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    • 7. 发明授权
    • Process for heat sealing polyurethane foam
    • 聚氨酯泡沫热封工艺
    • US4302272A
    • 1981-11-24
    • US112046
    • 1980-01-14
    • Barry A. PhillipsKeith G. SpitlerRichard E. Keegan
    • Barry A. PhillipsKeith G. SpitlerRichard E. Keegan
    • B29C65/56C08G18/50C08J5/12B32B31/20
    • C08J5/121B29C44/56C08G18/5009C08J2375/04Y10S521/904Y10S521/914Y10T428/249953
    • The instant invention is directed to a process for heat sealing flexible polyurethane foam, comprising:A. reacting and foaming a polyurethane foam produced by the steps comprising reacting:(I) an organic polyisocyanate;(II) a polyol having a molecular weight of 2,000 to 8,000 comprising the adduct obtained by sequentially reacting:(a) a polyhydroxyl initiator, with a functionality of 2 to 5 and a weight average molecular weight as determined by gel permeation chromatography of from 62 to 200; with(b) 10 to 90%, most preferably 10 to 50%, by weight, based on the total oxide present in (b)+(c)+(d), a first alkylene oxide; and subsequently reacting the product with(c) 10 to 80%, preferably 20 to 50% by weight, based on the total oxide present in (b)+(c)+(d), 4,4,4-trichloro-1,2-epoxybutane and/or epihalohydrin; and subsequently reacting the product with(d) 10 to 60%, most preferably 10 to 40%, by weight, based on the total oxide present in (b)+(c)+(d), a second alkylene oxide.(III) foaming agent; and optionally(IV) catalyst;B. heating a portion of the surface of said flexible polyurethane foam of (A) above its melting or fusion point; andC. cooling said flexible polyurethane foam below its melting or fusion point.
    • 本发明涉及一种用于热封柔性聚氨酯泡沫的方法,其包括:A.使由以下步骤制备的聚氨酯泡沫反应并发泡,所述步骤包括:(I)有机多异氰酸酯; (II)分子量为2,000至8,000的多元醇,其包含通过顺序地使以下反应获得的加合物:(a)通过凝胶渗透色谱法测定的官能度为2-5的多羟基引发剂和通过62测定的重均分子量 至200; 与(b)+(c)+(d)中存在的总氧化物相比,(b)10至90%,最优选10至50重量%的第一烯化氧; (c)+(d)中存在的总氧化物,4,4,4-三氯-1(ⅰ)和(c)+(d))中的总氧化物,随后使产物与(c)10至80重量%,优选20至50重量% ,2-环氧丁烷和/或表卤代醇; 然后使产物与(b)+(c)+(d)中存在的总氧化物,第二烯化氧反应,与(d)10至60重量%,最优选10至40重量%反应。 (三)发泡剂; 和任选的(Ⅳ)催化剂; B.将(A)的所述软质聚氨酯泡沫的表面的一部分加热到其熔点或熔点以上; 和C.将所述软质聚氨酯泡沫体冷却到低于其熔点或熔点。
    • 8. 发明授权
    • Process for making fire-retardant polyurethane foam using crude 4,4,4-trichloro-1,2-epoxybutane
    • 使用原料4,4,4-三氯-1,2-环氧丁烷制备阻燃聚氨酯泡沫的方法
    • US3847844A
    • 1974-11-12
    • US40863773
    • 1973-10-23
    • OLIN CORP
    • POLAK RFUZESI SLAPKIN M
    • C07D303/08C08G18/50C08G65/22C08G22/46C08G22/16
    • C07D303/08C08G18/5009C08G65/223
    • 1. IN PROCESS FOR PREPARING A POLYURETHANE FOAM BY REACTING A POLYETHER POLYOL WITH AN ORGANIC POLYISOCYANATE IN THE PRESENCE OF A REACTION CATALYST AND A FOAMING AGENT, SAID POLYETHER POLYOL COMPRISING THE PRODUCT OF REACTING 4,4,4, - TRICHLORO -1,2- EPOSYBUTANE WITH A MIXTURE OF (1) DEXTROSE AND (2) WATER, A POLYHYDRIC ALIPHATIC ALCOHOL OR A MIXTURE OF WATER AND A POLYHYDRIC ALIPHATIC ALCOHOL, THE IMPROVEMENT WHICH COMPRISES USING SAID EPOXYBUTANE AS A CRUDE MATERIAL HAVING NO MORE THAN ABOUT 5% BY WEIGHT OF VOLATILE COMPONENTS AND CONTAINING FROM ABOUT 15 TO ABOUT ABOUR 42% BY WEIGHT OF IMPURITIES AND CORRESPONDINGLY FROM ABOUT 85 TO ABOUT 58% OF SAID EPOXYBUTANE, SAID CRUDE EPOXYBUTANE BEING PREPARED BY A PROXESS CONSISTING ESSENTIALLY OF (A) REACTING, AT A TEMPERATURE FROM ABOUT 35 TO ABOUT 62* C., 4,4,4-TRICHLORO-2-HALOBUTANOL WITH AN AQUEOUS SOLUTION AF AN ALKALI METAL HYDROXIDE OR AN ALKALINE EARTH METAL HYDROXIDE, SAID AQUEOUS SOLUTION BEING EMPLOYED IN A SUFFICIENT PROPORTION TO PROVIDE AT LEAST A STOICIOMETRIC AMOUNT OF HYDROXIDE WHICH IS REQUIRED TO REACT WITH SAID 4,4,4, - TRICHLORO -2HALOGUTANOL, THEREBY FORMING A TWO-PHASE REACTION PRODUCT MIXTURE, NAMELY, AN AQUEOUS PHASE AND A NON-AQUEOUS PHASE CONTAINING SAID CRUDE EPOXYBUTANE, AND (B) SEPARATING SAID TWO PHASES AND RECOVERING SAID CRUDE EPOXYBUTANE.