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    • 1. 发明申请
    • AGGLOMERATED PARTICLES OF FINELY DIVIDED POLYMERS WHICH ARE WATER-SOLUBLE OR CAPABLE OF SWELLING IN WATER AND CONTAIN AMMONIUM CARBOXYLATE GROUPS
    • 附聚的聚合物微粒,水溶性或水羧酸铵含有聚合物的
    • WO1996010589A1
    • 1996-04-11
    • PCT/EP1995003772
    • 1995-09-23
    • BASF AKTIENGESELLSCHAFTRÜBENACKER, MartinSCHNEIDER, ReinhardNIEBERLE, JürgenHARTMANN, HeinrichDENZINGER, WalterKISTENMACHER, Axel
    • BASF AKTIENGESELLSCHAFT
    • C08F06/22
    • C08F220/04C08F6/18
    • The invention concerns agglomerated particles of finely divided polymers which are water-soluble or capable of swelling in water and contain ammonium carboxlyate groups, and a process for their preparation by azeotropic dehydration of water-in-oil emulsions of the polymers, which are water-soluble or capable of swelling in water and contain ammonium carboxylate groups, in the presence of 0.1 to 40 wt %, relative to the polymers, of polyalkylene glycols, which have an agglomerating effect and are obtained by the addition of C2 to C4 alkylene oxides to alcohols, phenols, amines or carboxylic acids and which contain at least two alkylene oxide units incorporated by polymerization, and additionally from 0.1 to 20 wt %, relative to the polymers, of protective colloids which are obtained by radical copolymerization of C8 to C40 mono-olefins with monoethylenically unsaturated C4 to C6 dicarboxylic acid anhydrides in the manner of a substance polymerization at temperatures from 80 to 300 DEG C to form copolymers having molar masses of 500 to 20,000 g/mol. The invention further concerns the use of the agglomerated polymer particles as thickeners for textile pigment printing inks.
    • 附聚的聚合物颗粒由细碎的,水溶性的或水可铵用于通过共沸除去水包油中的0.1存在下水溶性或水溶胀性的含铵羧酸根的聚合物的乳液的制备它们的聚合物和方法,以40重量%,含羧酸盐的基础上 含有附聚的聚亚烷基二醇,其通过加入C2的可获得至C4与醇,酚,胺或共聚形式的羧酸和所述至少两个氧化烯单元和另外的烯化氧为0.1〜20重量%的聚合物,基于 聚合物保护胶体,其是由C8的自由基共聚至C40单烯烃与单烯类不饱和C4通过本体聚合方法,在从80℃至300℃至C6二羧酸酐,得到具有分子量共聚物从500至20,000克/摩尔获得的, SI 次和使用附聚的聚合物颗粒用作增稠剂纺织颜料的印刷油墨的。
    • 3. 发明申请
    • WATER SOLUBLE POLYMERS AND THEIR USE IN COSMETIC FORMULATIONS
    • 水溶性聚合物及其用途化妆品配方中
    • WO1998004596A1
    • 1998-02-05
    • PCT/EP1997004122
    • 1997-07-29
    • BASF AKTIENGESELLSCHAFTNIESSNER, ManfredRÜBENACKER, MartinNILZ, ClaudiaHÖSSEL, Peter
    • BASF AKTIENGESELLSCHAFT
    • C08F08/00
    • A61Q5/06A61K8/817A61Q5/00A61Q5/02A61Q5/12A61Q11/00A61Q19/00C08F8/00C08F26/02
    • This invention concerns water-soluble polymers which include units of formula (I) and/or (II) as characteristic structural elements, in which R stands for H, alkyl, cycloalkyl, aryl or aralkyl, R and R are defined independently from each other as R or are selected from among substituted alkyl, substituted cycloalkyl, substituted aryl or substituted aralkyl, wherein the substituents are selected from among OH, O-alkyl, O-aryl, SH, S-alkyl, S-aryl, NH2, NH-alkyl, NH-aryl, N(alkyl)2, optionally in protonated form, N(alkyl)3 Z , wherein Z stands for the radical of an inorganic or organic acid, COOH, COO-alkyl, CONH2, CONH-alkyl, CON(alkyl)2, CN and SO3H, and the indexes x each stand independently from each other for a whole number from 1 to 20, and the acid addition salts of these polymers; processes for producing these polymers, as well as their use in cosmetic substances.
    • 本发明涉及一种水溶性聚合物,其包括作为特征的结构元件,所述式(I)和/或(II)其中,R <1>为H,烷基,环烷基,芳基或芳烷基,R <2>和R <3>的单位 彼此独立地为R <1>所定义或从取代的烷基,取代的环烷基,取代的芳基或取代的芳烷基,其中取代基选自OH被选择,O-烷基,O-芳基,SH,S-烷基,S-芳基 ,NH 2,NH-烷基,NH-芳基,N(烷基)2,可能在质子化形式,N(烷基)3 <+>ž< - >,其中Z是基团的无机酸或有机酸,COOH,COO 烷基,CONH 2,CONH-烷基,CON(烷基)2,CN和SO 3 H; 和指数x各自独立地为1至20的整数; 和这些聚合物的酸加成盐; 一种用于这些聚合物的制备方法,以及它们在化妆品产品中使用。
    • 8. 发明申请
    • GRAFT POLYMERS MADE OF ALKYLENE OXIDE UNITS-CONTAINING POLYMERS AND ETHYLENICALLY UNSATURATED COMPOUNDS, PROCESS FOR PREPARING THE SAME AND THEIR USE
    • 亚烷基的接枝聚合物含有聚合物的和烯属不饱和化合物,生产和使用方法
    • WO1996034903A1
    • 1996-11-07
    • PCT/EP1996001663
    • 1996-04-20
    • BASF AKTIENGESELLSCHAFTDENZINGER, WalterRÜBENACKER, MartinNILZ, ClaudiaLORENCAK, PrimozMÖNCH, DietmarSCHUHMACHER, RudolfSTANGE, Andreas
    • BASF AKTIENGESELLSCHAFT
    • C08F283/06
    • D21H21/18C08F8/44C08F283/00C09B67/0085C09D17/00D21H21/10D21H21/16C08F226/02C08F8/12C08F283/06
    • Graft polymers are obtained by radically initiated polymerisation of (A) monomers or monomer mixtures of (a) 10 to 100 % by weight N-vinyl carboxylic acid amides having the formula (I), in which R stands for R and C1-C6 alkyl, (b) 0 to 90 % by weight other monoethylenically unsaturated monomers that may be copolymerised with monomers (a), and (c) 0 to 5 % by weight of at least two ethylenically unsaturated monomers that contain non-conjugated double bonds in their molecule, in the presence of (B) polymers that contain at least 3 units of a C2-C4 alkylene oxide and/or polytetrahydrofuranes, in a weight ratio (A):(B) equal to (95 to 10):(5 to 80). The group (IV) is then optionally separated from the polymerised monomer (a) of the graft polymer, forming at least units having the formula (1). Also disclosed are a process for preparing said graft polymers and their use as dry and wet strength-increasing agents, as fixatives for impurities and fillers, as retention and dewatering agents for paper-making, as promoters during paper, cardboard and paperboard diketen gluing, as pigment dispersants, as starch cationising agents and as auxiliary substances for producing paper tissues.
    • 接枝聚合物,其是由包含(a)10至100重量的式(I)的N-乙烯基羧酰胺的%(A)单体或单体混合物的自由基聚合而得到,其中R <1>,R <2 = H>,和 C1-意味着至C 6烷基,(b)0至90重量的其它%,与所述单体(a)共聚的单烯属不饱和单体和(c)0至5重量%,在所述至少两个烯属不饱和非共轭双键的% 分子,其包括在含有至少3个单位之间的C 2至C 4亚烷基氧化物(B)的聚合物,和/或聚四氢呋喃中(95至10):( 5至80)和的重量比(A):( B)的存在下的单体 任选地随后进行消除从裂解掉接枝聚合物的聚合单体(a)的基团(IV)的至少以形成式(1)的单元。 一种用于移植物和使用该接枝聚合物作为干和湿强度剂,如固定污染物和填料,如在制造的纸,以及在纸张,纸板和卡纸板的双烯酮启动子助留助滤剂剂,作为分散剂用于颜料的制备过程中, 淀粉阳离子化和生产的纸巾艾滋病。
    • 10. 发明申请
    • AMPHIPHILIC GRAFT POLYMERS BASED ON GRAFT BASES CONTAINING N-VINYLCARBOXYLIC ACID UNITS, PROCESS FOR THEIR PREPARATION AND THEIR USE
    • 基于N-乙烯基羧酰胺单元含接枝两亲性接枝聚合物,其制造方法相同,并且它们的用途
    • WO1998025981A1
    • 1998-06-18
    • PCT/EP1997006652
    • 1997-11-28
    • BASF AKTIENGESELLSCHAFTNEGELE, AntonRÜBENACKER, MartinUTECHT, JensMEIXNER, Hubert
    • BASF AKTIENGESELLSCHAFT
    • C08F271/00
    • A61K8/91A61Q5/12A61Q11/00A61Q19/10B01F17/005C04B24/2652C04B2103/0059C04B2103/408C08F8/12C08F271/00C08F271/02C11D3/3788D21H21/02C08F212/08C08F2220/1825
    • The invention concerns amphiphilic graft polymers in which the graft base is a polymer containing at least 5 wt % of units of formula (I) and optionally units of formula (II), R , R being H or C1-C6 alkyl, wherein (a) styrene, C1-C2 alkylstyrene and/or vinyltoluene and optionally (b) other monoethylenically unsaturated monomers which can be copolymerized therewith are grafted onto the graft base in a weight ratio of between 1: 99 and 99: 1, and wherein the group (c) is optionally partially or completely cleaved off the graft polymers, forming amino groups. The invention also concerns processes for preparing and using the amphiphilic graft polymers as consolidating agents for paper, as fixing agents for disruptive water-soluble and water-insoluble agents in paper manufacture, as dispersants for inorganic and organic pigments, dyes, concrete and plant-protecting agents, as detergent additives, as coating material for fertilisers and plant-protecting agents, as floor-maintenance agents, as protective colloids for aqueous polymer dispersions, as thickeners for cosmetic formulations, as conditioners for skin-care agents and as a component of hair-cosmetic preparations and cosmetic preparations for oral hygiene.
    • 两亲性接枝聚合物,其中所述接枝的碱是含有至少5的聚合物重量的式(I)和式任选单元为单位%(II)其中,R <1>,R <2> = H或C1至 -C 6 - 烷基,其中所述接枝碱(A)苯乙烯,C1-C2烷基的苯乙烯和/或乙烯基甲苯和,任选地,(b)中其它单烯属不饱和单体与之共聚的重量比为1:99至99:1,其中所述接枝组 (c)中任选地部分或完全移除,以形成接枝聚合物的氨基,制造和使用的两亲性接枝聚合物作为固化剂用于纸,作为用于生产纸的水溶性和水不溶性的干扰物质的固定剂,作为分散剂用于无机和有机颜料的方法 ,染料,混凝土和作物保护剂,作为洗涤剂添加剂,作为用于D中涂料 ngemittel和杀虫剂,作为地板护理剂,作为用于水性聚合物分散体的保护性胶体,作为化妆品配方中的增稠剂,作为用于护肤组合物的调理剂和化妆品如头发制剂的成分和用于口腔护理化妆品制剂。