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1. 发明申请

US20130333832A1 PROCESS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS IN A TUBULAR REACTOR WITH AT LEAST TWO REACTION ZONES HAVING DIFFERENT CONCENTRATIONS OF CHAIN TRANSFER AGENT 审中-公开
标题翻译：在具有链转移剂不同浓度的至少两个反应区的管状反应器中制备乙烯共聚物或共聚物的方法
公开(公告)号：US20130333832A1
公开(公告)日：2013-12-19
申请号：US14002242
申请日：2012-03-01
申请人： Iakovos Vittorias , Barbara Gall , Sebastian Weiand , Andrei Gonioukh , Stephan Schmitz , Klaus Berhalter , Gerd Mannebach , Markus Busch , Thomas Herrmann
发明人： Iakovos Vittorias , Barbara Gall , Sebastian Weiand , Andrei Gonioukh , Stephan Schmitz , Klaus Berhalter , Gerd Mannebach , Markus Busch , Thomas Herrmann
IPC分类号： C08F2/38
CPC分类号： C08F2/38 , B29C48/022 , B29C48/09 , B29C48/154 , C08F10/02 , C08F110/02 , C08F210/02 , C08F2/00 , C08F2500/09 , C08F2500/10 , C08F218/08 , C08F4/38
摘要： Process for preparing ethylene homopolymers or copolymers in the presence of free-radical polymerization initiator and at least one chain transfer agent at pressures in the range of from 110 MPa to 350 MPa and temperatures in the range of from 100° C. to 350° C. in a tubular reactor with at least two reaction zones having different concentrations of the chain transfer agent, wherein the concentration of the chain transfer agent in the first reaction zone is less than 70% of the concentration of the chain transfer agent in the reaction zone with the highest concentration of the chain transfer agent, ethylene homopolymers or copolymers obtainable by such a process, the use of the ethylene homopolymers or copolymers for extrusion coating and a process for extrusion coating a substrate selected from the group consisting of paper, paperboard, polymeric film, and metal, with such ethylene homopolymers or copolymers.
摘要翻译：在自由基聚合引发剂和至少一种链转移剂的存在下，在110MPa至350MPa的压力和100℃至350℃的温度范围内制备乙烯均聚物或共聚物的方法在具有不同浓度的链转移剂的至少两个反应区的管式反应器中，其中第一反应区中链转移剂的浓度小于反应区中链转移剂浓度的70％具有最高浓度的链转移剂，乙烯均聚物或可通过这种方法得到的共聚物，使用乙烯均聚物或共聚物进行挤出涂布，以及用于挤出涂布选自纸，纸板，聚合物膜和金属，与这种乙烯均聚物或共聚物。

2. 发明授权

US06815571B1 Method for producing ethylene polymers in a high-pressure process 有权
标题翻译：在高压工艺中生产乙烯聚合物的方法
公开(公告)号：US06815571B1
公开(公告)日：2004-11-09
申请号：US10466117
申请日：2003-07-23
申请人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
发明人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
IPC分类号： C07C202
CPC分类号： A61Q1/06 , A61K8/8111 , A61Q1/02 , A61Q1/10 , C08F10/02 , C08F110/02 , C08K5/07 , C08K5/14 , Y10S585/946 , C08F4/36 , C08F2/00
摘要： A process for preparing ethylene polymers by the high-pressure method comprises dissolving one or more free-radical initiators in one or more ketones of the formula I where R1 and R2 are identical or different and are selected from among C1-C6-alkyl and C3-C12-cycloalkyl and R1 and R2 may also be covalently linked to one another to form a 4- to 13-membered ring, prior to the polymerization, compressing the solution, metering it into the polymerization reactor at one or more points and subsequently carrying out the polymerization at from 150 to 380° C. and from 500 to 4500 bar.
摘要翻译：通过高压法制备乙烯聚合物的方法包括将一种或多种自由基引发剂溶解在一种或多种式I的酮中，其中R 1和R 2相同或不同，并且选自C1- C6-烷基和C3-C12-环烷基，并且R 1和R 2也可以彼此共价连接以形成4-至13-元环，在聚合之前，将溶液压缩，将其计量聚合反应器在一个或多个点处，随后在150至380℃和500至4500巴下进行聚合反应。

3. 发明申请

US20070123678A1 Continuous preparation of ethylene homopolymers or copolymers 有权
标题翻译：连续制备乙烯均聚物或共聚物
公开(公告)号：US20070123678A1
公开(公告)日：2007-05-31
申请号：US10577695
申请日：2004-10-27
申请人： Andrei Gonioukh , Gernot Kohler , Theo Teubner , Thomas Droge
发明人： Andrei Gonioukh , Gernot Kohler , Theo Teubner , Thomas Droge
IPC分类号： C08F110/02
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F2/06 , C08F4/32 , C08F2/00 , C08F4/34 , C08F2/38 , C08F2500/12
摘要： The invention relates to a process for the continuous preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators and, if desired, molecular weight regulators at from 120° C. to 350° C. and pressures in the range from 100 to 4000 bar, in which the polymer is separated from unpolymerized ethylene in a high-pressure stage at a pressure of from 100 to 500 bar and at least one low-pressure stage at a pressure of from 1 to 100 bar and the ethylene separated off in the high-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a high-pressure circuit and the ethylene separated off in the low-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a low-pressure circuit. The initiator is used as a solution in an isoparaffinic solvent having a boiling point of not more than 160° C. and the solvent is separated from the other monomeric, oligomeric and/or polymeric constituents in the low-pressure circuit. The solvent is then, if appropriate after being admixed with fresh solvent, reused for dissolving initiator.
摘要翻译：本发明涉及一种在自由基聚合引发剂存在下连续制备乙烯均聚物或共聚物的方法，如果需要，本发明涉及120℃至350℃的分子量调节剂，并且在100 至4000巴，其中聚合物在100至500巴的压力和至少一个压力为1至100巴的压力下的高压阶段中与未聚合的乙烯分离，乙烯分离在高压阶段与剩余的单体，低聚物和/或聚合物组分分离，并在高压回路中再循环到管式反应器的入口，并将在低压级分离的乙烯与剩余的单体，低聚物和/或聚合物组分，并在低压回路中再循环到管式反应器的入口。引发剂用作沸点不超过160℃的异链烷烃溶剂中的溶液，并将溶剂与低压回路中的其它单体，低聚物和/或聚合物成分分离。如果在与新鲜溶剂混合后适当，溶剂再次用于溶解引发剂。

4. 发明授权

US06593437B1 Metal organic catalysts for polymerizing unsaturated compounds 有权
标题翻译：用于聚合不饱和化合物的金属有机催化剂
公开(公告)号：US06593437B1
公开(公告)日：2003-07-15
申请号：US09959382
申请日：2001-10-24
申请人： Andrei Gonioukh , Wolfgang Micklitz , Benno Bildstein , Michael Malaun , Andreas Hradsky
发明人： Andrei Gonioukh , Wolfgang Micklitz , Benno Bildstein , Michael Malaun , Andreas Hradsky
IPC分类号： C08F470
CPC分类号： C08G67/02 , C07C249/02 , C07C2603/20 , C07F17/02 , C08F4/00 , C08F4/61908 , C08F4/61912 , C08F4/61925 , C08F10/00 , C08F110/02 , C08F2410/03 , C08F2500/17 , C07C251/08 , C07C251/20 , C07C251/24 , C08F4/7006
摘要： A process for preparing 1,2-diimine compounds of the formula I where R1 and R2 are, independently of one another, alkyl, aryl or metallocenyl radicals, and R3, R4 are, independently of one another, H, alkyl or aryl radicals or R3 and R4 are joined so as to form, with inclusion of the two imine carbon atoms, a 5- to 8-membered ring which may be saturated or unsaturated and may be unsubstituted or substituted by any hydrocarbon radicals. The process involves reacting 1,2-dicarbonyl compounds with primary amines, which have been activated with trialkylaluminum compounds prior to the reaction with the 1,2-dicarbonyl compounds. 1,2-Diimine compounds of the formula I in which R1 and R2 are, independently of one another, metallocenyl radicals can be used to prepare metal complexes which can be used as catalysts in a process for the polymerization of unsaturated compounds.
摘要翻译：制备式I的1,2-二亚胺化合物的方法，其中R 1和R 2彼此独立地为烷基，芳基或金属茂基，且R 3，R 4彼此独立地为H，烷基或芳基或R 3 并且R4连接以形成包含两个亚胺碳原子的5-8元环，其可以是饱和或不饱和的，并且可以是未取代的或被任何烃基取代。该方法包括使1,2-二羰基化合物与伯胺反应，伯胺在与1,2-二羰基化合物反应之前已用三烷基铝化合物活化。其中R 1和R 2彼此独立地为金属茂基的式I的1,2-二亚胺化合物可用于制备可在不饱和化合物的聚合方法中用作催化剂的金属络合物。

5. 发明授权

US07273940B2 Catalysts for the polymerization of unsaturated compounds 有权
标题翻译：用于不饱和化合物聚合的催化剂
公开(公告)号：US07273940B2
公开(公告)日：2007-09-25
申请号：US10959212
申请日：2004-10-07
申请人： Marc Oliver Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
发明人： Marc Oliver Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
IPC分类号： C07D333/12
CPC分类号： C07D213/53 , C07F15/025 , C07F15/065 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2500/03 , C08F2500/04 , C08F2500/08 , C08F2500/07 , C08F2500/10 , C08F210/14 , C08F4/7042 , C08F4/7047
摘要： Bisimine compounds of the formula (I) where the symbols have the following meanings: A is a nonmetal selected from among N, S, O and P, R1 is a radical of the formula NR5R6, R2 is a radical of the formula NR5R6 or NR7R8, alkyl, aryl or cycloalkyl, R5 and R6 together with the N atom form a 5-, 6- or 7-membered ring in which one or more of the —CH— or —CH2— groups may be replaced by suitable heteroatom groups and which may be saturated or unsaturated and unsubstituted or substituted or be fused with further carbacyclic or heterocarbacyclic 5- or 6-membered rings which may in turn be saturated or unsaturated and substituted or unsubstituted, and R7 and R8 are, independently of one another, alkyl, aryl or cycloalkyl radicals, and R3, R4 are, independently of one another, H or alkyl, aryl or cycloalkyl radicals, and n is 1 or 2, are used to prepare bisimidinato complexes which can be used in the polymerization of unsaturated compounds.
摘要翻译：式（I）的双亚胺化合物，其中符号具有以下含义：A是选自N，S，O和P的非金属，R 1是式NR的基团， 5，R 6，R 2是下式的基团NR 5 R 6或NR 6 烷基，芳基或环烷基，R 5和R 6以及N原子一起形成一个 5-，6-或7-元环，其中一个或多个-CH-或-CH 2 - 亚基可以被合适的杂原子基团取代，并且可以是饱和或不饱和和未取代的或取代或与另外的碳环或杂碳环五或六元环稠合，其又可以是饱和的或不饱和的和取代或未取代的，R 7和R 8是独立地为烷基，芳基或环烷基，R 3，R 4彼此独立地为H或烷基，芳基或环烷基，以及 n为1或2，用于制备可用于不饱和化合物聚合的双嘧啶络合物。

6. 发明授权

US06949611B2 Preparation of ethylene polymers by the high-pressure method 失效
标题翻译：通过高压法制备乙烯聚合物
公开(公告)号：US06949611B2
公开(公告)日：2005-09-27
申请号：US10845396
申请日：2004-05-14
申请人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
发明人： Lars Wittkowski , Andreas Deckers , Wilhelm Weber , Thomas Dröge , Andrei Gonioukh , Frank-Olaf Mähling
IPC分类号： C08F2/00 , C08F2/38 , C08F10/00 , C08F10/02 , C08F110/02 , C08K5/07 , C08K5/14 , C08F2/02
CPC分类号： A61Q1/06 , A61K8/8111 , A61Q1/02 , A61Q1/10 , C08F10/02 , C08F110/02 , C08K5/07 , C08K5/14 , Y10S585/946 , C08F4/36 , C08F2/00
摘要： A process for preparing ethylene polymers by the high-pressure method comprises dissolving one or more free-radical initiators in one or more ketones of the formula I where R1 and R2 are identical or different and are selected from among C1-C6-alkyl and C3-C12-cycloalkyl and R1 and R2 may also be covalently linked to one another to form a 4- to 13-membered ring, prior to the polymerization, compressing the solution, metering it into the polymerization reactor at one or more points and subsequently carrying out the polymerization at from 150 to 380° C. and from 500 to 4500 bar.
摘要翻译：通过高压法制备乙烯聚合物的方法包括将一种或多种自由基引发剂溶解在式I中的一种或多种酮中，其中R 1和R 2，相同或不同，并且选自C 1 -C 6 - C 6 - 烷基和C 3 -C 12 - 环烷基和R 1和R 2可以在聚合之前彼此共价连接以形成4-至13-元环，压缩溶液，在一个或多个点将其计量到聚合反应器中，随后在150至380℃和500至4500巴下进行聚合。

7. 发明授权

US06818715B1 Bisimidino compounds and the transitional metal complexes thereof as well as the use thereof as catalysts 有权
标题翻译：双嘧啶系化合物及其过渡金属络合物及其作为催化剂的用途
公开(公告)号：US06818715B1
公开(公告)日：2004-11-16
申请号：US10049861
申请日：2002-02-19
申请人： Marc Oliver Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
发明人： Marc Oliver Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
IPC分类号： C08F406
CPC分类号： C07D213/53 , C07F15/025 , C07F15/065 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2500/03 , C08F2500/04 , C08F2500/08 , C08F2500/07 , C08F2500/10 , C08F210/14 , C08F4/7042 , C08F4/7047
摘要： Bisimine compounds of the formula (I) where the symbols are defined in the specification are used to prepare bisimidinato complexes which can be used in the polymerization of unsaturated compounds.
摘要翻译：用于说明书中定义的符号的式（I）的双亚胺化合物用于制备可用于不饱和化合物聚合的双嘧啶络合物。

8. 发明授权

US06500907B1 Catalyst system with aluminum fluoride activator 失效
标题翻译：催化剂体系与氟化铝活化剂
公开(公告)号：US06500907B1
公开(公告)日：2002-12-31
申请号：US09673148
申请日：2000-10-11
申请人： Carsten Süling , Marc Oliver Kristen , Günther Schweier , Andrei Gonioukh , Gerhard Hauck
发明人： Carsten Süling , Marc Oliver Kristen , Günther Schweier , Andrei Gonioukh , Gerhard Hauck
IPC分类号： C08F414
CPC分类号： C08F10/00 , C08F4/61908 , C08F4/61922 , C08F110/02 , Y10S526/943 , C08F4/61912 , C08F4/76 , C08F2500/17 , C08F2500/03 , C08F4/7006
摘要： Catalyst system suitable for polymerizing unsaturated monomers and comprising active constituents obtainable by reacting A) a transition metal compound with B) aluminum trifluoride, C) a cation-forming compound and, if desired, D) further components.
摘要翻译：适用于聚合不饱和单体的催化剂体系，包括通过使A）过渡金属化合物与B）三氟化铝反应获得的活性成分，C）阳离子形成化合物，以及如果需要，D）另外的组分。

9. 发明授权

US07737229B2 Continuous preparation of ethylene homopolymers or copolymers 有权
标题翻译：连续制备乙烯均聚物或共聚物
公开(公告)号：US07737229B2
公开(公告)日：2010-06-15
申请号：US10577695
申请日：2004-10-27
申请人： Andrei Gonioukh , Gernot Köhler , Theo Teuber , Thomas Dröge
发明人： Andrei Gonioukh , Gernot Köhler , Theo Teuber , Thomas Dröge
IPC分类号： C08F2/00 , C08F10/14
CPC分类号： C08F10/02 , C08F10/00 , C08F110/02 , C08F2/06 , C08F4/32 , C08F2/00 , C08F4/34 , C08F2/38 , C08F2500/12
摘要： The invention relates to a process for the continuous preparation of ethylene homopolymers or copolymers in the presence of free-radical polymerization initiators and, if desired, molecular weight regulators at from 120° C. to 350° C. and pressures in the range from 100 to 4000 bar, in which the polymer is separated from unpolymerized ethylene in a high-pressure stage at a pressure of from 100 to 500 bar and at least one low-pressure stage at a pressure of from 1 to 100 bar and the ethylene separated off in the high-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a high-pressure circuit and the ethylene separated off in the low-pressure stage is separated from remaining monomeric, oligomeric and/or polymeric constituents and recirculated to the inlet of the tube reactor in a low-pressure circuit. The initiator is used as a solution in an isoparaffinic solvent having a boiling point of not more than 160° C. and the solvent is separated from the other monomeric, oligomeric and/or polymeric constituents in the low-pressure circuit. The solvent is then, if appropriate after being admixed with fresh solvent, reused for dissolving initiator.
摘要翻译：本发明涉及一种在自由基聚合引发剂存在下连续制备乙烯均聚物或共聚物的方法，如果需要，本发明涉及120℃至350℃的分子量调节剂，并且在100 至4000巴，其中聚合物在100至500巴的压力和至少一个压力为1至100巴的压力下的高压阶段中与未聚合的乙烯分离，乙烯分离在高压阶段与剩余的单体，低聚物和/或聚合物组分分离，并在高压回路中再循环到管式反应器的入口，并将在低压级分离的乙烯与剩余的单体，低聚物和/或聚合物组分，并在低压回路中再循环到管式反应器的入口。引发剂用作沸点不超过160℃的异链烷烃溶剂中的溶液，并将溶剂与低压回路中的其它单体，低聚物和/或聚合物成分分离。如果在与新鲜溶剂混合后适当，溶剂再次用于溶解引发剂。

10. 发明申请

US20050085527A1 Catalysts for the polymerization of unsaturated compounds 有权
标题翻译：用于不饱和化合物聚合的催化剂
公开(公告)号：US20050085527A1
公开(公告)日：2005-04-21
申请号：US10959212
申请日：2004-10-07
申请人： Marc Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
发明人： Marc Kristen , Andrei Gonioukh , Dieter Lilge , Stephan Lehmann , Benno Bildstein , Christoph Amort , Michael Malaun
IPC分类号： C07D401/14 , B01J31/18 , C07B61/00 , C07D213/53 , C07D409/12 , C07F15/02 , C07F15/06 , C08F4/70 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C07D333/12 , A61K31/381 , A61K31/382 , A61K31/4025 , C07D333/20
CPC分类号： C07D213/53 , C07F15/025 , C07F15/065 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2500/03 , C08F2500/04 , C08F2500/08 , C08F2500/07 , C08F2500/10 , C08F210/14 , C08F4/7042 , C08F4/7047
摘要： Bisimine compounds of the formula (I) where the symbols have the following meanings: A is a nonmetal selected from among N, S, O and P, R1 is a radical of the formula NR5R6, R2 is a radical of the formula NR5R6 or NR7R8, alkyl, aryl or cycloalkyl, R5 and R6 together with the N atom form a 5-, 6- or 7-membered ring in which one or more of the —CH— or —CH2— groups may be replaced by suitable heteroatom groups and which may be saturated or unsaturated and unsubstituted or substituted or be fused with further carbacyclic or heterocarbacyclic 5- or 6-membered rings which may in turn be saturated or unsaturated and substituted or unsubstituted, and R7 and R8 are, independently of one another, alkyl, aryl or cycloalkyl radicals, and R3, R4 are, independently of one another, H or alkyl, aryl or cycloalkyl radicals, and n is 1 or 2, are used to prepare bisimidinato complexes which can be used in the polymerization of unsaturated compounds.
摘要翻译：式（I）的双亚胺化合物，其中符号具有以下含义：A是选自N，S，O和P的非金属，R 1是式NR的基团， 5，R 6，R 2是下式的基团NR 5 R 6或NR 6 烷基，芳基或环烷基，R 5和R 6以及N原子一起形成一个 5-，6-或7-元环，其中一个或多个-CH-或-CH 2 - 亚基可以被合适的杂原子基团取代，并且可以是饱和或不饱和和未取代的或取代或与另外的碳环或杂碳环五或六元环稠合，其又可以是饱和的或不饱和的和取代或未取代的，R 7和R 8是独立地为烷基，芳基或环烷基，R 3，R 4彼此独立地为H或烷基，芳基或环烷基，以及 n为1或2，用于制备可用于不饱和化合物聚合的双嘧啶络合物。

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