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1. 发明申请

WO2010108862A1 NOVEL OLIGOFUNCTIONAL PHOTOINITIATORS 审中-公开
标题翻译：新颖的功能性摄影机
公开(公告)号：WO2010108862A1
公开(公告)日：2010-09-30
申请号：PCT/EP2010/053607
申请日：2010-03-19
申请人： BASF SE , BERENS, Ulrich , BIRBAUM, Jean-Luc , STUDER, Katia
发明人： BERENS, Ulrich , BIRBAUM, Jean-Luc , STUDER, Katia
IPC分类号： C07C69/76 , C07C69/80 , C07C69/82 , C07C45/63 , C07C45/64
CPC分类号： C07C45/63 , B33Y70/00 , C07C45/64 , C07C67/14 , C07C69/76 , C07C69/80 , C07C69/82 , C09D11/101 , C07C49/813 , C07C49/83
摘要： The invention pertains to novel oligofunctional photoinitiators of the formula (1) or (1A). R 1 and R 2 are methyl or together are -(CH 2 ) 5 -; and n is 2 or 3, and the solvent in (1A) is water or an organic solvent; and their use in photopolymerizable compositions, in particular inks.
摘要翻译：本发明涉及式（1）或（1A）的新型低官能光引发剂。 R1和R2是甲基或一起是 - （CH2）5-; n为2或3，（1A）中的溶剂为水或有机溶剂; 以及它们在可光聚合组合物中的用途，特别是油墨。

2. 发明申请

WO2010112410A1 POLYMERIZABLE COMPOSITIONS 审中-公开
标题翻译：可聚合组合物
公开(公告)号：WO2010112410A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/053969
申请日：2010-03-26
申请人： BASF SE , NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
IPC分类号： C07C245/24 , C08F2/50 , C08F8/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR 8 R 9 )-, Z 1 is -O-, -NR 10 -, -CH 2 -,-(CR 11 R 12 )- or -C(=O)- and R 1 to R 12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.
摘要翻译：本发明涉及其中Q是直接键或二价基 - （CR 8 R 9） - ，Z 1是-O-，-NR 10 - ， - CH 2 - ， - （CR 11 R 12） - 或 - C（= O） - 和R 1至R 12是任选取代的烃残基，作为可用于由自由基引发的反应的基团的前体，例如不饱和单体的聚合和聚烯烃的降解。式（I）的大多数三氮烯也是新型的，并且还要求制备式（I）的三氮烯和包含它们的可聚合组合物。

3. 发明申请

WO2010063612A1 SILSESQUIOXANE PHOTOINITIATORS 审中-公开
标题翻译： SILSESQUIOXANE照相机
公开(公告)号：WO2010063612A1
公开(公告)日：2010-06-10
申请号：PCT/EP2009/065695
申请日：2009-11-24
申请人： BASF SE , FREY, Markus , FROSSARD, Christophe , STUDER, Katia , POWELL, Karin , BIRBAUM, Jean-Luc , MÜLLER, Martin
发明人： FREY, Markus , FROSSARD, Christophe , STUDER, Katia , POWELL, Karin , BIRBAUM, Jean-Luc , MÜLLER, Martin
IPC分类号： C07F7/21
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1') wherein n is 2m; m is an integer of 2 to 30; the sum of n' + a is an integer 4-60; n' is an even-numbered integer; a is an even-or uneven-numbered integer; and for example different A C 1 -C 12 alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C 1 -C 3 alkylene, preferably propylene; R 1 and R 2 for example are a photoactive moiety Q, or C 2 - 20 alkyl; Q is for example a group of formula (4); Z 2 is for example C 1 -C 6 alkylene which is unsubstituted or substituted by one or more OR 6 ; and R 6 , R 12 , R 13 and R 14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.
摘要翻译：光引发剂化合物，其包含与多面体低聚倍半硅氧烷结合的光活性部分和胺官能团，该光引发剂由式（1）或（1'）表示，其中n为2m; m为2〜30的整数。 n'+ a的和为4-60的整数; n'是偶数整数; a是偶数或不均匀的整数; 例如不同的A C1-C12烷基或光活性部分Q1或式（2）的基团; E例如是直接键合，L是直链或支链C1-C3亚烷基，优选丙烯; R1和R2例如是光活性部分Q或C2-20烷基; Q例如是式（4）的一组; Z2为例如未被取代或被一个或多个OR 6取代的C 1 -C 6亚烷基; R 6，R 12，R 13和R 14例如为氢; 特别适用于低迁移性光引发剂。

4. 发明申请

WO2014060450A1 HYBRID PHOTOINITIATORS 审中-公开
标题翻译：混合摄影机
公开(公告)号：WO2014060450A1
公开(公告)日：2014-04-24
申请号：PCT/EP2013/071582
申请日：2013-10-16
申请人： BASF SE
发明人： NESVADBA, Peter , BIRBAUM, Jean-Luc , PILAK, Yvonne , SPONY, Bruno , ZIEGLER, Florian
IPC分类号： C07C69/616 , C08F2/50
CPC分类号： C08F2/50 , C07C67/14 , C07C69/003 , C07C69/616 , C07C69/716 , C07C69/738 , C09D4/00
摘要： Compounds of the formula (I), wherein m is 1 or 2; R 1 , R 2 , R 4 and R 5 independently of one another are hydrogen, C 1 -C 4 alkyl, C 5 -C 7 cyclo-alkyl, phenyl, C 1 -C 4 alkoxy, C 5 -C 7 cycloalkoxy or phenoxy; R 3 , if m is 1, has one of the meanings as given above for R 1 , R 2 , R 4 and R 5 ; R 3 , if m is 2, is a divalent group; R 6 is hydrogen or C 1 -C 4 alkyl; R 7 is hydrogen, and if R 6 is hydrogen then R 7 may additionally be C 1 -C 4 alkyl; R 8 is group (A) or (B) X is O, O-CH 2 - or -O(CHR 14 )-; n is 0-10; provided that (i) if n is 0, and X is O, then R 8 is a group A; (ii) if n is other than 0, then X is O and R 8 is the group A; R 9 and R 10 independently of one another are hydrogen or C 1 -C 4 alkyl; R 11 and R 12 independently of one another are C 1 -C 4 alkyl or form together with the C atom to which they are attached a 5 to 7 membered saturated carbocyclic ring; R 13 is hydrogen, C 1 -C 4 alkyl, C 5 -C 7 cycloalkyl, 2-tetrahydropyranyl or Si(C 1 -C 4 alkyl) 3 ; R 14 is a group (A'); and R' 13 has one of the meanings as given for R 13 or is the group (C); are effective photoinitiator compounds.
摘要翻译：式（I）化合物，其中m为1或2; R 1，R 2，R 4和R 5彼此独立地是氢，C 1 -C 4烷基，C 5 -C 7环烷基，苯基，C 1 -C 4烷氧基，C 5 -C 7环烷氧基或苯氧基; R3如果m为1，具有如上对R1，R2，R4和R5所给出的含义之一; R3如果m为2，则为二价基团; R6是氢或C1-C4烷基; R7是氢，如果R6是氢，则R7可以另外是C 1 -C 4烷基; R8是基团（A）或（B）X是O，O-CH2-或-O（CHR14） - ; n为0-10; 条件是（i）如果n为0，X为O，则R 8为A组; （ii）如果n不为0，则X为O且R 8为A组; R 9和R 10彼此独立地是氢或C 1 -C 4烷基; R 11和R 12彼此独立地是C 1 -C 4烷基或与它们所连接的C原子一起形成5至7元饱和碳环; R 13是氢，C 1 -C 4烷基，C 5 -C 7环烷基，2-四氢吡喃基或Si（C 1 -C 4烷基）3; R14是一组（A'）; 和R'13具有R 13给出的含义之一或是（C）基团; 是有效的光引发剂化合物。

5. 发明公开

EP2411359A1 NOVEL OLIGOFUNCTIONAL PHOTOINITIATORS 有权转让
标题翻译：新型寡光引发剂
公开(公告)号：EP2411359A1
公开(公告)日：2012-02-01
申请号：EP10709233.0
申请日：2010-03-19
申请人： BASF SE
发明人： BERENS, Ulrich , BIRBAUM, Jean-Luc , STUDER, Katia
IPC分类号： C07C69/76 , C07C69/80 , C07C69/82 , C07C45/63 , C07C45/64
CPC分类号： C07C45/63 , B33Y70/00 , C07C45/64 , C07C67/14 , C07C69/76 , C07C69/80 , C07C69/82 , C09D11/101 , C07C49/813 , C07C49/83
摘要： The invention pertains to novel oligofunctional photoinitiators of the formula (1) or (1A). R
1 and R
2 are methyl or together are -(CH
2 )
5 -; and n is 2 or 3, and the solvent in (1A) is water or an organic solvent; and their use in photopolymerizable compositions, in particular inks.

6. 发明公开

EP2909165A1 HYBRID PHOTOINITIATORS 有权转让
标题翻译： HYBRID FOTOINITIATOREN
公开(公告)号：EP2909165A1
公开(公告)日：2015-08-26
申请号：EP13779551.4
申请日：2013-10-16
申请人： BASF SE
发明人： NESVADBA, Peter , BIRBAUM, Jean-Luc , PILAK, Yvonne , SPONY, Bruno , ZIEGLER, Florian
IPC分类号： C07C69/616 , C08F2/50
CPC分类号： C08F2/50 , C07C67/14 , C07C69/003 , C07C69/616 , C07C69/716 , C07C69/738 , C09D4/00
摘要： Compounds of the formula I wherein m is 1 or 2; R1, R2, R4 and R5 independently of one another are hydrogen, C1-C4alkyl, C5-C7 cycloalkyl, phenyl, C1-C4alkoxy, C5-C7cycloalkoxy or phenoxy; R3, if m is 1, has one of the meanings as given above for R1, R2, R4 and R5; R3, if m is 2, is a divalent group; R6 is hydrogen or C1-C4alkyl; R7 is hydrogen, and if R6 is hydrogen then R7 may additionally be C1-C4alkyl; R8 is group A or B X is O, O—CH2— or —O(CHR14)—; n is 0-10; provided that (i) if n is 0, and X is O, then R8 is a group A; (ii) if n is other than 0, then X is O and R8 is the group A; R9 and R10 independently of one another are hydrogen or C1-C4alkyl; R11 and R12 independently of one another are C1-C4alkyl or form together with the C atom to which they are attached a 5 to 7 membered saturated carbocyclic ring; R13 is hydrogen, C1-C4alkyl, C5-C7cycloalkyl, 2-tetrahydropyranyl or Si(C1-C4alkyl)3; R14 is a group A′ and R′13 has one of the meanings as given for R13 or is the group C are effective photoinitiator compounds.

7. 发明授权

EP1711862B1 FUNCTIONALIZED PHOTOINITIATORS 有权转让
标题翻译： FUNKTIONALISIERTE FOTOINITIATOREN
公开(公告)号：EP1711862B1
公开(公告)日：2014-09-10
申请号：EP05707825.5
申请日：2005-01-24
申请人： BASF SE
发明人： DIETLIKER, Kurt , HÜSLER, Rinaldo , BIRBAUM, Jean-Luc , WOLF, Jean-Pierre
IPC分类号： G03F7/031 , C08F2/50 , G03F7/00
CPC分类号： C08F2/50 , B33Y70/00 , G03F7/0007 , G03F7/001 , G03F7/0037 , G03F7/031

8. 发明公开

EP2414324A1 POLYMERIZABLE COMPOSITIONS 审中-公开
标题翻译：聚合组合物
公开(公告)号：EP2414324A1
公开(公告)日：2012-02-08
申请号：EP10710350.9
申请日：2010-03-26
申请人： BASF SE
发明人： NESVADBA, Peter , BUGNON FOLGER, Lucienne , BIRBAUM, Jean-Luc , FALLER, Marc , CARROY, Antoine
IPC分类号： C07C245/24 , C08F2/50 , C08F8/50
CPC分类号： C08F4/04 , C07D211/98 , C08F2/46 , C09D175/14
摘要： The invention relates to the use of triazenes of formula (I) wherein Q is a direct bond or a bivalent radical -(CR
8 R
9 )-, Z
1 is -O-, -NR
10 -, -CH
2 -,-(CR
11 R
12 )- or -C(=O)- and R
1 to R
12 are optionally substituted hydrocarbon residues, as precursors for radicals useful in reactions triggered by free radicals, such as polymerization of unsaturated monomers and degradation of polyolefins. Most of the triazenes of formula (I) are novel and claimed, too, as well as the preparation of triazenes of formula (I) and polymerisable compositions comprising them.

9. 发明授权

EP2370449B1 SILSESQUIOXANE PHOTOINITIATORS 失效转让
标题翻译： SILSESQUIOXANE ALS FOTOINITIATOREN
公开(公告)号：EP2370449B1
公开(公告)日：2013-08-14
申请号：EP09756320.9
申请日：2009-11-24
申请人： BASF SE
发明人： FREY, Markus , FROSSARD, Christophe , STUDER, Katia , POWELL, Karin , BIRBAUM, Jean-Luc , MÜLLER, Martin
IPC分类号： C07F7/21
CPC分类号： C07F7/21 , B33Y70/00

10. 发明公开

EP2370449A1 SILSESQUIOXANE PHOTOINITIATORS 失效转让
标题翻译：半硅氧烷AS光引发剂
公开(公告)号：EP2370449A1
公开(公告)日：2011-10-05
申请号：EP09756320.9
申请日：2009-11-24
申请人： BASF SE
发明人： FREY, Markus , FROSSARD, Christophe , STUDER, Katia , POWELL, Karin , BIRBAUM, Jean-Luc , MÜLLER, Martin
IPC分类号： C07F7/21
CPC分类号： C07F7/21 , B33Y70/00
摘要： Photoinitiator compounds comprising both a photoactive moiety and an amine functionality, bonded to a polyhedral oligomeric silsesquioxane, which photoinitiator is represented by formula (1) or (1') wherein n is 2m; m is an integer of 2 to 30; the sum of n' + a is an integer 4-60; n' is an even-numbered integer; a is an even-or uneven-numbered integer; and for example different A C
1 -C
12 alkyl, or a photoactive moiety Q1, or a group of formula (2); E for example is a direct bond, L is linear or branched C
1 -C
3 alkylene, preferably propylene; R
1 and R
2 for example are a photoactive moiety Q, or C
2 -
20 alkyl; Q is for example a group of formula (4); Z
2 is for example C
1 -C
6 alkylene which is unsubstituted or substituted by one or more OR
6 ; and R
6 , R
12 , R
13 and R
14 for example are hydrogen; are especially suitable as low-migrating photoinitiators.

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