electroactive, at least semi-transparent and has one or more of a large internal pore surface area, pore size and pore volume. It can be used for various applications in photovoltaics, sensing electrochromics, separations, reversible ion exchange and control of protein activity. The method employs hydrothermal treatment and/or substantially complete drying to obtain the desirable properties of the monolith. Conducting polymer can be covalently bound to the internal pore surfaces and polymerized in situ to partially or completely fill the pores producing increased mechanical strength and a high conductivity per unit area.
摘要翻译：本发明涉及一种含有聚（3,4-亚乙二氧基噻吩）等导电性聚合物的中孔整料及其制造方法。中孔整料是电活性的，至少是半透明的并且具有一个或多个大的内孔表面积，孔径和孔体积。它可用于各种光伏应用，感测电致变色，分离，可逆离子交换和蛋白质活性的控制。该方法采用水热处理和/或基本上完全干燥以获得整料的理想特性。导电聚合物可以共价结合到内孔表面，并原位聚合以部分或完全填充孔隙，产生增加的机械强度和每单位面积的高导电率。

8. 发明授权

US06869784B2 Passivation of nerve agents by surface modified enzymes stabilized by non-covalent immobilization on robust, stable particles 失效
标题翻译：通过表面修饰的酶将神经毒剂钝化，通过非共价固定化稳定稳定的稳定颗粒
公开(公告)号：US06869784B2
公开(公告)日：2005-03-22
申请号：US09725309
申请日：2000-11-29
申请人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
发明人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
IPC分类号： C12N9/16 , C12N9/96 , C12N11/02 , C12N11/14
CPC分类号： C12N11/02 , C12N9/16 , C12N9/96 , C12N11/14
摘要： Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes. A stable carrier to accommodate and bind the selected enzyme is constructed, and the enzyme is non-covalently linked to the carrier, generally through metal salts of iminodiacetate.
摘要翻译：通过引入用于将酶连接到靶表面的锚定位点而不破坏酶的催化活性来修饰酶。构建适应和结合选定酶的稳定载体，通常通过亚氨基二乙酸盐的金属盐将酶非共价连接到载体上。

9. 发明申请

US20100081205A1 FLUOROPHORE EMBEDDED/INCORPORATING/BRIDGED PERIODIC MESOPOROUS ORGANOSILICAS AS RECOGNITION ELEMENTS FOR OPTICAL SENSORS 有权
标题翻译：作为光学传感器的识别元件的荧光嵌入/连接/串联的周期性有机有机物
公开(公告)号：US20100081205A1
公开(公告)日：2010-04-01
申请号：US11465343
申请日：2006-08-17
申请人： Mazyar Zeinali , Brandy J. White , Paul T. Charles , Michael A. Markowitz
发明人： Mazyar Zeinali , Brandy J. White , Paul T. Charles , Michael A. Markowitz
IPC分类号： G01N33/00 , G01N21/75 , G01N30/96
CPC分类号： G01N21/77 , G01N2021/7706 , G01N2021/7726 , G01N2021/7786 , Y10T436/173076
摘要： Periodic mesoporous organosilicas (PMO) which incorporate an optically active molecule into the material for use as an optical indicator of target binding. This material combines the stability, selectivity, and high density of binding sites characteristic of the PMO with the sensitivity and selectivity of the optically active molecule. The material undergoes a change when exposed to a sample containing a target molecule. The change can be observed by visual inspection or through the use of fluorescence spectra.
摘要翻译：周期性介孔有机硅（PMO），其将光学活性分子掺入到用作目标结合的光学指示剂的材料中。该材料将PMO特征的结合位点的稳定性，选择性和高密度与光学活性分子的灵敏度和选择性相结合。当暴露于含有靶分子的样品时，材料发生变化。可以通过视觉检查或通过使用荧光光谱来观察变化。

10. 发明申请

US20090325261A1 Passivation of nerve agents by surface modified enzymes stabilized by non-covalent immobilization on robust, stable particles 审中-公开
标题翻译：通过表面修饰的酶将神经毒剂钝化，通过非共价固定化稳定稳定的稳定颗粒
公开(公告)号：US20090325261A1
公开(公告)日：2009-12-31
申请号：US11001600
申请日：2004-11-29
申请人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
发明人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
IPC分类号： C12N11/14
CPC分类号： C12N11/02 , C12N9/16 , C12N9/96 , C12N11/14
摘要： Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes. A stable carrier to accommodate and bind the selected enzyme is constructed, and the enzyme is non-covalently liked to the carrier, generally through metal salts of iminodiacetate
摘要翻译：通过引入用于将酶连接到靶表面的锚定位点而不破坏酶的催化活性来修饰酶。构建适应和结合选定酶的稳定载体，并且该酶通常通过亚氨基二乙酸盐的金属盐非共价地与载体一致

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