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1. 发明授权

US06828468B2 Preparation of higher &agr;, &bgr;-unsaturated alcohols 失效
标题翻译：制备较高级的α，β-不饱和醇
公开(公告)号：US06828468B2
公开(公告)日：2004-12-07
申请号：US10138338
申请日：2002-05-06
申请人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
发明人： Andreas Ansmann , Jochem Henkelmann , Alois Kindler , Heinz Etzrodt , Carsten Oost , Susanne Stutz , Christian Tragut , Bernhard Bockstiegel , Klaus Reimer , Manfred Stroezel , Walter Dobler
IPC分类号： C07C3304
CPC分类号： C07C49/203 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0225 , C07C29/17 , C07C29/42 , C07C45/62 , C07C45/676 , C07C33/02 , C07C33/048 , C07C49/04
摘要： Higher &agr;,&bgr;-unsaturated alcohols are prepared by monoethynylation of a ketone by the NH3/KOH method, if desired hydrogenation of the acetylene alcohol in the presence of hydrogen over a Pd-containing thin layer catalyst, purifying distillation of the hydrogenation product, preferably in a dividing wall column with recirculation of the unreacted ketone to the ethynylation step, and, if desired, preparation of higher alcohols having in each case 5 more carbon atoms in the chain by reacting the alcohols prepared by monoethynylation and, if desired, partial hydrogenation with alkyl acetoacetates diketene in a Carroll reaction to form ketones and using these as starting materials for the steps ethynylation, optional hydrogenation and fractional distillation.
摘要翻译：如果需要在氢气存在下在含Pd的薄层催化剂上氢化乙炔醇，纯化氢化产物的蒸馏，优选的是通过NH 3 / KOH方法将酮单异构化制备较高级的α，β-不饱和醇在具有未反应酮再循环至乙炔化步骤的分隔壁塔中，并且如果需要，通过使通过单异丁烯基化制备的醇和如果需要的话进行部分氢化制备在各种情况下在链中多出5个碳原子的高级醇在Carroll反应中使用烷基乙酰乙酸酯双烯酮形成酮，并将其用作步骤乙炔化，任选的氢化和分馏的起始原料。

2. 发明授权

US6051741A Preparation of .gamma.,.delta.-unsaturated ketones by the Carroll reaction, novel catalysts therefor and the preparation thereof 失效
标题翻译：通过Carroll反应制备γ，δ-不饱和酮，其新型催化剂及其制备
公开(公告)号：US6051741A
公开(公告)日：2000-04-18
申请号：US168378
申请日：1998-10-08
申请人： Heinz Etzrodt , Dietmar Weller , Carsten Oost , Hagen Jaedicke , Manfred Stroezel , Bernhard Bockstiegel , Lothar Laupichler , Klaus Reimer
发明人： Heinz Etzrodt , Dietmar Weller , Carsten Oost , Hagen Jaedicke , Manfred Stroezel , Bernhard Bockstiegel , Lothar Laupichler , Klaus Reimer
IPC分类号： B01J31/02 , B01J31/14 , C07B61/00 , C07C45/67 , C07C45/68 , C07C49/203 , C07F5/06 , C07C45/00
CPC分类号： C07F5/069 , B01J31/0211 , C07C45/676
摘要： A process for preparing .gamma.,.delta.-unsaturated ketones of the general formula I ##STR1## by reacting an allyl alcohol of the general formula II ##STR2## in which R.sup.1 is H or a hydrocarbon radical having 1 to 20 carbon atoms, with diketene or an alkyl acetoacetate of the general formula III ##STR3## in which R.sup.2 is alkyl having 1 to 4 carbon atoms in an unmodified or modified Carroll reaction in the presence of an aluminum catalyst, wherein aluminum compounds which are stable liquids at room temperature, or a mixture of such aluminum compounds, which comprise at least one radical formed from an alkyl acetoacetate and 1 or 2 alkoxy radicals, or else comprise exclusively radicals formed from alkyl acetoacetates, which are esterified with sec-butanol or isobutanol, or else are esterified with at least two different alcohols, are used as aluminum catalyst. Also claimed are the novel mixtures of aluminum compounds which comprise radicals which are formed exclusively from alkyl acetoacetates and are esterified with at least two different alkanols, and the batchwise and continuous preparation of the liquid aluminum catalysts.
摘要翻译：通过使通式II的烯丙醇（其中R 1为H或具有1至20个碳原子的烃基）的烯丙醇与二烯酮或一般的乙酰乙酸烷基酯反应制备通式I的γ，β-不饱和酮的方法式III其中R2是在未改性或改性的Carroll反应中在铝催化剂存在下具有1至4个碳原子的烷基，其中在室温下为稳定液体的铝化合物或这种铝化合物的混合物，其包含在由烷基乙酰乙酸酯和1或2个烷氧基形成的至少一个基团，或者仅由烷基乙酰乙酸酯形成的由仲丁醇或异丁醇酯化的酰基或者由至少两种不同的醇酯化的基团用作铝催化剂。还要求的是铝化合物的新型混合物，其包含仅由乙酰乙酸烷基酯形成并且与至少两种不同的链烷醇酯化的基团，以及液体铝催化剂的分批连续制备。

3. 发明授权

US06329554B1 Continuous preparation of unsaturated ketones 失效
标题翻译：连续制备不饱和酮
公开(公告)号：US06329554B1
公开(公告)日：2001-12-11
申请号：US09391619
申请日：1999-09-07
申请人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Bernhard Bockstiegel , Klaus Reimer , Gerd Kaibel , Hagen Jaedicke
发明人： Carsten Oost , Manfred Stroezel , Heinz Etzrodt , Dietmar Weller , Bernhard Bockstiegel , Klaus Reimer , Gerd Kaibel , Hagen Jaedicke
IPC分类号： C07C4500
CPC分类号： C07C45/676 , B01D3/009 , B01D3/14 , B01D3/141 , B01D3/322 , B01J19/24 , B01J2219/00103 , B01J2219/00162 , B01J2219/00777 , B01J2219/32268 , Y02P20/127 , Y02P20/582 , C07C49/203 , C07C49/255
摘要： Process for the continuous preparation of unsaturated ketones of the formula I where the dashed line can be an additional C—C bond, R1 is an alkyl, and R2 is an aliphatic hydrocarbon having from 1 to 37 carbons, a cycloalkyl or a cycloalkylalkyl, by reacting an unsaturated alcohol of the formula II with an alkyl acetoacetate of the formula III where R3 is an alkyl having from 1 to 5 carbons, in the presence or organic aluminum compounds as catalyst.
摘要翻译：用于连续制备式I的不饱和酮的方法，其中虚线可以是另外的CC键，R 1是烷基，R 2是具有1至37个碳的脂族烃，环烷基或环烷基烷基，通过使不饱和的式II的醇与式III的乙酰乙酸烷基酯反应，其中R 3是具有1至5个碳的烷基，在有机铝化合物作为催化剂存在下进行。

4. 发明授权

US06365790B2 Preparation of C10-C30-alkenes by partial hydrogenation of alkynes over fixed-bed supported palladium catalysts 失效
标题翻译：通过固定床负载的钯催化剂上的炔进行部分氢化制备C10-C30-烯烃
公开(公告)号：US06365790B2
公开(公告)日：2002-04-02
申请号：US09734024
申请日：2000-12-12
申请人： Klaus Reimer , Gerd Kaibel , Ulrich Kammel , Franz Josef Bröcker , Andreas Ansmann , Heinz Etzrodt , Manfred Stroezel , Mathias Haake , Lothar Laupichler , Bernhard Bockstiegel
发明人： Klaus Reimer , Gerd Kaibel , Ulrich Kammel , Franz Josef Bröcker , Andreas Ansmann , Heinz Etzrodt , Manfred Stroezel , Mathias Haake , Lothar Laupichler , Bernhard Bockstiegel
IPC分类号： C07C2900
CPC分类号： C07C29/17 , B01J23/44 , B01J23/50 , B01J35/04 , B01J35/06 , B01J37/0217 , B01J37/0225 , B01J37/08 , C07C5/09 , C07C2523/44 , C07C11/02 , C07C33/025 , C07C33/02
摘要： Alkenes are prepared by partial hydrogenation of alkynes in the liquid phase at from 20 to 250° C. and hydrogen partial pressures of from 0.3 to 200 bar over fixed-bed supported palladium catalysts which are obtainable by heating the support material in the air, cooling, applying a palladium compound and, if required, additionally other metal ions for doping purposes, molding and processing to give monolithic catalyst elements, by a process in which A) alkynes of 10 to 30 carbon atoms are used as starting compounds, B) the palladium compound and, if required, the other metal ions are applied to the support material by impregnation of the heated and cooled support material with a solution containing palladium salts and, if required, other metal ions and subsequent drying, and C) from 10 to 2000 ppm of carbon monoxide (CO) are added to the hydrogenation gas or a corresponding amount of CO is allowed to form in the liquid phase by slight decomposition of a compound which is added to the reaction mixture and eliminates CO under the reaction conditions. The process is particularly advantageous if the partial hydrogenation is carried out in a tube reactor by the trickle-bed or liquid phase procedure with product recycling at cross-sectional loadings of from 20 to 500 m3/m2*h. The process is particularly suitable for the preparation of 3,7,11,15-tetramethyl-1-hexadecen-3-ol (isophytol), 3,7,11-trimethyl-l-dodecen-3-ol (tetrahydronerolidol), 3,7,11-trimethyl-1,4-dodecadien-3-ol, 3,7,11-trimethyl-1,6-dodecadien-3-ol (dihydronerolidol), 3,7-dimethyloct-1,6-dien-3-ol or 3,7-dimethyloct-1-en-3-ol from the corresponding alkynes.
摘要翻译：烯烃通过液相中炔烃在20至250℃的部分氢化和固定床负载的钯催化剂的0.3至200巴的氢分压来制备，其可通过加热空气中的载体材料，冷却使用钯化合物，另外还需要另外的金属离子用于掺杂目的，通过使用10-30个碳原子的炔烃作为起始化合物的方法，模塑和加工以得到整体式催化剂元素，B）钯如果需要，另外的金属离子通过用含有钯盐的溶液浸渍加热和冷却的载体材料以及如果需要的话其它金属离子并随后干燥而被施加到载体材料上，C）为10-2000ppm 的一氧化碳（CO）加入到氢化气体中，或者相应量的CO在液相中形成，通过轻微分解添加到真空中的化合物并且在反应条件下消除CO。如果部分氢化在管式反应器中通过滴流床或液相方法进行，则该方法是特别有利的，其中产物回收的横截面负荷为20-500m 3 / m2 * h。该方法特别适用于制备3,7,11,15-四甲基-1-十六碳烯-3-醇（异山梨糖醇），3,7,11-三甲基-1-十二碳烯-3-醇（四氢化吗啉醇），3 ，7,11-三甲基-1,4-十二碳二烯-3-醇，3,7,11-三甲基-1,6-十二碳二烯-3-醇（二氢吗啉醇），3,7-二甲基辛-1,6-二烯 - 3-醇或3,7-二甲基辛-1-烯-3-醇。

5. 发明授权

US06426540B1 Optimized border of semiconductor components 失效
标题翻译：优化半导体元件的边界
公开(公告)号：US06426540B1
公开(公告)日：2002-07-30
申请号：US09555040
申请日：2000-08-23
申请人： Roland Sittig , Detlef Nagel , Ralf-Ulrich Dudde , Bernd Wagner , Klaus Reimer
发明人： Roland Sittig , Detlef Nagel , Ralf-Ulrich Dudde , Bernd Wagner , Klaus Reimer
IPC分类号： H01L27095
CPC分类号： H01L29/7811 , H01L29/402 , H01L29/404 , H01L29/7813 , H01L29/872
摘要： The invention relates to a semiconductor component which is capable of blocking such as an (IGBT), a thyristor, a GTO or diodes, especially schottky diodes. An insulator profile section (10a, 10b, 10c, 10d, 11) provided in the border area of an anode metallic coating (1, 31) is fixed (directly in the edge area) on the substrate (9) of the component. The insulator profile has a curved area (KB) and a base area (SB), said curved area having a surface (OF) which begins flat and curves outward and upward in a steadily increasing manner. A metallic coating MET1; 30a, 30b, 30c, 30d, 31b) is deposited on the surface (OF). Said coating directly follows the surface curvature and laterally extends the inner anode metallic coating. The upper end of the curved metallic coating (MET1; 30a, 30b . . . ) is distanced and insulated from one of these surrounding outer metallic coatings (MET2; 3) by the surrounding base area (SB) of the insulator profile (10a, . . . , 11) such that an extensively constant course of the line of force which evades extreme values results between both metallic coatings (1, 31, MET1; 3, MET2) when reverse voltage or blocking voltage is applied between the interspaced metallic coatings.
摘要翻译：本发明涉及能够阻挡（IGBT），晶闸管，GTO或二极管，特别是肖特基二极管的半导体元件。设置在阳极金属涂层（1,31）的边界区域中的绝缘体轮廓部分（10a，10b，10c，10d，11）在组件的基底（9）上固定（直接在边缘区域中）。绝缘体轮廓具有弯曲区域（KB）和基部区域（SB），所述弯曲区域具有开始平坦并以稳定增加的方式向外和向上弯曲的表面（OF）。金属涂层MET1; 30a，30b，30c，30d，31b）沉积在表面（OF）上。所述涂层直接遵循表面曲率并横向延伸内阳极金属涂层。弯曲金属涂层（MET1; 30a，30b ...）的上端通过绝缘体轮廓（10a，30b ...）的周围基部区域（SB）与这些周围的外部金属涂层（MET2; 3）之一间隔开并隔离，这样，当在间隔金属涂层之间施加反向电压或阻挡电压时，在金属涂层（1,31，MET1; 3，MET2）之间产生逃避极值的力线的广泛恒定过程。

6. 发明授权

US06956249B2 Termination of semiconductor components 失效
标题翻译：半导体元件的终止
公开(公告)号：US06956249B2
公开(公告)日：2005-10-18
申请号：US10669024
申请日：2003-09-23
申请人： Roland Sittig , Detlef Nagel , Ralf-Ulrich Dudde , Bernd Wagner , Klaus Reimer
发明人： Roland Sittig , Detlef Nagel , Ralf-Ulrich Dudde , Bernd Wagner , Klaus Reimer
IPC分类号： H01L29/06 , H01L29/40 , H01L29/47 , H01L29/74 , H01L29/78 , H01L29/861 , H01L29/872
CPC分类号： H01L29/7811 , H01L29/402 , H01L29/404 , H01L29/7813 , H01L29/872
摘要： The invention relates to a semiconductor component which is capable of blocking such as an (IGBT), a thyristor, a GTO or diodes, especially schottky diodes. An insulator profile section (10a, 10b, 10c, 10d, 11) provided in the border area of an anode metallic coating (1, 31) is fixed (directly in the edge area) on the substrate (9) of the component. The insulator profile has a curved area (KB) and a base area (SB), said curved area having a surface (OF) which begins flat and curves outward and upward in a steadily increasing manner. A metallic coating (MET1; 30a, 30b, 30c, 30d, 31b) is deposited on the surface (OF). Said coating directly follows the surface curvature and laterally extends the inner anode metallic coating. The upper end of the curved metallic coating (MET1; 30a, 30b . . . ) is distanced and insulated from one of these surrounding outer metallic coatings (MET2; 3) by the surrounding base area (SB) of the insulator profile (10a, . . . , 11) such that an extensively constant course of the line of force which evades extreme values results between both metallic coatings (1, 31, MET1; 3, MET2) when reverse voltage or blocking voltage is applied between the interspaced metallic coatings.
摘要翻译：本发明涉及能够阻挡（IGBT），晶闸管，GTO或二极管，特别是肖特基二极管的半导体元件。设置在阳极金属涂层（1,31）的边界区域中的绝缘体轮廓部分（10a，10b，10b，10d，11）被固定（直接在边缘区域中）在基底（9）上组件。绝缘体轮廓具有弯曲区域（KB）和基部区域（SB），所述弯曲区域具有开始平坦并以稳定增加的方式向外和向上弯曲的表面（OF）。金属涂层（MET 1; 30 a，30 b，30 c，30 d，31 b）沉积在表面（OF）上。所述涂层直接遵循表面曲率并横向延伸内阳极金属涂层。弯曲的金属涂层（MET 1; 30 a，30 b ...）的上端通过绝缘体的周围基部区域（SB）与这些周围的外部金属涂层（MET2; 3）中的一个隔开并绝缘（10 a，...，11），使得当反向电压或阻塞电压时，在金属涂层（1,31，MET1; 3，MET2）之间产生逃避极值的力线的广泛恒定过程应用于间隔金属涂层之间。

7. 发明授权

US06653553B2 Cover, constructed as a solar generator, for closing an opening in the bodywork of a vehicle 失效
公开(公告)号：US06653553B2
公开(公告)日：2003-11-25
申请号：US10107895
申请日：2002-03-27
申请人： Klaus Reimer
发明人： Klaus Reimer
IPC分类号： H01L31048
CPC分类号： B60J7/00 , Y10S136/291
摘要： A cover, constructed as a solar generator, for closing an opening in the bodywork of a vehicle which consists of a transparent panel, an assembly attached to the underside of the panel, which assembly consists of a solar cell field and a plastics material in which the latter is embedded, a frame foamed onto the peripheral edge area of the panel, optionally reinforced by embedded profiled bars, and a foam-molded backing layer connected in one piece with the frame. The simply constructed solar cover producible in this way without seal and foam-restricting arrangements exerting contact pressure forces on the assembly allows the application of elevated foaming pressures without the risk of damage to the sensitive solar cells. The backing layer protects the assembly from below and allows the foaming on of projections, ribs and the like. A preferred method of producing the solar cover is also proposed, in which the foaming pressure is >1 bar.

8. 发明授权

US6034320A Sunshine roof panel for a vehicle 失效
标题翻译：阳光屋顶板车
公开(公告)号：US6034320A
公开(公告)日：2000-03-07
申请号：US150475
申请日：1998-09-09
申请人： Joseph Malcherczyk , Reinhard Walter , Fred Melzian , Klaus Reimer , Hans Gochermann , Werner Schwarz
发明人： Joseph Malcherczyk , Reinhard Walter , Fred Melzian , Klaus Reimer , Hans Gochermann , Werner Schwarz
IPC分类号： B60R16/04 , B32B5/18 , B60J7/00 , B60J7/02 , H01L31/048 , H02S30/10 , H01L25/00
CPC分类号： H01L31/048 , B32B17/10018 , B32B17/10788 , B60J7/00 , H02S30/10 , Y02E10/50 , Y02T10/88
摘要： A roof panel incorporating a solar power generator, for a motor vehicle sunshine roof, has a foamed plastic frame around the edge of the panel and a plurality of crystalline solar cells forming a field of solar cells extending considerably into the region of the frame. Special precautions ensure that the crystalline solar cells, which are susceptible to breakage, are not damaged when foaming around the cover to form the frame. The solar cell field enables good use of solar energy and can be accommodated in a lightweight panel.
摘要翻译：包括用于机动车辆阳光屋顶的太阳能发电机的屋顶面板具有围绕面板边缘的发泡塑料框架和多个晶体太阳能电池，其形成相当大的框架区域的太阳能电池区域。特殊的预防措施可确保在盖周围发泡以形成框架时，容易破损的结晶太阳能电池不会损坏。太阳能电池领域能够很好地利用太阳能，并且可以容纳在轻质面板中。

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