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1. 发明授权

US5606095A 2-aminooxymethylenephenylacetic acid derivatives 失效
标题翻译： 2-氨氧基亚甲基苯乙酸衍生物
公开(公告)号：US5606095A
公开(公告)日：1997-02-25
申请号：US462259
申请日：1995-06-05
申请人： Albert Pfiffner , Stephan Trah , Hugo Ziegler
发明人： Albert Pfiffner , Stephan Trah , Hugo Ziegler
IPC分类号： C07C239/08 , C07C239/20 , C07C255/57 , C07C323/23 , C07F9/38 , C07F9/40 , C07C229/00
CPC分类号： C07C239/20
摘要： 2-Aminooxymethylenephenylacetic acid ester derivatives of the formula ##STR1## wherein Z.sub.1 and Z.sub.2 are hydrogen, halogen, hydroxy, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkylcarbonyl, phenoxy, nitro or cyano, or Z.sub.1 and Z.sub.2, together with the linking phenyl radical, are naphthalene or hydrogenated naphthalene, and R.sub.3 is hydrogen or C.sub.1 -C.sub.12 alkyl. The compounds of this invention may be used as the free base or as a protic acid salt and are important intermediates for the manufacture of microbicides for plant protection.
摘要翻译：式（I）的2-氨氧基亚甲基苯基乙酸酯衍生物其中Z 1和Z 2是氢，卤素，羟基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，C 1 -C 4烷基羰基，苯氧基，硝基或氰基或Z 1和Z 2与连接的苯基一起是萘或氢化萘，并且R 3是氢或C 1 -C 12烷基。本发明的化合物可以用作游离碱或质子酸盐，并且是制备用于植物保护的杀微生物剂的重要中间体。

2. 发明授权

US5710314A Microbicides 失效
标题翻译：杀菌剂
公开(公告)号：US5710314A
公开(公告)日：1998-01-20
申请号：US460397
申请日：1995-06-02
申请人： Albert Pfiffner , Stephan Trah
发明人： Albert Pfiffner , Stephan Trah
IPC分类号： C07C67/31 , A01N37/38 , A01N37/50 , C07C67/343 , C07C69/736 , C07C251/48 , C07C251/52 , C07C255/54 , C07C255/61 , C07C69/76 , A01N37/12 , C07C233/00
CPC分类号： A01N37/38 , A01N37/50 , C07C251/52 , C07C255/61 , C07C69/736
摘要： Compounds of formula I ##STR1## and possible isomers and isomeric mixtures thereof, wherein a) X is CH.sub.2 F or CHF.sub.2 ; Y is CH and Z is OMe, or b) X is CH.sub.2 F or CHF.sub.2 ; Y is a nitrogen atom and Z is OMe or NHCH.sub.3, and wherein also m is 0, 1, 2, 3, 4 or 5 and U represents identical or different substituents selected from halogen, cyano, nitro, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkenyloxyiminomethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxyiminomethyl, C.sub.1 -C.sub.2 haloalkyl, C.sub.1 -C.sub.2 haloalkoxy, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy and unsubstituted or substituted benzyl or represents substituents at two adjacent positions of the phenyl ring of formula I that define a fused hydrocarbon bridge so as to form a larger hydrocarbon ring having up to 14 carbon atoms, are suitable for controlling and preventing microorganisms, insects and Acarina on plants. They can be used in the form of commercially customary formulated compositions.
摘要翻译：式I化合物Ⅰ和其可能的异构体和异构体混合物，其中a）X是CH 2 F或CHF 2; Y是CH，Z是OMe，或b）X是CH 2 F或CHF 2; Y是氮原子，Z是OMe或NHCH 3，其中m是0,1,2,3,4或5，U代表相同或不同的选自卤素，氰基，硝基，C 1 -C 12烷基，C 3 -C 8环烷基 C 3 -C 6烯基氧基亚氨基甲基，C 1 -C 4烷氧基，C 1 -C 4烷氧基亚氨基甲基，C 1 -C 2卤代烷基，C 1 -C 2卤代烷氧基，未取代或取代的苯基，未取代或取代的苯氧基和未取代或取代的苄基或在苯环的两个相邻位置定义稠合烃桥以形成具有至多14个碳原子的较大烃环的式I化合物适用于控制和防止植物上的微生物，昆虫和蜱螨属。它们可以以商业习惯配制的组合物的形式使用。

3. 发明授权

US06420423B1 Pesticides 失效
标题翻译：农药
公开(公告)号：US06420423B1
公开(公告)日：2002-07-16
申请号：US09343662
申请日：1999-06-29
申请人： Saleem Farooq , Stephan Trah , Hugo Ziegler , René Zurflüh , Alfons Pascual , Henry Szczepanski , Roger Graham Hall
发明人： Saleem Farooq , Stephan Trah , Hugo Ziegler , René Zurflüh , Alfons Pascual , Henry Szczepanski , Roger Graham Hall
IPC分类号： A61K3124
CPC分类号： C07D213/53 , A01N37/36 , A01N37/38 , A01N37/50 , A01N43/10 , A01N43/40 , A01N43/54 , A01N43/60 , A01N55/00 , C07C249/12 , C07C251/48 , C07C251/60 , C07C255/54 , C07C323/20 , C07C323/47 , C07C2601/02 , C07C2601/08 , C07D239/26 , C07D241/12 , C07D275/03 , C07D317/64 , C07D333/22 , C07F7/081
摘要： Compounds of the formula: in which n, q, A, X, G, Y, Z, R, R2, R3, R4, R5, R7 and R9 are as defined in claim 1, and, where appropriate, E/Z isomers, E/Z isomer mixtures and/or tautomers thereof, in each case in the free form or in an agrochemically suitable salt form, can be used as agrochemical active compounds and can be prepared in a manner known per se.
摘要翻译：下式的化合物：其中n，q，A，X，G，Y，Z，R，R 2，R 3，R 4，R 5，R 7和R 9如权利要求1中所定义，并且在适当的情况下，E / ，在各种情况下以游离形式或农业化学合适的盐形式的E / Z异构体混合物和/或互变异构体可以用作农业化学活性化合物，并且可以以本身已知的方式制备。

4. 发明授权

US6156923A Process for the preparation of pesticides 失效
标题翻译：农药制备工艺
公开(公告)号：US6156923A
公开(公告)日：2000-12-05
申请号：US762217
申请日：1996-12-06
申请人： Saleem Farooq , Stephan Trah , Hugo Ziegler , Rene Zurfluh
发明人： Saleem Farooq , Stephan Trah , Hugo Ziegler , Rene Zurfluh
IPC分类号： C07C249/04 , C07C249/12 , C07C251/48 , C07C251/60
CPC分类号： C07C249/12 , C07C251/48 , C07C251/60
摘要： The invention relates to a process for the preparation of compounds of the formula ##STR1## or, if appropriate, a tautomer thereof, in each case in the free form or in salt form, in whichA, X, Y, Z, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.7, R.sub.9 and n are as defined in claim 1 and the C.dbd.N double bond marked with E has the E configuration, which comprisesa1) reacting either a compound of the formula (II) mentioned above with a compound of the formula (III) mentioned above, in which X.sub.1 is a leaving group, ora2) a compound of the formula (IV) mentioned above, if appropriate in the presence of a base, with a compound of the formula (V) mentioned above, orb1) reacting a compound of the formula (VI) mentioned above with a compound of the formula R.sub.7 --A--X.sub.2 (VII), in which X.sub.2 is a leaving group, and either further reacting the compound thus obtainable, of the formula (IV), for example according to method a2), orb2) reacting it with hydroxylamine or a salt thereof, if appropriate in the presence of a basic or acid catalyst, and further reacting the compound thus obtainable, of the formula (II), for example according to method a1), orc) reacting a compound of the formula (VII), mentioned above with a C.sub.1 -C.sub.6 alkyl nitrite and further reacting the compound thus obtainable, of the formula (VI), for example according to method b), the E isomers of the compounds of the formulae (II), (IV) and (VI), a process for their preparation and their use for the preparation of compounds of the formula (I).
摘要翻译：本发明涉及一种制备下式的化合物或其合适的互变异构体的方法，其各自为游离形式或盐形式，其中A，X，Y，Z，R 2，R 3，R 4 ，R 5，R 7，R 9和n如权利要求1中所定义，并且用E标记的C = N双键具有E构型，其包括a1）使上述式（II）的化合物与上述式（III），其中X1是离去基团，或a2）上述式（Ⅳ）化合物，如果合适，在碱的存在下，与上述式（Ⅴ）化合物，或b1）使上述式（Ⅵ）化合物与式R7-A-X2（Ⅶ）化合物反应，其中X 2为离去基团，并进一步使由此得到的化合物（式（Ⅴ） IV），例如根据方法a2），或b2）如果合适，在碱性或酸性催化剂存在下，使其与羟胺或其盐反应，进一步使由式（II）得到的化合物，例如按照方法a1）进行反应，或c）使上述式（Ⅶ）化合物与亚硝酸C 1 -C 6烷基酯反应，然后进一步使化合物式（Ⅵ）化合物的E异构体，其制备方法及其制备方法（Ⅵ）的制备方法及其制备方法式（I）的化合物。

5. 发明授权

US5932583A Triazoline and isoxazoline bis-oxime derivatives and their use as pesticides 失效
标题翻译：三唑啉和异恶唑啉双肟衍生物及其作为农药的用途
公开(公告)号：US5932583A
公开(公告)日：1999-08-03
申请号：US981116
申请日：1997-12-23
申请人： Hugo Ziegler , Stephan Trah , Rene Zurfluh , Anthony Cornelius O'Sullivan
发明人： Hugo Ziegler , Stephan Trah , Rene Zurfluh , Anthony Cornelius O'Sullivan
IPC分类号： A01N43/647 , A01N43/653 , A01N43/80 , C07C251/52 , C07C251/58 , C07C251/60 , C07C265/12 , C07C279/18 , C07C281/06 , C07C331/28 , C07C335/18 , C07D249/08 , C07D249/12 , C07D261/10 , C07D261/12 , C07D401/12 , C07D403/12 , C07D413/12 , C07D417/12 , A61K31/41 , A61K31/42 , C07C249/08
CPC分类号： C07D261/10 , A01N43/647 , A01N43/80 , C07C251/52 , C07C251/58 , C07C251/60 , C07C265/12 , C07C279/18 , C07C331/28 , C07C335/18 , C07D249/12 , C07D261/12 , C07D401/12 , C07D403/12 , C07D413/12 , C07D417/12
摘要： Bis-oxime derivatives of the formula I ##STR1## W is oxygen or sulfur, and the other substituents defined as follows: R.sub.1 =hydrogen, C.sub.1 -C.sub.4 alkyl; cyclopropyl;R.sub.2 =hydrogen, C.sub.1 -C.sub.6 alkyl; halo(C.sub.1 -C.sub.6) alkyl; C.sub.2 -C.sub.6 alkoxyalkyl; C.sub.3 -C.sub.6 cycloalkyl; substituted or unsubstituted aryl; substituted or unsubstituted heteroaryl; cyano; C.sub.1 -C.sub.6 alkoxycarbonyl; C.sub.1 -C.sub.6 alkyl-S(O).sub.n ; substituted or unsubstituted aryl-S(O).sub.n ; C.sub.1 -C.sub.6 alkoxy; substituted or unsubstituted aryloxy; substituted or unsubstituted heteroaryloxy; unsubstituted or mono- to trimethyl-substituted heterocyclyl; substituted or unsubstituted aryl-C.sub.1 -C.sub.6 alkyl; substituted or unsubstituted heteroaryl-C.sub.1 -C.sub.6 alkyl;R.sub.3 =hydrogen; C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.6 haloalkyl having 1 to 5 halogen atoms; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.2 -alkyl; unsubstituted or mono- to trihalo-substituted C.sub.1 -C.sub.6 alkenyl; C.sub.2 -C.sub.6 alkynyl; unsubstituted or mono- to tetrahalo-substituted C.sub.3 -C.sub.6 cycloalkyl-C.sub.1 -C.sub.4 alkyl;n=0 to 2;R.sub.8 =H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl;X=OR.sub.5, SR.sub.5, NR.sub.6 R.sub.7, halogen (especially Cl);R.sub.6, R.sub.7 =independently of one another H, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl;R.sub.5 =C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl, are fungicidal, acaricidal and insecticidal active ingredients for agriculture. They can be employed as formulated crop protection compositions.
摘要翻译： PCT No.PCT / EP96 / 02695 Sec。 371 1997年12月23日第 102（e）1997年12月23日PCT PCT 1996年6月21日PCT公布。出版物WO97 / 02255 日期1997年1月23日式I W的双肟衍生物是氧或硫，其它取代基定义如下：R1 =氢，C1-C4烷基; 环丙基 R2 =氢，C1-C6烷基; 卤代（C 1 -C 6）烷基; C2-C6烷氧基烷基; C 3 -C 6环烷基; 取代或未取代的芳基; 取代或未取代的杂芳基; 氰基; C1-C6烷氧基羰基; C 1 -C 6烷基-S（O）n; 取代或未取代的芳基-S（O）n; C1-C6烷氧基; 取代或未取代的芳氧基; 取代或未取代的杂芳氧基; 未取代或单 - 三甲基取代的杂环基; 取代或未取代的芳基-C 1 -C 6烷基; 取代或未取代的杂芳基-C 1 -C 6烷基; R3 =氢; C1-C6烷基; 具有1至5个卤素原子的C 1 -C 6卤代烷基; C 1 -C 4烷氧基-C 1 -C 2 - 烷基; 未取代或单 - 三卤代取代的C 1 -C 6烯基; C2-C6炔基; 未取代或单 - 四卤代取代的C 3 -C 6环烷基-C 1 -C 4烷基; n = 0〜2; R8 = H，C1-C4烷基，C1-C4卤代烷基，C3-C6环烷基; X = OR5，SR5，NR6R7，卤素（特别是Cl）; R6，R7 =彼此独立地为H，C1-C4烷基，C3-C4链烯基，C3-C4炔基; R5 = C1-C4烷基，C1-C3卤代烷基，是农业的杀真菌，杀螨和杀虫活性成分。它们可以用作配制的作物保护组合物。

6. 发明授权

US06525092B1 Pesticidal bis-oxime compounds 失效
标题翻译：杀虫双肟化合物
公开(公告)号：US06525092B1
公开(公告)日：2003-02-25
申请号：US09787481
申请日：2001-04-27
申请人： Hugo Ziegler , Stephan Trah
发明人： Hugo Ziegler , Stephan Trah
IPC分类号： A01N3734
CPC分类号： C07C251/48 , A01N37/50 , C07C251/60 , C07C255/61
摘要： Bis-oxime compounds of the general formula (I) are provided wherein X, Y, R1, R2 R3 and n are as defined in the specification. The bis-oxime compounds possess pesticidal activity, which may provide plants with protection from phytopathogenic microorganisms.
摘要翻译：提供通式（I）的双肟化合物，其中X，Y，R 1，R 2，R 3和n如说明书中所定义。双肟化合物具有杀虫活性，可为植物提供植物病原微生物的保护。

7. 发明授权

US5977182A O-benzyl oxime ether derivatives and their use as pesticides 失效
标题翻译： O-苄基肟醚衍生物及其作为农药的用途
公开(公告)号：US5977182A
公开(公告)日：1999-11-02
申请号：US836176
申请日：1997-05-01
申请人： Rene Zurfluh , Hugo Ziegler , Stephan Trah
发明人： Rene Zurfluh , Hugo Ziegler , Stephan Trah
IPC分类号： A01C1/08 , A01N35/10 , A01N37/34 , A01N37/50 , A01N37/52 , A01N55/10 , C07C251/38 , C07C251/48 , C07C251/52 , C07C251/54 , C07C251/60 , C07C255/62 , C07C255/64 , C07C257/06 , C07C257/14 , C07C257/22 , C07C317/32 , C07C323/47 , C07C327/40 , C07C327/58 , C07D213/76 , C07D277/10 , C07D277/12 , C07D277/28 , C07D295/185 , C07D295/30 , C07D521/00 , A01N33/24 , A01N43/40
CPC分类号： C07D295/185 , A01N37/50 , A01N37/52 , C07C251/38 , C07C251/48 , C07C255/64 , C07C257/06 , C07C257/14 , C07C257/22 , C07D295/30 , C07C2101/02
摘要： Compounds of formula (I), wherein Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, OH, CN, NO.sub.2, Si(CH.sub.3).sub.3, CF.sub.3 or halogen, and T is a group (a) or (b), and wherein the remaining substituents have the following definitions: X is O, S or NR.sub.13 ; A is O or NR.sub.4 ; R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, halo-C.sub.1 -C.sub.4 alkyl, cyclopropyl, C.sub.1 -C.sub.4 alkoxymethyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio or cyano; R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, cyano unsubstituted or substituted C.sub.1 -C.sub.6 alkoxycarbonyl, unsubstituted or substituted di(C.sub.1 -C.sub.6 alkyl)aminocarbonyl, unsubstituted or substituted C.sub.1 -C.sub.6 alkyl-S(O).sub.q, unsubstituted or substituted aryl-S(O).sub.q, unsubstituted or substituted heteroaryl, unsubstituted or substituted heterocyclyl, unsubstituted or substituted heterocyclylcarbonyl or unsubstituted or substituted phenyl; and R.sub.3 is hydrogen, unsubstituted or substituted alkyl, unsubstituted or substituted C.sub.3 -C.sub.6 cycloalkyl, unsubstituted or substituted phenyl or unsubstituted or substituted pyridyl; and wherein the remaining substituents are as defined herein, are pesticidal active ingredients. They can be used in pest control, especially as microbicides, insecticides and acaricides in agriculture, in horticulture and in the hygiene sector. ##STR1##
摘要翻译： PCT No.PCT / EP95 / 04357 Sec。 371日期1997年5月1日 102（e）日期1997年5月1日PCT提交1995年11月6日PCT公布。公开号WO96 / 16026 日期：5月30日，式（I）的化合物，其中Y为氢，C1-C4烷基，C1-C4烷氧基，OH，CN，NO2，Si（CH3）3，CF3或卤素，T为（a）或 b），其中其余取代基具有以下定义：X是O，S或NR 13; A为O或NR4; R 1是氢，C 1 -C 4烷基，卤代C 1 -C 4烷基，环丙基，C 1 -C 4烷氧基甲基，C 1 -C 4烷氧基，C 1 -C 4烷硫基或氰基; 未取代或取代的二（C 1 -C 6烷基）氨基羰基，未取代或取代的C 1 -C 6烷基-S（O）q，未取代或取代的芳基-S（O）q，C 1 -C 6烷基，C 3 -C 6环烷基，氰基未取代或取代的C 1 -C 6烷氧基羰基，（O）q，未取代或取代的杂芳基，未取代或取代的杂环基，未取代或取代的杂环基羰基或未取代或取代的苯基; 未取代或取代的烷基，未取代或取代的C 3 -C 6环烷基，未取代或取代的苯基或未取代或取代的吡啶基; 并且其中剩余的取代基如本文所定义，是杀虫活性成分。它们可用于病虫害防治，特别是作为农业，园艺和卫生领域的杀菌剂，杀虫剂和杀螨剂。

8. 发明授权

US5554735A Azo oxime ethers and their use as fungicides 失效
标题翻译：偶氮肟醚及其用作杀真菌剂
公开(公告)号：US5554735A
公开(公告)日：1996-09-10
申请号：US295775
申请日：1994-08-26
申请人： Hugo Ziegler , Stephan Trah
发明人： Hugo Ziegler , Stephan Trah
IPC分类号： C07D251/22 , A01N37/52 , A01N43/40 , C07C259/20 , C07C311/38 , C07C323/48 , C07D209/08 , C07D209/88 , C07D213/76 , C07D213/77 , C07D215/38 , C07D215/40 , C07D215/42 , C07D217/02 , C07D231/38 , C07D231/56 , C07D235/30 , C07D237/20 , C07D239/42 , C07D241/20 , C07D253/06 , C07D257/02 , C07D261/14 , C07D275/02 , C07D277/20 , C07D277/50 , C07D277/82 , C07D285/06 , C07D285/12 , C07D285/135 , C07D285/18 , C07D295/12 , C07D311/80 , C07D317/66 , C07D319/16 , C07D319/18 , C07D333/38 , C07D471/04 , C07D521/00 , C07C245/02 , A01N33/26 , C07C245/04 , C07C251/12
CPC分类号： C07D213/77 , A01N37/52 , A01N43/40 , C07C259/20 , C07C311/38 , C07D319/18 , C07C2101/02
摘要： Azo oxime ethers of formula (I), in which X is CH or N, R.sub.1 is hydrogen, C.sub.1 -C.sub.3 alkyl, trifluoromethyl or cylclopopy and R.sub.2 is aryl or heteroaryl, have an activity against phytopathogenic fungi. They can be used in the form of formulaions as crop protection products, seed-dressing products and wood preservatives.
摘要翻译：式（I）的偶氮肟醚，其中X为CH或N，R 1为氢，C 1 -C 3烷基，三氟甲基或环丙基，R2为芳基或杂芳基，具有抗植物病原性真菌的活性。它们可以作为作物保护产品，拌种产品和木材防腐剂的形式使用。

9. 发明授权

US5756426A Phenyl acetic acid derivatives as pesticides 失效
标题翻译：苯乙酸衍生物作为农药
公开(公告)号：US5756426A
公开(公告)日：1998-05-26
申请号：US526859
申请日：1995-09-11
申请人： Hugo Ziegler , Stephan Trah , Saleem Farooq , Rene Zurfluh
发明人： Hugo Ziegler , Stephan Trah , Saleem Farooq , Rene Zurfluh
IPC分类号： A01N37/34 , A01N37/36 , A01N37/44 , A01N37/50 , A01N43/28 , A01N43/30 , A01N43/36 , A01N43/40 , A01N43/46 , A01N43/653 , A01N43/84 , A01N55/00 , C07C229/00 , C07C251/60 , C07C251/76 , C07C251/80 , C07C255/00 , C07C255/54 , C07C255/61 , C07D213/77 , C07D295/088 , C07D295/30 , C07D317/18 , C07D317/58 , C07D333/22 , C07D521/00 , A61K31/275
CPC分类号： C07D213/77 , A01N37/36 , A01N37/50 , A01N43/28 , A01N43/30 , A01N43/36 , A01N43/40 , A01N43/46 , A01N43/653 , A01N43/84 , A01N55/00 , C07C251/60 , C07C251/76 , C07C251/80 , C07C255/54 , C07C255/61 , C07D231/12 , C07D233/56 , C07D249/08 , C07D295/088 , C07D295/30 , C07D317/18 , C07D317/58 , C07D333/22 , C07C2101/02
摘要： Described herein are compounds of the formula I ##STR1## and the isomers thereof, in which either a) X is an N atom and Y is OR.sub.11 or N(R.sub.12)R.sub.13, or b) X is CH and Y is OR.sub.11, and in which furthermore: R.sub.11 is C.sub.1 -C.sub.4 alkyl; R.sub.12 and R.sub.13, independently, are hydrogen or C.sub.1 -C.sub.4 alkyl; A is an O atom or the group NR.sub.4 ; and wherein R.sub.1, R.sub.2 and R.sub.3 are as defined herein, are pesticidal active ingredients. They can be used for pest control, in particular as microbicides, insecticides and acaricides in agriculture, horticulture and in the hygiene sector.
摘要翻译：本文描述的是式I的化合物及其异构体，其中a）X是N原子，Y是OR 11或N（R 12）R 13，或b）X是CH，Y是OR 11，以及其中R11为C1-C4烷基; R 12和R 13独立地是氢或C 1 -C 4烷基; A是O原子或NR4基团; 并且其中R1，R2和R3如本文所定义，是农药活性成分。它们可以用于害虫控制，特别是作为农业，园艺和卫生领域的杀菌剂，杀虫剂和杀螨剂。

10. 发明授权

US06646151B1 Process for the preparation of pesticides 失效
标题翻译：农药制备工艺
公开(公告)号：US06646151B1
公开(公告)日：2003-11-11
申请号：US09670147
申请日：2000-09-26
申请人： Saleem Farooq , Stephan Trah , Hugo Ziegler , René Zurflüh
发明人： Saleem Farooq , Stephan Trah , Hugo Ziegler , René Zurflüh
IPC分类号： C07C24904
CPC分类号： C07C249/12 , C07C251/48 , C07C251/60
摘要： The invention relates to a process for the preparation of compounds of the formula or, if appropriate, a tautomer thereof, in each case in the free form or in salt form, in which A, X, Y, Z, R2, R3, R4, R5, R7, R9 and n are as defined in claim 1 and the C═N double bond marked with E has the E configuration, which comprises a1) reacting either a compound of the formula (II) mentioned above with a compound of the formula (III) mentioned above, in which X1 is a leaving group, or a2) a compound of the formula (IV) mentioned above, if appropriate in the presence of a base, with a compound of the formula (V) mentioned above, or b1) reacting a compound of the formula (VI) mentioned above with a compound of the formula R7—A—X2 (VII), in which X2 is a leaving group, and either further reacting the compound thus obtainable, of the formula (IV), for example according to method a2), or b2) reacting it with hydroxylamine or a salt thereof, if appropriate in the presence of a basic or acid catalyst, and further reacting the compound thus obtainable, of the formula (II), for example according to method a1), or c) reacting a compound of the formula (VIII), mentioned above with a C1-C6alkyl nitrite and further reacting the compound thus obtainable, of the formula (VI), for example according to method b), the E isomers of the compounds of the formulae (II), (IV) and (VI), a process for their preparation and their use for the preparation of compounds of the formula (I).
摘要翻译：本发明涉及一种制备式的化合物的方法，如果合适，其合适的是其互变异构体，其各自为游离形式或盐形式，其中A，X，Y，Z，R 2，R 3，R 4， R5，R7，R9和n如权利要求1中所定义，并且用E标记的C = N双键具有E构型，其包括a）使上述式（II）的化合物与式（II） III），其中X1是离去基团，ora2）如果合适的话，在碱的存在下，上述式（Ⅳ）的化合物与上述式（Ⅴ）的化合物相同，反应1）使上述式（Ⅵ）化合物与式R7-A-X2（Ⅶ）化合物反应，其中X 2为离去基团，并进一步使由此得到的式（Ⅳ）化合物与根据方法a2）的示例，orb2）如果合适，在碱性或酸性催化剂存在下，使其与羟胺或其盐反应，以及进一步使由式（II）得到的化合物，例如按照方法a1）进行反应，或者使上述式（Ⅷ）化合物与亚硝酸C 1 -C 6烷基酯反应，并进一步使由此得到的化合物，式（Ⅵ）化合物的方法，例如根据方法b），式（II），（Ⅳ）和（Ⅵ）化合物的E异构体，其制备方法及其制备方法式（I）。

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