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    • 3. 发明授权
    • N-(2-nitrophenyl)-2-aminopyrimidine derivatives, the preparation and use
thereof
    • N-(2-硝基苯基)-2-氨基嘧啶衍生物,的制备及应用
    • US4659363A
    • 1987-04-21
    • US632161
    • 1984-07-18
    • Adolf HubeleHelmut ZondlerPeter RiebliWolfgang Eckhardt
    • Adolf HubeleHelmut ZondlerPeter RiebliWolfgang Eckhardt
    • A01N43/54C07D239/42C07D239/46C07D239/47C07D239/52C07D239/56C07D401/12
    • C07D239/42A01N43/54C07D239/47C07D239/52C07D239/56C07D401/12
    • The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2R.sub.3 is halogen,R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio,R.sub.5, R.sub.6 and R.sub.7 are each independently hydrogen, halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 -haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms; or are the Q--(E).sub.n --(X).sub.m -group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur.Also disclosed are methods of preparing these compounds, and also agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or, compositions containing them, in agriculture and related fields.
    • 本发明公开了通式I(I)的新型N-(2-硝基苯基)-2-氨基嘧啶衍生物,其中R 1和R 2各自独立地为NO 2或CF 3,条件是仅R 1或R 2可为NO 2 R 3 C 1 -C 3烷氧基或C 1 -C 3烷硫基,R 5,R 6和R 7各自独立地为氢,R 4为氢或-C(O)R'基团,其中R'为未被取代或被卤素取代的C 1 -C 4烷基, 卤素,硝基,氰基,硫氰基,C 1 -C 12烷基,C 3 -C 8环烷基,C 1 -C 8烷硫基,C 1 -C 6烷基磺酰基,C 1 -C 6烷基亚磺酰基,C 3 -C 6烯基,C 3 -C 6卤代烯基,C 3 -C 6炔基,C 3 -C 6卤代炔基,C 3 -C 6烯氧基, C 6-卤代链烯氧基,C 3 -C 6烯基硫基,C 3 -C 6炔氧基,C 3 -C 6卤代炔氧基,被卤素,氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基,未取代的C 1 -C 8烷氧基或卤素取代的C 1 -C 8烷氧基, 其可被一个或多个单个氧原子中断; 或者是Q-(E)n-(X)m-基,其中n为0或1,m为0或1,Q为未被取代或被卤素,硝基,C 1 -C 3烷基,CF 3和 或C1-C3烷氧基,或是含有一个或多个杂原子的饱和或不饱和杂环基,E是C1-C3亚烷基桥,X是氧或硫。 还公开了制备这些化合物的方法,以及含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中新颖化合物或含有它们的组合物的用途。
    • 6. 发明授权
    • Pesticidal compositions
    • 杀虫剂组合物
    • US4694009A
    • 1987-09-15
    • US746432
    • 1985-06-19
    • Adolf HubeleHelmut ZondlerPeter RiebliWolfgang Eckhardt
    • Adolf HubeleHelmut ZondlerPeter RiebliWolfgang Eckhardt
    • A01N43/54C07D239/42C07D239/46C07D239/47C07D239/52A61K31/505
    • C07D239/42A01N43/54C07D239/47
    • The invention discloses novel N-(2-nitrophenyl)-2-aminopyrimidine derivatives of the general formula I ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen, NO.sub.2 or CF.sub.3, with the proviso that only R.sub.1 or R.sub.2 can be NO.sub.2 ;R.sub.4 is hydrogen or the --C(O)R' group, in which R' is C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkylthio;R.sub.5, R.sub.6 and R.sub.7 are each independently halogen, nitro, cyano, thiocyano, C.sub.1 -C.sub.12 alkyl, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.8 alkylthio, C.sub.1 -C.sub.6 alkylsulfonyl, C.sub.1 -C.sub.6 alkylsulfoxyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 haloalkenyl, C.sub.3 -C.sub.6 alkynyl, C.sub.3 -C.sub.6 haloalkynyl, C.sub.3 -C.sub.6 alkenyloxy, C.sub.3 -C.sub.6 haloalkenyloxy, C.sub.3 -C.sub.6 alkenylthio, C.sub.3 -C.sub.6 alkynyloxy, C.sub.3 -C.sub.6 haloalkynyloxy, C.sub.1 -C.sub.8 alkyl which is substituted by halogen, cyano and/or C.sub.1 -C.sub.4 alkoxy, or are unsubstituted C.sub.1 -C.sub.8 alkoxy or halogen-substituted C.sub.1 -C.sub.8 alkoxy, the alkyl moiety of which may be interrupted by one or more single oxygen atoms, or are the Q--(E).sub.n --(X).sub.m group, in which n is 0 or 1, m is 0 or 1, Q is phenyl which is unsubstituted or substituted by halogen, nitro, C.sub.1 -C.sub.3 alkyl, CF.sub.3 and/or C.sub.1 -C.sub.3 alkoxy, or is a saturated or unsaturated heterocyclic radical containing one or more hetero atoms, E is a C.sub.1 -C.sub.3 alkylene bridge, and X is oxygen or sulfur, and R.sub.6 and/or one of the radicals R.sub.5 or R.sub.7 can also be hydrogen.Also disclosed are methods of preparing these compounds, and agrochemical compositions which contain one such compound as active ingredient. The invention further relates to the use of the novel compounds, or compositions containing them, in agriculture and related fields.
    • 本发明公开了通式I(I)的新型N-(2-硝基苯基)-2-氨基嘧啶衍生物,其中R 1和R 2是氢,NO 2或CF 3,条件是只有R 1或R 2可以是NO 2; R 4是氢或-C(O)R'基团,其中R'是未被取代或被卤素,C 1 -C 3烷氧基或C 1 -C 3烷硫基取代的C 1 -C 4烷基; R5,R6和R7各自独立地为卤素,硝基,氰基,氰基,C1-C12烷基,C3-C8环烷基,C1-C8烷硫基,C1-C6烷基磺酰基,C1-C6烷基亚磺酰基,C3-C6链烯基,C3-C6卤代烯基,C3-C6炔基, C 6卤代炔基,C 3 -C 6烯氧基,C 3 -C 6卤代烯氧基,C 3 -C 6烯基硫基,C 3 -C 6炔氧基,C 3 -C 6卤代炔氧基,被卤素,氰基和/或C 1 -C 4烷氧基取代的C 1 -C 8烷基,或未取代的C 1 -C 8烷氧基或卤素取代的C 1 C 1-8烷氧基,其烷基部分可被一个或多个单个氧原子间隔,或是Q-(E)n-(X)m基团,其中n为0或1,m为0或1,Q 是未取代的或被卤素,硝基,C 1 -C 3烷基,CF 3和/或C 1 -C 3烷氧基取代的苯基,或是含有一个或多个杂原子的饱和或不饱和杂环基,E是C 1 -C 3亚烷基桥,X是 氧或硫,R6和/或基团R5或R7之一也可以是氢。 还公开了制备这些化合物的方法和含有一种这样的化合物作为活性成分的农药组合物。 本发明还涉及在农业和相关领域中使用含有它们的新化合物或组合物。
    • 9. 发明授权
    • Organotin compounds and pesticidal compositions
    • 有机锡化合物和杀虫剂组合物
    • US4546109A
    • 1985-10-08
    • US504021
    • 1983-06-13
    • Adolf HubelePeter Riebli
    • Adolf HubelePeter Riebli
    • A01N55/04C07F7/22A61K31/32
    • A01N55/04C07F7/2244
    • There are described novel organotin compounds of the formula I ##STR1## wherein R.sub.1 is unsubstituted or substituted lower alkyl, lower alkenyl, cycloalkyl, furyl or tetrahydrofuryl;R.sub.2 is unsubstituted or substituted aryl;R.sub.3 and R.sub.4 independently of one another are each hydrogen, or unsubstituted or substituted lower alkyl; andR.sub.5, R.sub.6 and R.sub.7 independently of one another are each unsubstituted or substituted lower alkyl, cycloalkyl or aryl.There are also disclosed methods of producing these products, and also pesticidal compositions containing one of the said compounds as active ingredient. Also described is a method for controlling plant pests, which method is based on the application of the stated active substances or of compositions prepared therefrom.
    • 描述了式I的新型有机锡化合物(I)其中R 1是未取代的或取代的低级烷基,低级烯基,环烷基,呋喃基或四氢呋喃基; R2是未取代或取代的芳基; R 3和R 4彼此独立地为氢,或未取代或取代的低级烷基; R 5,R 6和R 7彼此独立地是各自未取代或取代的低级烷基,环烷基或芳基。 还公开了生产这些产品的方法,以及含有所述化合物之一作为活性成分的杀虫组合物。 还描述了一种用于控制植物害虫的方法,该方法基于所述活性物质或由其制备的组合物的应用。