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    • 45. 发明授权
    • Coating compositions containing alkoxysilanes
    • 含有烷氧基硅烷的涂料组合物
    • US06281322B1
    • 2001-08-28
    • US09451539
    • 1999-12-01
    • Stefan GrothReinhard HalpaapMarkus MechtelLutz SchmalstiegPhilip E. Yeske
    • Stefan GrothReinhard HalpaapMarkus MechtelLutz SchmalstiegPhilip E. Yeske
    • C08G7726
    • C08G18/792C08G18/282C08G18/289C08G18/758C09D175/04Y10T428/31551Y10T428/31663
    • The present invention relates to coating compositions containing 40 to 100% by weight, based on resin solids, of an alkoxysilyl-functional polyisocyanate polyurea which is reaction product of A) a polyisocyanate component having an average functionality of 2.5 to 5.5, an NCO content of 11.0 to 20.0% by weight and a monomeric diisocyanate content of less than 10% by weight, and containing at least 50% by weight of a polyisocyanate prepared from 4,4′-diisocyanatodicyclohexyl-methane with B) at least 0.7 equivalents, based on the equivalents of isocyanate groups, of an aminosilane corresponding to formula (I) (RO)nY(3−n)Si—CH2CH2CH2—NHZ  (I),  wherein R represents methyl or ethyl, Y represents methyl, Z represents H, a C1-C12 alkyl or CH2CH2CH2—Si(OR)nY3−n, and n is 1, 2 or 3, and C) optionally other isocyanate-reactive compounds. The present invention also relates the hydrolyzates/condensates that are prepared by adding water or an aqueous solution of a catalyst to the coating compositions according to the invention.
    • 本发明涉及基于树脂固体含有40-100重量%的烷氧基甲硅烷基官能多异氰酸酯聚脲的涂料组合物,其是A)平均官能度为2.5至5.5的多异氰酸酯组分,NCO含量为11.0 至20.0重量%,并且单体二异氰酸酯含量小于10重量%,并且含有至少50重量%的由4,4'-二异氰酸根合二环己基甲烷制备的聚异氰酸酯与B)至少0.7当量,基于当量 的异氰酸酯基,对应于式(I)的氨基硅烷,其中R表示甲基或乙基,Y表示甲基,Z表示H,C1-C12烷基或CH2CH2CH2-Si(OR)nY3-n,n为1,2或3 ,和C)任选其它异氰酸酯反应性化合物。 本发明还涉及通过将水或催化剂的水溶液加入到根据本发明的涂料组合物中制备的水解产物/缩合物。
    • 48. 发明授权
    • Polyisocyanate mixtures which are liquid at greater than 5.degree. C
    • 在大于5℃下为液体的多异氰酸酯混合物
    • US5610260A
    • 1997-03-11
    • US599640
    • 1996-02-09
    • Lutz SchmalstiegJosef PedainHarald Mertes
    • Lutz SchmalstiegJosef PedainHarald Mertes
    • C08G18/76C07C275/60C08G18/78C08G18/79C08G18/83C09D175/00C09D175/04C08G18/10
    • C08G18/7837C07C275/60
    • The present invention relates to polyisocyanate mixtures which are reaction products of 4,4'-diphenylmethane diisocyanate as the isocyanate component, are liquid at greater than 5.degree. C. and have an NCO content of 14.5 to 24% by weight and an allophanate group content (calculated as C.sub.2 HN.sub.2 O.sub.3, molecular weight = 101) of 7.7 to 14.5% by weight; a process for the production of these polyisocyanate mixtures by reacting 4,4'-diphenylmethane diisocyanate as the exclusive isocyanate component with one or more monohydric alcohols having 4 to 16 carbon atoms at an NCO/OH equivalent ratio of 5:1 to 8.5:1 and at a temperature of up to 160.degree. C. to form urethane groups and during or subsequent to urethane formation, converting the urethane groups to allophanate groups in the presence of a catalyst which promotes allophanate formation; and the use of these polyisocyanate mixtures as the polyisocyanate component in two-component polyurethane coating compositions.
    • 本发明涉及作为异氰酸酯成分的4,4'-二苯基甲烷二异氰酸酯的反应产物的多异氰酸酯混合物,其液体在大于5℃,NCO含量为14.5〜24重量%,脲基甲酸酯基含量 (以C 2 H N 2 O 3计算,分子量= 101)为7.7〜14.5重量% 通过使4,4'-二苯基甲烷二异氰酸酯作为异氰酸酯异氰酸酯组分与一种或多种具有4至16个碳原子的一元醇(NCO / OH当量比为5:1至8.5:1)反应生产这些多异氰酸酯混合物的方法 并且在高达160℃的温度下形成氨基甲酸酯基团,并且在氨基甲酸酯形成期间或之后,在促进脲基甲酸酯形成的催化剂的存在下将氨基甲酸酯基团转化为脲基甲酸酯基团; 以及这些多异氰酸酯混合物作为双组分聚氨酯涂料组合物中的多异氰酸酯组分的用途。