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1. 发明授权

US06649709B1 Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
标题翻译：气相流化床法和使用所述方法获得的乙烯均聚物和共聚物
公开(公告)号：US06649709B1
公开(公告)日：2003-11-18
申请号：US09555594
申请日：2000-05-31
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

2. 发明授权

US06849699B2 Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
标题翻译：气相流化床方法和由此制备的乙烯均聚物和共聚物
公开(公告)号：US06849699B2
公开(公告)日：2005-02-01
申请号：US10658916
申请日：2003-09-11
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08J5/18 , C08F2/34 , C08F4/02 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/02
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

3. 发明授权

US06180729B2 Continuous gas-phase polymerization process 有权
标题翻译：连续气相聚合法
公开(公告)号：US06180729B2
公开(公告)日：2001-01-30
申请号：US09201084
申请日：1998-11-30
申请人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
发明人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
IPC分类号： C08F240
CPC分类号： C08F10/00 , C08F2/005 , C08F210/16 , Y02P20/584 , C08F2/34 , C08F2/40 , C08F2/007 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： In a continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or a mixture of ethylene or propene and C3-C8-&agr;-monoolefins is polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and a pressure of from 1 to 100 bar in the gas phase in a bed of finely divided polymer in the presence of a catalyst, where the reactor gas is circulated to remove the heat of polymerization, polymer deposits in the circulating gas line are prevented by metering a catalyst poison having a boiling point above the maximum temperature within the circulating gas line into this circulating gas line in at most such an amount that it does not significantly impair the productivity of the catalyst in the reactor.
摘要翻译：在用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法中，其中乙烯，丙烯或乙烯或丙烯和C 3 -C 8-α-单烯烃的混合物在气相聚合反应器的聚合区中聚合在催化剂存在下，在细分散的聚合物床中的气相中，在30至125℃和1至100巴的压力下，其中反应器气体循环以除去聚合热，聚合物沉积物通过将沸点高于循环气体管线中的最高温度的催化剂毒物计量到该循环气体管线中，至多使其不显着损害反应器中催化剂的生产率的程度来防止循环气体管线。

4. 发明授权

US06936666B2 Continuous gas-phase polymerization process 有权
标题翻译：连续气相聚合法
公开(公告)号：US06936666B2
公开(公告)日：2005-08-30
申请号：US10486395
申请日：2002-10-29
申请人： Shahram Mihan , Rainer Karer , Manfred Hecker , Philipp Rosendorfer , Kasper Evertz , Armin Lange
发明人： Shahram Mihan , Rainer Karer , Manfred Hecker , Philipp Rosendorfer , Kasper Evertz , Armin Lange
IPC分类号： B01J8/00 , B01J8/24 , B01J19/00 , C08F2/00 , C08F2/34 , C08F2/42 , C08F6/08 , C08F10/00 , C08F210/16
CPC分类号： C08F10/00 , B01J8/0055 , B01J8/24 , B01J19/002 , B01J2208/00256 , B01J2208/00274 , B01J2208/00707 , B01J2219/00272 , C08F210/16 , Y10S526/901 , C08F2/42 , C08F2/34 , C08F2/007 , C08F210/14 , C08F2500/12
摘要： Continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or mixtures comprising ethylene or propene and C3-C8-α-monoolefins are polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and pressures of from 1 to 100 bar in the gas phase in a bed comprising finely divided polymer in the presence of a catalyst. To remove the heat of polymerization, the reactor gas is circulated and firstly passes through a cyclone after leaving the reactor. To prevent polymer deposits in the circulating gas system, a catalyst poison having a boiling point above the maximum temperature within the circulating gas system is fed into this circulating gas system at a position between the reactor and the cyclone.
摘要翻译：用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法，其中乙烯，丙烯或包含乙烯或丙烯和C 3 -C 8 -Ca-单烯烃的混合物在气相聚合反应器的聚合区中在30至125℃下聚合，并且在催化剂存在下在包含细碎聚合物的床中在气相中压力为1至100巴。为了除去聚合热，反应器气体循环，首先在离开反应器之后通过旋风分离器。为了防止循环气体系统中的聚合物沉积，在反应器和旋风分离器之间的位置处将沸点高于循环气体系统中的最大温度的催化剂毒物进料到该循环气体系统中。

5. 发明授权

US06462150B1 Method for isolating olefins from polyolefin plants 有权
标题翻译：从聚烯烃工厂中分离烯烃的方法
公开(公告)号：US06462150B1
公开(公告)日：2002-10-08
申请号：US09913074
申请日：2001-08-09
申请人： Stefan Bitterlich , Kaspar Evertz , Manfred Hecker , Hans-Jacob Feindt
发明人： Stefan Bitterlich , Kaspar Evertz , Manfred Hecker , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F6/001 , B01J8/007 , B01J8/24 , C07C7/005 , C07C11/02
摘要： The present invention relates to a method for the isolation of olefins from a gas mixture comprising one or more olefins, inert gas and catalyst poison, where the gas mixture is fed to a separation unit (18) and separated into olefin and inert gas. The method according to the invention has the special feature that an apparatus (17) is installed upstream or downstream of the separation unit (18) and that i) in the case of an upstream apparatus (17), the catalyst poison is at least partially removed from the gas mixture, and ii) in the case of a downstream apparatus (17), the catalyst poison is at least partially removed from the separated-off olefin. The olefins here are preferably isolated from a gas mixture formed as offgas in catalytic gas-phase polymerization for the preparation of polyolefins. The recovery of the olefins from the offgas is of economic importance.
摘要翻译：本发明涉及从包含一种或多种烯烃，惰性气体和催化剂毒物的气体混合物中分离烯烃的方法，其中气体混合物被供给到分离单元（18）并分离成烯烃和惰性气体。根据本发明的方法具有以下特征：设备（17）安装在分离单元（18）的上游或下游，并且在上游设备（17）的情况下，催化剂毒物至少部分地被去除在下游装置（17）的情况下，催化剂毒物至少部分地从分离的烯烃中除去。这里的烯烃优选与催化气体 - 气体中的废气形成的气体混合物分离，用于制备聚烯烃的相聚合。从废气中回收烯烃是经济重要的。

6. 发明授权

US09090761B2 Polyethylene for injection moldings 有权
标题翻译：注塑用聚乙烯
公开(公告)号：US09090761B2
公开(公告)日：2015-07-28
申请号：US13060076
申请日：2009-08-27
申请人： Gerd Mannebach , Harald Schmitz , Shahram Mihan , Rainer Karer , Manfred Hecker , Guido Funk , Adrian Popa
发明人： Gerd Mannebach , Harald Schmitz , Shahram Mihan , Rainer Karer , Manfred Hecker , Guido Funk , Adrian Popa
IPC分类号： C08F110/02 , C08F110/14 , C08F110/06 , C08L23/04
CPC分类号： C08L23/04 , C08L2205/02 , Y10T428/139 , C08L2666/06
摘要： A polyethylene for IM having excellent processing properties in terms of spiral flow testing is devised.
摘要翻译：设计了一种在螺旋流动测试方面具有优异加工性能的用于IM的聚乙烯。

7. 发明申请

US20120065335A1 Polyethylene composition suitable for the preparation of films and process for preparing the same 有权
标题翻译：适用于制备薄膜的聚乙烯组合物及其制备方法
公开(公告)号：US20120065335A1
公开(公告)日：2012-03-15
申请号：US13301495
申请日：2011-11-21
申请人： Jennifer Kipke , Shahram Mihan , Rainer Karer , Jörg Auffermann , Manfred Hecker , Paulus De Lange , Harald Schmitz
发明人： Jennifer Kipke , Shahram Mihan , Rainer Karer , Jörg Auffermann , Manfred Hecker , Paulus De Lange , Harald Schmitz
IPC分类号： C08L23/06
CPC分类号： C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2205/035 , C08L2308/00 , C08L2314/06 , C08L2666/06 , C08L2666/02
摘要： A polyethylene composition, in particular suitable for the preparation of films, and a process for preparing the same are described. The polyethylene composition of the invention comprises from 50 to 89% by weight of a first polyethylene component comprising at least one multimodal polyethylene including a plurality of ethylene polymer fractions having distinct molecular weights and comonomer contents, at least one of said plurality of ethylene polymer fractions being prepared by the use of a single site catalyst, and from 50 to 11% by weight of a second polyethylene component comprising a low or medium density polyethylene.
摘要翻译：描述了特别适用于制备薄膜的聚乙烯组合物及其制备方法。本发明的聚乙烯组合物包含50至89重量％的第一聚乙烯组分，其包含至少一种多峰聚乙烯，其包含具有不同分子量和共聚单体含量的多种乙烯聚合物级分，所述多种乙烯聚合物级分中的至少一种通过使用单中心催化剂制备，以及50至11重量％的包含低密度或中密度聚乙烯的第二聚乙烯组分。

8. 发明申请

US20130131300A1 PROCESS AND APPARATUS FOR MIXING AND SPLITTING FLUID STREAMS 有权
标题翻译：混合和分流流体流的方法和装置
公开(公告)号：US20130131300A1
公开(公告)日：2013-05-23
申请号：US13813604
申请日：2011-08-02
申请人： Michael Olmscheid , Manfred Hecker , Rainer Karer , Paulus-Petrus Maria De Lange
发明人： Michael Olmscheid , Manfred Hecker , Rainer Karer , Paulus-Petrus Maria De Lange
IPC分类号： B29B7/00
CPC分类号： B29B7/007 , B01F3/0803 , B01F15/00162 , B01F15/00253 , B01F15/00344 , B01J4/008 , C08F10/00 , C08F110/02 , C08F2/01
摘要： A process for continuously mixing at least two fluid streams and splitting the stream of the mixture into at least two partial streams, comprising a) providing streams of the at least two fluids via separated conduits; b) combining the streams of the fluids and forming a homogeneous mixture; c) measuring the pressure in the conduit conveying the mixture of the fluids; d) splitting the stream of the mixture of the fluids into at least two partial streams and feeding each of the partial streams to a conduit equipped with a flow control device controlled by a controller; and e) adjusting the flow rates of the partial streams of the mixture of the fluids by feeding the pressure information measured in step c) as process variable to the controllers controlling the flow control devices, a process for feeding a mixture of at least two fluids via at least two feeding points, an apparatuses for carrying out such processes and a process for polymerizing olefins.
摘要翻译：一种用于连续混合至少两种流体流并将混合物流分解为至少两个部分流的方法，包括a）经由分离的导管提供所述至少两种流体的流; b）组合流体流并形成均匀的混合物; c）测量输送流体混合物的管道中的压力; d）将流体混合物的流分成至少两个部分流，并将每个部分流输送到配备有由控制器控制的流量控制装置的导管; 以及e）通过将在步骤c）中测量的压力信息作为过程变量输入到控制流量控制装置的控制器，来调节流体混合物的部分流的流速;将至少两种流体通过至少两个进料点，用于进行这些方法的装置和聚合烯烃的方法。

9. 发明申请

US20100317755A1 Process For Preparation Of Ethylene Polymers For Blown Films 失效
标题翻译：乙烯聚合物制备吹塑膜的工艺
公开(公告)号：US20100317755A1
公开(公告)日：2010-12-16
申请号：US12223234
申请日：2007-01-24
申请人： Wolfgang Rohde , Lutz-Gerd Heinicke , Rainer Karer , Manfred Hecker
发明人： Wolfgang Rohde , Lutz-Gerd Heinicke , Rainer Karer , Manfred Hecker
IPC分类号： C08J9/00 , C08F10/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08J5/18 , C08J2323/08 , C08K5/005 , C08F4/025 , C08F4/24 , C08F2/34 , C08L23/04 , C08F2500/12 , C08F2500/04 , C08F2500/26 , C08F2500/17
摘要： Process for preparation of ethylene homopolymers or copolymers, comprising the steps of a) polymerization of ethylene or of ethylene with one or more other 1-olefins in the presence of a chromium catalyst at temperatures of from 20 to 200° C. and at pressures of from 0.1 to 20 MPa, where the chromium catalyst can be prepared via application of one or more chromium compounds to a silicate support and subsequent thermal activation under oxidative conditions at temperatures of from 620 to 900° C.; b) mixing of the polyethylene in the melt in the presence of from 1000 to 2000 ppm of an antioxidant comprising at least one sterically hindered phenol and comprising at least one phosphite in a mixing ratio of from 1:5 to 5:1, with specific energy input of at least 0.17 kWh/kg.
摘要翻译：乙烯均聚物或共聚物的制备方法，包括以下步骤：a）在铬催化剂存在下，在20〜200℃的温度下，在乙烯或乙烯与一种或多种其它1-烯烃的存在下，在 0.1至20MPa，其中可通过将一种或多种铬化合物施用于硅酸盐载体并随后在620-900℃的氧化条件下进行热活化来制备铬催化剂; b）在1000-2000ppm的包含至少一种空间位阻酚并且包含至少一种1:5至5:1的混合比的亚磷酸酯的抗氧化剂存在下，将聚乙烯混合在熔体中，能量输入至少为0.17 kWh / kg。

10. 发明申请

US20080014128A1 Apparatus and Process for the Gas-Phase Polymerization of Olefins 有权
标题翻译：用于烯烃气相聚合的装置和方法
公开(公告)号：US20080014128A1
公开(公告)日：2008-01-17
申请号：US11667417
申请日：2005-11-08
申请人： Eberhard Herrmann , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
发明人： Eberhard Herrmann , Manfred Hecker , Rainer Karer , Klaus Berhalter , Paulus de Lange , Jorg Halpap , Cyrus Ahmadzade-Youssefi
IPC分类号： C08F10/00 , B01J19/18
CPC分类号： B01J8/003 , B01J8/006 , B01J8/1872 , B01J2208/00256 , B01J2208/00274 , B01J2208/00761 , C08F10/00 , C08F110/02 , C08F2/34
摘要： Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8). The inlet chamber (4) has a dividing wall (10) which is arranged essentially parallel to the filter medium (9) and separates the inlet chamber (4) into an inflow region (4a), which is connected to the gas inlet (6), and a filter region (4b) in which the filter medium is located and has an upper opening and a lower opening which are dimensioned so that from 60 to 90% of the volume flow flows through the upper opening so that flow along the filter medium (9) from the top downward results.
摘要翻译：用于烯烃聚合的设备，特别是乙烯，包括气相流化床反应器（1），用于从反应器（1）连续或不连续地获取聚合物颗粒的出口管线（15），该管线（15））连接到用于分离聚合物颗粒和气体的减压容器（2），用于释放连接到减压容器（2）的夹带的细颗粒的气体的循环气体过滤器（3），压缩已经被释放细颗粒并将其再循环到反应器（1）中，循环气体过滤器（3）具有设置有气体入口（6）的入口室（4），设置有气体出口的出口室（5） 7），用于保持将入口室（4）与出口室（5）分离的细颗粒和颗粒出口（8）的基本垂直的片状过滤介质（9）。入口室（4）具有基本上与过滤介质（9）平行布置的分隔壁（10），并将入口室（4）分离成入口区域（4a），该入口区域连接到气体入口 6）和过滤器区域（4b），其中过滤介质位于并具有上开口和下开口，其尺寸使得体积流量的60％至90％流过上开口，使得沿着过滤介质（9）从顶部向下的结果。

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