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1. 发明授权

US06180729B2 Continuous gas-phase polymerization process 有权
标题翻译：连续气相聚合法
公开(公告)号：US06180729B2
公开(公告)日：2001-01-30
申请号：US09201084
申请日：1998-11-30
申请人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
发明人： Armin Lange , Wolfgang Micklitz , Rainer Karer , Kaspar Evertz , Shahram Mihan , Hans-Jacob Feindt , Manfred Hecker , Peter Bauer , Philipp Rosendorfer
IPC分类号： C08F240
CPC分类号： C08F10/00 , C08F2/005 , C08F210/16 , Y02P20/584 , C08F2/34 , C08F2/40 , C08F2/007 , C08F2/002 , C08F210/14 , C08F2500/12 , C08F2500/18
摘要： In a continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or a mixture of ethylene or propene and C3-C8-&agr;-monoolefins is polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and a pressure of from 1 to 100 bar in the gas phase in a bed of finely divided polymer in the presence of a catalyst, where the reactor gas is circulated to remove the heat of polymerization, polymer deposits in the circulating gas line are prevented by metering a catalyst poison having a boiling point above the maximum temperature within the circulating gas line into this circulating gas line in at most such an amount that it does not significantly impair the productivity of the catalyst in the reactor.
摘要翻译：在用于制备乙烯和丙烯均聚物和共聚物的连续气相聚合方法中，其中乙烯，丙烯或乙烯或丙烯和C 3 -C 8-α-单烯烃的混合物在气相聚合反应器的聚合区中聚合在催化剂存在下，在细分散的聚合物床中的气相中，在30至125℃和1至100巴的压力下，其中反应器气体循环以除去聚合热，聚合物沉积物通过将沸点高于循环气体管线中的最高温度的催化剂毒物计量到该循环气体管线中，至多使其不显着损害反应器中催化剂的生产率的程度来防止循环气体管线。

2. 发明授权

US06649709B1 Gas phase fluidized bed method and ethylene homo- and copolymers obtained using said method 有权
标题翻译：气相流化床法和使用所述方法获得的乙烯均聚物和共聚物
公开(公告)号：US06649709B1
公开(公告)日：2003-11-18
申请号：US09555594
申请日：2000-05-31
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

3. 发明授权

US06849699B2 Vapor-phase fluidized-bed process and ethylene homopolymers and copolymers produced thereby 失效
标题翻译：气相流化床方法和由此制备的乙烯均聚物和共聚物
公开(公告)号：US06849699B2
公开(公告)日：2005-02-01
申请号：US10658916
申请日：2003-09-11
申请人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
发明人： Peter Bauer , Armin Lange , Rainer Karer , Philipp Rosendorfer , Manfred Hecker , Günther Schweier , Wolfgang Micklitz , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08J5/18 , C08F2/34 , C08F4/02 , C08F4/24 , C08F4/69 , C08F10/02 , C08F210/02
CPC分类号： C08F10/02 , C08F4/24 , C08F2/34
摘要： A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ⁢ ⁢ d ′ 0.84 - d ′ ( I ) and a lower envelope defined by equation II T L = 173 + 7.3 ⁢ ⁢ d ′ 0.837 - d ′ , ( II ) in which the variables have the following meanings: TH is the highest reaction temperature in ° C.; TL is the lowest reaction temperature in ° C.; d′ is the numerical value of the density d of the (co)polymer to be synthesized.
摘要翻译：用于制备密度为0.87至0.97g / cm 3的乙烯均聚物和共聚物的连续气相流化床方法，其中乙烯或乙烯和C 3 -C 8α-单烯烃的混合物（共）聚合在负载的铬催化剂的存在下，在气相流化床反应器的聚合区域的存在下，在压力范围为1至100巴，温度范围为30至125℃，气相在搅拌床包含颗粒聚合物的散装材料，通过冷却再循环的反应器气体除去所得到的聚合热，并将所得（共）聚合物从气相流化床反应器中除去，其中，为制备（共）聚合物特定密度d，（共）聚合在由等式I定义的上包络限制的范围内进行，并且由等式IIin定义的下包络，其中变量具有以下含义：T H是最高的反应温度，单位°C; TL是最低反应温度（℃）; d'是待合成的（共）聚合物的密度d的数值。

4. 发明授权

US06559087B1 Method and apparatus for the continuous treatment of catalyst and catalyst support material 失效
标题翻译：用于连续处理催化剂和催化剂载体材料的方法和装置
公开(公告)号：US06559087B1
公开(公告)日：2003-05-06
申请号：US09536356
申请日：2000-03-27
申请人： Paulus De Lange , Rainer Karer , Philipp Rosendorfer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt
发明人： Paulus De Lange , Rainer Karer , Philipp Rosendorfer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt
IPC分类号： B01J3708
CPC分类号： B65G53/22 , B01J8/10 , B01J8/26 , B01J8/46 , B01J19/18 , B01J19/22 , B01J37/00 , B01J2219/00033 , B01J2219/00132 , C08F10/00 , Y10S526/905 , C08F4/24
摘要： A method for the treatment of catalyst or catalyst support material in an apparatus in which the treatment is carried out continuously in such a way that the physical and/or chemical conditions change during entry of the catalyst or catalyst support material into the apparatus and/or during exit thereof from the apparatus and/or the catalyst or catalyst support material is transported in the apparatus through zones (5, 6, 7) having different physical and/or chemical conditions.
摘要翻译：一种在设备中处理催化剂或催化剂载体材料的方法，其中以使得催化剂或催化剂载体材料进入装置和/或其中的物理和/或化学条件改变的方式连续进行处理在从装置出来时和/或催化剂或催化剂载体材料在装置中通过具有不同物理和/或化学条件的区域（5,6,7）输送。

5. 发明授权

US07601303B1 Gaseous phase fluidized-bed reactor 失效
标题翻译：气相流化床反应器
公开(公告)号：US07601303B1
公开(公告)日：2009-10-13
申请号：US09700367
申请日：1999-05-04
申请人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： B01J8/18
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

6. 发明授权

US08034884B2 Gaseous phase fluidized-bed reactor 失效
标题翻译：气相流化床反应器
公开(公告)号：US08034884B2
公开(公告)日：2011-10-11
申请号：US12554964
申请日：2009-09-07
申请人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer Karer , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/00 , B01J8/18
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

7. 发明申请

US20100056734A1 GASEOUS PHASE FLUIDIZED-BED REACTOR 失效
标题翻译：气相流化床反应器
公开(公告)号：US20100056734A1
公开(公告)日：2010-03-04
申请号：US12554964
申请日：2009-09-07
申请人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
发明人： Rainer KARER , Kaspar Evertz , Wolfgang Micklitz , Hans-Jacob Feindt , Philipp Rosendorfer , Peter Kölle
IPC分类号： C08F2/01
CPC分类号： B01J8/1827 , B01J8/44 , B01J2208/00256 , B01J2208/00274 , C08F10/00 , C08F2/34 , C08F2/01
摘要： Gas-phase fluidized-bed reactor for polymerizing ethylenically unsaturated monomers, comprising a reactor chamber (1) in the form of a vertical tube, if desired a calming zone (2) following the upper section of the reactor chamber, a circulation gas line (3), a circulation gas compressor (4) and a cooling device (5), where, in the region of transition of the reaction gas from the circulation gas line into the reactor chamber and in the lower section of the reactor chamber itself, there is either no gas distributor plate at all or only a gas distributor plate the total surface area of whose gas orifices is more than 20% of the total surface area of said gas distributor plate.
摘要翻译：用于聚合烯键式不饱和单体的气相流化床反应器，包括垂直管形式的反应器室（1），如果需要，在反应器室的上部之后的平静区域（2），循环气体管线 3），循环气体压缩机（4）和冷却装置（5），其中在反应气体从循环气体管线进入反应器室和反应器室本身的下部的过渡区域完全不是气体分配器板，或者只有气体分配器板，其气体孔的总表面积大于所述气体分布板的总表面积的20％。

8. 发明授权

US07534341B2 Discontinuous metering of catalysts and process auxilliaries into a gas-phase fluidized-bed reactor 失效
标题翻译：催化剂和工艺助剂不连续计量进入气相流化床反应器
公开(公告)号：US07534341B2
公开(公告)日：2009-05-19
申请号：US10552853
申请日：2004-04-15
申请人： Rainer Karer , Kaspar Evertz , Peter Kölle , Hans-Jacob Feindt
发明人： Rainer Karer , Kaspar Evertz , Peter Kölle , Hans-Jacob Feindt
IPC分类号： C10G35/00 , C10G35/10
CPC分类号： B01J4/002 , B01J4/007 , B01J4/02 , B01J8/0035 , B01J8/004 , B01J8/1872 , B01J2208/00752 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2/00 , C08F2/01 , C08F2/34 , C08F2500/07 , C08F2500/12
摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.
摘要翻译：将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中至少一个计量点（10）。根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入这个地区。由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

9. 发明申请

US20070037935A1 Discontinuous metering of catalysts and process auxiliaries into a gas-phase fluidized-bed reactor 失效
标题翻译：催化剂和工艺助剂不连续计量进入气相流化床反应器
公开(公告)号：US20070037935A1
公开(公告)日：2007-02-15
申请号：US10552853
申请日：2004-04-15
申请人： Rainer Karer , Kaspar Evertz , Hans-Jacob Feindt
发明人： Rainer Karer , Kaspar Evertz , Hans-Jacob Feindt
IPC分类号： C08G85/00 , B32B27/04
CPC分类号： B01J4/002 , B01J4/007 , B01J4/02 , B01J8/0035 , B01J8/004 , B01J8/1872 , B01J2208/00752 , C08F10/00 , C08F110/02 , C08F210/16 , C08F2/00 , C08F2/01 , C08F2/34 , C08F2500/07 , C08F2500/12
摘要： Method of metering at least one solid, particulate catalyst into a reactor containing a fluidized bed (11) of particles in an at least partly gaseous medium, in which the catalyst is metered discontinuously at prescribed time intervals into the fluidized bed (11) at at least one metering point (10). According to the present invention, a fluid stream is firstly introduced into the reactor (5) so that a region having a reduced particle density is formed in the fluidized bed (11) around the metering point (10) and the catalyst is subsequently metered into this region. As a result of the prior introduction of a fluid stream (“preblowing”) before the actual introduction of the catalyst, the catalyst can penetrate significantly deeper into the fluidized bed from the metering point due to the reduced particle density and is dispersed better.
摘要翻译：将至少一种固体颗粒催化剂计量到含有至少部分气体介质中的颗粒流化床（11）的反应器的方法，其中催化剂以规定的时间间隔不连续地计量加入流化床（11）中至少一个计量点（10）。根据本发明，首先将流体流引入反应器（5），使得在流化床（11）周围形成具有减小的颗粒密度的区域，并将催化剂随后计量加入这个地区。由于在实际引入催化剂之前先前引入流体物流（“预吹扫”），由于颗粒密度降低，催化剂可以从计量点深入到流化床中，并且分散得更好。

10. 发明授权

US06462150B1 Method for isolating olefins from polyolefin plants 有权
标题翻译：从聚烯烃工厂中分离烯烃的方法
公开(公告)号：US06462150B1
公开(公告)日：2002-10-08
申请号：US09913074
申请日：2001-08-09
申请人： Stefan Bitterlich , Kaspar Evertz , Manfred Hecker , Hans-Jacob Feindt
发明人： Stefan Bitterlich , Kaspar Evertz , Manfred Hecker , Hans-Jacob Feindt
IPC分类号： C08F234
CPC分类号： C08F6/001 , B01J8/007 , B01J8/24 , C07C7/005 , C07C11/02
摘要： The present invention relates to a method for the isolation of olefins from a gas mixture comprising one or more olefins, inert gas and catalyst poison, where the gas mixture is fed to a separation unit (18) and separated into olefin and inert gas. The method according to the invention has the special feature that an apparatus (17) is installed upstream or downstream of the separation unit (18) and that i) in the case of an upstream apparatus (17), the catalyst poison is at least partially removed from the gas mixture, and ii) in the case of a downstream apparatus (17), the catalyst poison is at least partially removed from the separated-off olefin. The olefins here are preferably isolated from a gas mixture formed as offgas in catalytic gas-phase polymerization for the preparation of polyolefins. The recovery of the olefins from the offgas is of economic importance.
摘要翻译：本发明涉及从包含一种或多种烯烃，惰性气体和催化剂毒物的气体混合物中分离烯烃的方法，其中气体混合物被供给到分离单元（18）并分离成烯烃和惰性气体。根据本发明的方法具有以下特征：设备（17）安装在分离单元（18）的上游或下游，并且在上游设备（17）的情况下，催化剂毒物至少部分地被去除在下游装置（17）的情况下，催化剂毒物至少部分地从分离的烯烃中除去。这里的烯烃优选与催化气体 - 气体中的废气形成的气体混合物分离，用于制备聚烯烃的相聚合。从废气中回收烯烃是经济重要的。

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