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    • 5. 发明授权
    • High modulus, high strength melt-processible polyester of hydroquinone
poly (iso-terephthalates) containing residues of a p-hydroxybenzoic acid
    • 含有对羟基苯甲酸残基的氢醌聚(异对苯二甲酸酯)的高模量,高强度可熔融加工的聚酯
    • US5079289A
    • 1992-01-07
    • US499482
    • 1990-06-04
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • C08G63/60C08G63/83C08K7/02C08L67/00
    • C08K7/02C08G63/605C08G63/83C08L67/00
    • This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (V). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention". The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.
    • 本发明涉及基本上由单元(I),(II),(III)和(V)组成的新型共聚酯。 这些聚合物和由两者制成的制品的混合物。 单位(I),(II),(III)和(IV)按照“发明描述”中定义的特定比例存在。 立即共聚酯在熔融态显示取向,良好的纤维等级和高强度; 它们的熔点在约340℃至约400℃的范围内,并且是可熔融加工的。 有利地,填充有约30重量%的玻璃纤维的这些组合物在264psi的载荷下测量时,显示超过240℃至高达约280℃的热变形温度。 当混合时,某些性能得到改善,特别是它们更容易熔化制造,具有降低的起泡倾向和增加的强度。 这些聚合物和共混物可以有利地用于需要高温的烤箱,电子部件,电气设备和其它最终用途。
    • 9. 发明授权
    • Plastic ovenware compositions
    • 塑料烤箱组合物
    • US5132336A
    • 1992-07-21
    • US697809
    • 1991-05-09
    • Richard LaytonPaul J. HuspeniPaul D. Frayer
    • Richard LaytonPaul J. HuspeniPaul D. Frayer
    • A47J36/02C08G63/60C08K3/34C08L67/00
    • C08K3/34A47J36/02C08G63/605C08L67/00
    • A molded article of permanent ovenware comprising (A) 35-85% by weight of a wholly aromatic polyester resin; (B) 15-65% by weight of a specifically defined talc containing a minimum amount of materials decomposable at elevated temperatures; and (C) 0-20% titanium dioxide, wherein the wholly aromatic polyester resin (A) is a blend comprising a first resin based on repeating units of hydroquinone, isophthalic acid (or mixtures of iso- and terephthalic acids), and para-hydroxybenzoic acid, and a second resin based on repeating units of biphenol, isophthalic acid, terephthalic acid and para-hydroxybenzoic acid. The ovenware shows excellent resistance to blistering, bubbling and cracking during molding and oven use.
    • 一种永久性烤箱的模制品,其包含(A)35-85重量%的全芳族聚酯树脂; (B)15-65重量%的特定滑石,其含有在升高的温度下可分解的最小量的材料; 和(C)0-20%二氧化钛,其中全芳族聚酯树脂(A)是包含基于氢醌重复单元的第一树脂,间苯二甲酸(或异对苯二甲酸的混合物)和对 - 羟基苯甲酸和基于联苯酚,间苯二甲酸,对苯二甲酸和对羟基苯甲酸的重复单元的第二树脂。 烤箱在成型和烤箱使用过程中显示出优异的耐起泡,起泡和开裂性能。