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1. 发明授权

US06599635B1 Inorganic coating composition, a method for producing same and the use thereof 失效
标题翻译：无机涂料组合物，其制备方法及其用途
公开(公告)号：US06599635B1
公开(公告)日：2003-07-29
申请号：US10049920
申请日：2002-02-19
申请人： Markus Mechtel , Wolfgang Pütz , Lutz Schmalstieg , Holger Mundstock , Michael Sonntag
发明人： Markus Mechtel , Wolfgang Pütz , Lutz Schmalstieg , Holger Mundstock , Michael Sonntag
IPC分类号： B32B908
CPC分类号： C08G77/58 , C08G77/50 , C09D183/14
摘要： The present invention relates to inorganic coating compositions based on cyclic carbosiloxanes, inorganic polycondensates and &agr;,&ohgr;-functional linear oligosiloxanes, and also to a process for production thereof and to the use thereof and to a non-stick layer so obtained.
摘要翻译：本发明涉及基于环状碳硅氧烷，无机缩聚物和α，ω-官能的线性低聚硅氧烷的无机涂料组合物，以及其制备方法及其用途和如此获得的不粘层。

2. 发明授权

US06288198B1 Hybrid coating compositions 有权
标题翻译：混合涂料组合物
公开(公告)号：US06288198B1
公开(公告)日：2001-09-11
申请号：US09449109
申请日：1999-11-24
申请人： Markus Mechtel , Stefan Groth , Lutz Schmalstieg
发明人： Markus Mechtel , Stefan Groth , Lutz Schmalstieg
IPC分类号： C08G7726
CPC分类号： C08G18/289 , C08G18/837 , Y10T428/31551 , Y10T428/31663
摘要： The present invention relates to hybrid coating compositions containing A) 5 to 80 wt %, based on the weight of A) and B), of an aliphatic polyisocyanate-aminosilane adduct that is the reaction product of A1) a polyisocyanate component having an average NCO functionality of 2.5 to 5.5 and an isocyanate content, based on solids, of 9 to 50 wt % and containing aliphatic polyisocyanates with A2) at least 0.7 amino equivalents, based on the NCO equivalents of A1), of an aminosilane corresponding to formula (I) (RO)nY3−nSi—CH2CH2CH2—NHZ (I), wherein R and Y represent methyl and/or ethyl, Z represents H, C1-C12 alkyl, CH2CH2CH2-Si(OR)2Y3−n and n has a value of 1, 2 or 3 and A3) optionally isocyanate-reactive compounds other than A2), and B) 20 to 95 wt %, based on the weight of A) and B), of at least one hydrolyzable silane corresponding to formula (II) QSi(OX)3 (II), wherein X represents C1 to C4 alkyl and Q represents H, C1 to C8 alkyl, phenyl, methoxy, ethoxy, 3-glycidyloxypropyl, 3-aminopropyl and methacryloxypropyl and/or hydrolyzates/condensates obtained from these silanes. The present invention also relates to the use of these coating compositions for coating various substrates, such as paints, plastics, granite, marble, metal, wood, leather and textiles.
摘要翻译：本发明涉及混合涂料组合物，其包含A）5至80重量％，基于A）和B）的重量A）和B）的脂肪族多异氰酸酯 - 氨基硅烷加合物，其为A1）具有平均NCO官能度的多异氰酸酯组分 2.5至5.5，基于固体的异氰酸酯含量为9至50重量％，并且含有脂族多异氰酸酯与A 2）基于相当于式（I）的式（I）的氨基硅烷，至少0.7氨基当量，基于AlCO 3的NCO当量），其中R和 Y表示甲基和/或乙基，Z表示H，C 1 -C 12烷基，CH 2 CH 2 CH 2 -Si（OR）2 Y 3-n，n值为1,2或3，A 3）任选异氰酸酯反应性化合物，除了A2），和B） 20重量％至95重量％的A）和B）的至少一种对应于式（II）的可水解硅烷，其中X代表C1至C4烷基，Q代表H，C1至C8烷基，苯基，甲氧基，乙氧基， 3-缩水甘油氧基丙基，3-氨基丙基和甲基丙烯酰氧基丙基和/或水解产物/缩合物本发明还涉及这些涂料组合物用于涂覆各种基材如油漆，塑料，花岗岩，大理石，金属，木材，皮革和纺织品的用途。

3. 发明授权

US06844394B2 Polyfunctional carbosiloxanes with linear and cyclic components 失效
标题翻译：具有线性和环状组分的多官能碳硅氧烷
公开(公告)号：US06844394B2
公开(公告)日：2005-01-18
申请号：US10456407
申请日：2003-06-06
申请人： Lutz Schmalstieg , Wolfgang Frank , Markus Mechtel , Matthias Steiner
发明人： Lutz Schmalstieg , Wolfgang Frank , Markus Mechtel , Matthias Steiner
IPC分类号： C07F7/08 , C07F7/18 , C08G77/04 , C08G77/50 , C08L83/02 , C08L83/04 , C08L83/06 , C09D183/04 , C09D183/14
CPC分类号： C08L83/14 , C08G77/38 , C09D183/14 , C08L83/00
摘要： The invention relates to soluble organic-inorganic compositions comprising linear and cyclic hydrosiloxanes, to a novel process for preparing them and to their use as coating materials.
摘要翻译：本发明涉及包含直链和环状水硅氧烷的可溶性有机 - 无机组合物，涉及制备它们的新方法及其作为涂料的用途。

4. 发明授权

US06281322B1 Coating compositions containing alkoxysilanes 失效
标题翻译：含有烷氧基硅烷的涂料组合物
公开(公告)号：US06281322B1
公开(公告)日：2001-08-28
申请号：US09451539
申请日：1999-12-01
申请人： Stefan Groth , Reinhard Halpaap , Markus Mechtel , Lutz Schmalstieg , Philip E. Yeske
发明人： Stefan Groth , Reinhard Halpaap , Markus Mechtel , Lutz Schmalstieg , Philip E. Yeske
IPC分类号： C08G7726
CPC分类号： C08G18/792 , C08G18/282 , C08G18/289 , C08G18/758 , C09D175/04 , Y10T428/31551 , Y10T428/31663
摘要： The present invention relates to coating compositions containing 40 to 100% by weight, based on resin solids, of an alkoxysilyl-functional polyisocyanate polyurea which is reaction product of A) a polyisocyanate component having an average functionality of 2.5 to 5.5, an NCO content of 11.0 to 20.0% by weight and a monomeric diisocyanate content of less than 10% by weight, and containing at least 50% by weight of a polyisocyanate prepared from 4,4′-diisocyanatodicyclohexyl-methane with B) at least 0.7 equivalents, based on the equivalents of isocyanate groups, of an aminosilane corresponding to formula (I) (RO)nY(3−n)Si—CH2CH2CH2—NHZ (I), wherein R represents methyl or ethyl, Y represents methyl, Z represents H, a C1-C12 alkyl or CH2CH2CH2—Si(OR)nY3−n, and n is 1, 2 or 3, and C) optionally other isocyanate-reactive compounds. The present invention also relates the hydrolyzates/condensates that are prepared by adding water or an aqueous solution of a catalyst to the coating compositions according to the invention.
摘要翻译：本发明涉及基于树脂固体含有40-100重量％的烷氧基甲硅烷基官能多异氰酸酯聚脲的涂料组合物，其是A）平均官能度为2.5至5.5的多异氰酸酯组分，NCO含量为11.0 至20.0重量％，并且单体二异氰酸酯含量小于10重量％，并且含有至少50重量％的由4,4'-二异氰酸根合二环己基甲烷制备的聚异氰酸酯与B）至少0.7当量，基于当量的异氰酸酯基，对应于式（I）的氨基硅烷，其中R表示甲基或乙基，Y表示甲基，Z表示H，C1-C12烷基或CH2CH2CH2-Si（OR）nY3-n，n为1,2或3 ，和C）任选其它异氰酸酯反应性化合物。本发明还涉及通过将水或催化剂的水溶液加入到根据本发明的涂料组合物中制备的水解产物/缩合物。

5. 发明授权

US5952445A Water dispersible compounds containing alkoxysilane groups 失效
标题翻译：含有烷氧基硅烷基团的水分散化合物
公开(公告)号：US5952445A
公开(公告)日：1999-09-14
申请号：US57675
申请日：1998-04-09
申请人： Richard R. Roesler , Lutz Schmalstieg
发明人： Richard R. Roesler , Lutz Schmalstieg
IPC分类号： C09K3/10 , C08G18/00 , C08G18/28 , C08G18/38 , C08G18/70 , C08G18/77 , C08G18/79 , C08G18/80 , C08G77/26 , C09D175/04 , C09D183/08 , C09J175/04 , C09J183/08
CPC分类号： C08G18/289 , C08G18/706 , C08G18/809
摘要： The present invention relates to compounds which are substantially free from isocyanate groups, have an alkoxysilane group content (calculated as Si, MW 28) of 1 to 6% by weight, based on the weight of the compounds, and containing sufficient chemically incorporated hydrophilic groups to form a stable dispersion with water, wherein the alkoxysilane groups are incorporated as the reaction products ofa) a polyisocyanate component having a minimum average functionality of 2.4 and containing at least 50% by weight of polyisocyanate adducts andb) compounds containing secondary amino groups and alkoxysilane groups.The present invention also relates to the use of these compounds for the preparation of coatings, sealants and adhesives.
摘要翻译：本发明涉及基本上不含异氰酸酯基团的化合物，其烷基硅烷基含量（以Si计，MW 28计）为1至6重量％，基于化合物的重量，并含有足够的化学引入的亲水基团与水形成稳定的分散体，其中所述烷氧基硅烷基团作为a）具有最小平均官能度为2.4并且含有至少50重量％的多异氰酸酯加合物的多异氰酸酯组分的反应产物并且b）含有仲氨基的化合物和烷氧基硅烷基。本发明还涉及这些化合物在制备涂料，密封剂和粘合剂中的用途。

6. 发明授权

US5859118A Aqueous dispersions of polyurethane/ureas containing alkoxysilane groups and colloidal silicas 失效
标题翻译：含有烷氧基硅烷基团和胶体二氧化硅的聚氨酯/脲的水分散体
公开(公告)号：US5859118A
公开(公告)日：1999-01-12
申请号：US992550
申请日：1997-12-17
申请人： Richard R. Roesler , Lutz Schmalstieg , Lyuba K. Gindin
发明人： Richard R. Roesler , Lutz Schmalstieg , Lyuba K. Gindin
IPC分类号： C08G18/00 , C08G18/08 , C08G18/28 , C08G18/42 , C08K3/36 , C08L75/04 , C09D175/04 , C09J175/04 , C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/283 , C08G18/4238 , C08K3/36
摘要： The present invention relates to aqueous dispersions which containA) 30 to 90% by weight, based on the solids content of A) and B), of polyurethane/ureas containing 0.5 to 6% by weight, based on the weight of the polyurethane/ureas, of alkoxysilane groups (calculated as Si, MW 28) andB) 10 to 70% by weight, based on the solids content of A) and B), of colloidal silica.The present invention relates to coatings prepared from these aqueous dispersions.
摘要翻译：本发明涉及水分散体，其含有A）基于A）和B）的固体含量为30至90重量％的聚氨酯/脲的含量为0.5至6重量％，基于聚氨酯/ 脲，烷氧基硅烷基团（以Si计，MW 28计）和B）10至70重量％，基于胶体二氧化硅的A）和B）的固体含量。本发明涉及由这些水性分散体制备的涂料。

7. 发明授权

US5854338A Aqueous two-component binders and their use in coating and sealing compositions 失效
标题翻译：水性双组分粘合剂及其在涂料和密封组合物中的用途
公开(公告)号：US5854338A
公开(公告)日：1998-12-29
申请号：US57674
申请日：1998-04-09
申请人： Wieland Hovestadt , Lutz Schmalstieg , Christian Wamprecht , Karl-Ludwig Noble
发明人： Wieland Hovestadt , Lutz Schmalstieg , Christian Wamprecht , Karl-Ludwig Noble
IPC分类号： C03C17/30 , C04B41/48 , C08G18/70 , C08G18/72 , C08G18/77 , C08G18/79 , C08G18/80 , C09D175/04 , C09K3/10 , C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00
CPC分类号： C09D175/04 , C03C17/30 , C04B41/4884 , C08G18/706 , C08G18/725 , C08G18/792 , C08G18/809 , C09K3/1021 , C09K2200/0239 , C09K2200/0247 , C09K2200/0464 , C09K2200/0494
摘要： The present invention relates to a binder composition containing a) 30 to 90 wt. % of an aqueous, hydroxy- and/or amino-functional resin dispersion and b) 10 to 70 wt. % of a curing agent containing alkoxysilyl groups and having a free isocyanate group content of 10 to 23 wt. % and a viscosity of 50 to 10000 mPa.multidot.s at 23.degree. C., wherein the molar ratio of the hydroxyl groups of component a) to the isocyanate groups of component b) is 0.5:1 to 2:1. The present invention also relates to the use of these binder compositions in coating and sealing compositions.
摘要翻译：本发明涉及一种粘合剂组合物，其含有a）30〜90重量％羟基和/或氨基官能的树脂分散体的％，和b）10至70wt。含有烷氧基甲硅烷基且游离异氰酸酯基含量为10〜23重量％的固化剂的％％，在23℃下的粘度为50〜10000mPax，其中组分a）的羟基与组分b）的异氰酸酯基团的摩尔比为0.5:1至2:1。本发明还涉及这些粘合剂组合物在涂料和密封组合物中的用途。

8. 发明授权

US5672736A Polyisocyanates containing allophanate groups 失效
标题翻译：含有脲基甲酸酯基的多异氰酸酯
公开(公告)号：US5672736A
公开(公告)日：1997-09-30
申请号：US555200
申请日：1995-11-08
申请人： Martin Brahm , Lutz Schmalstieg , Josef Pedain
发明人： Martin Brahm , Lutz Schmalstieg , Josef Pedain
IPC分类号： C07C273/18 , C07C275/60 , C08G18/78 , C09D175/00 , C07C263/00
CPC分类号： C08G18/7837 , C07C275/60
摘要： The present invention relates to a process for preparing polyisocyanates containing allophanate groups by reacting compounds a), which i) contain urethane groups, but which are substantially free of hydroxyl groups and isocyanate groups, ii) have an average of at least two urethane groups per molecule, iii) are prepared by reacting organic isocyanates a1) with organic hydroxyl compounds a2) and iv) have an average molecular weight of at most 2,500, with excess quantities, based on the urethane groups, of distillable organic polyisocyanates b) to form polyisocyanates containing allophanate groups and subsequently removing by distillation the unreacted excess of component b) to a residual content of less than 0.5 wt. %, provided that polyisocyanates a1) and polyisocyanates b) are different. The present invention also relates to the products obtained from this process and to their use as binders or binder components in coating compositions.
摘要翻译：本发明涉及通过使具有氨基甲酸酯基但不含羟基和异氰酸酯基的化合物a）反应制备含有脲基甲酸酯基团的多异氰酸酯的方法，ii）基本上不含羟基和异氰酸酯基团，ii）平均具有至少两个氨基甲酸酯基团分子，iii）通过使有机异氰酸酯a1）与有机羟基化合物a2）和iv）具有至多2500的平均分子量，基于氨基甲酸酯基团的过量的可蒸馏有机多异氰酸酯b）来制备，以形成多异氰酸酯含有脲基甲酸酯基团，随后通过蒸馏将未反应的组分b）过量除去至少于0.5wt。％，条件是多异氰酸酯a1）和多异氰酸酯b）不同。本发明还涉及从该方法获得的产品及其作为涂料组合物中的粘合剂或粘合剂组分的用途。

9. 发明授权

US5563207A Water-dispersible polyisocyanate compositions 失效
标题翻译：水分散性多异氰酸酯组合物
公开(公告)号：US5563207A
公开(公告)日：1996-10-08
申请号：US428753
申请日：1995-04-25
申请人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
发明人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/28 , C08G18/48 , C08G18/70 , C08G18/72 , C08G18/80 , C09D5/00 , C09D175/00 , C09D175/04 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/706 , C08G18/283 , C08G18/8064
摘要： Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.
摘要翻译：基于脂肪族和芳族二异氰酸酯并且基于固体的NCO含量为6〜21重量％，结合的TDI单元与加入的HDI单元的重量比为6:1至0.1:1的水分散性多异氰酸酯组合物和排列在末端聚醚链内的环氧乙烷单元的含量为5-40重量％; 通过使多异氰酸酯组分与NCO / OH当量比为2:1至120:1的含有环氧乙烷单元的单价聚醚醇反应来制备这些多异氰酸酯组合物的方法; 以及含有这些多异氰酸酯组合物和多羟基化合物作为粘合剂的水性涂料组合物。

10. 发明授权

US5459214A Olefinically unsaturated isocyanates 失效
标题翻译：烯属不饱和异氰酸酯
公开(公告)号：US5459214A
公开(公告)日：1995-10-17
申请号：US195726
申请日：1994-02-11
申请人： Martin Brahm , Eberhard Arning , Lutz Schmalstieg , Bernd Riberi
发明人： Martin Brahm , Eberhard Arning , Lutz Schmalstieg , Bernd Riberi
IPC分类号： C07C269/02 , C07C271/20 , C07C271/24 , C08G18/28 , C08G18/80 , C08G18/81 , C09D175/14 , C09D175/16 , C08F26/02
CPC分类号： C07C271/20 , C07C271/24 , C08G18/2825 , C08G18/8064 , C07C2101/14
摘要： The present invention relates to olefinically unsaturated, urethane group-containing isocyanates which are prepared by reacting at an NCO/OH equivalent ratio of 4 to 40a) an isocyanate component substantially containing urethane group-free cycloaliphatic diisocyanates withb) an unsaturated alcohol component substantially containing monohydric olefinically unsaturated alcoholsand subsequently removing distillable unreacted isocyanates by distillation. The present invention also relates to a process for the preparation of these isocyanates and to their use as a binder component in one-component, coating compositions which may be cured at room temperature.
摘要翻译：本发明涉及通过使NCO / OH当量比为4至40反应制备的烯属不饱和的含氨基甲酸酯基的异氰酸酯a）基本上含有不含氨基甲酸酯基的脂环族二异氰酸酯的异氰酸酯组分和b）不饱和醇组分基本上含有一元烯属不饱和醇，然后通过蒸馏除去可蒸馏的未反应的异氰酸酯。本发明还涉及一种制备这些异氰酸酯的方法以及它们在单组分涂料组合物中作为粘合剂组分的用途，其可以在室温下固化。

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