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    • 52. 发明授权
    • Selective barrier metal polishing method
    • 选择性屏障金属抛光方法
    • US07981316B2
    • 2011-07-19
    • US11975804
    • 2007-10-22
    • Zhendong LiuRoss E. Barker, II
    • Zhendong LiuRoss E. Barker, II
    • C09K13/00C09K13/04C09K13/06H01L21/302
    • C09G1/02C09K3/1409C09K3/1463C23F3/06H01L21/3212H01L21/7684
    • The polishing method uses a polishing solution for removing barrier materials in the presence of interconnect metals and dielectrics. The polishing solution comprises, by weight percent, 0.1 to 10 hydrogen peroxide, at least one pH adjusting agent selected from the group consisting of nitric acid, sulfuric acid, hydrochloric acid and phosphoric acid for adjusting a pH level of the polishing solution to less than 3, at least 0.0025 benzotriazole inhibitor for reducing removal rate of the interconnect metals, 0 to 10 surfactant, 0.01 to 10 colloidal silica having an average particle size of less than 50 nm and balance water and incidental impurities. The polishing solution has a tantalum nitride material to copper selectivity of at least 3 to 1 and a tantalum nitride to TEOS selectivity of at least 3 to 1.
    • 抛光方法使用在互连金属和电介质存在下去除阻挡材料的抛光溶液。 抛光溶液以重量百分比计包含0.1至10种过氧化氢,至少一种选自硝酸,硫酸,盐酸和磷酸的pH调节剂,用于将抛光溶液的pH值调节至小于 3,至少含有0.0025的苯并三唑抑制剂,用于降低互连金属的去除速率,0至10表面活性剂,0.01至10个平均粒度小于50nm的胶体二氧化硅,余量为水和附带杂质。 抛光溶液的氮化钽材料至铜选择性为至少3比1,氮化钽至TEOS选择性为至少3比1。
    • 55. 发明授权
    • Selective barrier metal polishing solution
    • 选择性屏障金属抛光液
    • US07300602B2
    • 2007-11-27
    • US10349792
    • 2003-01-23
    • Zhendong LiuRoss E. Barker, II
    • Zhendong LiuRoss E. Barker, II
    • C09K13/00C09K13/04C09K13/06H01L21/302
    • C09G1/02C09K3/1409C09K3/1463C23F3/06H01L21/3212H01L21/7684
    • The polishing solution is useful for removing barrier materials in the presence of interconnect metals and dielectrics. The polishing solution comprises, by weight percent, 0.1 to 10 hydrogen peroxide, at least one pH adjusting agent selected from the group consisting of nitric acid, sulfuric acid, hydrochloric acid and phosphoric acid for adjusting a pH level of the polishing solution to less than 3, at least 0.0025 benzotriazole inhibitor for reducing removal rate of the interconnect metals, 0 to 10 surfactant, 0.01 to 10 colloidal silica having an average particle size of less than 50 nm and balance water and incidental impurities. The polishing solution has a tantalum nitride material to copper selectivity of at least 3 to 1 and a tantalum nitride to TEOS selectivity of at least 3 to 1.
    • 抛光溶液可用于在存在互连金属和电介质的情况下去除阻挡材料。 抛光溶液以重量百分比计包含0.1至10种过氧化氢,至少一种选自硝酸,硫酸,盐酸和磷酸的pH调节剂,用于将抛光溶液的pH值调节至小于 3,至少含有0.0025的苯并三唑抑制剂,用于降低互连金属的去除速率,0至10表面活性剂,0.01至10个平均粒度小于50nm的胶体二氧化硅,余量为水和附带杂质。 抛光溶液的氮化钽材料至铜选择性为至少3比1,氮化钽至TEOS选择性为至少3比1。
    • 57. 发明申请
    • Corrosion-resistant barrier polishing solution
    • 耐腐蚀屏障抛光液
    • US20060163530A1
    • 2006-07-27
    • US11044769
    • 2005-01-26
    • Zhendong Liu
    • Zhendong Liu
    • C09K13/00C03C15/00H01L21/302
    • H01L21/31053C09G1/02H01L21/3212
    • The polishing solution is useful for removing barrier materials in the presence of at least one nonferrous interconnect metal with limited erosion of dielectrics. The polishing solution contains 0 to 20 weight percent oxidizer, at least 0.001 weight percent inhibitor for reducing removal rate of the nonferrous interconnect metals, 0.0005 to 5 weight percent of at least one nonferrous accelerator selected from the group of a complexing agent for complexing the nonferrous metal and a water-soluble polymer containing an acrylic acid functional group and having a number average molecular weight of 100 to 1,000,000, 0 to 50 weight percent abrasive and balance water at a pH less than 7.
    • 在至少一种具有有限的电介质腐蚀的有色互连金属的存在下,抛光溶液可用于去除阻挡材料。 抛光溶液含有0至20重量%的氧化剂,至少0.001重量%的用于降低有色互连金属去除速率的抑制剂,0.0005至5重量%的至少一种非铁质促进剂,其选自用于络合有色金属的络合剂 金属和含有丙烯酸官能团的水溶性聚合物,其数均分子量为100至1,000,000,0至50重量%的磨料和平衡的水,其pH值小于7。
    • 58. 发明授权
    • Automatic valve assembly for a water cooler reservoir
    • 水冷却器水箱的自动阀组件
    • US07051902B2
    • 2006-05-30
    • US10791769
    • 2004-03-04
    • Dennis RivardZhendong LiuFan Kun
    • Dennis RivardZhendong LiuFan Kun
    • B67D5/62
    • B67D3/0032B67D3/0025B67D3/0038
    • An automatic valve assembly for a water cooler having a reservoir of the type that has its upper end generally sealed to the atmosphere by a water bottle adapter that receives and supports an inverted water bottle. The valve assembly comprises a ventilation passageway that permits air to enter the reservoir, and an actuator arm hingedly mounted within the interior of the water cooler. The actuator arm is operable to move between an open and a closed position in response to changing water levels within the reservoir. When in its open position the actuator arm allows the unrestricted passage of air into the reservoir through the ventilation passageway. When in its closed position the actuator arm restricts the flow of air and fluids through the ventilation passageway.
    • 一种用于水冷却器的自动阀组件,其具有一种储存器,该储存器的上端通过接收和支撑倒水瓶的水瓶适配器大致密封于大气。 阀组件包括允许空气进入储存器的通风通道和铰链地安装在水冷却器内部的致动器臂。 致动器臂可操作以响应于储存器内的水位变化而在打开和关闭位置之间移动。 当处于其打开位置时,致动器臂允许空气通过通风通道不受限制地通入储存器。 当处于其关闭位置时,致动器臂限制空气和流体通过通风通道的流动。