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1. 发明授权

US5723564A Process for preparing isocyanurate group-containing polyisocyanates and their use in two-component coating compositions 失效
标题翻译：制备含异氰脲酸酯基的多异氰酸酯的方法及其在双组分涂料组合物中的用途
公开(公告)号：US5723564A
公开(公告)日：1998-03-03
申请号：US667568
申请日：1996-06-21
申请人： Lutz Schmalstieg , Carl-Gerd Dieris , Wolfgang Kremer , Bernd Riberi
发明人： Lutz Schmalstieg , Carl-Gerd Dieris , Wolfgang Kremer , Bernd Riberi
IPC分类号： C08G18/02 , C07D251/34 , C08G18/79 , C08G18/80 , C09D175/00 , C09D175/04
CPC分类号： C07D251/34 , C08G18/794 , C08G18/8064
摘要： A process for the preparation of isocyanurate group-containing polyisocyanates in solvents which are inert towards isocyanate groups by reacting 0.2 to 1.5% of the isocyanate groups of diisocyanatotoluene with an aliphatic monohydric alcohol having 6 to 22 carbon atoms and subsequently trimerizing at least a portion of the isocyanate groups of the urethanized diisocyanates in the form of 40 to 70 wt. % solutions in lacquer solvents which are inert towards isocyanate groups, and the use of these polyisocyanates in two-component polyurethane coating compositions.
摘要翻译：通过使0.2〜1.5％的二异氰酸基甲苯的异氰酸酯基与具有6〜22个碳原子的脂肪族一元醇反应，然后将至少一部分的三聚化来制备含异氰脲酸酯基的多异氰酸酯在对异氰酸酯基团呈惰性的溶剂中的方法氨基甲酸酯化二异氰酸酯的异氰酸酯基团为40至70wt。在对异氰酸酯基团是惰性的漆溶剂中的％溶液，以及这些多异氰酸酯在双组分聚氨酯涂料组合物中的用途。

2. 发明授权

US5468804A Water-soluble or water-dispersible polyisocyanate composition, a process for its preparation and its use in coating compositions 失效
标题翻译：水溶性或水分散性多异氰酸酯组合物，其制备方法及其在涂料组合物中的应用
公开(公告)号：US5468804A
公开(公告)日：1995-11-21
申请号：US306335
申请日：1994-09-15
申请人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
发明人： Lutz Schmalstieg , Wolfgang Kremer , Martin Brahm , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/10 , C08G18/28 , C08G18/32 , C08G18/48 , C08G18/62 , C08G18/70 , C08G18/76 , C08G18/80 , C09D175/00 , C09D175/04 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/283 , C08G18/706 , C08G18/8035 , C08G18/8064 , Y10T428/31551
摘要： A water-dispersible polyisocyanate composition obtained by the partial urethanization of the isocyanate groups of 2,4- and/or 2,6-diisocyanatotoluene with monohydric and polyhydric alcohols, a process for its production, its use as the binder for an aqueous two-component coating composition in combination with a water-soluble or water-dispersible polyhydroxyl component and coatings for water-resistant sheet-form substrates prepared from this coating composition.
摘要翻译：通过2,4-和/或2,6-二异氰酸基甲苯与一元醇和多元醇的异氰酸酯基团的部分氨基甲酸酯化获得的水分散性多异氰酸酯组合物，其生产方法，其用作二级和多元醇的粘合剂，组合涂料组合物与水溶性或水分散性多羟基组分的组合以及由该涂料组合物制备的用于防水片状基材的涂料。

3. 发明授权

US5563207A Water-dispersible polyisocyanate compositions 失效
标题翻译：水分散性多异氰酸酯组合物
公开(公告)号：US5563207A
公开(公告)日：1996-10-08
申请号：US428753
申请日：1995-04-25
申请人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
发明人： Martin Brahm , Wolfgang Kremer , Lutz Schmalstieg , Joachim Probst , Werner Kubitza
IPC分类号： C08G18/08 , C08G18/00 , C08G18/10 , C08G18/28 , C08G18/48 , C08G18/70 , C08G18/72 , C08G18/80 , C09D5/00 , C09D175/00 , C09D175/04 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/706 , C08G18/283 , C08G18/8064
摘要： Water-dispersible polyisocyanate compositions based on aliphatic and aromatic diisocyanates and having an NCO content, based on solids, of 6 to 21% by weight, a weight ratio of incorporated TDI units to incorporated HDI units of 6:1 to 0.1:1 and a content of ethylene oxide units, arranged within terminal polyether chains, of 5 to 40% by weight; a method for the preparation of these polyisocyanate compositions by reacting a polyisocyanate component with monovalent polyether alcohols containing ethylene oxide units at an NCO/OH equivalent ratio of 2:1 to 120:1; and aqueous coating compositions containing these polyisocyanate compositions and polyhydroxyl compounds as the binder.
摘要翻译：基于脂肪族和芳族二异氰酸酯并且基于固体的NCO含量为6〜21重量％，结合的TDI单元与加入的HDI单元的重量比为6:1至0.1:1的水分散性多异氰酸酯组合物和排列在末端聚醚链内的环氧乙烷单元的含量为5-40重量％; 通过使多异氰酸酯组分与NCO / OH当量比为2:1至120:1的含有环氧乙烷单元的单价聚醚醇反应来制备这些多异氰酸酯组合物的方法; 以及含有这些多异氰酸酯组合物和多羟基化合物作为粘合剂的水性涂料组合物。

4. 发明授权

US4921883A Unsaturated polyester resins, a process for their preparation and compositions containing these polyester resins 失效
标题翻译：不饱和聚酯树脂，其制备方法和含有这些聚酯树脂的组合物
公开(公告)号：US4921883A
公开(公告)日：1990-05-01
申请号：US169967
申请日：1988-03-18
申请人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
发明人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
IPC分类号： C08F2/50 , C08F299/04 , C08G63/553 , C09D167/06
CPC分类号： C09D167/06 , C08F299/0435 , C08G63/553
摘要： Unsaturated polyester resins having an acid number of from 0 to 50 and a hydroxyl number of from 10 to 150 which are composed of 0.6 to 0.8 moles of groups derived from maleic and/or fumaric acid, 0.2 to 0.4 moles of groups derived from norbornene dicarboxylic acid, 0.6 to 0.8 moles of groups derived from ethylene and/or propylene glycol, 0.2 to 0.4 moles of groups derived from diethylene glycol, 0.1 to 0.2 moles of groups derived from benzylalcohol and/or benzoic acid and 0 to 0.2 moles of groups derived from other alcohols, a process for their manufacture by a solvent-free or azeotropic esterification of said monomers and compositions which can be cured under influence of UV radiation, containing from 40 to 80 parts by weight of said polyester resins, from 20 to 60 parts by weight of styrene from 0.5 to 5 parts by weight of at least one photoinitiator and optionally known auxiliary agents and additives.
摘要翻译：由0.6至0.8摩尔衍生自马来酸和/或富马酸的基团组成的酸值为0至50且羟基数为10至150的不饱和聚酯树脂，衍生自降冰片烯二羧酸的基团为0.2至0.4摩尔酸，0.6至0.8摩尔衍生自乙烯和/或丙二醇的基团，0.2至0.4摩尔衍生自二甘醇的基团，0.1至0.2摩尔衍生自苄醇和/或苯甲酸的基团和0至0.2摩尔衍生的基团来自其它醇的方法，其通过所述单体的无溶剂或共沸酯化制备的方法，所述单体和组合物可以在UV辐射的影响下固化，所述组合物含有40至80重量份的所述聚酯树脂，20至60重量份的苯乙烯0.5至5重量份的至少一种光引发剂和任选地已知的助剂和添加剂。

5. 发明授权

US4404298A Aqueous dispersions based on cellulose nitrates, polyester of alkyd resins and aminoplast resins, processes for the production thereof and the use thereof for the production of coatings 失效
标题翻译：基于硝酸纤维素的水性分散体，醇酸树脂和氨基塑料树脂的聚酯，其生产方法及其用于生产涂料的用途
公开(公告)号：US4404298A
公开(公告)日：1983-09-13
申请号：US337020
申请日：1982-01-04
申请人： Hans-Joachim Traenckner , Wolfgang Kremer
发明人： Hans-Joachim Traenckner , Wolfgang Kremer
IPC分类号： C09D101/18 , C09D167/00 , C08L1/18
CPC分类号： C09D101/18 , C09D167/00 , Y10T428/31957
摘要： Nitrocellulose/polyester or alkyd resin dispersions having a high pot life and low requirement for coalescing agent may be prepared with the aid of water-insoluble aminoplast resins if care is taken to ensure that a mixture of these components is present within the particles of the disperse phase.
摘要翻译：如果需要注意确保这些组分的混合物存在于分散体的颗粒内，则可以借助水不溶性氨基塑料树脂制备具有高适用期和聚结剂要求低的硝化纤维素/聚酯或醇酸树脂分散体相。

6. 发明授权

US06559225B1 Polyurethane dispersions 有权
标题翻译：聚氨酯分散体
公开(公告)号：US06559225B1
公开(公告)日：2003-05-06
申请号：US10030029
申请日：2002-02-27
申请人： Christoph Irle , Wolfgang Kremer , Günther Ruf , Rolf Roschu
发明人： Christoph Irle , Wolfgang Kremer , Günther Ruf , Rolf Roschu
IPC分类号： C08G1836
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/348 , C08G18/4018 , C08G18/4288 , C08G18/4854 , Y10T428/31551 , C08G18/3231
摘要： This invention relates to binders for aqueous coatings, to a process for the production thereof and to the use thereof for lacquers and coatings.
摘要翻译：本发明涉及用于水性涂料的粘合剂，其制备方法及其用于涂漆和涂料的用途。

7. 发明授权

US06197874B1 Polyurethane-polyacrylate hybrid dispersions containing allophanate groups 失效
标题翻译：含有脲基甲酸酯基团的聚氨酯 - 聚丙烯酸酯混合分散体
公开(公告)号：US06197874B1
公开(公告)日：2001-03-06
申请号：US09234866
申请日：1999-01-21
申请人： Christoph Irle , Harald Blum , Martin Brahm , Wolfgang Kremer , Rolf Roschu , Erhard Lühmann , Josef Pedain , Christian Wamprecht
发明人： Christoph Irle , Harald Blum , Martin Brahm , Wolfgang Kremer , Rolf Roschu , Erhard Lühmann , Josef Pedain , Christian Wamprecht
IPC分类号： C08J300
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/7837 , C09D175/04 , C08G18/3228 , C08L33/00
摘要： The present invention relates to polyurethane-polyacrylate hybrid dispersions comprising A) 20 to 99% by weight, based on resin solids, of a polyurethane wherein i) the polyurethane is rendered hydrophilic by ionic and/or nonionic hydrophilic groups and ii) the polyisocyanate component used to prepare the polyurethane contains an aliphatic or cycloaliphatic polyisocyanate containing allophanate groups, and B) 1 to 80% by weight, based on resin solids) of a polyacrylate polymer, wherein the sum of components A and B is 100%, based on the total weight of A) and B). The present invention also relates to the use of these hybrid dispersions for coating substrates, in particular wood.
摘要翻译：本发明涉及聚氨酯 - 聚丙烯酸酯混合分散体，其包含A）基于树脂固体为20至99重量％的聚氨酯，其中i）通过离子和/或非离子亲水基团使聚氨酯变得亲水，和ii）所使用的多异氰酸酯组分为了制备聚氨酯，含有含有脲基甲酸酯基团的脂肪族或脂环族多异氰酸酯，B）1〜80重量％，基于树脂固体）聚丙烯酸酯聚合物，其中组分A和B的总和为100重量％，基于总重量的A）和B）。本发明还涉及这些混合分散体用于涂覆基材，特别是木材的用途。

8. 发明授权

US5142015A Unsaturated urethanized polyester resins, a process for their production and their use for the production of coatings 失效
标题翻译：不饱和聚酯聚酯树脂，其生产工艺及其用于生产涂料的工艺
公开(公告)号：US5142015A
公开(公告)日：1992-08-25
申请号：US600557
申请日：1990-10-19
申请人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
发明人： Jurgen Meixner , Wolfgang Kremer , Manfred Muller
IPC分类号： C08F299/06 , C08F290/00 , C08G18/42 , C08G18/67 , C08G18/68 , C08G63/52 , C08G63/91 , C09D167/06 , C09D175/00 , C09D175/04 , C09D175/06 , C09D175/14
CPC分类号： C09D175/14 , C08G18/6715 , C08G18/686
摘要： The present invention relates to a process for the production of olefinically unsaturated polyester resins containing at least 0.025 moles of urethane groups per 100 g of resin by reactingA) olefinically unsaturated polyester resins which contain alcoholic hydroxyl groups, have a molecular weight (M.sub.n) of 800 to 10,000, an acid vlaue of 0 to 50 and a hydroxyl number of 30 to 120, and are based on the reaction product ofI) a dicarboxylic acid component containing a) 90 to 100 mole percent of maleic acid, maleic anhydride and/or fumaric acid and b) 0 to 10 mole percent of another carboxylic acid andII) 1.1 to 1.5 moles, based on one mole of the dicarboxylic acid component, of a polyol component containing c) 0.1 to 0.5 moles of at least one saturated cycloaliphatic diol having 6 to 18 carbon atoms, d) 0.5 to 0.9 moles of at least one saturated aliphatic diol having 2 to 6 carbon atoms and e) 0.1 to 0.5 moles of at least one .beta.,.gamma.-ethylenically unsaturated ether alcohol having 5 to 14 carbon atoms, withB) an organic polyisocyanate baased on a member selected from the group of biuret-, isocyanurate-, uretdione- and urethane-modified polyisocyanates having 8 to 30% by weight of (cyclo)-aliphatically bound isocyanate groups in an amount sufficient to provide a ratio of isocyanate groups of component B) to hydroxyl groups of component A) of 0.1:1 to 1:1.The present invention also relates to the olefinically unsaturated polyester resins containing urethane groups obtained by this process and to coatings prepared from coating compositions based on these olefinically unsaturated polyester resins and cured by free radical polymerization.
摘要翻译：本发明涉及一种通过使A）含有醇羟基的烯属不饱和聚酯树脂，其分子量（Mn）为 800至10,000，酸值为0至50，羟值为30至120，并且基于I）的反应产物，含有a）90至100摩尔％的马来酸，马来酸酐和/ 或富马酸，和b）0至10摩尔％的另一种羧酸和II）基于1摩尔二羧酸组分的1.1至1.5摩尔多元醇组分，其含有c）0.1至0.5摩尔的至少一种饱和脂环族具有6至18个碳原子的二醇，d）0.5至0.9摩尔的至少一种具有2-6个碳原子的饱和脂肪族二醇和e）0.1-0.5摩尔至少一种具有5个碳原子的β，γ-烯属不饱和醚醇至少14个碳原子，其中B）有机多异氰酸酯位于选自缩二脲，异氰脲酸酯，脲二酮和氨基甲酸酯改性的多异氰酸酯基团中的组分，其具有8至30重量％的（环） - 阴离子结合的异氰酸酯基团足以提供组分B）的异氰酸酯基团与组分A）的羟基的比例为0.1:1至1:1的量。本发明还涉及通过该方法获得的含有氨基甲酸酯基团的烯属不饱和聚酯树脂和由基于这些烯属不饱和聚酯树脂的涂料组合物制备并通过自由基聚合固化的涂料。

9. 发明授权

US06541536B2 Polyurethane dispersions 失效
标题翻译：聚氨酯分散体
公开(公告)号：US06541536B2
公开(公告)日：2003-04-01
申请号：US09818200
申请日：2001-03-27
申请人： Jan Weikard , Erhard Lühmann , Wolfgang Kremer , Jürgen Meixner
发明人： Jan Weikard , Erhard Lühmann , Wolfgang Kremer , Jürgen Meixner
IPC分类号： C08G1864
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/34 , C08G18/68 , C08K5/101 , Y10T428/31551 , Y10T428/31591 , C08L75/14
摘要： The present invention relates to radiation curable aqueous polyurethane dispersions containing 0.05 to 20 wt. %, based on the weight of the non-aqueous constituents of the aqueous polyurethane dispersions, of 2,2-dimethyl-3-hydroxypropionic acid-(2,2-dimethyl-3-hydroxypropyl ester), (HPSNPG, calculated as MW 204.3). The invention also relates to substrates coated with these polyurethane dispersions, in particular to coated wood substrates with good grain enhancing properties.
摘要翻译：本发明涉及含有0.05-20重量％的可辐射固化水性聚氨酯分散体。以2,2-二甲基-3-羟基丙酸 - （2,2-二甲基-3-羟丙基酯）为原料的（HPSNPG，按MW204.3计算）的水性聚氨酯分散体的非水成分的重量％）。本发明还涉及涂覆有这些聚氨酯分散体的基材，特别是具有良好的增强颗粒性能的涂布的木质基材。

10. 发明授权

US06521702B1 Aqueous polyurethane emulsions 失效
标题翻译：水性聚氨酯乳液
公开(公告)号：US06521702B1
公开(公告)日：2003-02-18
申请号：US09716741
申请日：2000-11-20
申请人： Jan Weikard , Erhard Lühmann , Dieter Erdmann , Wolfgang Fischer , Wolfgang Kremer
发明人： Jan Weikard , Erhard Lühmann , Dieter Erdmann , Wolfgang Fischer , Wolfgang Kremer
IPC分类号： C08J303
CPC分类号： C08G18/673 , C08G18/0823 , C08G18/6725 , C08G18/68 , C09D175/16 , Y10T428/31551 , Y10T428/31591
摘要： The present invention relates to a radiation-curable, aqueous polyurethane emulsion which is prepared by I) reacting A) 40 to 90 wt. % of an isocyanate-reactive component that contains a polyester acrylate containing hydroxyl groups and having an OH content of 40 to 200 mg KOH/g and optionally other isocyanate-reactive compounds other than B) and B) 0.5 to 20 wt. % of one or more monofunctional and/or difunctional isocyanate-reactive compounds that contain cationic or anionic groups, potential cationic or anionic or hydrophilic ether groups, with C) 10 to 50 wt. % of one or more diisocyanates and/or polyisocyanates, II) optionally converting any potential cationic or anionic groups into cationic or anionic groups by salt formation and III) forming a dispersion of the reaction product of A), B) and C) in water and reacting it with D) 0.1 to 10 wt. % of one or more diamines and/or polyamines, wherein the wt. % percentages of (A) to (D) add up to 100%, and the equivalent ratio of the sum of the isocyanate-reactive groups in (A) and (B) to the isocyanate groups in (C) is 0.8:1 to 1.25:1 and the reaction of components (A) and (B) with (C) is carried out such that 65 to 95% of the isocyanate groups in (C) react with the isocyanate-reactive groups of (A) and (B). The present invention also relates to a process of making these polyurethane emulsions and to substrates coated with the polyurethane emulsions.
摘要翻译：本发明涉及可辐射固化的水性聚氨酯乳液，其通过以下方法制备：I）将40至90重量％％的异氰酸酯反应性组分，其含有含羟基并且OH含量为40至200mg KOH / g的聚酯丙烯酸酯和任选的除B）和B）外的其它异氰酸酯反应性化合物，和B）0.5至20wt。含有阳离子或阴离子基团的潜在阳离子或阴离子或亲水醚基团的一种或多种单官能和/或二官能异氰酸酯反应性化合物的％，C）10至50wt。％的一种或多种二异氰酸酯和/或多异氰酸酯，II）任选地通过盐形成将任何潜在的阳离子或阴离子基团转化为阳离子或阴离子基团; III）在水中形成A），B）和C）的反应产物的分散体，以及与D）反应0.1〜10重量％％的一种或多种二胺和/或多胺，其中wt。（A）至（D）的百分比百分比加起来为100％，（A）和（B）中异氰酸酯反应性基团与（C）中异氰酸酯基团之和的当量比为0.8:1至（A）和（B）与（C）的反应进行，使得（C）中的异氰酸酯基中的65〜95％与（A）和（B）的异氰酸酯反应性基团反应）。本发明还涉及制备这些聚氨酯乳液和用聚氨酯乳液涂覆的基材的方法。

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