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    • 2. 发明授权
    • Thermally curable wet-impregnated rovings
    • 热固性湿浸粗纱
    • US4531354A
    • 1985-07-30
    • US578435
    • 1984-02-09
    • Mark R. ZentnerOrvid R. Cutler, Jr.
    • Mark R. ZentnerOrvid R. Cutler, Jr.
    • C08G59/18C08J5/24D02G3/40
    • C08J5/24C08G59/18C08J2363/00Y10T428/2918Y10T428/2933Y10T428/2936Y10T428/2938Y10T428/2964
    • Thermally curable wet-impregnated rovings in which the fibers of the roving are impregnated with liquid polyepoxides lacking polymerizable unsaturation and having dispersed therein a latent heat-activatable epoxy curing catalyst, such as dicyandiamide. The polyepoxide dispersion has a room temperature viscosity of from 2000 to 5000 centipoises and a tack of less than about 6 on a Thwing-Albert inkometer. The rovings are produced without organic solvent using an elevated temperature which is insufficient to activate the curing catalyst and which lowers the viscosity to enable uniform impregnation in the absence of excess impregnant. The wet rovings can be stored without running in a supply package which may be cop wound, and running is also resisted in a void-free wet fiber composite so that the wet composite can be wrapped and then heated to cure the same.
    • 可热固化的湿浸粗纱,其中粗纱纤维用不可聚合不饱和度的液体聚环氧化物浸渍并分散有潜热可激活的环氧固化催化剂如双氰胺。 聚环氧化物分散体在Thwing-Albert墨水计上具有2000-5000厘泊的室温粘度和小于约6的粘性。 使用不足以活化固化催化剂的升高的温度而不使用有机溶剂制备粗纱,并且降低粘度以使得在不存在过量浸渍剂的情况下能够均匀浸渍。 湿粗纱可以在没有运行在可以被卷绕的供应包装中的情况下存储,并且在无空隙的湿纤维复合材料中也可以运行,使得湿复合材料可以被包裹然后被加热以使其固化。
    • 4. 发明授权
    • Single-coated optical fiber
    • 单涂层光纤
    • US4932750A
    • 1990-06-12
    • US448252
    • 1982-12-09
    • Robert E. AnselOrvid R. Cutler, Jr.
    • Robert E. AnselOrvid R. Cutler, Jr.
    • C03C25/10C08F299/06C08G18/10C08G18/67
    • C08G18/671C03C25/106C08F299/065C08G18/10
    • Radiation-curable coating compositions particularly adapted for the single coat coating of optical fibers are disclosed. These comprise (1) from 65% to 85% of a diethylenic-terminated polyurethane, which may contain urea groups, the polyurethane being based on a diisocyanate having an average molecular weight of from 400 to 5000; and (2) from 5% to 25% of an ether of a C.sub.2 -C.sub.4 alkylene glycol monoester of a monoethylenically unsaturated monocarboxylic acid, the ether being selected from the group consisting of ethoxyethyl, dicyclopentenyl, phenyl, and mixtures thereof. Ethoxyethoxyethyl acrylate is particularly preferred. A triacrylate ester, such as trimethylol propane triacrylate, is also desirably present.
    • 公开了特别适用于光纤的单涂层涂层的可辐射固化涂料组合物。 这些包括(1)65%至85%的可含有尿素基团的二亚乙基封端的聚氨酯,所述聚氨酯基于平均分子量为400至5000的二异氰酸酯; 和(2)5%至25%的单烯属不饱和一元羧酸的C 2 -C 4亚烷基二醇单酯的醚,所述醚选自乙氧基乙基,二环戊烯基,苯基及其混合物。 特别优选丙烯酸乙氧基乙氧基乙酯。 还希望存在三丙烯酸酯,如三羟甲基丙烷三丙烯酸酯。