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1. 发明申请

WO2010028206A1 LIQUID FUEL COMPOSITIONS BASED ON CATALYTICALLY DEOXYGENATED AND CONDENSATED OXYGENATED CARBONHYDRATES 审中-公开
标题翻译：基于催化去氧化和浓缩氧化碳水化合物的液体燃料组合物
公开(公告)号：WO2010028206A1
公开(公告)日：2010-03-11
申请号：PCT/US2009/055976
申请日：2009-09-04
申请人： SHELL OIL COMPANY , SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , BAULDREAY, Joanna Margaret , BLOMMEL, Paul George , CORTRIGHT, Randy Douglas , PRICE, Richard John
发明人： BAULDREAY, Joanna Margaret , BLOMMEL, Paul George , CORTRIGHT, Randy Douglas , PRICE, Richard John
IPC分类号： C10G3/00 , C10L1/04
CPC分类号： C10L1/04 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/49 , C10G2300/1011 , C10G2300/20 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/305 , C10G2300/307 , C10G2300/308 , C10G2300/805 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , Y02P30/20
摘要： The present invention provides a liquid fuel composition comprising a distillation fraction of a component having at least one C 4+ compound derived from a water-soluble oxygenated hydrocarbon prepared by a method comprising: providing water and a water-soluble oxygenated hydrocarbon comprising a C 1+ O 1+ hydrocarbon in an aqueous liquid phase and/or a vapor phase; providing H 2 ; catalytically reacting in the liquid and/or vapor phase the oxygenated hydrocarbon with the H 2 in the presence of a deoxygenation catalyst at a deoxygenation temperature and deoxygenation pressure to produce an oxygenate comprising a C 1+ O 1-3 hydrocarbon in a reaction stream; and catalytically reacting in the liquid and/or vapor phase the oxygenate in the presence of a condensation catalyst at a condensation temperature and condensation pressure to produce the C 4+ compound, wherein the C 4+ compound comprises a member selected from the group consisting of C 4+ alcohol, C 4+ ketone, C 4+ alkane, C 4+ alkene, C 5+ cycloalkane, C 5+ cycloalkene, aryl, fused aryl, and a mixture thereof; wherein the liquid fuel composition is selected from: a gasoline composition having an initial boiling point in the range of from 15 °C to 70 °C (IP123), a final boiling point of at most 230 °C (IP123), a RON in the range of from 85 to 110 (ASTM D2699) and a MON in the range of from 75 to 100 (ASTM D2700); a diesel fuel composition having an initial boiling point in the range of from 130 °C to 230 °C (IP123), a final boiling point of at most 410 °C (IP123) and a cetane number in the range of from 35 to 120 (ASTM D613); and a kerosene composition having an initial boiling point in the range of from 80 to 150 °C, a final boiling point in the range of from 200 to 320 °C and a viscosity at -20° C in the range of from 0.8 to 10 mm 2 /s (ASTM D445).
摘要翻译：本发明提供了一种液体燃料组合物，其包含具有至少一种衍生自水溶性氧化烃的C4 +化合物的组分的蒸馏馏分，该方法包括：提供水和包含C1 + O1 +烃的水溶性氧化烃在水性液相和/或气相中; 提供H2; 在脱氧催化剂存在下，在脱氧温度和脱氧压下，在液相和/或气相中氧化烃与H 2催化反应，以在反应流中产生包含C1 + O1-3烃的含氧化合物; 并在冷凝温度和冷凝压力下，在缩合催化剂存在下，在液相和/或气相中催化反应生成C4 +化合物，其中C4 +化合物包括选自C4 +醇，C4 + 酮，C4 +烷烃，C4 +烯烃，C5 +环烷烃，C5 +环烯烃，芳基，稠合芳基及其混合物; 其中所述液体燃料组合物选自：起始沸点在15℃至70℃（IP123），最终沸点至多230℃（IP123）的沸点的汽油组合物，范围为85至110（ASTM D2699）和MON为75至100（ASTM D2700）范围内的MON; 初始沸点在130℃至230℃范围内（IP123），最终沸点至多410℃（IP123）和十六烷值在35至120范围内的柴油燃料组合物（ASTM D613）; 初馏点为80-150℃，终沸点为200-320℃，-20℃下的粘度在0.8-10的范围内的煤油组合物 mm2 / s（ASTM D445）。

2. 发明申请

WO2010000760A2 GASOLINE COMPOSITIONS 审中-公开
标题翻译：汽油组合物
公开(公告)号：WO2010000760A2
公开(公告)日：2010-01-07
申请号：PCT/EP2009/058227
申请日：2009-06-30
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CLARKE, Lionel , FELIX-MOORE, Alison , LOUIS, Jurgen Johannes Jacobus , PRICE, Richard John , SMITH, Johanne
发明人： CLARKE, Lionel , FELIX-MOORE, Alison , LOUIS, Jurgen Johannes Jacobus , PRICE, Richard John , SMITH, Johanne
IPC分类号： C10L1/14 , C10L1/182 , C10L1/185 , C10L1/19 , C10L10/10
CPC分类号： C10L1/14 , C10L1/1824 , C10L1/1852 , C10L1/1855 , C10L1/19 , C10L10/10
摘要： The present invention provides a gasoline composition comprising: (i) base gasoline; and (ii) a composition comprising component A and at least one component selected from categories (a) and (b) below: (a) component B, and (b) one component selected from components C, D and E, wherein: component A is an ester or mixture of esters having formula (I): R 1 C(O)-O-R 2 wherein R 1 is selected from a C 1-6 alkyl group and R 2 is selected from a C 1-4 alkyl group and wherein the total number of carbon atoms in R 1 and R 2 is in the range of from 5-9, with the proviso that component A has a boiling point or boiling point range within the temperature range of from 90 to 200 0 C; component B is ethanol; component C is a compound of formula (II) or formula (III). wherein the R 3 , R 4 , R 5 and R 6 groups are independently selected from hydrogen and C 1-6 hydrocarbyl groups, with the proviso that component C has a boiling point or boiling point range of at most 110 0 C; component D is butanol; and component E is an ether of the general formula (IV): R 7 -O-C(Me) 3 wherein R 7 is selected from methyl, ethyl or mixtures thereof, wherein the concentration of the components in the composition is calculated using the following equation (equation I ). wherein : n = 1 is component B, n = 2 is component A, n = 3 is any one of components C, D or E, V fn is the volume fraction of the component n = 1, 2 or 3 in the composition comprising component A and at least one component selected from components B, C, D and E, E70 n is the blending E70 value of the component represented by n, E1OO n is the blending E1OO value of the component represented by n, E70 base is in the range of from 10 to 55 %vol., and ElOO base is in the range of from 35 to 75 %vol..
摘要翻译：本发明提供一种汽油组合物，其包含：（i）汽油; 和（ii）包含组分A和选自以下类别（a）和（b）中的至少一种组分的组合物：（a）组分B和（b）选自组分C，D和E的一种组分，其中：组分 A是具有式（I）的酯或酯的混合物：R 1 C（O）-O-R 2，其中R 1选自C 1-6烷基，R 2选自C 1-4烷基， R1和R2中的碳原子在5-9的范围内，条件是组分A的沸点或沸点范围在90至200℃的温度范围内; 组分B是乙醇; 组分C是式（II）或式（III）的化合物。其中R 3，R 4，R 5和R 6基团独立地选自氢和C 1-6烃基，条件是组分C的沸点或沸点范围至多为110℃; 组分D为丁醇; 并且组分E是通式（IV）的醚：R7-OC（Me）3，其中R7选自甲基，乙基或其混合物，其中组合物中组分的浓度使用下式计算（方程式一世）。其中：n = 1是组分B，n = 2是组分A，n = 3是组分C，D或E中的任一个，V fn是包含组分的组合物中组分n = 1,2或3的体积分数 A和至少一种选自组分B，C，D和E的组分，E70 n是由n表示的组分的共混E70值，E100n是由n表示的组分的共混E100值，E70base在 10至55％体积，ElOObase为35至75体积％。

3. 发明申请

WO2009083466A1 LIQUID FUEL COMPOSITIONS 审中-公开
标题翻译：液体燃料组合物
公开(公告)号：WO2009083466A1
公开(公告)日：2009-07-09
申请号：PCT/EP2008/067809
申请日：2008-12-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CLARK, Richard Hugh , ORLEBAR, Caroline Nicola , PRICE, Richard John , WARDLE, Robert Wilfred Matthews
发明人： CLARK, Richard Hugh , ORLEBAR, Caroline Nicola , PRICE, Richard John , WARDLE, Robert Wilfred Matthews
IPC分类号： C10L1/02
CPC分类号： C10L1/023 , Y02P30/20
摘要： The present invention provides a liquid fuel composition suitable for use in an internal combustion engine comprising: (a) from 50 to 90 %v/v of a C 1 -C 4 alcohol; (b) from 10 to 50 %v/v of a Fischer-Tropsch derived naphtha; and optionally (c) up to 10 %v/v of a C 3 -C 6 hydrocarbon component. The present invention further provides a process for preparing a liquid fuel composition and a method of operating an internal combustion engine.
摘要翻译：本发明提供一种适用于内燃机的液体燃料组合物，其包含：（a）50至90％v / v的C 1 -C 4醇; （b）10至50％v / v的费 - 托衍生的石脑油; 和（c）至多10％v / v的C 3 -C 6烃组分。本发明还提供了制备液体燃料组合物的方法和操作内燃机的方法。

4. 发明申请

WO2009068539A2 GASOLINE COMPOSITIONS 审中-公开
标题翻译：汽油组合物
公开(公告)号：WO2009068539A2
公开(公告)日：2009-06-04
申请号：PCT/EP2008/066172
申请日：2008-11-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CLAYTON, Christopher William , PRICE, Richard John , TAIT, Nigel Peter , TAYLOR, Robert Ian
发明人： CLAYTON, Christopher William , PRICE, Richard John , TAIT, Nigel Peter , TAYLOR, Robert Ian
IPC分类号： C10L1/16 , C10L1/14 , C10L1/06
CPC分类号： C10L1/1616 , C10L1/06 , C10L1/14
摘要： The present invention provides a gasoline composition comprising: (a) a major amount of gasoline; and (b) from 0.1 to 5 wt%, based on the overall gasoline composition, of a base oil having a kinematic viscosity at 100 0C of at least 1 cSt which is derived from the product of a Fischer-Tropsch synthesis process. The present invention further provides a process for preparing a gasoline composition and a method of operating a four-stroke spark-ignition internal combustion engine.
摘要翻译：本发明提供一种汽油组合物，其包含：（a）主要量的汽油; 和（b）基于总体汽油组成的0.1至5重量％的基于100.0℃的运动粘度为至少1cSt的基础油，其衍生自费 - 托合成方法的产物。本发明还提供一种制备汽油组合物的方法和一种操作四冲程火花点火内燃机的方法。

5. 发明申请

WO2006067233A1 FUEL COMPOSITIONS 审中-公开
标题翻译：燃料组合物
公开(公告)号：WO2006067233A1
公开(公告)日：2006-06-29
申请号：PCT/EP2005/057156
申请日：2005-12-23
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , CLAYTON, Christopher William , DAHLSTROM, Mary Ann , LEE, George Robert , PRICE, Richard John , SMITH, Susan Jane , TAIT, Nigel Peter , WALLINGTON, Jessica F
发明人： CLAYTON, Christopher William , DAHLSTROM, Mary Ann , LEE, George Robert , PRICE, Richard John , SMITH, Susan Jane , TAIT, Nigel Peter , WALLINGTON, Jessica F
IPC分类号： C10L1/08 , C10L10/02
CPC分类号： C10L1/08 , C10L10/02
摘要： A fuel composition comprising a major amount of a fuel suitable for use in a compression-ignition engine, which fuel comprises one or more hydrocarbon components boiling within the diesel boiling range, at least one of which hydrocarbon components has been treated with a metal adsorbing or absorbing material in a different physical phase from the hydrocarbon component (s) , preferably to reduce the level of at least one metal, more preferably the level of at least one heavier metal, most preferably the level of zinc, in said at least one hydrocarbon component, for the purpose of reducing the emission of NOx, and optionally particulates, from a compression-ignition engine into the combustion chambers of which said fuel composition is introduced, said treatment including physical separation of the hydrocarbon component from the metal adsorbing or absorbing phase; a process for the preparation of such a composition; and the reduction of the emission of NOx, and optionally particulates, from such an engine.
摘要翻译：一种燃料组合物，其包含主要量的适用于压燃式发动机的燃料，该燃料包括在柴油沸程范围内沸腾的一种或多种烃组分，其中至少一种烃组分已用金属吸附处理在与烃组分不同的物理相中吸收材料，优选在所述至少一种烃中降低至少一种金属的含量，更优选至少一种较重金属的水平，最优选锌的含量组分，为了将来自压燃式发动机的NOx和任选的颗粒物的排放减少到其中引入所述燃料组合物的燃烧室，所述处理包括烃组分与金属吸附或吸收相的物理分离 ; 制备这种组合物的方法; 以及从这种发动机减少NOx和任选的颗粒物的排放。

6. 发明申请

WO2012143568A2 LIQUID FUEL COMPOSITION 审中-公开
标题翻译：液体燃料组合物
公开(公告)号：WO2012143568A2
公开(公告)日：2012-10-26
申请号：PCT/EP2012057409
申请日：2012-04-23
申请人： SHELL INT RESEARCH , PRICE RICHARD JOHN , SCHAVERIEN COLIN JOHN , JANSSEN ANDRIES HENDRIK , HARRIS JOHN WILLIAM , GOSSELINK JOHAN WILLEM , WAY NICOLAAS WILHELMUS JOSEPH
发明人： PRICE RICHARD JOHN , SCHAVERIEN COLIN JOHN , JANSSEN ANDRIES HENDRIK , HARRIS JOHN WILLIAM , GOSSELINK JOHAN WILLEM , WAY NICOLAAS WILHELMUS JOSEPH
IPC分类号： C10G3/00 , C10G1/00 , C10G1/08 , C10L1/04 , C10L1/06
CPC分类号： C10G3/57 , C10G1/08 , C10G3/42 , C10G2300/1011 , C10G2300/1022 , C10G2300/104 , C10G2300/301 , C10G2300/305 , C10G2300/80 , C10G2400/02 , C10L1/023 , C10L1/06 , C10L1/14 , C10L1/16 , C10L1/1616 , C10L1/1691 , C10L1/18 , C10L1/1824 , C10L1/1832 , C10L1/1852 , C10L1/19 , C10L2200/0415 , C10L2200/0423 , C10L2200/0469 , C10L2200/0492 , C10L2270/023 , Y02P30/20
摘要： Liquid fuel compositions comprising a biofuel component, respectively in the range of 0.5 to 20 vol.% of C4-C8-olefins, which C4-C8-olefins contain in the range from equal to or more than 0.02 wt% to equal to less than 100 wt% of bio-carbon, based on the total weight of carbon present in the C4-C8-olefins, and processes for producing such liquid fuel compositions
摘要翻译：液体燃料组合物包含分别在0.5至20体积％的C 4 -C 8烯烃范围内的生物燃料组分，其中C 4 -C 8烯烃含有等于或大于0.02重量％至等于小于基于存在于C 4 -C 8烯烃中的碳的总重量计100重量％的生物碳，以及制备这种液体燃料组合物的方法

7. 发明申请

WO2011061221A3 FUEL FORMULATIONS 审中-公开
标题翻译：燃油配方
公开(公告)号：WO2011061221A3
公开(公告)日：2012-05-03
申请号：PCT/EP2010067674
申请日：2010-11-17
申请人： SHELL INT RESEARCH , PRICE RICHARD JOHN , TAIT NIGEL PETER
发明人： PRICE RICHARD JOHN , TAIT NIGEL PETER
IPC分类号： C10L1/02 , C10L1/18
CPC分类号： C10L1/026 , Y02E50/13
摘要： A compression ignition (CI) (typically diesel) fuel formulation containing (i) a C4 to C8 dialkyl ether (DAE), (ii) a naphtha fuel component and (iii) a low boiling component selected from low boiling hydrocarbons, ethers and mixtures thereof. The formulation may be produced along with a gasoline fuel formulation, by (1) preparing a gasoline fuel formulation in a manner which yields a naphtha fuel component as a byproduct, and (2) blending at least some of the naphtha byproduct with a C4 to C8 DAE and a low boiling component (iii) so as to produce the CI fuel formulation.
摘要翻译：包含（i）C4至C8二烷基醚（DAE），（ii）石脑油燃料组分和（iii）低沸点组分的压缩点火（CI）（通常为柴油）燃料制剂，其选自低沸点烃，醚和混合物它们。该制剂可以与汽油燃料配方一起生产，（1）以产生作为副产物的石脑油燃料组分的方式制备汽油燃料配方，和（2）将至少一些石脑油副产物与C4混合， C8DAE和低沸点组分（iii），以产生CI燃料配方。

8. 发明申请

WO2011161032A1 DIESEL FUEL FORMULATION 审中-公开
标题翻译：柴油燃料配方
公开(公告)号：WO2011161032A1
公开(公告)日：2011-12-29
申请号：PCT/EP2011/060180
申请日：2011-06-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , FELIX-MOORE, Allison , LEE, George Robert , PRICE, Richard John
发明人： FELIX-MOORE, Allison , LEE, George Robert , PRICE, Richard John
IPC分类号： C10L1/185 , C10L1/19
CPC分类号： C10L1/1852 , C10L1/185 , C10L1/19 , C10L2230/14
摘要： The invention provides (a) a diesel fuel formulation containing a triethoxypropane and a palm oil methyl ester (POME), and (b) a diesel fuel supplement containing a premix of a triethoxypropane and a POME. The triethoxypropane may be 1, 2, 3-triethoxypropane or 1,1,3- triethoxypropane. Also provided is a process for preparing the formulation, and its use in an internal combustion engine. A triethoxypropane may be used, in a POME or in a diesel fuel formulation containing a POME, to stabilise a glyceride, in particular a saturated monoglyceride. It may also be used to reduce the cloud point of a POME or of a POME-containing diesel fuel formulation, by an amount greater than conventional theory would have predicted to be possible.
摘要翻译：本发明提供（a）含有三乙氧基丙烷和棕榈油甲酯（POME）的柴油燃料配方，和（b）含有三乙氧基丙烷和POME的预混物的柴油燃料补充剂。三乙氧基丙烷可以是1,2,3-三乙氧基丙烷或1,1,3-三乙氧基丙烷。还提供了制备该制剂的方法及其在内燃机中的应用。可以在POME或含有POME的柴油燃料配方中使用三乙氧基丙烷以稳定甘油酯，特别是饱和甘油单酯。它还可用于减少POME或含POME的柴油燃料配方的浊点，其量大于常规理论预期可能的量。

9. 发明申请

WO2011061221A2 FUEL FORMULATIONS 审中-公开
标题翻译：燃油配方
公开(公告)号：WO2011061221A2
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067674
申请日：2010-11-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , PRICE, Richard John , TAIT, Nigel Peter
发明人： PRICE, Richard John , TAIT, Nigel Peter
IPC分类号： C10L1/02 , C10L1/18
CPC分类号： C10L1/026 , Y02E50/13
摘要： A compression ignition (CI) (typically diesel) fuel formulation containing (i) a C4 to C8 dialkyl ether (DAE), (ii) a naphtha fuel component and (iii) a low boiling component selected from low boiling hydrocarbons, ethers and mixtures thereof. The formulation may be produced along with a gasoline fuel formulation, by (1) preparing a gasoline fuel formulation in a manner which yields a naphtha fuel component as a byproduct, and (2) blending at least some of the naphtha byproduct with a C4 to C8 DAE and a low boiling component (iii) so as to produce the CI fuel formulation.
摘要翻译：包含（i）C4至C8二烷基醚（DAE），（ii）石脑油燃料组分和（iii）低沸点组分的压缩点火（CI）（通常为柴油）燃料制剂，其选自低沸点烃，醚和混合物它们。制剂可以与汽油燃料制剂一起生产，（1）以产生作为副产物的石脑油燃料组分的方式制备汽油燃料制剂，和（2）将至少一些石脑油副产物与C4共混至 C8DAE和低沸点组分（iii），以产生CI燃料制剂。

10. 发明申请

WO2011076736A1 PROCESS FOR PREPARING HYDROCARBONS 审中-公开
标题翻译：制备油料的方法
公开(公告)号：WO2011076736A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/070239
申请日：2010-12-20
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , PRICE, Richard, John
发明人： VAN BUIJTENEN, Jeroen , LANGE, Jean-Paul , PRICE, Richard, John
IPC分类号： C07D307/12 , C07D307/44 , C10L1/18
CPC分类号： C07D307/12 , C07D307/44
摘要： A process for preparing a hydrocarbon or mixture of hydrocarbons comprising the steps of (i) hydrogenating furfural, 5-hydroxymethylfurfural or a mixture of furfural and 5-hydroxymethylfurfural to provide furfuryl alcohol, 2, 5-furandimethanol or a mixture of furfuryl alcohol and 2, 5-furandimethanol; (ii) oligomerizing the alcohol or mixture of alcohols of step (i) in the presence of an acidic catalyst to provide a carbon-carbon coupled oligomer; and (iii) hydrogenating the oligomer of step (ii) is provided. The hydrocarbons are useful as fuel blending components. Processes for controlling the oligomerization of alcohol or mixture of alcohols to optimise the production of oligomers suitable for conversion to hydrocarbons useful as kerosene and diesel components are also provided.
摘要翻译：一种制备碳氢化合物或烃混合物的方法，包括以下步骤：（ⅰ）氢化糠醛，5-羟甲基糠醛或糠醛与5-羟甲基糠醛的混合物，得到糠醇，2,5-呋喃二甲醇或糠醇与2 ，5-呋喃二甲醇; （ii）在酸性催化剂存在下使步骤（ⅰ）的醇或醇的混合物低聚以提供碳 - 碳偶合的低聚物; 和（iii）氢化步骤（ⅱ）的低聚物。烃可用作燃料混合组分。还提供了用于控制醇或醇混合物的低聚的方法以优化适用于转化为用作煤油和柴油组分的烃的低聚物的生产。

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