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1. 发明申请

US20110223331A1 Mesoporous Monoliths Containing Conducting Polymers 审中-公开
标题翻译：包含导电聚合物的介孔整体
公开(公告)号：US20110223331A1
公开(公告)日：2011-09-15
申请号：US12884278
申请日：2010-09-17
申请人： Brett D. Martin , Michael A. Markowitz , Brian Melde
发明人： Brett D. Martin , Michael A. Markowitz , Brian Melde
IPC分类号： B05D7/14 , B05D7/00
CPC分类号： H01B1/20 , H01L51/0037 , Y10T428/249953
摘要： The present invention relates to a mesoporous monolith containing a conducting polymer such as poly(3,4-ethylenedioxythiophene) and methods for making the monolith. The mesoporous monolith is electroactive, at least semi-transparent and has one or more of a large internal pore surface area, pore size and pore volume. It can be used for various applications in photovoltaics, sensing electrochromics, separations, reversible ion exchange and control of protein activity. The method employs hydrothermal treatment and/or substantially complete drying to obtain the desirable properties of the monolith. Conducting polymer can be covalently bound to the internal pore surfaces and polymerized in situ to partially or completely fill the pores producing increased mechanical strength and a high conductivity per unit area.
摘要翻译：本发明涉及一种含有聚（3,4-亚乙二氧基噻吩）等导电性聚合物的中孔整料及其制造方法。中孔整料是电活性的，至少是半透明的并且具有一个或多个大的内孔表面积，孔径和孔体积。它可用于各种光伏应用，感测电致变色，分离，可逆离子交换和蛋白质活性的控制。该方法采用水热处理和/或基本上完全干燥以获得整料的理想特性。导电聚合物可以共价结合到内孔表面，并原位聚合以部分或完全填充孔隙，产生增加的机械强度和每单位面积的高导电率。

2. 发明申请

US20090130422A1 MESOPOROUS MONOLITHS CONTAINING CONDUCTING POLYMERS 审中-公开
标题翻译：包含导电聚合物的多孔单体
公开(公告)号：US20090130422A1
公开(公告)日：2009-05-21
申请号：US11942542
申请日：2007-11-19
申请人： Brett D. Martin , Michael A. Markowitz , Brian Melde
发明人： Brett D. Martin , Michael A. Markowitz , Brian Melde
IPC分类号： B32B3/26 , B05D7/22
CPC分类号： H01B1/20 , H01L51/0037 , Y10T428/249953
摘要： The present invention relates to a mesoporous monolith containing a conducting polymer such as poly(3,4-ethylenedioxythiophene) and methods for making the monolith. The mesoporous monolith is electroactive, at least semi-transparent and has one or more of a large internal pore surface area, pore size and pore volume. It can be used for various applications in photovoltaics, sensing electrochromics, separations, reversible ion exchange and control of protein activity. The method employs hydrothermal treatment and/or substantially complete drying to obtain the desirable properties of the monolith. Conducting polymer can be covalently bound to the internal pore surfaces and polymerized in situ to partially or completely fill the pores producing increased mechanical strength and a high conductivity per unit area.
摘要翻译：本发明涉及一种含有聚（3,4-亚乙二氧基噻吩）等导电性聚合物的中孔整料及其制造方法。中孔整料是电活性的，至少是半透明的并且具有一个或多个大的内孔表面积，孔径和孔体积。它可用于各种光伏应用，感测电致变色，分离，可逆离子交换和蛋白质活性的控制。该方法采用水热处理和/或基本上完全干燥以获得整料的理想特性。导电聚合物可以共价结合到内孔表面，并原位聚合以部分或完全填充孔隙，产生增加的机械强度和每单位面积的高导电率。

3. 发明申请

US20100073847A1 TETHER-CONTAINING CONDUCTING POLYMERS 有权
标题翻译：包含导电聚合物
公开(公告)号：US20100073847A1
公开(公告)日：2010-03-25
申请号：US12564270
申请日：2009-09-22
申请人： Brett D. Martin , Banahalli R. Ratna , Jawad Naciri , Michael A. Markowitz
发明人： Brett D. Martin , Banahalli R. Ratna , Jawad Naciri , Michael A. Markowitz
IPC分类号： H01G9/00 , C07D333/04 , C08G75/06 , H01G9/016
CPC分类号： H01G9/028 , C07D333/38 , C08G61/126 , C08G65/3324 , C08G65/3344 , C08G65/3346 , C08G2261/1424 , C08G2261/1432 , C08G2261/1452 , C08G2261/44 , C08G2650/50 , Y10T29/41 , Y10T29/417
摘要： A compound having the formula below. X is hydroxyl, a sulfonic ester or salt thereof, a phosphonate or salt thereof, a carboxylate or salt thereof, or a boronic ester or salt thereof. The value n is an integer greater than or equal to 2. A polymer made by polymerizing the compound. A method of: reacting NH2—(CH2—CH2—O)n—CH2—CH2—OH with thiophene acid chloride to form a (SC4H3)—CO—NH—(CH2—CH2—O)n—CH2—CH2—OH amide; reacting the amide with a vinyl sulfonic ester, a vinyl phosphonate, a vinyl carboxylate, or a vinyl boronic ester to form an intermediate; and converting the intermediate to a salt form.
摘要翻译：具有下式的化合物。 X是羟基，磺酸酯或其盐，膦酸盐或其盐，羧酸盐或其盐，或硼酸酯或其盐。值n是大于或等于2的整数。通过聚合该化合物制成的聚合物。一种使NH2-（CH2-CH2-O）n-CH2-CH2-OH与噻吩酰氯反应形成（SC4H3）-CO-NH-（CH2-CH2-O）n-CH2-CH2-OH 酰胺; 使酰胺与乙烯基磺酸酯，乙烯基膦酸酯，羧酸乙烯酯或乙烯基硼酸酯反应形成中间体; 并将中间体转化成盐形式。

4. 发明授权

US09302995B2 Electrically conducting oligo(pyrazoles) 有权
标题翻译：导电寡聚（吡唑）
公开(公告)号：US09302995B2
公开(公告)日：2016-04-05
申请号：US14280002
申请日：2014-05-16
申请人： Brett D. Martin , Scott A. Trammell , Jeffrey R. Deschamps , Jawad Naciri , Jeffrey C. DePriest
发明人： Brett D. Martin , Scott A. Trammell , Jeffrey R. Deschamps , Jawad Naciri , Jeffrey C. DePriest
IPC分类号： C08G73/06 , C07D231/38
CPC分类号： C07D231/38
摘要： This disclosure concerns two novel electrically conducting organic oligomers: oligo(3-amino-1H-pyrazole-4-carbonitrile) or “oligo(AP-CN)” and oligo(4-nitro-1H-pyrazole-3-yl-amine) or “oligo(AP-NO2)”, and methods of making thereof.
摘要翻译：本公开涉及两种新型导电有机低聚物：低聚（3-氨基-1H-吡唑-4-腈）或“寡聚（AP-CN）”和低聚（4-硝基-1H-吡唑-3-基 - 胺）或“寡聚（AP-NO 2）”及其制备方法。

5. 发明授权

US08931114B2 Elastomeric composites with tether-containing, conducting polymers for nanoscale diffusion control 有权
标题翻译：弹性体复合材料与系链，用于纳米级扩散控制的导电聚合物
公开(公告)号：US08931114B2
公开(公告)日：2015-01-13
申请号：US13296920
申请日：2011-11-15
申请人： Brett D. Martin , Martin H. Moore , Banahalli R. Ratna , Gusphyl Justin , Jawad Naciri
发明人： Brett D. Martin , Martin H. Moore , Banahalli R. Ratna , Gusphyl Justin , Jawad Naciri
IPC分类号： A41D13/00 , C07D333/38 , C08G61/12 , C08G65/332 , C08G65/334 , H01G9/028
CPC分类号： C07D333/38 , C08G61/126 , C08G65/3324 , C08G65/3344 , C08G65/3346 , C08G65/3348 , C08G2261/135 , C08G2261/1424 , C08G2261/1426 , C08G2261/1432 , C08G2261/1452 , C08G2261/147 , C08G2261/44 , C08G2261/516 , C08G2650/50 , H01G9/028
摘要： A redox-active conductive polymer includes a charged tether. An interpenetrating network including such a conducting polymer can be switched between two states of diffusivity (porosity) by application of a voltage. Such a material can be useful in breathable protective clothing, controlled release, intelligent sensing/filtration, novel separation processes, nanomanufacturing, and other areas.
摘要翻译：氧化还原活性导电聚合物包括带电的系链。包括这种导电聚合物的互穿网络可以通过施加电压在两种扩散状态（孔隙率）之间切换。这种材料可用于透气防护服，控释，智能感应/过滤，新型分离工艺，纳米制造等领域。

6. 发明授权

US08040443B2 Method for stacking thermal actuators with liquid crystal elastomer 有权
标题翻译：用液晶弹性体堆叠热致动器的方法
公开(公告)号：US08040443B2
公开(公告)日：2011-10-18
申请号：US13049503
申请日：2011-03-16
申请人： Christopher M Spillmann , David A Cylinder , Banahalli R Ratna , Jawad Naciri , Brett D. Martin
发明人： Christopher M Spillmann , David A Cylinder , Banahalli R Ratna , Jawad Naciri , Brett D. Martin
IPC分类号： G02F1/133
CPC分类号： F03G7/06 , Y10T29/49826
摘要： A method comprising arranging a first heating element on a first liquid crystal elastomer, arranging a first layer of thermal paste on the first heating element, and arranging a second liquid crystal elastomer on the first layer of thermal paste.
摘要翻译：一种方法，包括在第一液晶弹性体上布置第一加热元件，在第一加热元件上布置第一层热膏，并在第一层热浆上设置第二液晶弹性体。

7. 发明授权

US07785770B2 Sugar-containing hydrogel for immobilization 有权
标题翻译：含糖水凝胶用于固定
公开(公告)号：US07785770B2
公开(公告)日：2010-08-31
申请号：US11444819
申请日：2006-05-19
申请人： Mark S. Spector , David A. Stenger , Charles H. Patterson, Jr. , Brett D. Martin , Paul T. Charles
发明人： Mark S. Spector , David A. Stenger , Charles H. Patterson, Jr. , Brett D. Martin , Paul T. Charles
IPC分类号： C12Q1/00
CPC分类号： G01N33/548 , G01N33/54353
摘要： The use of sugar-containing hydrogels as very highly porous, aqueous support material for the immobilization of oligonucleotides, peptides, proteins, antigens, antibodies, polysaccharides, and other biomolecules for sensor applications. Unusually large sizes of interconnected pores allow large target molecules to pass rapidly into and through the gel and bind to immobilized biomolecules. Sugar-containing hydrogels have extremely low non-specific absorption of labeled target molecules, providing low background levels. Some hydrogel materials do not have this type of homogeneous interconnected macroporosity, thus large target molecules cannot readily diffuse through them. Additionally, they nearly always experience non-specific absorption of labeled target molecules, limiting their usefulness in sensor applications. A method is provided for preparing sugar polyacrylate hydrogels with functional chemical groups which covalently bond oligonucleotides and peptides. A method for copolymerizing acrylate-terminated oligonucleotides with sugar acrylate monomers and diacrylate cross-linking agents is also provided.
摘要翻译：使用含糖水凝胶作为用于固定寡核苷酸，肽，蛋白质，抗原，抗体，多糖和其他用于传感器应用的生物分子的非常高度多孔的水性支持材料。异常大尺寸的相互连通的孔允许大的目标分子快速通过并通过凝胶并结合固定化的生物分子。含糖水凝胶对标记的靶分子具有极低的非特异性吸收，提供低的背景水平。一些水凝胶材料不具有这种类型的均匀相互连接的大孔隙度，因此大的靶分子不能容易地通过它们扩散。此外，它们几乎总是经历对标记的靶分子的非特异性吸收，限制了它们在传感器应用中的用途。提供了一种制备具有共价键合寡核苷酸和肽的功能化学基团的糖聚丙烯酸酯水凝胶的方法。还提供了将丙烯酸酯封端的寡核苷酸与糖丙酯单体和二丙烯酸酯交联剂共聚的方法。

8. 发明申请

US20140364621A1 Electrically Conducting Oligo(pyrazoles) 有权
标题翻译：导电寡糖（吡唑）
公开(公告)号：US20140364621A1
公开(公告)日：2014-12-11
申请号：US14280002
申请日：2014-05-16
申请人： Brett D. Martin , Scott A. Trammell , Jeffrey R. Deschamps , Jawad Naciri , Jeffrey C. DePriest
发明人： Brett D. Martin , Scott A. Trammell , Jeffrey R. Deschamps , Jawad Naciri , Jeffrey C. DePriest
IPC分类号： C07D231/38
CPC分类号： C07D231/38
摘要： This disclosure concerns two novel electrically conducting organic oligomers: oligo(3-amino-1H-pyrazole-4-carbonitrile) or “oligo(AP-CN)” and oligo(4-nitro-1H-pyrazole-3-yl-amine) or “oligo(AP-NO2)”, and methods of making thereof.
摘要翻译：本公开涉及两种新型导电有机低聚物：低聚（3-氨基-1H-吡唑-4-腈）或“寡聚（AP-CN）”和低聚（4-硝基-1H-吡唑-3-基 - 胺）或“寡聚（AP-NO 2）”及其制备方法。

9. 发明申请

US20110185557A1 Method for Stacking Thermal Actuators 有权
标题翻译：堆叠热传动器的方法
公开(公告)号：US20110185557A1
公开(公告)日：2011-08-04
申请号：US13049503
申请日：2011-03-16
申请人： Christopher M. Spillmann , David Cylinder , Banahalli R. Ratna , Jawad Naciri , Brett D. Martin
发明人： Christopher M. Spillmann , David Cylinder , Banahalli R. Ratna , Jawad Naciri , Brett D. Martin
IPC分类号： B23P11/00
CPC分类号： F03G7/06 , Y10T29/49826
摘要： A method comprising arranging a first heating element on a first liquid crystal elastomer, arranging a first layer of thermal paste on the first heating element, and arranging a second liquid crystal elastomer on the first layer of thermal paste.
摘要翻译：一种方法，包括在第一液晶弹性体上布置第一加热元件，在第一加热元件上布置第一层热膏，并在第一层热浆上设置第二液晶弹性体。

10. 发明授权

US07936404B2 Method for stacking thermal actuators with liquid crystal elastomer 失效
标题翻译：用液晶弹性体堆叠热致动器的方法
公开(公告)号：US07936404B2
公开(公告)日：2011-05-03
申请号：US11896306
申请日：2007-08-30
申请人： Christopher M. Spillmann , David Cylinder , Banahalli R. Ratna , Jawad Naciri , Brett D. Martin
发明人： Christopher M. Spillmann , David Cylinder , Banahalli R. Ratna , Jawad Naciri , Brett D. Martin
IPC分类号： G02F1/133
CPC分类号： F03G7/06 , Y10T29/49826
摘要： An apparatus comprising a first liquid crystal elastomer, a first heating element, a first layer of thermal paste, and a second liquid crystal elastomer. The apparatus further comprising a second heating element, a second layer of thermal paste, and a third liquid crystal elastomer. The heating element can be a nickel-chromium heating element. A method comprising arranging a first heating element on a first liquid crystal elastomer, arranging a first layer of thermal paste on the first heating element, and arranging a second liquid crystal elastomer on the first layer of thermal paste.
摘要翻译：一种包括第一液晶弹性体，第一加热元件，第一热敏膏层和第二液晶弹性体的装置。该装置还包括第二加热元件，第二层热浆料和第三液晶弹性体。加热元件可以是镍铬加热元件。一种方法，包括在第一液晶弹性体上布置第一加热元件，在第一加热元件上布置第一层热膏，并在第一层热浆上设置第二液晶弹性体。

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