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    • 3. 发明申请
    • O-IMINO-ISO-UREA COMPOUNDS AND POLYMERIZABLE COMPOSITIONS THEREOF
    • O-IMINO-ISO-UREA化合物及其可聚合组合物
    • WO2010128062A1
    • 2010-11-11
    • PCT/EP2010/056063
    • 2010-05-05
    • BASF SENESVADBA, PeterBUGNON FOLGER, LucienneCARROY, AntoineFALLER, MarcSPONY, Bruno
    • NESVADBA, PeterBUGNON FOLGER, LucienneCARROY, AntoineFALLER, MarcSPONY, Bruno
    • C07C275/70C08F4/00
    • C08F120/18C07C251/58C07C275/70C07C2601/14C07C2601/20C08F4/00C08F8/32C09D135/02
    • The invention relates to the use of O-imino-iso-urea compounds as source of radicals to polymerizable compositions comprising these O-imino-iso-urea and to new O-imino-iso-urea compounds. The O-lmino-isoureas compounds are compounds of the Formula (I), wherein n is 1, 2, 3 or 4, R 100 and R 101 are independently H, C 1-18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 1 -C 14 heteroaryl, C 7 -C 15 aralkyl, C 2 -C 14 heteroaralkyl, Cyano, or R 100 and R 101 form together with the carbon to which they are attached a mono or polycyclic C 3 -C 18 carbocyclic or C 1 -C 18 heterocyclic ring; R 102 and R 103 are independently C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 6 -C 14 aryl once or more than once substituted by C 1 -C 18 alkyl; C 7 -C 15 aralkyl, (CH 3 ) 3 Si-; or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 6 -C 14 aryl, C 7 -C 15 aralkyl or R 102 and R 103 are C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl which are interrupted or substituted by O or by N containing groups selected from C 1 -C 18 alkylamino, bis(C 1 -C 18 alkyl)amino or tris(C 1 -C 1t alkyl)ammonium; R 104 if n is 1 is is H, C 1 -C 18 alkyl, C 3 -C 12 cycloalkyl, C 7 -C 14 aralkyl, C 6 -C 14 aryl or acyl selected from the group consisting of the following acyls -C(=O)-H, -C(=O)-C 1 -C 18 alkyl, -C(=O)-C 2 -d 18 alkenyl, -C(=O)-C 6 -C 14 aryl, -C(=O)-C 2 -C 18 alkenyl-C 6 -C 14 aryl, -C(=O)-O-C 1 C 18 alkyl, -C(=O)-O-C 6 -C 14 aryl, -C(=O)-NH-C 1 -C 18 alkyl, -C(=O)-NH-C 6 -C 14 aryl and -C(=O)-N(C 1 C 18 alkyl) 2 ; or R 102 and R 104 if n is 1 form together with the nitrogen atom to which they are attached a 5 to 12 membered ring which may contain additional heteroatoms, R 104 if n is more than 1 is di-, tri-, tetra-C 1 -C 18 alkylidene, diacyls, triacyls or tetraacyls and salts thereof.
    • 本发明涉及O-亚氨基 - 异脲化合物作为自由基源的用途,其包含这些O-亚氨基 - 异脲和包含新的O-亚氨基 - 异脲化合物的可聚合组合物。 O - 异喹啉化合物是式(I)化合物,其中n为1,2,3或4,R 101和R 101独立地为H,C 1-18烷基,C 3 -C 12环烷基,C 6 -C 14芳基,C 1 -C 14杂芳基, C 1 -C 15芳烷基,C 2 -C 14杂芳烷基,氰基或R 100和R 101与它们所连接的碳一起形成单或多环C 3 -C 18碳环或C 1 -C 18杂环; R 102和R 103独立地是C 1 -C 18烷基,C 3 -C 12环烷基,C 6 -C 14芳基,C 1 -C 14芳基,其一次或多于一个被C 1 -C 18烷基取代; C 7 -C 15芳烷基,(CH 3)3 Si- 或R 102和R 103为C 1 -C 18烷基,C 3 -C 12环烷基,C 6 -C 14芳基,C 7 -C 15芳烷基或R 102和R 103为C 1 -C 18烷基,C 3 -C 12环烷基,其被O或含N的基团所取代或被取代,所述基团选自C 1 -C 18烷基氨基, 双(C1-C18烷基)氨基或三(C1-C1烷基)铵; 如果n为1,R 104为H,C 1 -C 18烷基,C 3 -C 12环烷基,C 7 -C 14芳烷基,C 6 -C 14芳基或选自以下酰基-C(= O)-H,-C(= O) -C(= O)-C 2 -C 18芳基,-C(= O)-C 6 -C 14芳基,-C(= O)-C 2 -C 18烯基-C 6 -C 14芳基,-C(= O)-O C 1 -C 18烷基,-C(= O)-O-C 6 -C 14芳基,-C(= O)-NH-C 1 -C 18烷基,-C(= O)-NH-C 6 -C 14芳基和-C(= O)-N (C1C18alkyl)2; 如果n为1,则与R 102和R 104一起形成与它们所连接的氮原子一起形成可含有其它杂原子的5至12元环,如果n大于1,则R104是二 - ,三 - ,四-C1-C18亚烷基 ,二酰基,三酰基或四酰基及其盐。