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1. 发明授权

US5296542A Heat resistant polymers and blends of hydroquinone poly (isoterephthalates) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（对苯二甲酸丙二醇酯）的耐热聚合物和共混物
公开(公告)号：US5296542A
公开(公告)日：1994-03-22
申请号：US790663
申请日：1991-11-08
申请人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer , Markus Matzner
发明人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer , Markus Matzner
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00 , C08F20/00 , C08G63/00 , C08G63/02
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.
摘要翻译：本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。（*化学结构*）（I）（*化学结构*）（II）（*化学结构*）（III）（*化学结构*）（IV）和由两者制成的这些聚合物和制品的共混物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的指定比例存在。立即共聚酯在熔融态显示取向，良好的纤维等级和高强度; 它们的熔点在约340℃至约400℃的范围内，并且是可熔融加工的。有利地，填充有约30重量百分比的玻璃纤维的这些组合物在264psi的负载下测量时显示高于240摄氏度至高达约280摄氏度的热变形温度。当混合时，某些性能得到改善，特别是它们更容易熔化制造，具有降低的起泡倾向和增加的强度。这些聚合物和共混物可以有利地用于需要高温的烤箱，电子部件，电气设备和其它最终用途。

2. 发明授权

US5204417A High strength polymers and blends of hydroquinone poly(iso-terephthalates) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（异对苯二甲酸酯）的高强度聚合物和共混物
公开(公告)号：US5204417A
公开(公告)日：1993-04-20
申请号：US929667
申请日：1992-08-13
申请人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
发明人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00 , Y10T428/31786 , Y10T428/3179
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1##and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
摘要翻译：本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。（IV）和（II）这两种聚合物和制品的共混物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的指定比例存在。立即共聚酯显示熔融状态的取向，良好的纤维等级和高强度。有利地，本发明的聚合物显示出纯聚合物的粘度和可模塑性的显着改善。该聚合物具有优异的机械和表面性能，包括起泡性，强度，韧性和气相焊料的能力，并形成强力纤维，同时仍保持高的热变形温度。它们的熔点在约250℃至约360℃的范围内，并且是可熔融加工的。有利地，填充有约30重量％的玻璃纤维的这些组合物在264psi的载荷下测量时，显示高达240℃的热变形温度。聚合物可以混合以定制特性。这些聚合物和共混物可以有利地用于生产纤维和电气设备，电子部件和需要适度高温的其它最终用途。

3. 发明授权

US4624978A High temperature polyimide processing aid 失效
标题翻译：高温聚酰亚胺加工助剂
公开(公告)号：US4624978A
公开(公告)日：1986-11-25
申请号：US728480
申请日：1985-04-29
申请人： Paul D. Frayer
发明人： Paul D. Frayer
IPC分类号： C08K5/3415 , C08K5/34 , C08L79/08
CPC分类号： C08K5/3415
摘要： A high temperature processing aid for melt processing polyimide polymers and a method of doing same is presented wherein a compatible, high boiling point N-alkyl- or N-alicyclic-substituted pyrrolidone is added to a polyimide polymer in amounts sufficient to lower the glass transition temperature of said polyimide.
摘要翻译：提出了用于熔融加工聚酰亚胺聚合物的高温加工助剂及其制备方法，其中相当的高沸点N-烷基或N-脂环取代的吡咯烷酮以足以降低玻璃化转变的量加入到聚酰亚胺聚合物中所述聚酰亚胺的温度。

4. 发明授权

US06656398B2 Process of making a pattern in a film 有权
标题翻译：在电影中制作图案的过程
公开(公告)号：US06656398B2
公开(公告)日：2003-12-02
申请号：US09884641
申请日：2001-06-19
申请人： William R. Birch , Alain R. E. Carre , Paul D. Frayer , Kenjiro Hasui
发明人： William R. Birch , Alain R. E. Carre , Paul D. Frayer , Kenjiro Hasui
IPC分类号： B29C3364
CPC分类号： B82Y30/00 , B29C33/64 , B29C37/0067 , B29C59/02
摘要： A method for forming a pattern in a film carried on a substrate includes depositing a layer of alkyl silane on a surface of a mold having a pattern, bringing the mold in contact with the film on the substrate and pressing the mold into the film so as to emboss the pattern on the mold in the film, wherein the film comprises a thermoplastic polymer, and removing the mold from the film.
摘要翻译：在基板上形成图案的方法包括在具有图案的模具的表面上沉积烷基硅烷层，使模具与基板上的膜接触并将模具压入膜中，以便以在膜中的模具上压花图案，其中所述膜包括热塑性聚合物，并从所述膜移除所述模具。

5. 发明授权

US06268425B1 Glass/polymer melt blends 失效
标题翻译：玻璃/聚合物熔体共混物
公开(公告)号：US06268425B1
公开(公告)日：2001-07-31
申请号：US09229379
申请日：1999-01-11
申请人： Paul D. Frayer , Roy J. Monahan , Michelle D. Pierson
发明人： Paul D. Frayer , Roy J. Monahan , Michelle D. Pierson
IPC分类号： C08K340
CPC分类号： C03C14/00 , C03C2214/12 , C03C2214/30
摘要： This invention is directed to the preparation of alloy articles consisting essentially of 65 wt. % or more glass and high temperature organic thermoplastic or thermosetting polymers having working temperatures which are compatible with that of the glass and/or the precursor glass for the glass-ceramic. The glass and polymer are combined at the working temperature to form an intimate mixture; i.e., the glass and polymer are in a sufficiently fluid state to be blended together to yield a body exhibiting an essentially uniform, fine-grained microstructure wherein, desirably, there is at least partial miscibility and/or a reaction between the glass and the polymer to promote adhesion and bonding therebetween. A body is shaped from the mixture and cooled to room temperature.
摘要翻译：本发明涉及制备基本上由65重量％百分比或更多的玻璃和高温有机热塑性或热固性聚合物，其工作温度与玻璃和/或用于玻璃 - 陶瓷的前体玻璃相容。玻璃和聚合物在工作温度下结合形成密实的混合物; 即，玻璃和聚合物处于足够流动的状态以混合在一起以产生表现出基本上均匀的细晶粒微结构的主体，其中，理想地，玻璃和聚合物之间存在至少部分混溶性和/或反应以促进它们之间的粘合和粘合。将体从混合物成型并冷却至室温。

6. 发明授权

US5147967A High strength polymer of hydroquinone poly(iso-terephthalate) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（对苯二甲酸丙二醇酯）的高强度聚合物
公开(公告)号：US5147967A
公开(公告)日：1992-09-15
申请号：US499483
申请日：1990-06-04
申请人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
发明人： Brian A. Stern , Markus Matzner , Richard Layton , Paul J. Huspeni , Paul D. Frayer , James W. Cleary
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00
摘要： This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention".The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
摘要翻译： PCT No.PCT / US89 / 04331 Sec。 371日期1990年6月4日第 102（e）1990年6月4日PCT PCT。于1989年10月10日提交。本发明涉及基本上由单元（I），（II），（III）和（IV）组成的新型共聚酯。这些聚合物和由两者制成的制品的混合物。单位（I），（II），（III）和（IV）按照“发明描述”中定义的特定比例存在。立即共聚酯显示熔融状态的取向，良好的纤维等级和高强度。有利地，本发明的聚合物显示出纯聚合物的粘度和可模塑性的显着改善。该聚合物具有优异的机械和表面性能，包括起泡性，强度，韧性和气相焊料的能力，并形成强力纤维，同时仍保持高的热变形温度。它们的熔点在约250℃至约360℃的范围内，并且是可熔融加工的。有利地，填充有约30重量％的玻璃纤维的这些组合物在264psi的载荷下测量时，显示高达240℃的热变形温度。聚合物可以混合以定制特性。这些聚合物和共混物可以有利地用于生产纤维和电气设备，电子部件和需要适度高温的其它最终用途。

7. 发明授权

US6103810A Glass/polymer melt blends 失效
标题翻译：玻璃/聚合物熔体共混物
公开(公告)号：US6103810A
公开(公告)日：2000-08-15
申请号：US883775
申请日：1997-06-27
申请人： Paul D. Frayer , Roy J. Monahan , Michelle D. Pierson
发明人： Paul D. Frayer , Roy J. Monahan , Michelle D. Pierson
IPC分类号： C03C14/00 , C08K3/40 , C01B25/26
CPC分类号： C03C14/00 , C03C2214/12 , C03C2214/30
摘要： This invention is directed to the preparation of alloy articles consisting essentially of glass and high temperature organic thermoplastic or thermosetting polymers having working temperatures which are compatible with that of the glass and/or the precursor glass for the glass-ceramic. The glass and polymer are combined at the working temperature to form an intimate mixture; i.e., the glass and polymer are in a sufficiently fluid state to be blended together to yield a body exhibiting an essentially uniform, fine-grained microstructure wherein, desirably, there is at least partial miscibility and/or a reaction between the glass and the polymer to promote adhesion and bonding therebetween. A body is shaped from the mixture and cooled to room temperature.
摘要翻译：本发明涉及制备基本上由玻璃和高温有机热塑性材料或热固性聚合物组成的合金制品，其工作温度与玻璃和/或用于玻璃 - 陶瓷的前体玻璃相容。玻璃和聚合物在工作温度下结合形成密实的混合物; 即，玻璃和聚合物处于足够流动的状态以混合在一起以产生表现出基本上均匀的细晶粒微结构的主体，其中，理想地，玻璃和聚合物之间存在至少部分混溶性和/或反应以促进它们之间的粘合和粘合。将体从混合物成型并冷却至室温。

8. 发明授权

US5216092A Blends of liquid crystalline polymers of hydroquinone poly(isoterephthalates) p-hydroxybenzoic acid polymers and another LCP containing oxybisbenzene and naphthalene derivatives 失效
标题翻译：对苯二酚聚（对苯二甲酸酯）对羟基苯甲酸聚合物和另外含有氧双苯和萘衍生物的LCP的液晶聚合物的共混物
公开(公告)号：US5216092A
公开(公告)日：1993-06-01
申请号：US499480
申请日：1990-06-04
申请人： Paul J. Huspeni , Brian A. Stern , Paul D. Frayer , Richard Layton , Markus Matzner
发明人： Paul J. Huspeni , Brian A. Stern , Paul D. Frayer , Richard Layton , Markus Matzner
IPC分类号： C08K7/14 , C08G63/06 , C08G63/60 , C08G63/83 , C08L67/00
CPC分类号： C08G63/83 , C08G63/605 , C08L67/00
摘要： This invention relates to a blend comprising a first LCP polyester polymer consisting essentially of units (I), (II), (III), and (IV). ##STR1## having a melting point under about 420.degree. C., p is approximately equal to r+q, r is from about 0.05 to about 0.9, q is from about 0.95 to about 0.1 and s is from about 0.05 to about 9, and a second LCP polyester polymer comprising at least one moiety selected from the group consisting of hydroxybenzoic acid, hydroxynaphthalene carboxylic acid, dihydroxy naphthalene, naphthalene dicarboxylic acid, oxybisbenzoic acid and substituted hydroquinones wherein the said moiety or moieties comprise(s) at least about 5 mole percent of the units in said second LCP polyester.
摘要翻译： PCT No.PCT / US89 / 04330 Sec。 371日期1990年6月4日第 102（e）日期1990年6月4日PCT提交1989年10月10日PCT公布。出版物WO90 / 04002 1990年04月19日。本发明涉及包含基本上由单元（I），（II），（III）和（IV）组成的第一LCP聚酯聚合物的共混物。（I）（II）（III）（IV）具有约420℃的熔点，p约等于r + q，r为约0.05至约0.9，q为约0.95至约0.1，s为约0.05至约9，第二LCP聚酯聚合物包含至少一个选自羟基苯甲酸，羟基萘羧酸，二羟基萘，萘二羧酸的部分酸，氧双苯甲酸和取代的氢醌，其中所述部分或部分包含所述第二LCP聚酯中的至少约5摩尔％的单元。

9. 发明授权

US5097001A Hydroquinone poly(iso-terephthalates) containing residues of p-hydroxybenzoic acid 失效
标题翻译：含有对羟基苯甲酸残基的氢醌聚（异对苯二甲酸酯）
公开(公告)号：US5097001A
公开(公告)日：1992-03-17
申请号：US412785
申请日：1989-09-26
申请人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer
发明人： Richard Layton , James W. Cleary , Paul J. Huspeni , Paul D. Frayer
IPC分类号： C08G63/60 , C08G63/83 , C08K7/02 , C08L67/00
CPC分类号： C08K7/02 , C08G63/605 , C08G63/83 , C08L67/00
摘要： A high modulus, high strength melt processable copolyester consisting essentially of recurring units (I), (II), (III) and (IV): ##STR1## wherein said copolyester has a melting point in the range of from about 340.degree. C. to 400.degree. C., a crystallization temperature of from about 300.degree. C.-340.degree. C., and a crystallization rate of at least 1,000 counts/minute.
摘要翻译：基本上由重复单元（I），（II），（III）和（IV）组成的高模量，高强度的可熔融加工的共聚酯：其中所述共聚酯的熔点范围为约340 ℃至400℃，结晶温度为约300℃-340℃，结晶速率为至少1,000次/分钟。

10. 发明授权

US06284192B1 Extruding electrode material 有权
标题翻译：挤出电极材料
公开(公告)号：US06284192B1
公开(公告)日：2001-09-04
申请号：US09429132
申请日：1999-10-28
申请人： Everett W. Coonan , Paul D. Frayer , Roy J. Monahan , Kathleen A. Wexell
发明人： Everett W. Coonan , Paul D. Frayer , Roy J. Monahan , Kathleen A. Wexell
IPC分类号： B22F320
CPC分类号： C22C32/0094 , B22F3/20 , B29C47/0004 , B29C47/0009 , B29C47/38 , B29C47/402 , B29C47/6093 , B29K2027/18 , H01M4/04 , H01M4/0404 , H01M4/0411 , H01M4/0416 , H01M4/26
摘要： A method of extruding an electrode, batch material, particularly a zinc or nickel, electrode material, and an extruder assembly for extruding the material, are described. The method and extruder are designed to produce a low compaction of the material and low, back pressure, whereby working of the batch material is limited.
摘要翻译：描述了挤出电极，批料，特别是锌或镍电极材料和用于挤出材料的挤出机组件的方法。该方法和挤出机设计用于产生材料的低压实度和低的背压，由此批料的加工受到限制。

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