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    • 5. 发明申请
    • GRAFT POLYMERS MADE OF ALKYLENE OXIDE UNITS-CONTAINING POLYMERS AND ETHYLENICALLY UNSATURATED COMPOUNDS, PROCESS FOR PREPARING THE SAME AND THEIR USE
    • 亚烷基的接枝聚合物含有聚合物的和烯属不饱和化合物,生产和使用方法
    • WO1996034903A1
    • 1996-11-07
    • PCT/EP1996001663
    • 1996-04-20
    • BASF AKTIENGESELLSCHAFTDENZINGER, WalterRÜBENACKER, MartinNILZ, ClaudiaLORENCAK, PrimozMÖNCH, DietmarSCHUHMACHER, RudolfSTANGE, Andreas
    • BASF AKTIENGESELLSCHAFT
    • C08F283/06
    • D21H21/18C08F8/44C08F283/00C09B67/0085C09D17/00D21H21/10D21H21/16C08F226/02C08F8/12C08F283/06
    • Graft polymers are obtained by radically initiated polymerisation of (A) monomers or monomer mixtures of (a) 10 to 100 % by weight N-vinyl carboxylic acid amides having the formula (I), in which R stands for R and C1-C6 alkyl, (b) 0 to 90 % by weight other monoethylenically unsaturated monomers that may be copolymerised with monomers (a), and (c) 0 to 5 % by weight of at least two ethylenically unsaturated monomers that contain non-conjugated double bonds in their molecule, in the presence of (B) polymers that contain at least 3 units of a C2-C4 alkylene oxide and/or polytetrahydrofuranes, in a weight ratio (A):(B) equal to (95 to 10):(5 to 80). The group (IV) is then optionally separated from the polymerised monomer (a) of the graft polymer, forming at least units having the formula (1). Also disclosed are a process for preparing said graft polymers and their use as dry and wet strength-increasing agents, as fixatives for impurities and fillers, as retention and dewatering agents for paper-making, as promoters during paper, cardboard and paperboard diketen gluing, as pigment dispersants, as starch cationising agents and as auxiliary substances for producing paper tissues.
    • 接枝聚合物,其是由包含(a)10至100重量的式(I)的N-乙烯基羧酰胺的%(A)单体或单体混合物的自由基聚合而得到,其中R <1>,R <2 = H>,和 C1-意味着至C 6烷基,(b)0至90重量的其它%,与所述单体(a)共聚的单烯属不饱和单体和(c)0至5重量%,在所述至少两个烯属不饱和非共轭双键的% 分子,其包括在含有至少3个单位之间的C 2至C 4亚烷基氧化物(B)的聚合物,和/或聚四氢呋喃中(95至10):( 5至80)和的重量比(A):( B)的存在下的单体 任选地随后进行消除从裂解掉接枝聚合物的聚合单体(a)的基团(IV)的至少以形成式(1)的单元。 一种用于移植物和使用该接枝聚合物作为干和湿强度剂,如固定污染物和填料,如在制造的纸,以及在纸张,纸板和卡纸板的双烯酮启动子助留助滤剂剂,作为分散剂用于颜料的制备过程中, 淀粉阳离子化和生产的纸巾艾滋病。
    • 8. 发明申请
    • AQUEOUS ALKYLDIKETENE DISPERSIONS AND THEIR USE AS SIZE FOR PAPER
    • 烷基双烯酮水分散体及其作为纸张使用
    • WO1997017491A1
    • 1997-05-15
    • PCT/EP1996004638
    • 1996-10-25
    • BASF AKTIENGESELLSCHAFTETTL, RolandREUTHER, WolfgangLORENCAK, PrimozBONN, Johann
    • BASF AKTIENGESELLSCHAFT
    • D21H17/72
    • D21H17/72D06M13/13D06M15/11D21H17/09D21H17/10D21H17/17D21H17/23D21H17/29D21H21/16
    • The invention concerns aqueous alkyldiketene dispersions containing an alkyldiketene, cationic starch with an amylopectin content of at least 95 % by wt. and the following anionic dispersants: (a) 0.05 to 1.0 % by wt. of lignin sulphonic acid, condensation products of naphtalene sulphonic acid and formaldehyde, sulphonated polystyrene or salts or mixtures of such polymers and (b) 0.05 to 1.5 % by wt. of sulphuric acid half esters of alcohols with at least 10 C-atoms, mono- or diphosphoric acid half esters of alkoxylated alcohols with at least 10 C-atoms, sulphuric acid half esters of alkoxylated alcohols with at least 10 C-atoms, mono- or diphosphoric acid esters of alkoxylated alcohols with at least 10 C-atoms, C12-C30 alkyl sulphonic acids or salts or mixtures of such compounds. The invention also concerns the use of such alkyldiketene dispersions as bulk size in the manufacture of paper, paperboard and cardboard, as well as in making cellulose fibres water-repellent.
    • 水性分散体烷基双烯酮其中烷基双烯酮,具有至少95重量%的支链淀粉含量和阴离子分散剂(A)0.05〜1.0重量%的木素磺酸,萘磺酸和甲醛,磺化聚苯乙烯的缩合物,盐的阳离子淀粉 并且所述的混合物具有至少10,至少10个碳原子,单 - 或具有至少10个碳原子,烷氧基化醇的硫酸单酯的醇的二酯聚合物和醇(b)的0.05〜1.5重量%硫酸单酯 个碳原子,单 - 或具有至少10个碳原子的烷氧基化醇的二酯,C12至C30包括烷基磺酸,盐和所述化合物的混合物,并在造纸,板的使用水性烷基双烯酮分散体作为发动机尺寸和 纸板防水和纤维素纤维。