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41. 发明授权

US06060042A Use of cholesteric, liquid-crystalline compositions as UV filters in cosmetic and pharmaceutical preparations 失效
标题翻译：在化妆品和药物制剂中使用胆固醇，液晶组合物作为UV过滤器
公开(公告)号：US06060042A
公开(公告)日：2000-05-09
申请号：US324712
申请日：1999-06-03
申请人： Peter Schuhmacher , Norbert Schneider , Horst Westenfelder , Sylke Haremza , Thorsten Habeck , Frank Meyer
发明人： Peter Schuhmacher , Norbert Schneider , Horst Westenfelder , Sylke Haremza , Thorsten Habeck , Frank Meyer
IPC分类号： A61K8/00 , A61K8/02 , A61K8/23 , A61K8/25 , A61K8/29 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61K8/86 , A61K8/89 , A61K8/97 , A61K8/98 , A61K31/255 , A61K31/34 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q1/10 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C09B67/20 , C09C3/08 , C09K3/00 , A61K7/42 , A61K7/00 , A61K7/44
CPC分类号： A61K8/0295 , A61K8/4973 , A61Q17/04 , A61Q19/00 , A61K2800/52 , A61Q19/001
摘要： The use of cholesteric, liquid-crystalline compositions comprisinga) at least one chiral, liquid-crystalline, polymerizable monomer of the formula I,[Z.sup.1 -Y.sup.1 -(A.sup.1).sub.m -Y.sup.2 -M.sup.1 -Y.sup.3 -].sub.n -XI by means of which a cholesteric, liquid-crystalline phase with a pitch of less than 450 nm can be obtained, orb) a mixture ofb.sub.1) at least one achiral, liquid-crystalline, polymerizable monomer of the formula IIZ.sup.2 -Y.sup.4 -(A.sup.2)-.sub.o -Y.sup.5 -M.sup.2 -Y.sup.6 -(A.sup.3).sub.p -Y.sup.7 -Z.sup.3 lI andb.sub.2) at least one chiral additive by means of which a cholesteric, liquid-crystalline phase with a pitch of less than 450 nm can be obtained,where the variables are as defined in the description, as UV filters in cosmetic and pharmaceutical preparations for protecting the human skin or human hair against sunlight, alone or together with UV-absorbent compounds which are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用胆甾型液晶组合物，其包含a）至少一种式I的手性，液晶可聚合单体[Z1-Y1-（A1）m-Y2-M1-Y3-] n-XI，通过方法其中可以获得具有小于450nm的间距的胆甾型液晶相，或b）b1）至少一种式IIZ2-Y4-（A2）的非手性，液晶的可聚合单体的混合物， -o-Y5-M2-Y6-（A3）p-Y7-Z3I1和b2）至少一种手性添加剂，借此可以获得具有小于450nm的间距的胆甾醇型液晶相，其中变量如说明书中所定义的，作为用于保护人类皮肤或人类头发免受阳光照射的化妆品和药物制剂中的紫外线过滤器，单独或与化妆品和药物制剂本身已知的紫外线吸收剂化合物一起使用。

42. 发明授权

US6001337A Cosmetic composition with polymer-bound benzophenone chromophores 失效
标题翻译：具有聚合物键合的二苯甲酮发色团的化妆品组合物
公开(公告)号：US6001337A
公开(公告)日：1999-12-14
申请号：US916392
申请日：1997-08-22
申请人： Harald Keller , Karin Sperling-Vietmeier , Horst Westenfelder
发明人： Harald Keller , Karin Sperling-Vietmeier , Horst Westenfelder
IPC分类号： A61K8/30 , A61K8/00 , A61K8/35 , A61K8/81 , A61Q17/04 , A61K31/765 , C08F8/14 , C08F220/10
CPC分类号： A61Q17/04 , A61K8/35 , A61K8/8164
摘要： Cosmetic compositions contain a polymer with the repeating structural unit (I) ##STR1## where the radicals have the meanings stated in the description.
摘要翻译：化妆品组合物含有具有重复结构单元（I）的聚合物，其中基团具有说明书中所述的含义。

43. 发明授权

US5968484A Cosmetic preparations comprising photostable UV-A filters 失效
公开(公告)号：US5968484A
公开(公告)日：1999-10-19
申请号：US916361
申请日：1997-08-22
申请人： Thorsten Habeck , Alexander Aumueller , Volker Schehlmann , Horst Westenfelder , Thomas Wunsch
发明人： Thorsten Habeck , Alexander Aumueller , Volker Schehlmann , Horst Westenfelder , Thomas Wunsch
IPC分类号： A61K8/00 , A61K8/30 , A61K8/40 , A61K8/49 , A61K8/92 , A61Q1/00 , A61Q1/04 , A61Q17/04 , C07C255/40 , C07D307/52 , C07D317/54 , C07D333/24 , A61K7/42 , A61K7/00 , C07C255/03
CPC分类号： C07C255/40 , A61K8/40 , A61K8/4973 , A61K8/4986 , A61Q1/04 , A61Q17/04 , C07D317/54 , C07D333/24 , A61K2800/52 , A61Q19/001
摘要： A cosmetic preparation which comprises a sunscreen agent for protecting the human epidermis against UV light in the range from 280 to 400 nm, which comprises, in a cosmetically suitable carrier, alone or together with compounds which absorb in the UV region and are known for cosmetic preparations, as photostable UV-A filters, effective amounts of compounds of the formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are hydrogen or aliphatic or cycloaliphatic radicals each having up to 18 carbon atoms, it being possible for any two of the radicals R.sup.1, R.sup.2 and R.sup.3 together to form a 5- or 6-membered ring, and R.sup.4 and R.sup.5 are an unsubstituted or substituted aromatic or heteroaromatic radical having 5 to 12 ring atoms, and R.sup.5 can additionally be hydrogen.

44. 发明授权

US5932195A Arylaminomethylenecamphor derivatives 失效
标题翻译：芳基亚甲基am卟啉衍生物
公开(公告)号：US5932195A
公开(公告)日：1999-08-03
申请号：US6175
申请日：1998-01-13
申请人： Michael Drogemuller , Volker Bomm , Volker Schehlmann , Horst Westenfelder
发明人： Michael Drogemuller , Volker Bomm , Volker Schehlmann , Horst Westenfelder
IPC分类号： C07D215/42 , A61K8/00 , A61Q17/04 , C07C225/14 , C07C229/54 , C07C237/30 , C07C309/46 , C07C311/39 , C09K3/00 , A61K7/42 , A61K7/44 , C07C229/56
CPC分类号： C07C225/14 , C07C2102/42
摘要： Arylaminomethylenecamphor derivatives of the formula (1) ##STR1## where the C.dbd.C double bond is in the Z or E configuration, and the variables have the following meanings:R.sup.1 H, CH.sub.3,R.sup.2 H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.8 -cycloalkenyl, aryl or substituted aryl,R.sup.3 H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, aryl, substituted aryl, C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.8 -acyl,Ar aryl, substituted aryl, hetaryl or substituted hetaryl,are used as sunscreen agents, especially in cosmetic and pharmaceutical formulations.
摘要翻译：其中C = C双键为Z或E构型的式（1）的芳基亚氨基亚甲基am卟啉衍生物，并且变量具有以下含义：R 1 H，CH 3，R 2 H，C 1 -C 6烷基，C 3 -C 8 - 环烷基，C 2 -C 6 - 烯基，C 3 -C 8 - 环烯基，芳基或取代的芳基，R 3 H，C 1 -C 6 - 烷基，C 3 -C 8 - 环烷基，芳基，取代的芳基，C 1 -C 6 - 烷氧基，C 1 -C 8酰基， Ar芳基，取代芳基，杂芳基或取代的杂芳基用作防晒剂，特别是在化妆品和药物制剂中。

45. 发明申请

US20080318833A1 Stabilizing Composition 有权
标题翻译：稳定成分
公开(公告)号：US20080318833A1
公开(公告)日：2008-12-25
申请号：US12096067
申请日：2006-11-27
申请人： Roland Jermann , Caroline Ploton , Horst Westenfelder
发明人： Roland Jermann , Caroline Ploton , Horst Westenfelder
IPC分类号： A61K8/37 , A61Q13/00
CPC分类号： C09K15/24 , A61K8/35 , A61K8/37 , A61K8/40 , A61K2800/434 , A61K2800/52 , A61K2800/522 , A61Q1/02 , A61Q1/04 , A61Q3/02 , A61Q5/006 , A61Q5/008 , A61Q5/02 , A61Q5/06 , A61Q5/12 , A61Q17/04 , A61Q19/00 , A61Q19/002 , A61Q19/10 , C08K5/07 , C08K5/315 , C09D7/48 , C09D11/03 , C09D11/38 , C11D3/2072 , C11D3/2093 , C11D3/26 , D06M16/00
摘要： The present invention relates to compositions of UV absorbers and optionally additional antioxidants. The compositions are useful for the protection and stabilization of photosensitive ingredients such as colorants, dyes, scents, fragrances and active ingredients in body care products, household products or inks against the deleterious effects of ultraviolet radiation and oxygen.
摘要翻译：本发明涉及UV吸收剂和任选的其它抗氧化剂的组合物。该组合物可用于保护和稳定感光成分，例如身体护理产品，家用产品或墨水中的着色剂，染料，香料，香料和活性成分，以抵抗紫外线辐射和氧气的有害影响。

46. 发明授权

US06545174B2 Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
标题翻译：含有光稳定紫外线过滤器的化妆品和药物制剂
公开(公告)号：US06545174B2
公开(公告)日：2003-04-08
申请号：US09765624
申请日：2001-01-22
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
IPC分类号： C07C6976
CPC分类号： C07C235/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/42 , A61K31/12 , A61K31/122 , A61K31/216 , A61K31/277 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C69/618 , C07C233/11
摘要： 4,4-Diarylbutadienes of the formula I, where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings: R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate, or ammonium residues; R3 is COOR5, CONR5R6; R4 is COOR6, CONR5R6; R5 and R6 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C7-C10-bicycloalkyl, C3-C10-cycloalkenyl, C7-C10-bicycloalkenyl, aryl, hetaryl, unsubstituted or substituted; n is 1 to 3; and R3 and R4 are not COOCH3 when R1 and R2 are hydrogen, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：式I的4,4-二芳基丁二烯，其中二烯体系具有Z，Z; Z，E; E，Z或E，E构型或其混合物，其中彼此独立的变量具有以下含义：R 1和R 2为氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基， C 3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基，杂芳基，未取代或取代的取代基，其赋予在水中的溶解性并且选自由羧酸盐，磺酸盐或铵残基组成; R3为COOR5，CONR5R6; R4是COOR6，CONR5R6; R 5和R 6是氢，C 1 -C 20烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 7 -C 10 - 双环烷基，C 3 -C 10 - 环烯基，C 7 -C 10 - 双环烯基，芳基，杂芳基，未取代或取代的; n为1〜3; 当R 1和R 2为氢时，R 3和R 4不是COOCH 3，用作化妆品和药物制剂中的光稳定性UV过滤剂，以保护人皮肤或人类头发免受太阳光线的影响，单独或与在UV区域吸收的化合物一起，本身就是化妆品和药物制剂。

47. 发明授权

US06436373B1 Oligomeric diarylbutadienes 失效
标题翻译：低聚二芳基丁二烯
公开(公告)号：US06436373B1
公开(公告)日：2002-08-20
申请号：US09455484
申请日：1999-12-06
申请人： Thorsten Habeck , Thomas Wünsch , Horst Westenfelder
发明人： Thorsten Habeck , Thomas Wünsch , Horst Westenfelder
IPC分类号： A61K742
CPC分类号： A61Q17/04 , A61K8/40 , C07C69/618 , C07C255/41
摘要： Oligomeric 4,4-diarylbutadienecarboxylates and -carboxamides of the formula I in which R1 and R2 independently of one another are hydrogen, an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical or substituents which confer solubility in water, chosen from the group consisting of carboxylate, sulfonate or ammonium radicals; R3 is an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical or a radical which is bonded by a carbonyl, sulfonyl or a phosphonyl group, or is a carboxylate or a cyano group; Y is the group; in which R4 is hydrogen, an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical and m is from 2 to 10, n is from 1 to 3, and x is the m-valent radical of a polyol having from 2 to 10 hydroxyl groups.
摘要翻译：式Iin的低聚4,4'-二芳基丁二羧酸酯和羧酰胺，其中R 1和R 2彼此独立地是氢，脂族，脂环族，芳族，芳脂族或杂环基或其在水中赋予溶解性的取代基，其选自羧酸酯，磺酰基或铵基; R 3是脂族，脂环族，芳族，芳脂族或杂环基或通过羰基，磺酰基或膦酰基键合或者是羧酸酯或氰基键合的基团; Y是基团;其中R 4 是氢，脂族，脂环族，芳族，芳脂族或杂环基团，且m为2至10，n为1至3，x为具有2至10个羟基的多元醇的m价基团。

48. 发明授权

US06413503B1 Use of cyclic enamines as light protection agents 失效
标题翻译：使用环状烯胺作为防晒剂
公开(公告)号：US06413503B1
公开(公告)日：2002-07-02
申请号：US09583288
申请日：2000-05-31
申请人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
发明人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
IPC分类号： A61K742
CPC分类号： A61K8/4946 , A61K8/49 , A61K8/494 , A61K2800/52 , A61Q1/04 , A61Q17/04
摘要： The use of compounds of the formula I in which R1 and R2 are identical or different, electron-withdrawing radicals chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl and optionally substituted aminocarbonyl, R3 is a hydrogen atom, a C1-C20-alkyl radical or a C3-C20-cycloalkyl radical or a radical of the formula —CH2-CH2—SO3—M+, where M+ is a cation, X is the divalent radical of oxygen, sulfur or the radical where R3 is as defined above, Z is the divalent radical of the formula II or III, which forms a fused system with the radical of the formula I where R4 can be bonded one or more times to the benzylidene ring I or naphthylidene ring II, and is hydrogen, alkyl, cycloalkyl, alkyloxy, cycloalkyloxy, alkoxycarbonyl, mono- or dialkylaminocarbonyl, alkylamino, dialkylamino, each having up to 20 carbon atoms, and also cyano, amino and SO3—M+, where M+ is a cation, as photostable UV filters in cosmetic and pharmaceutical preparations to protect human skin and human hair against solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用其中R 1和R 2相同或不同的式Iin化合物，选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基和任选取代的氨基羰基的吸电子基，R 3是氢原子，C 1 -C 20 - 烷基或C 3 -C 20环烷基或式-CH 2 -CH 2 -SO 3 -M +的基团，其中M +是阳离子，X是氧，硫或R3的二价基团，其中R 3为 Z是式II或III的二价基团，其与式I基团形成稠合体系，其中R4可以与亚苄基环I或亚萘基环II键合一次或多次，并且是氢，烷基，环烷基，烷氧基，环烷氧基，烷氧基羰基，单或二烷基氨基羰基，烷基氨基，二烷基氨基，各自具有至多20个碳原子，以及氰基，氨基和SO3-M +，其中M +是阳离子，作为化妆品中的光稳定性紫外线过滤器药物制剂保护人类亲和人类头发对抗太阳光线，单独或与在UV区域吸收的化合物一起，并且本身已知用于化妆品和药物制剂。

49. 发明授权

US6143906A Ascorbyl sorbates 失效
标题翻译：抗坏血酸山梨酸盐
公开(公告)号：US6143906A
公开(公告)日：2000-11-07
申请号：US178428
申请日：1998-10-26
申请人： Harald Streicher , Linda von dem Bussche-Hunnefeld , Horst Westenfelder , Hans-Ulrich Wekel
发明人： Harald Streicher , Linda von dem Bussche-Hunnefeld , Horst Westenfelder , Hans-Ulrich Wekel
IPC分类号： A61K8/00 , A61K8/67 , A61K31/00 , A61K31/375 , A61K47/22 , A61P17/00 , A61Q1/00 , A61Q1/04 , A61Q1/06 , A61Q17/00 , A61Q17/04 , A61Q19/00 , C07D307/62 , C07D307/40 , C07D307/42
CPC分类号： A61Q1/06 , A61K8/676 , A61Q17/00 , A61Q19/00 , C07D307/62 , A61K2800/522 , A61Q17/04 , A61Q19/08
摘要： Ascorbyl sorbates of the formula I, ##STR1## where the variables independently of one another have the following meanings:R.sup.1 and R.sup.2are hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.20 -acyl;where R.sup.1 and R.sup.2, together with the oxygen atoms to which they are bonded and the carbon atoms bonded to the oxygen atoms, can form an unsubstituted or substituted heterocycle;R.sup.3 is hydrogen or a cation selected from the group consisting of alkali metals and alkaline earth metals.
摘要翻译：式I的抗坏血酸山梨酸酯，其中各个变量彼此独立地具有以下含义：R 1和R 2是氢，C 1 -C 12烷基，C 1 -C 20酰基; 其中R 1和R 2与它们键合的氧原子和与氧原子键合的碳原子可以形成未取代或取代的杂环; R3是氢或选自碱金属和碱土金属的阳离子。

50. 发明授权

US6143850A Lipophilic polymeric UV absorbers 有权
标题翻译：亲脂性聚合物紫外线吸收剂
公开(公告)号：US6143850A
公开(公告)日：2000-11-07
申请号：US131391
申请日：1998-08-07
申请人： Harald Keller , Volker Schehlmann , Horst Westenfelder , Thomas Preiss
发明人： Harald Keller , Volker Schehlmann , Horst Westenfelder , Thomas Preiss
IPC分类号： A61K8/00 , A61K8/90 , A61Q1/00 , A61Q1/04 , A61Q5/00 , A61Q17/04 , C08F216/14 , C08F216/18 , C08F218/00 , C08F218/10 , C08F220/36 , C09K3/00 , C08F20/58
CPC分类号： C08F218/00 , A61K8/90 , A61Q1/04 , A61Q17/04 , C08F216/18
摘要： Polymeric UV absorbers based on the units shown in the schematized formula I ##STR1## where the sequence of the units is arbitrary, the sum of a+b+c+d=100 anda is a value from 5 to 95,b is a value from 0 to 70,c is a value from 5 to 95,d is a value from 0 to 70and the radicals R have the meaning explained in the description, are described.
摘要翻译：聚合紫外吸收剂基于所示单位所示的单位，其中单元的序列是任意的，a + b + c + d = 100的和和a是5至95的值，b是0 至70，c为5至95的值，d为0至70的值，基团R具有在说明书中说明的含义。

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