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    • 59. 发明授权
    • Replacement metal gate with a conductive metal oxynitride layer
    • 替代金属栅极与导电金属氧氮化物层
    • US08404530B2
    • 2013-03-26
    • US13177692
    • 2011-07-07
    • Takashi AndoVijay Narayanan
    • Takashi AndoVijay Narayanan
    • H01L21/338
    • H01L21/28088H01L21/28176H01L29/4966H01L29/513H01L29/517H01L29/518H01L29/66545H01L29/66628H01L29/66772H01L29/78654
    • A disposable gate structure and a gate spacer are formed on a semiconductor substrate. A disposable gate material portion is removed and a high dielectric constant (high-k) gate dielectric layer and a metal nitride layer are formed in a gate cavity and over a planarization dielectric layer. The exposed surface portion of the metal nitride layer is converted into a metal oxynitride by a surface oxidation process that employs exposure to ozonated water or an oxidant-including solution. A conductive gate fill material is deposited in the gate cavity and planarized to provide a metal gate structure. Oxygen in the metal oxynitride diffuses, during a subsequent anneal process, into a high-k gate dielectric underneath to lower and stabilize the work function of the metal gate without significant change in the effective oxide thickness (EOT) of the high-k gate dielectric.
    • 在半导体衬底上形成一次性栅极结构和栅极间隔物。 去除一次性栅极材料部分,并且在栅极腔中和平坦化介电层上形成高介电常数(高k)栅极电介质层和金属氮化物层。 金属氮化物层的暴露表面部分通过使用暴露于臭氧化水或含氧化剂的溶液的表面氧化工艺转化为金属氮氧化物。 导电栅极填充材料沉积在栅极腔中并被平坦化以提供金属栅极结构。 金属氧氮化物中的氧在随后的退火过程中扩散到下面的高k栅极电介质中,以降低和稳定金属栅极的功函数,而不会在高k栅极电介质的有效氧化物厚度(EOT)上显着变化 。