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    • 2. 发明申请
    • PROCESS FOR THE PREPARATION OF HYDROXYALKYLATED POLYETHYLENEIMINES
    • 用于生产烷氧基化聚乙烯亚胺
    • WO1997020879A1
    • 1997-06-12
    • PCT/EP1996005250
    • 1996-11-28
    • BASF AKTIENGESELLSCHAFTMOHR, JürgenMAHR, NorbertFUNHOFF, AngelikaLEININGER, HartmutMALLM, HeikeMEIXNER, HubertOPPENLÄNDER, KnutSCHERR, GünterWEISER, Jürgen
    • BASF AKTIENGESELLSCHAFT
    • C08G73/02
    • C08G73/0206C08G73/0233C08G73/024
    • The invention relates to a process for the preparation of hydroxyalkylated polyethyleneimines by hydroxyalkylation of polyethyleneimines in one or two procedural stages to form reaction products which contain 1 to 200 mol alkylene oxide groups per NH group in the polyethyleneimine. In the one-stage process, there are anhydrous polyethyleneimines and 1 to 20 mol %, in relation to the polyethyleneimines, of at least one anhydrous base, or aqueous solutions of said substances are dehydrated and after removing all the water are reacted at temperatures above 135-150 DEG C with at least one alkylene oxide. Alternatively, in the two-stage process, in the first stage polyethyleneimine is reacted at temperatures of from 80 to 100 DEG C with 0.7 to 0.9 mol, in relation to a mol NH group in the polymerisate, of at least one alkylene oxide in an aqueous solution, and in the second stage the reaction product obtained in the first step is reacted in the presence of 1 to 20 mol %, in relation to polyethyleneimine, of an alkaline catalyst in the absence of water at temperatures of from 120 to 150 DEG C with at least one alkylene oxide to form hydroxyalkylated polyethyleneimines which contain 1 to 200 mol of alkylene oxide groups per NH group in the polyethyleneimine. The consequent alkoxylated products are only slightly coloured.
    • 一种用于通过在一个或两个工艺步骤的聚乙烯亚胺烷氧基化制备烷氧基化的聚乙烯亚胺,以形成反应产物,其含有从1至200摩尔每NH基团的氧化烯中的聚乙烯亚胺,得到在单阶段工艺过程的聚乙烯亚胺的无水和1〜20摩尔%,基于聚亚乙基亚胺处理 至少一种无水碱礼物或干燥这些物质的水溶液,并使其在80〜100的温度以大于135的温度下除去所有水的〜150℃与至少一种烯化氧或两阶段工艺过程中的第一过程阶段聚乙烯亚胺后反应 ℃下与0.7基于所述聚合物中的NH基团之一摩尔反应,以0.9摩尔,在水溶液中的至少一种烯化氧,和在所述第二处理阶段中的1存在下,在第一处理阶段中获得〜20摩尔的反应产物 %,基于聚 被允许在120的温度下发生反应的乙烯亚胺,碱催化剂在不存在水至150℃与至少一种烯化氧烷氧基化的聚乙烯亚胺,它含有从1至200摩尔的聚亚乙基亚胺每NH基团的氧化烯的。 以这种方式得到的烷氧基化产品只是稍微着色。
    • 6. 发明申请
    • METHOD FOR CONTINUOUS CROSS-LINKING CONDENSATES AND ADDITIVES
    • 方法冷凝加成产物的持续联网
    • WO1998022524A1
    • 1998-05-28
    • PCT/EP1997006433
    • 1997-11-18
    • BASF AKTIENGESELLSCHAFTDECKER, JürgenMEIXNER, HubertREUTHER, WolfgangSCHERR, GünterSTEUERLE, UlrichWEBERNDÖRFER, Volkmar
    • BASF AKTIENGESELLSCHAFT
    • C08G73/02
    • B01J19/28B01J19/1806B01J19/1887B01J2219/00094B01J2219/00168C08G69/48C08G73/0213C08G73/022C08G73/028C08G73/0286
    • The present invention pertains to a method for continuous cross-linking water-soluble condensates and additives containing amino groups, involving at least bifunctional cross-linking reagents in an aqueous solution or organic solvents in water at a temperature of 20 DEG C to 180 DEG C, resulting in cross-linked reaction products which are water-soluble and characterized, for 20 wt. % of an aqueous solution at a temperature of 20 DEG C, by a viscosity of 50 to 2000 mPas. A mixture of water-soluble condensates and additives containing amino groups and cross-linking reagents, or both reaction partners, are continuously fed into a tubular reactor, inside which they circulate under laminal flow (Reynolds number: 0,005 - 500), then continuously polycondensated in a cylindrical stirrer, whereby the reagents involved in the reaction are let, from one side of a double coaxial cylinder, into the intermediate space between the inner cylinder and the outer cylinder for the purposes of polycondensation. At least one cylinder of the double coaxial cylinder is caused to rotate, with an angular speed relative to the other cylinder, thereby producing Taylor swirls (Taylor number: 20 to 2000) in the reaction mixture. Thereafter, the reaction mixture is isolated at the end of the reactor cycle.
    • 为水溶性的,含氨基的缩合和加成产物的连续交联在水溶液或在20的温度至180℃的水溶性有机溶剂中的至少双官能交联剂处理,以形成交联的,水溶性的反应产物在20米重量%的含水 溶液在20℃下具有50至2000毫帕·秒的粘度,其特征在于,一个单独的水溶性,含氨基的缩合或加成产物与交联剂或两种反应物的混合物:连续地进料至管式反应器,并且与雷诺数的层流 0.005交联至500; 或在Zylinderrührer连续缩聚通过在空间引入内筒和从双气缸的一侧的同轴双圆筒的外圆筒和缩聚在其中间的反应物,所述同轴双圆筒的至少一个气缸在相对于其他气缸的角速度旋转时, 使得发生在反应混合物中泰勒旋涡和是20至2000之间的泰勒数; 和通过反应器之后的反应混合物中分离。
    • 10. 发明申请
    • AMPHIPHILIC GRAFT POLYMERS BASED ON GRAFT BASES CONTAINING N-VINYLCARBOXYLIC ACID UNITS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    • 基于N-乙烯基羧酰胺单元含接枝两亲性接枝聚合物,其制造方法相同,并且它们的用途
    • WO1998025981A1
    • 1998-06-18
    • PCT/EP1997006652
    • 1997-11-28
    • BASF AKTIENGESELLSCHAFTNEGELE, AntonRÜBENACKER, MartinUTECHT, JensMEIXNER, Hubert
    • BASF AKTIENGESELLSCHAFT
    • C08F271/00
    • A61K8/91A61Q5/12A61Q11/00A61Q19/10B01F17/005C04B24/2652C04B2103/0059C04B2103/408C08F8/12C08F271/00C08F271/02C11D3/3788D21H21/02C08F212/08C08F2220/1825
    • The invention concerns amphiphilic graft polymers in which the graft base is a polymer containing at least 5 wt % of units of formula (I) and optionally units of formula (II), R , R being H or C1-C6 alkyl, wherein (a) styrene, C1-C2 alkylstyrene and/or vinyltoluene and optionally (b) other monoethylenically unsaturated monomers which can be copolymerized therewith are grafted onto the graft base in a weight ratio of between 1: 99 and 99: 1, and wherein the group (c) is optionally partially or completely cleaved off the graft polymers, forming amino groups. The invention also concerns processes for preparing and using the amphiphilic graft polymers as consolidating agents for paper, as fixing agents for disruptive water-soluble and water-insoluble agents in paper manufacture, as dispersants for inorganic and organic pigments, dyes, concrete and plant-protecting agents, as detergent additives, as coating material for fertilisers and plant-protecting agents, as floor-maintenance agents, as protective colloids for aqueous polymer dispersions, as thickeners for cosmetic formulations, as conditioners for skin-care agents and as a component of hair-cosmetic preparations and cosmetic preparations for oral hygiene.
    • 两亲性接枝聚合物,其中所述接枝的碱是含有至少5的聚合物重量的式(I)和式任选单元为单位%(II)其中,R <1>,R <2> = H或C1至 -C 6 - 烷基,其中所述接枝碱(A)苯乙烯,C1-C2烷基的苯乙烯和/或乙烯基甲苯和,任选地,(b)中其它单烯属不饱和单体与之共聚的重量比为1:99至99:1,其中所述接枝组 (c)中任选地部分或完全移除,以形成接枝聚合物的氨基,制造和使用的两亲性接枝聚合物作为固化剂用于纸,作为用于生产纸的水溶性和水不溶性的干扰物质的固定剂,作为分散剂用于无机和有机颜料的方法 ,染料,混凝土和作物保护剂,作为洗涤剂添加剂,作为用于D中涂料 ngemittel和杀虫剂,作为地板护理剂,作为用于水性聚合物分散体的保护性胶体,作为化妆品配方中的增稠剂,作为用于护肤组合物的调理剂和化妆品如头发制剂的成分和用于口腔护理化妆品制剂。