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1. 发明申请

WO2014064064A1 IMINOXYTRIAZINES AS RADICAL GENERATORS 审中-公开
标题翻译：作为辐射发生器的IMINOXYTRIAZINES
公开(公告)号：WO2014064064A1
公开(公告)日：2014-05-01
申请号：PCT/EP2013/072006
申请日：2013-10-22
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc
IPC分类号： C07D251/30 , C07D251/42 , C07D403/14
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107
摘要： Iminoxytriazine compounds of the formula (I), wherein n is 1 or 2; R 1 and R 2 independently of each other are hydrogen, NH 2 , NHR 5 , NR 5 R 6 , COR 5 , COOR 5 , CONH 2 , CONHR 5 , CONR 5 R 6 , CN, SR 5 , OR 5 , C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl, wherein said C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy, or R 1 and R 2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C 1 -C 12 alkyl, C 3 -C 12 -cycloalkyl, phenyl, halogen and C 1 -C 12 alkoxy; R 3 is F, Cl, OH, OR, SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 1, R 4 is F, Cl, OH, OR 5 , SH, SR 5 , NH 2 , NHR 5 , NR 5 R 6 or R 1 R 2 C=N-O-; wherein R 1 and R 2 in all groups R 1 R 2 C=N-O- in the compound of the formula I are identical or different; if n is 2, R 4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R 5 and R 6 independently of each other are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl or C 2 -C 14 heteroaryl; are suitable as radical generating agents.
摘要翻译：式（I）的亚氨基三嗪化合物，其中n为1或2; R 1和R 2彼此独立地是氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5 R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基其中所述C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基是未取代的或被一个或多个选自C 1 -C 12烷基，C 3 -C 12 - 环烷基，苯基，卤素和C 1 -C 12烷氧基的基团取代或被R 1和 R2与它们所连接的C原子一起形成4-12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基; R3是F，Cl，OH，OR，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n是1，R4是F，Cl，OH，OR5，SH，SR5，NH2，NHR5，NR5R6或R1R2C = N-O-; 其中式I化合物中所有基团R1R2C = N-O-中的R1和R2相同或不同; 如果n为2，则R4为衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基产生剂。

2. 发明申请

WO2010128062A1 O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 审中-公开
标题翻译： O-IMINO-ISO-UREA化合物及其可聚合组合物
公开(公告)号：WO2010128062A1
公开(公告)日：2010-11-11
申请号：PCT/EP2010/056063
申请日：2010-05-05
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
IPC分类号： C07C275/70 , C08F4/00
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R 100 and R 101 are independently H, C 1-18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 1 -C 14 heteroaryl, C 7 -C 15 aralkyl, C 2 -C 14 heteroaralkyl, Cyano, or R 100 and R 101 form together with the carbon to which they are attached a mono or polycyclic C 3 -C 18 carbocyclic or C 1 -C 18 heterocyclic ring; R 102 and R 103 are independently C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 6 -C 14 aryl once or more than once substituted by C 1 -C 18 alkyl; C 7 -C 15 aralkyl, (CH 3 ) 3 Si-; or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 7 -C 15 aralkyl or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C 1 -C 18 alkylamino, bis(C 1 -C 18 alkyl)amino or tris(C 1 -C 1t alkyl)ammonium; R 104 if n is 1 is is H, C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 7 -C 14 aralkyl, C 6 -C 14 aryl or acyl selected from the group consisting of the following acyls -C(=O)-H, -C(=O)-C 1 -C 18 alkyl, -C(=O)-C 2 -d 18 alkenyl, -C(=O)-C 6 -C 14 aryl, -C(=O)-C 2 -C 18 alkenyl-C 6 -C 14 aryl, -C(=O)-O-C 1 C 18 alkyl, -C(=O)-O-C 6 -C 14 aryl, -C(=O)-NH-C 1 -C 18 alkyl, -C(=O)-NH-C 6 -C 14 aryl and -C(=O)-N(C 1 C 18 alkyl) 2 ; or R 102 and R 104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R 104 if n is more than 1 is di-, tri-, tetra-C 1 -C 18 alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
摘要翻译：本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途，其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O - 异喹啉化合物是式（I）化合物，其中n为1,2,3或4，R 101和R 101独立地为H，C 1-18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14杂芳基， C 1 -C 15芳烷基，C 2 -C 14杂芳烷基，氰基或R 100和R 101与它们所连接的碳一起形成单或多环C 3 -C 18碳环或C 1 -C 18杂环; R 102和R 103独立地是C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 1 -C 14芳基，其一次或多于一个被C 1 -C 18烷基取代; C 7 -C 15芳烷基，（CH 3）3 Si- 或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，其被O或含N的基团所取代或被取代，所述基团选自C 1 -C 18烷基氨基，双（C1-C18烷基）氨基或三（C1-C1烷基）铵; 如果n为1，R 104为H，C 1 -C 18烷基，C 3 -C 12环烷基，C 7 -C 14芳烷基，C 6 -C 14芳基或选自以下酰基-C（= O）-H，-C（= O） -C（= O）-C 2 -C 18芳基，-C（= O）-C 6 -C 14芳基，-C（= O）-C 2 -C 18烯基-C 6 -C 14芳基，-C（= O）-O C 1 -C 18烷基，-C（= O）-O-C 6 -C 14芳基，-C（= O）-NH-C 1 -C 18烷基，-C（= O）-NH-C 6 -C 14芳基和-C（= O）-N （C1C18alkyl）2; 如果n为1，则与R 102和R 104一起形成与它们所连接的氮原子一起形成可含有其它杂原子的5至12元环，如果n大于1，则R104是二 - ，三 - ，四-C1-C18亚烷基，二酰基，三酰基或四酰基及其盐。

3. 发明申请

WO2012136606A1 PHOTO-LATENT TITANIUM-OXO-CHELATE CATALYSTS 审中-公开
标题翻译：紫外 - 钛 - 氧化钛催化剂
公开(公告)号：WO2012136606A1
公开(公告)日：2012-10-11
申请号：PCT/EP2012/055920
申请日：2012-04-02
申请人： BASF SE , HINTERMANN, Tobias , CARROY, Antoine , LORDELOT, Caroline , BAUER, Didier , KOHLI STECK, Rachel , FALLER, Marc
发明人： HINTERMANN, Tobias , CARROY, Antoine , LORDELOT, Caroline , BAUER, Didier , KOHLI STECK, Rachel , FALLER, Marc
IPC分类号： B01J31/02 , B01J31/22 , C08G18/22
CPC分类号： C09D175/16 , B01J31/0208 , B01J31/2234 , B01J2231/14 , B01J2231/48 , B01J2531/46 , C08G18/222 , C08G18/6229 , C08G18/68 , C08G18/792 , C09J175/04 , Y02P20/52
摘要： A titanium-oxo-chelate catalyst formulation, comprising: (i) at least one compound of the formula (I), wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 independently of each other are for example hydrogen, halogen, C 1 -C 20 alkyl, C 6 -C 14 aryl which is unsubstituted or substituted; or R 1 , R 2 and R 3 and/or R 4 , R 5 and R 6 and/or R 7 , R 8 and R 9 and/or R 10 , R 11 and R 12 together with the C-atom to which they are attached each form a C 6 - C 14 aryl group which is unsubstituted or substituted; or R 1 and R 2 and/or R 4 and R 5 and/or R 7 and R 8 and/or R 10 and R 11 together with the C-atom to which they are attached form a 5- to 7-membered carbocyclic ring; at least one chelate ligand compound of the formula (lla), (lIb) or (lIc), wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are defined as above for formula (I), is suitable as photolatent catalyst formulation for polymerizing compounds, which are capable to crosslink in the presence of a Lewis acid.
摘要翻译：一种钛 - 氧代 - 螯合催化剂制剂，其包含：（i）至少一种式（I）化合物，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11和R 12独立地彼此是例如氢，卤素，未取代或取代的C 1 -C 20烷基，C 6 -C 14芳基; 或R 1，R 2和R 3和/或R 4，R 5和R 6和/或R 7，R 8和R 9和/或R 10，R 11和R 12与它们所连接的C原子一起形成C 6 -C 14芳基，未取代或取代的; 或R 1和R 2和/或R 4和R 5和/或R 7和R 8和/或R 10和R 11与它们所连接的C原子一起形成5-至7-元碳环; 至少一种式（Ⅰla），（IIIb）或（IIIc）的螯合配体化合物，其中R 1，R 2，R 3，R 4，R 5和R 6如上文对式（I）所定义，适合作为用于聚合化合物，其能够在路易斯酸存在下交联。

4. 发明申请

WO2010112410A1 POLYMERIZABLE COMPOSITIONS 审中-公开
标题翻译：可聚合组合物
公开(公告)号：WO2010112410A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/053969
申请日：2010-03-26
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
IPC分类号： C07C245/24 , C08F2/50 , C08F8/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR 8 R 9 )-, Z 1 is -O-, -NR 10 -, -CH 2 -,-(CR 11 R 12 )- or -C(=O)- and R 1 to R 12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.
摘要翻译：本发明涉及其中Q是直接键或二价基 - （CR 8 R 9） - ，Z 1是-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。式（I）的大多数三氮烯也是新型的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。

5. 发明申请

WO2010079102A1 POLYMERISATION INITIATOR 审中-公开
标题翻译：聚合反应器
公开(公告)号：WO2010079102A1
公开(公告)日：2010-07-15
申请号：PCT/EP2009/067947
申请日：2009-12-28
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine Christian , FALLER, Marc
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine Christian , FALLER, Marc
IPC分类号： C07D211/94 , C08F4/00 , C08K5/3435
CPC分类号： C07D211/94 , C07C291/02 , C07C2601/14
摘要： The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.
摘要翻译：本发明涉及新的O-二烷基氨基 - 异脲和包含通式（I）化合物的这些O-二烷基氨基 - 异脲的可聚合组合物。本发明还涉及O-二烷基氨基 - 异脲作为聚合引发剂的用途，特别是制备涂料或用于聚烯烃的可控降解。

6. 发明公开

EP2414324A1 POLYMERIZABLE COMPOSITIONS 审中-公开
标题翻译：聚合组合物
公开(公告)号：EP2414324A1
公开(公告)日：2012-02-08
申请号：EP10710350.9
申请日：2010-03-26
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
IPC分类号： C07C245/24 , C08F2/50 , C08F8/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR
8 R
9 )-, Z
1 is -O-, -NR
10 -, -CH
2 -,-(CR
11 R
12 )- or -C(=O)- and R
1 to R
12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.

7. 发明授权

EP2912023B1 IMINOXYTRIAZINES AS RADICAL GENERATORS 有权
标题翻译：作为基础生成物的亚胺基三嗪
公开(公告)号：EP2912023B1
公开(公告)日：2017-01-11
申请号：EP13779846.8
申请日：2013-10-22
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc
IPC分类号： C07D251/30 , C07D251/42 , C07D403/14
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107

8. 发明授权

EP2427428B1 O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 有权
标题翻译： O-亚硝基异脲化合物及其可聚合组合物
公开(公告)号：EP2427428B1
公开(公告)日：2015-08-19
申请号：EP10721387.8
申请日：2010-05-05
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
IPC分类号： C07C275/70 , C08F4/00
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02

9. 发明公开

EP2427428A1 O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF 有权
标题翻译： O-亚硝基异脲化合物及其可聚合组合物
公开(公告)号：EP2427428A1
公开(公告)日：2012-03-14
申请号：EP10721387.8
申请日：2010-05-05
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc , SPONY, Bruno
IPC分类号： C07C275/70 , C08F4/00
CPC分类号： C08F120/18 , C07C251/58 , C07C275/70 , C07C2601/14 , C07C2601/20 , C08F4/00 , C08F8/32 , C09D135/02
摘要： The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R
100 and R
101 are independently H, C
1-18 alkyl, C
3 -C
12 cycloalkyl, C
6 -C
14 aryl, C
1 -C
14 heteroaryl, C
7 -C
15 aralkyl, C
2 -C
14 heteroaralkyl, Cyano, or R
100 and R
101 form together with the carbon to which they are attached a mono or polycyclic C
3 -C
18 carbocyclic or C
1 -C
18 heterocyclic ring; R
102 and R
103 are independently C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl, C
6 -C
14 aryl, C
6 -C
14 aryl once or more than once substituted by C
1 -C
18 alkyl; C
7 -C
15 aralkyl, (CH
3 )
3 Si-; or R
102 and R
103 are C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl, C
6 -C
14 aryl, C
7 -C
15 aralkyl or R
102 and R
103 are C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C
1 -C
18 alkylamino, bis(C
1 -C
18 alkyl)amino or tris(C
1 -C
1t alkyl)ammonium; R
104 if n is 1 is is H, C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl, C
7 -C
14 aralkyl, C
6 -C
14 aryl or acyl selected from the group consisting of the following acyls -C(=O)-H, -C(=O)-C
1 -C
18 alkyl, -C(=O)-C
2 -d
18 alkenyl, -C(=O)-C
6 -C
14 aryl, -C(=O)-C
2 -C
18 alkenyl-C
6 -C
14 aryl, -C(=O)-O-C
1 C
18 alkyl, -C(=O)-O-C
6 -C
14 aryl, -C(=O)-NH-C
1 -C
18 alkyl, -C(=O)-NH-C
6 -C
14 aryl and -C(=O)-N(C
1 C
18 alkyl)
2 ; or R
102 and R
104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R
104 if n is more than 1 is di-, tri-, tetra-C
1 -C
18 alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
摘要翻译：本发明涉及O-亚氨基 - 异脲化合物作为自由基来源在包含这些O-亚氨基 - 异脲和新的O-亚氨基 - 异脲化合物的可聚合组合物中的用途。 O-氨基异脲化合物是式（I）的化合物，其中n是1,2,3或4，R 100和R 101独立地是H，C 1-18烷基，C 3 -C 12环烷基，C 6 -C 12环烷基， C 1 -C 14杂芳基，C 7 -C 15芳烷基，C 2 -C 14杂芳烷基，氰基或R 100和R 101与它们所连接的碳一起形成单环或多环C 3 -C 18碳环或 C 1 -C 18杂环; R 102和R 103独立地为C 1 -C 18烷基取代一次或多次的C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 6 -C 14芳基; C 7 -C 15芳烷基，（CH 3）3 Si-; 或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基，C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基，C 3 -C 12环烷基为被O或被选自C 1 -C 18烷基氨基，双（C 1 -C 18烷基）氨基或三（C 1 -C 1烷基）铵的含N的基团中断或取代; 如果n为1，则R 104为H，C 1 -C 18烷基，C 3 -C 12环烷基，C 7 -C 14烷基，C 6 -C 14芳基或酰基，所述酰基选自下列酰基-C（= O）（= O）-C 1 -C 18烷基，-C（= O）-C 2 -C 18链烯基，-C（= O）-C 6 -C 14芳基，-C（= O）-C （= O）-OC 1 -C 18烷基，-C（= O）-OC 6 -C 14芳基，-C（= O）-NH-C 1 -C 18烷基，C 2 -C 18链烯基-C 6 -C 14芳基， -C（= O）-NH-C 6 -C 14芳基和-C（= O）-N（C 1 -C 18烷基）2; 或者如果n为1，则R 102和R 104与它们所连接的氮原子一起形成可含有另外的杂原子的5至12元环，如果n大于1，则R 104为二 - ，三 - ，四 - C 1 -C 18烷叉基，二酰基，三酰基或四酰基及其盐。

10. 发明公开

EP2912023A1 IMINOXYTRIAZINES AS RADICAL GENERATORS 有权
标题翻译：作为基础生成物的亚胺基三嗪
公开(公告)号：EP2912023A1
公开(公告)日：2015-09-02
申请号：EP13779846.8
申请日：2013-10-22
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , CARROY, Antoine , FALLER, Marc
IPC分类号： C07D251/30 , C07D251/42 , C07D403/14
CPC分类号： C09J133/14 , C07D251/30 , C07D251/42 , C07D403/14 , C09D11/107
摘要： Iminoxytriazine compounds of the formula (I), wherein n is 1 or 2; R
1 and R
2 independently of each other are hydrogen, NH
2 , NHR
5 , NR
5 R
6 , COR
5 , COOR
5 , CONH
2 , CONHR
5 , CONR
5 R
6 , CN, SR
5 , OR
5 , C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl, C
6 -C
14 aryl or C
2 -C
14 heteroaryl, wherein said C
3 -C
12 cycloalkyl, C
6 -C
14 aryl or C
2 -C
14 heteroaryl is unsubstituted or substituted by one or more radicals selected from the group consisting of C
1 -C
12 alkyl, C
3 -C
12 -cycloalkyl, phenyl, halogen and C
1 -C
12 alkoxy, or R
1 and R
2 together with the C atom to which they are linked form a 4 to 12 membered carbocyclic or heterocyclic saturated or unsaturated ring which is unsubstituted or substituted by one or more radicals selected from the group consisting of C
1 -C
12 alkyl, C
3 -C
12 -cycloalkyl, phenyl, halogen and C
1 -C
12 alkoxy; R
3 is F, Cl, OH, OR, SH, SR
5 , NH
2 , NHR
5 , NR
5 R
6 or R
1 R
2 C=N-O-; wherein R
1 and R
2 in all groups R
1 R
2 C=N-O- in the compound of the formula I are identical or different; if n is 1, R
4 is F, Cl, OH, OR
5 , SH, SR
5 , NH
2 , NHR
5 , NR
5 R
6 or R
1 R
2 C=N-O-; wherein R
1 and R
2 in all groups R
1 R
2 C=N-O- in the compound of the formula I are identical or different; if n is 2, R
4 is a difunctional group derived from a diol, diamine, aminoalcohol or mercaptoalcohol; R
5 and R
6 independently of each other are C
1 -C
18 alkyl, C
3 -C
12 cycloalkyl, C
6 -C
14 aryl or C
2 -C
14 heteroaryl; are suitable as radical generating agents.
摘要翻译：式（I）的氨基氧基三嗪化合物，其中n是1或2; R 1和R 2彼此独立地为氢，NH 2，NHR 5，NR 5 R 6，COR 5，COOR 5，CONH 2，CONHR 5，CONR 5R 6，CN，SR 5，OR 5，C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基，其中所述C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基未被取代或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基的基团，或者R 1和R 2与它们连接的C原子一起形成4 至12元碳环或杂环饱和或不饱和环，其未被取代或被一个或多个选自C 1 -C 12烷基，C 3 -C 12环烷基，苯基，卤素和C 1 -C 12烷氧基 ; R 3是F，Cl，OH，OR，SH，SR 5，NH 2，NHR 5，NR 5 R 6或R 1 R 2C = N-O-; 其中式I化合物中所有基团R 1 R 2 C = N-O-中的R 1和R 2相同或不同; 如果n为1，则R 4为F，Cl，OH，OR 5，SH，SR 5，NH 2，NHR 5，NR 5 R 6或R 1R 2C = N-O-; 其中式I化合物中所有基团R 1 R 2 C = N-O-中的R 1和R 2相同或不同; 如果n是2，则R 4是衍生自二醇，二胺，氨基醇或巯基醇的双官能团; R 5和R 6彼此独立地为C 1 -C 18烷基，C 3 -C 12环烷基，C 6 -C 14芳基或C 2 -C 14杂芳基; 适合作为自由基生成剂。

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