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1. 发明申请

US20130011459A1 Composite for Controleed Release of Small Molecules in Aquatic Environments 审中-公开
标题翻译：在水生环境中小分子释放的复合物
公开(公告)号：US20130011459A1
公开(公告)日：2013-01-10
申请号：US13612442
申请日：2012-09-12
申请人： Brian Melde , Michael A. Markowitz
发明人： Brian Melde , Michael A. Markowitz
IPC分类号： A01N25/08 , A01P17/00 , A01P15/00 , A01N55/08
CPC分类号： C09D5/1625 , C09D5/1631 , C09D5/1656 , Y10T428/249954 , Y10T428/249956 , Y10T428/249978 , Y10T428/249979 , Y10T428/25
摘要： A composite material formulated for slow release of a small molecule in seawater includes a porous inorganic oxide framework and micelles embedded within the pores of the framework. The micelles include a surfactant and a small molecule, the surfactant being present in the composite material at no more than 80 parts by weight per 100 parts by weight inorganic oxide, the composite material being stable in seawater for releasing the small molecule over at least 20 days.
摘要翻译：配制用于在海水中缓慢释放小分子的复合材料包括嵌入框架孔内的多孔无机氧化物骨架和胶束。胶束包括表面活性剂和小分子，表面活性剂以每100重量份无机氧化物不超过80重量份存在于复合材料中，该复合材料在海水中稳定，用于将至少20分钟的小分子释放天。

2. 发明申请

US20110305894A1 COMPOSITE FOR CONTROLLED RELEASE OF SMALL MOLECULES IN AQUATIC ENVIRONMENTS 有权
标题翻译：用于水生环境中小分子的控制释放的复合材料
公开(公告)号：US20110305894A1
公开(公告)日：2011-12-15
申请号：US12813916
申请日：2010-06-11
申请人： Brian Melde , Michael A. Markowitz
发明人： Brian Melde , Michael A. Markowitz
IPC分类号： B32B5/16 , C09D5/16
CPC分类号： C09D5/1625 , C09D5/1631 , C09D5/1656 , Y10T428/249954 , Y10T428/249956 , Y10T428/249978 , Y10T428/249979 , Y10T428/25
摘要： A composite material formulated for slow release of a small molecule in seawater includes a porous inorganic oxide framework and micelles embedded within the pores of the framework. The micelles include a surfactant and a small molecule, the surfactant being present in the composite material at no more than 80 parts by weight per 100 parts by weight inorganic oxide, the composite material being stable in seawater for releasing the small molecule over at least 20 days.
摘要翻译：配制用于在海水中缓慢释放小分子的复合材料包括嵌入框架孔内的多孔无机氧化物骨架和胶束。胶束包括表面活性剂和小分子，表面活性剂以每100重量份无机氧化物不超过80重量份存在于复合材料中，该复合材料在海水中稳定，用于将至少20分钟的小分子释放天。

3. 发明授权

US07749438B2 Fluorophore embedded/incorporating/bridged periodic mesoporous organosilicas as recognition elements for optical sensors 有权
标题翻译：荧光团嵌入/掺入/桥联周期性介孔有机硅作为光学传感器的识别元件
公开(公告)号：US07749438B2
公开(公告)日：2010-07-06
申请号：US11465343
申请日：2006-08-17
申请人： Mazyar Zeinali , Brandy J White , Paul T Charles , Michael A Markowitz
发明人： Mazyar Zeinali , Brandy J White , Paul T Charles , Michael A Markowitz
IPC分类号： G01N33/00
CPC分类号： G01N21/77 , G01N2021/7706 , G01N2021/7726 , G01N2021/7786 , Y10T436/173076
摘要： Periodic mesoporous organosilicas (PMO) which incorporate an optically active molecule into the material for use as an optical indicator of target binding. This material combines the stability, selectivity, and high density of binding sites characteristic of the PMO with the sensitivity and selectivity of the optically active molecule. The material undergoes a change when exposed to a sample containing a target molecule. The change can be observed by visual inspection or through the use of fluorescence spectra.
摘要翻译：周期性介孔有机硅（PMO），其将光学活性分子掺入到用作目标结合的光学指示剂的材料中。该材料将PMO特征的结合位点的稳定性，选择性和高密度与光学活性分子的灵敏度和选择性相结合。当暴露于含有靶分子的样品时，材料发生变化。可以通过视觉检查或通过使用荧光光谱来观察变化。

4. 发明申请

US20100083736A1 HYBRID PRECONCENTRATOR FOR DETECTION OF MATERIALS 有权
标题翻译：用于检测材料的混合预处理器
公开(公告)号：US20100083736A1
公开(公告)日：2010-04-08
申请号：US12246573
申请日：2008-10-07
申请人： Michael A. Markowitz , Mazyar Zeinali , R. Andrew McGill , Anne W. Kusterbeck , Jennifer L. Stepnowski
发明人： Michael A. Markowitz , Mazyar Zeinali , R. Andrew McGill , Anne W. Kusterbeck , Jennifer L. Stepnowski
IPC分类号： G01N1/28
CPC分类号： G01N1/405 , G01N1/4022 , G01N2001/022
摘要： A device having: one or more substrates in an enclosure having an inlet and an outlet; a template directed molecular imprinted material on the substrates; and a heater to heat the material. A method of: providing the above device including a sensor coupled to the outlet; flowing a gas though the device; heating the material; and flowing any vapor evolved from the material into the sensor.
摘要翻译：一种装置，其具有：具有入口和出口的外壳中的一个或多个基板; 在基板上定向分子印迹材料的模板; 以及用于加热材料的加热器。一种方法：提供上述装置，包括耦合到出口的传感器; 通过设备流动气体; 加热材料; 并且将从材料放出的任何蒸气流入传感器。

5. 发明授权

US06713416B2 Molecularly-imprinted material made by template-directed synthesis 失效
标题翻译：通过模板指导合成制备的分子印迹材料
公开(公告)号：US06713416B2
公开(公告)日：2004-03-30
申请号：US10337723
申请日：2003-01-08
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C03C100
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.
摘要翻译：制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。

6. 发明授权

US06310110B1 Molecularly-imprinted material made by template-directed synthesis 失效
标题翻译：通过模板指导合成制备的分子印迹材料
公开(公告)号：US06310110B1
公开(公告)日：2001-10-30
申请号：US09363819
申请日：1999-07-30
申请人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
发明人： Michael A. Markowitz , Paul E. Schoen , Bruce P. Gaber , Banahalli R. Ratna , Paul R. Kust , David C. Turner , Douglas S. Clark , Jonathan S. Dordick
IPC分类号： C01B3312
CPC分类号： B82Y30/00 , B01J37/00 , C01B37/02 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2006/16 , C09C1/3081 , Y10T436/10
摘要： A method of making a molecularly imprinted porous structure makes use of a surfactant analog of the molecule to be imprinted that has the imprint molecule portion serving as the surfactant headgroup. The surfactant analog is allowed to self-assemble in a mixture to create at least one supramolecular structure having exposed imprint groups. The imprinted porous structure is formed by adding reactive monomers to the mixture and allowing the monomers to polymerize, with the supramolecular structure serving as a template. The resulting solid structure has a shape that is complementary to the shape of the supramolecular structure and has cavities that are the mirror image of the imprint group. Similarly, molecularly imprinted particles may be made by using the surfactant to create a water-in-oil microemulsion wherein the imprint groups are exposed to the water phase. When reactive monomers are allowed to polymerize in the water phase to form particles, the surface of the particles have cavities that are the mirror image of the imprint group.
摘要翻译：制作分子印迹多孔结构的方法利用具有印迹分子部分作为表面活性剂头基的要印迹的分子的表面活性剂类似物。允许表面活性剂类似物在混合物中自组装以产生具有暴露的印迹基团的至少一个超分子结构。通过将反应性单体加入到混合物中并使单体以超分子结构作为模板聚合而形成印迹多孔结构。所得到的固体结构具有与超分子结构的形状互补的形状，并且具有作为印迹组的镜像的空腔。类似地，分子印迹的颗粒可以通过使用表面活性剂来制备油包水微乳液，其中印迹组暴露于水相。当使反应性单体在水相中聚合以形成颗粒时，颗粒的表面具有作为印迹组的镜像的空腔。

7. 发明授权

US08652853B2 Hybrid preconcentrator for detection of materials 有权
标题翻译：用于材料检测的混合预浓缩器
公开(公告)号：US08652853B2
公开(公告)日：2014-02-18
申请号：US12246573
申请日：2008-10-07
申请人： Michael A Markowitz , Mazyar Zeinali , R Andrew McGill , Anne W Kusterbeck , Jennifer L Stepnowski
发明人： Michael A Markowitz , Mazyar Zeinali , R Andrew McGill , Anne W Kusterbeck , Jennifer L Stepnowski
IPC分类号： G01N33/543
CPC分类号： G01N1/405 , G01N1/4022 , G01N2001/022
摘要： A device having: one or more substrates in an enclosure having an inlet and an outlet; a template directed molecular imprinted material on the substrates; and a heater to heat the material. A method of: providing the above device including a sensor coupled to the outlet; flowing a gas though the device; heating the material; and flowing any vapor evolved from the material into the sensor.
摘要翻译：一种装置，其具有：具有入口和出口的外壳中的一个或多个基板; 在基板上定向分子印迹材料的模板; 以及用于加热材料的加热器。一种方法：提供上述装置，包括耦合到出口的传感器; 通过设备流动气体; 加热材料; 并且将从材料放出的任何蒸气流入传感器。

8. 发明申请

US20110223331A1 Mesoporous Monoliths Containing Conducting Polymers 审中-公开
标题翻译：包含导电聚合物的介孔整体
公开(公告)号：US20110223331A1
公开(公告)日：2011-09-15
申请号：US12884278
申请日：2010-09-17
申请人： Brett D. Martin , Michael A. Markowitz , Brian Melde
发明人： Brett D. Martin , Michael A. Markowitz , Brian Melde
IPC分类号： B05D7/14 , B05D7/00
CPC分类号： H01B1/20 , H01L51/0037 , Y10T428/249953
摘要： The present invention relates to a mesoporous monolith containing a conducting polymer such as poly(3,4-ethylenedioxythiophene) and methods for making the monolith. The mesoporous monolith is electroactive, at least semi-transparent and has one or more of a large internal pore surface area, pore size and pore volume. It can be used for various applications in photovoltaics, sensing electrochromics, separations, reversible ion exchange and control of protein activity. The method employs hydrothermal treatment and/or substantially complete drying to obtain the desirable properties of the monolith. Conducting polymer can be covalently bound to the internal pore surfaces and polymerized in situ to partially or completely fill the pores producing increased mechanical strength and a high conductivity per unit area.
摘要翻译：本发明涉及一种含有聚（3,4-亚乙二氧基噻吩）等导电性聚合物的中孔整料及其制造方法。中孔整料是电活性的，至少是半透明的并且具有一个或多个大的内孔表面积，孔径和孔体积。它可用于各种光伏应用，感测电致变色，分离，可逆离子交换和蛋白质活性的控制。该方法采用水热处理和/或基本上完全干燥以获得整料的理想特性。导电聚合物可以共价结合到内孔表面，并原位聚合以部分或完全填充孔隙，产生增加的机械强度和每单位面积的高导电率。

9. 发明申请

US20100081205A1 FLUOROPHORE EMBEDDED/INCORPORATING/BRIDGED PERIODIC MESOPOROUS ORGANOSILICAS AS RECOGNITION ELEMENTS FOR OPTICAL SENSORS 有权
标题翻译：作为光学传感器的识别元件的荧光嵌入/连接/串联的周期性有机有机物
公开(公告)号：US20100081205A1
公开(公告)日：2010-04-01
申请号：US11465343
申请日：2006-08-17
申请人： Mazyar Zeinali , Brandy J. White , Paul T. Charles , Michael A. Markowitz
发明人： Mazyar Zeinali , Brandy J. White , Paul T. Charles , Michael A. Markowitz
IPC分类号： G01N33/00 , G01N21/75 , G01N30/96
CPC分类号： G01N21/77 , G01N2021/7706 , G01N2021/7726 , G01N2021/7786 , Y10T436/173076
摘要： Periodic mesoporous organosilicas (PMO) which incorporate an optically active molecule into the material for use as an optical indicator of target binding. This material combines the stability, selectivity, and high density of binding sites characteristic of the PMO with the sensitivity and selectivity of the optically active molecule. The material undergoes a change when exposed to a sample containing a target molecule. The change can be observed by visual inspection or through the use of fluorescence spectra.
摘要翻译：周期性介孔有机硅（PMO），其将光学活性分子掺入到用作目标结合的光学指示剂的材料中。该材料将PMO特征的结合位点的稳定性，选择性和高密度与光学活性分子的灵敏度和选择性相结合。当暴露于含有靶分子的样品时，材料发生变化。可以通过视觉检查或通过使用荧光光谱来观察变化。

10. 发明申请

US20090325261A1 Passivation of nerve agents by surface modified enzymes stabilized by non-covalent immobilization on robust, stable particles 审中-公开
标题翻译：通过表面修饰的酶将神经毒剂钝化，通过非共价固定化稳定稳定的稳定颗粒
公开(公告)号：US20090325261A1
公开(公告)日：2009-12-31
申请号：US11001600
申请日：2004-11-29
申请人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
发明人： Alok Singh , Mehran Pazirandeh , Paul E. Schoen , Michael A. Markowitz , J. Matthew Mauro
IPC分类号： C12N11/14
CPC分类号： C12N11/02 , C12N9/16 , C12N9/96 , C12N11/14
摘要： Enzymes are modified by incorporating anchor sites for linking the enzymes to a target surface without destroying the catalytic activity of the enzymes. A stable carrier to accommodate and bind the selected enzyme is constructed, and the enzyme is non-covalently liked to the carrier, generally through metal salts of iminodiacetate
摘要翻译：通过引入用于将酶连接到靶表面的锚定位点而不破坏酶的催化活性来修饰酶。构建适应和结合选定酶的稳定载体，并且该酶通常通过亚氨基二乙酸盐的金属盐非共价地与载体一致

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