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    • 1. 发明授权
    • High strength polymer of hydroquinone poly(iso-terephthalate) containing
residues of p-hydroxybenzoic acid
    • 含有对羟基苯甲酸残基的氢醌聚(对苯二甲酸丙二醇酯)的高强度聚合物
    • US5147967A
    • 1992-09-15
    • US499483
    • 1990-06-04
    • Brian A. SternMarkus MatznerRichard LaytonPaul J. HuspeniPaul D. FrayerJames W. Cleary
    • Brian A. SternMarkus MatznerRichard LaytonPaul J. HuspeniPaul D. FrayerJames W. Cleary
    • C08G63/60C08G63/83C08K7/02C08L67/00
    • C08K7/02C08G63/605C08G63/83C08L67/00
    • This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention".The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree. C., when measured under a load of 264 psi. The polymers may be blended to tailor properties. These polymers and blends may be used advantageously in producing fibers and in electrical equipment, electronic components and other end uses requiring moderately high temperatures.
    • PCT No.PCT / US89 / 04331 Sec。 371日期1990年6月4日第 102(e)1990年6月4日PCT PCT。于1989年10月10日提交。本发明涉及基本上由单元(I),(II),(III)和(IV)组成的新型共聚酯。 这些聚合物和由两者制成的制品的混合物。 单位(I),(II),(III)和(IV)按照“发明描述”中定义的特定比例存在。 立即共聚酯显示熔融状态的取向,良好的纤维等级和高强度。 有利地,本发明的聚合物显示出纯聚合物的粘度和可模塑性的显着改善。 该聚合物具有优异的机械和表面性能,包括起泡性,强度,韧性和气相焊料的能力,并形成强力纤维,同时仍保持高的热变形温度。 它们的熔点在约250℃至约360℃的范围内,并且是可熔融加工的。 有利地,填充有约30重量%的玻璃纤维的这些组合物在264psi的载荷下测量时,显示高达240℃的热变形温度。 聚合物可以混合以定制特性。 这些聚合物和共混物可以有利地用于生产纤维和电气设备,电子部件和需要适度高温的其它最终用途。
    • 4. 发明授权
    • High modulus, high strength melt-processible polyester of hydroquinone
poly (iso-terephthalates) containing residues of a p-hydroxybenzoic acid
    • 含有对羟基苯甲酸残基的氢醌聚(异对苯二甲酸酯)的高模量,高强度可熔融加工的聚酯
    • US5079289A
    • 1992-01-07
    • US499482
    • 1990-06-04
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • C08G63/60C08G63/83C08K7/02C08L67/00
    • C08K7/02C08G63/605C08G63/83C08L67/00
    • This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (V). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention". The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.
    • 本发明涉及基本上由单元(I),(II),(III)和(V)组成的新型共聚酯。 这些聚合物和由两者制成的制品的混合物。 单位(I),(II),(III)和(IV)按照“发明描述”中定义的特定比例存在。 立即共聚酯在熔融态显示取向,良好的纤维等级和高强度; 它们的熔点在约340℃至约400℃的范围内,并且是可熔融加工的。 有利地,填充有约30重量%的玻璃纤维的这些组合物在264psi的载荷下测量时,显示超过240℃至高达约280℃的热变形温度。 当混合时,某些性能得到改善,特别是它们更容易熔化制造,具有降低的起泡倾向和增加的强度。 这些聚合物和共混物可以有利地用于需要高温的烤箱,电子部件,电气设备和其它最终用途。
    • 7. 发明授权
    • N-Methyl pyrrolidone-2 purification
    • N-甲基吡咯烷酮-2纯化
    • US4501902A
    • 1985-02-26
    • US451668
    • 1982-12-21
    • James W. Cleary
    • James W. Cleary
    • C07D207/26
    • C07D207/26
    • A process for removing compounds from aprotic solvents in which aprotic solvent containing at least one acidic compound is contacted with a solid inorganic compound chosen from alkaline earth carbonates, alkaline earth hydroxides, alkaline earth oxides, and alumina in which the contact of the solvent with a solid inorganic compound is by the process of fluidized bed contact, stirred slurry contact or trickle bed contact. Contaminated NMP from poly(phenylene sulfide) production is substantially freed of acidic contaminants by a series of fractionations with a treatment of the kettle liquid of at least one fractionation by the method described above and/or a treatment of the overhead of the last fractionation in series by the method described above.
    • 从非质子溶剂中除去含有至少一种酸性化合物的非质子溶剂的化合物与选自碱土金属碳酸盐,碱土金属氢氧化物,碱土金属氧化物和氧化铝的固体无机化合物接触的方法,其中溶剂与 固体无机化合物是通过流化床接触的过程,搅拌浆液接触或滴流床接触。 来自聚苯硫醚生产的受污染的NMP通过一系列分馏基本上没有酸性污染物,通过上述方法处理至少一个分馏的釜液体和/或最后分馏的塔顶馏出物的处理 通过上述方法进行。
    • 10. 发明授权
    • Heat resistant polymers and blends of hydroquinone poly
(isoterephthalates) containing residues of p-hydroxybenzoic acid
    • 含有对羟基苯甲酸残基的氢醌聚(对苯二甲酸丙二醇酯)的耐热聚合物和共混物
    • US5296542A
    • 1994-03-22
    • US790663
    • 1991-11-08
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • Richard LaytonJames W. ClearyPaul J. HuspeniPaul D. FrayerMarkus Matzner
    • C08G63/60C08G63/83C08K7/02C08L67/00C08F20/00C08G63/00C08G63/02
    • C08K7/02C08G63/605C08G63/83C08L67/00
    • This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1## and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength; they have melting points in the range of from about 340.degree. to about 400.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of over 240.degree. C. up to about 280.degree. C. and higher, when measured under a load of 264 psi. When blended, certain properties are improved, particularly they are easier to melt fabricate, have a decreased tendency to blister and increased strength. These polymers and blends may be used advantageously in ovenware, electronic components, electrical equipment, and other end uses requiring high temperatures.
    • 本发明涉及基本上由单元(I),(II),(III)和(IV)组成的新型共聚酯。 (*化学结构*)(I)(*化学结构*)(II)(*化学结构*)(III)(*化学结构*)(IV)和由两者制成的这些聚合物和制品的共混物。 单位(I),(II),(III)和(IV)按照“发明描述”中定义的指定比例存在。 立即共聚酯在熔融态显示取向,良好的纤维等级和高强度; 它们的熔点在约340℃至约400℃的范围内,并且是可熔融加工的。 有利地,填充有约30重量百分比的玻璃纤维的这些组合物在264psi的负载下测量时显示高于240摄氏度至高达约280摄氏度的热变形温度。 当混合时,某些性能得到改善,特别是它们更容易熔化制造,具有降低的起泡倾向和增加的强度。 这些聚合物和共混物可以有利地用于需要高温的烤箱,电子部件,电气设备和其它最终用途。