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1. 发明授权

US08034884B2 Gaseous phase fluidized-bed reactor 失效
标题翻译：气相流化床反应器
公开(公告)号：US08034884B2
公开(公告)日：2011-10-11
申请号：US12554964
申请日：2009-09-07
申请人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/00 , B01J8/18
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

2. 发明授权

US06248829B1 Polymers of propene 有权
标题翻译：丙烯聚合物
公开(公告)号：US06248829B1
公开(公告)日：2001-06-19
申请号：US09268721
申请日：1999-03-17
申请人： David Fischer , John Russell Grasmeder , Heike Gregorius , Stefan Seelert , Franz Langhauser , Wolfgang Micklitz , Klaus-Dieter Rümpler
发明人： David Fischer , John Russell Grasmeder , Heike Gregorius , Stefan Seelert , Franz Langhauser , Wolfgang Micklitz , Klaus-Dieter Rümpler
IPC分类号： C08F800
CPC分类号： C08F210/06 , C08F4/65912 , C08F4/65927 , C08F10/06 , C08F110/06 , C08L23/10 , C08L23/14 , C08L2314/06 , C08F4/65916 , C08F4/65904 , C08L2666/04 , C08F2500/03 , C08F2500/15 , C08F2500/17 , C08F2500/20 , C08F210/08 , C08F2500/12
摘要： Polymers of propene consist of from 50 to 99.9% by weight of an isotactic propene copolymer (A′) and from 0.1 to 50% by weight of a propene homopolymer or a propene copolymer (B′), where a) the propene copolymer (A′) consists of from 80 to 99.9 mol % of propene and from 0.1 to 20 mol % of ethene and/or a C4-C12-1-olefin, at least 80% of all propene diads are isotactic meso diads, the propene copolymer (A′) has a proportion (XS) of material soluble in xylene at 20° C. which satisfies the inequality (1) (XS) 1.9×10−11(TM)6.34+180 MPa (2), where in both inequalities (1) and (2) TM is the melting point in ° C., and b) the propene homopolymer or the propene copolymer (B′) consists of from 80 to 100 mol % of propene and from 0 to 20 mol % of ethene and/or a C4-C12-1-olefin, at least 55% of all regioregular propene diads are isotactic meso diads, an enthalpy of fusion &Dgr;Hm of less than 50 J/g is observed in the DSC measurement of (B′) and no crystalline ex sequences are detectable.
摘要翻译：丙烯的聚合物由50-99.9重量％的全同立构丙烯共聚物（A'）和0.1-50重量％的丙烯均聚物或丙烯共聚物（B'）组成，其中丙烯共聚物（A' ）由80至99.9mol％的丙烯和0.1至20mol％的乙烯和/或C 4 -C 12 -1-烯烃组成，所有丙烯二单元的至少80％是全同立构的内消旋二元环，丙烯共聚物（A '）具有在20℃下可溶于二甲苯的材料的比例（XS），其满足不等式（1）丙烯共聚物（A'）的拉伸弹性模量（E）（MPa）根据ISO 527测定（2），其中在两个不等式（1）和（2）中，TM是以℃为单位的熔点，和b）丙烯均聚物或丙烯共聚物（B'）由80-100mol％丙烯和0至20摩尔％的乙烯和/或C 4 -C 12 -1-烯烃，至少55％的所有区域规则丙烯二单元均为全同立构的内消旋二聚体，熔融焓DELTAHm小于5 在（B'）的DSC测量中观察到0J / g，并且不检测到结晶ex序列。

3. 发明申请

US20100056734A1 GASEOUS PHASE FLUIDIZED-BED REACTOR 失效
标题翻译：气相流化床反应器
公开(公告)号：US20100056734A1
公开(公告)日：2010-03-04
申请号：US12554964
申请日：2009-09-07
申请人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/01
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

4. 发明授权

US06849699B2 Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
标题翻译：气相流化床方法和由此制备的乙烯均聚物和共聚物
公开(公告)号：US06849699B2
公开(公告)日：2005-02-01
申请号：US10658916
申请日：2003-09-11
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08J5/18 , C08F2/34 , C08F4/02 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/02
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

5. 发明授权

US06180729B2 Continuous gas-phase polymerization process 有权
标题翻译：连续气相聚合法
公开(公告)号：US06180729B2
公开(公告)日：2001-01-30
申请号：US09201084
申请日：1998-11-30
申请人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
发明人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
IPC分类号： C08F240
CPC分类号： C08F10/00 , C08F2/005 , C08F210/16 , Y02P20/584 , C08F2/34 , C08F2/40 , C08F2/007 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： In a continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or a mixture of ethylene or propene and C3-C8-&agr;-monoolefins is polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and a pressure of from 1 to 100 bar in the gas phase in a bed of finely divided polymer in the presence of a catalyst, where the reactor gas is circulated to remove the heat of polymerization, polymer deposits in the circulating gas line are prevented by metering a catalyst poison having a boiling point above the maximum temperature within the circulating gas line into this circulating gas line in at most such an amount that it does not significantly impair the productivity of the catalyst in the reactor.
摘要翻译：在用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法中，其中乙烯，丙烯或乙烯或丙烯和C 3 -C 8-α-单烯烃的混合物在气相聚合反应器的聚合区中聚合在催化剂存在下，在细分散的聚合物床中的气相中，在30至125℃和1至100巴的压力下，其中反应器气体循环以除去聚合热，聚合物沉积物通过将沸点高于循环气体管线中的最高温度的催化剂毒物计量到该循环气体管线中，至多使其不显着损害反应器中催化剂的生产率的程度来防止循环气体管线。

6. 发明授权

US07601303B1 Gaseous phase fluidized-bed reactor 失效
标题翻译：气相流化床反应器
公开(公告)号：US07601303B1
公开(公告)日：2009-10-13
申请号：US09700367
申请日：1999-05-04
申请人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： B01J8/18
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

7. 发明授权

US5756607A Preparation of polymers of ethylene by suspension polymerization 失效
标题翻译：通过悬浮聚合制备乙烯聚合物
公开(公告)号：US5756607A
公开(公告)日：1998-05-26
申请号：US666409
申请日：1996-06-26
申请人： Martin Lux , Roland Saive , Franz Langhauser , Wolfgang Micklitz , Hans-Helmut Gortz , Dieter Lilge
发明人： Martin Lux , Roland Saive , Franz Langhauser , Wolfgang Micklitz , Hans-Helmut Gortz , Dieter Lilge
IPC分类号： C08F2/06 , C08F2/14 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/6592 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , C08F10/02 , C08F210/16 , C08F110/02 , C08F4/63912 , C08F4/63916 , C08F4/6392 , Y10S526/943
摘要： Homopolymers of ethylene or copolymers of ethylene with other olefins or mixtures thereof are prepared by suspension polymerization in the presence of catalyst systems by a process in which the catalyst systems used are those which contain, as active components, A) a finely divided carrier treated with trialkylaluminum, B) a metallocene complex, C) an open-chain or cyclic alumoxane compound and D) an alkali metal alkyl or alkaline earth metal alkyl or a mixture thereof.
摘要翻译： PCT No.PCT / EP94 / 04125 Sec。 371日期1996年6月26日第 102（e）日期1996年6月26日PCT 1994年12月13日PCT PCT。出版物WO95 / 18160 日期1995年7月6日乙烯的共聚物或乙烯与其它烯烃或其混合物的共聚物通过在催化剂体系的存在下通过悬浮聚合制备，其中使用的催化剂体系是含有作为活性组分的A）用三烷基铝处理的细分载体，B）茂金属络合物，C）开链或环状铝氧烷化合物，和D）碱金属烷基或碱土金属烷基或其混合物。

8. 发明授权

US06649709B1 Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
标题翻译：气相流化床法和使用所述方法获得的乙烯均聚物和共聚物
公开(公告)号：US06649709B1
公开(公告)日：2003-11-18
申请号：US09555594
申请日：2000-05-31
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

9. 发明授权

US06593437B1 Metal organic catalysts for polymerizing unsaturated compounds 有权
标题翻译：用于聚合不饱和化合物的金属有机催化剂
公开(公告)号：US06593437B1
公开(公告)日：2003-07-15
申请号：US09959382
申请日：2001-10-24
申请人： Andrei Gonioukh , Wolfgang Micklitz , Benno Bildstein , Michael Malaun , Andreas Hradsky
发明人： Andrei Gonioukh , Wolfgang Micklitz , Benno Bildstein , Michael Malaun , Andreas Hradsky
IPC分类号： C08F470
CPC分类号： C08G67/02 , C07C249/02 , C07C2603/20 , C07F17/02 , C08F4/00 , C08F4/61908 , C08F4/61912 , C08F4/61925 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/17 , C07C251/08 , C07C251/20 , C07C251/24 , C08F4/7006
摘要： A process for preparing 1,2-diimine compounds of the formula I where R1 and R2 are, independently of one another, alkyl, aryl or metallocenyl radicals, and R3, R4 are, independently of one another, H, alkyl or aryl radicals or R3 and R4 are joined so as to form, with inclusion of the two imine carbon atoms, a 5- to 8-membered ring which may be saturated or unsaturated and may be unsubstituted or substituted by any hydrocarbon radicals. The process involves reacting 1,2-dicarbonyl compounds with primary amines, which have been activated with trialkylaluminum compounds prior to the reaction with the 1,2-dicarbonyl compounds. 1,2-Diimine compounds of the formula I in which R1 and R2 are, independently of one another, metallocenyl radicals can be used to prepare metal complexes which can be used as catalysts in a process for the polymerization of unsaturated compounds.
摘要翻译：制备式I的1,2-二亚胺化合物的方法，其中R 1和R 2彼此独立地为烷基，芳基或金属茂基，且R 3，R 4彼此独立地为H，烷基或芳基或R 3 并且R4连接以形成包含两个亚胺碳原子的5-8元环，其可以是饱和或不饱和的，并且可以是未取代的或被任何烃基取代。该方法包括使1,2-二羰基化合物与伯胺反应，伯胺在与1,2-二羰基化合物反应之前已用三烷基铝化合物活化。其中R 1和R 2彼此独立地为金属茂基的式I的1,2-二亚胺化合物可用于制备可在不饱和化合物的聚合方法中用作催化剂的金属络合物。

10. 发明授权

US06559087B1 Method and apparatus for the continuous treatment of catalyst and catalyst support material 失效
标题翻译：用于连续处理催化剂和催化剂载体材料的方法和装置
公开(公告)号：US06559087B1
公开(公告)日：2003-05-06
申请号：US09536356
申请日：2000-03-27
申请人： Paulus De Lange , Rainer Karer , Philipp Rosendorfer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt
发明人： Paulus De Lange , Rainer Karer , Philipp Rosendorfer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt
IPC分类号： B01J3708
CPC分类号： B65G53/22 , B01J8/10 , B01J8/26 , B01J8/46 , B01J19/18 , B01J19/22 , B01J37/00 , B01J2219/00033 , B01J2219/00132 , C08F10/00 , Y10S526/905 , C08F4/24
摘要： A method for the treatment of catalyst or catalyst support material in an apparatus in which the treatment is carried out continuously in such a way that the physical and/or chemical conditions change during entry of the catalyst or catalyst support material into the apparatus and/or during exit thereof from the apparatus and/or the catalyst or catalyst support material is transported in the apparatus through zones (5, 6, 7) having different physical and/or chemical conditions.
摘要翻译：一种在设备中处理催化剂或催化剂载体材料的方法，其中以使得催化剂或催化剂载体材料进入装置和/或其中的物理和/或化学条件改变的方式连续进行处理在从装置出来时和/或催化剂或催化剂载体材料在装置中通过具有不同物理和/或化学条件的区域（5,6,7）输送。

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