会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • N-(.beta.-carbony- and .beta.-cyanovinyl)-2,2,6,6-tetramethyl-piperidine
derivatives
    • N-(β-羰基 - 和β-氰基乙烯基)-2,2,6,6-四甲基 - 哌啶衍生物
    • US5434202A
    • 1995-07-18
    • US244209
    • 1994-06-03
    • Alfred KrauseAlexander AumuellerHubert Trauth
    • Alfred KrauseAlexander AumuellerHubert Trauth
    • C07D211/46C07D211/54C07D211/58C07D401/04C07D405/06C07D409/06C08K5/3432C08K5/3435
    • C07D211/58C07D211/46C08K5/3435
    • N-(.beta.-carbonyl- and .beta.-cyanovinyl)-2,2,6,6-tetramethylpiperidine derivatives of the formula I ##STR1## where R.sup.1 is COOR.sup.3, COR.sup.4, CONR.sup.4 R.sup.5 or CN,R.sup.2 has the meanings of R.sup.1 or is C.sub.1 -C.sub.12 -alkyl or hydrogen,R.sup.3 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.5 -alkenyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,R.sup.4 and R.sup.5 are each hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl or phenyl which can be mono- to trisubstituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkoxycarbonyl, halogen, hydroxyl, phenoxy, phenyl, tolyl or xylyl,n is 1-4,X and A for each individual n have been defined in the specification.
    • PCT No.PCT / EP92 / 02733 Sec。 371日期:1994年6月3日 102(e)日期1994年6月3日PCT提交1992年11月27日PCT公布。 出版物WO93 / 11109 日期:6月10日,1993.N-(β-羰基 - 和β-氰基乙酰基)-2,2,6,6-四甲基哌啶衍生物,其中R1是COOR3,COR4,CONR4R5或CN,R2 具有R 1的意义或是C 1 -C 12 - 烷基或氢,R 3是氢,C 1 -C 8 - 烷基,C 5 -C 8 - 环烷基,C 3 -C 5 - 烯基或苯基,其可以被C1-C4- 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷氧基羰基,卤素,羟基,苯氧基,苯基,甲苯基或二甲苯基,R 4和R 5各自为氢,C 1 -C 12烷基,C 5 -C 8环烷基或苯基, - 被C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷氧基羰基,卤素,羟基,苯氧基,苯基,甲苯基或二甲苯基三取代,n为1-4,各个n的X和A定义 在规范中。
    • 4. 发明授权
    • Preparation of 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids
    • 4-烷基-2-羟基苯并噻吩-5-磺酸的制备
    • US5072034A
    • 1991-12-10
    • US627895
    • 1990-12-13
    • Peter NeumannHeinz EilingsfeldAlexander Aumueller
    • Peter NeumannHeinz EilingsfeldAlexander Aumueller
    • C07C309/42C07C303/08C07C309/44C07C309/59
    • C07C303/08
    • 4-alkoxy-2-hydroxybenzophenone-5-sulfonic acids of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by halogen, cyanao, hydroxyl, C.sub.1 -C.sub.20 -alkoxy, C.sub.2 -C.sub.20 -alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C.sub.1 -c.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, R.sup.2 and R.sup.3 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.12 -alkyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.4 -C.sub.12 -cycloalkylalkyl, cyano, hydroxyl or hydroxyethyl or are each phenoxy, C.sub.7 -C.sub.10 -phenalkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and/or halogen, and R.sup.4 is hydrogen or sulfo, are prepared by reacting a 4-alkoxy-2-hydroxybenzophenone of the general formula II ##STR2## with chlorosulfonic acid at from -20.degree. to +100.degree. C., by a novel and improved process in which the reaction is carried out in an aliphatic, cycloaliphatic and/or aromatic carboxylate as solvent.
    • 其中R 1是未被取代或被卤素,氰基,羟基,C 1 -C 20烷氧基,C 2 -C 20烷氧基取代的C 1 -C 20烷基的4-烷氧基-2-羟基二苯甲酮-5-磺酸 -C 20 - 烷氧基羰基,未被取代或被C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基和/或卤素取代的酰氧基和/或苯基,R 2和R 3彼此独立地为氢,卤素,C 1 -C 12 - 烷基 C 1 -C 12烷氧基,C 1 -C 4卤代烷基,C 3 -C 8环烷基,C 4 -C 12环烷基烷基,氰基,羟基或羟乙基,或各自为苯氧基,未取代或被C1- C4-烷基,C1-C4-烷氧基和/或卤素,R4是氢或磺基,是通过使通式II的4-烷氧基-2-羟基二苯甲酮与(II)的4-磺酰基-2- 通过一种新的改进的方法,其中反应在脂族,脂环族和/或芳族羧酸酯作为溶剂中进行。
    • 6. 发明授权
    • Bicyclo(3.3.1)nonane derivatives and use in stabilizing organic materials
    • 双酚(3.3.1)壬烷衍生物,用于稳定有机物质
    • US4943391A
    • 1990-07-24
    • US286295
    • 1988-12-10
    • Alexander AumuellerPeter NeumannHubert Trauth
    • Alexander AumuellerPeter NeumannHubert Trauth
    • C07D471/08C08K5/34C08K5/3412C08K5/3442C09D7/12C09K15/18
    • C07D471/08
    • Bicyclo[3.3.1]nonane derivatives of the general formula (I) ##STR1## where n is an integer from 1 to 70,R.sup.1 is hydrogen,R.sup.2 is hydrogen or hydroxyl, or the radical ##STR2## R.sup.3 and R.sup.4 are each independently of the other phenyl or 1- or 2-naphthyl, which phenyl or naphthyl may each be substituted by 1, 2 or 3 C.sub.1 -C.sub.12 -alkyls, C.sub.1 -C.sub.12 -alkoxys, chlorines, bromines, fluorines, trifluoromethyls or cyanos, in the case of 2 or 3 substituents these substituents being identical or different,A and B are each independently of the other a chemical bond, C.sub.1 -C.sub.22 -alkylene, cycloalkylene ##STR3## where m and o are each from 1 to 20 andR.sup.10 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.7 -C.sub.18 -phenylalkyl, phenyl or C.sub.2 -C.sub.22 -cyanoalkyl,M is a radical of the formula ##STR4## which may be bonded to A not only via the nitrogen atom but also via the carbon atom, andR.sup.11, R.sup.12, R.sup.13 and R.sup.14 are each independently of the others C.sub.1 -C.sub.4 -alkyl, orR.sup.11 and R.sup.12 and/or R.sup.13 and R.sup.14 are each together tetramethylene or pentamethylene,R.sup.5 is hydrogen, cyano, hydroxyl, ##STR5## R.sup.15 is hydrogen, C.sub.1 -C.sub.22 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.5 -C.sub.16 -phenylalkyl or a 5- or 6-membered heterocycle, or, when n is 1, --M--B--R.sup.5 is a radical of the formula ##STR6## where R.sup.16 is C.sub.1 -C.sub.4 -alkyl,R.sub.17 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy andR.sub.18 is hydrogen or C.sub.1 -C.sub.12 -alkyl, have remarkably good stabilizing properties in respect of plastics, are colorless, are highly compatible with organic polymers and are stable to thermal decomposition.
    • 双环[3.3.1]通式(I)的壬烷衍生物其中n是1至70的整数,R 1是氢,R 2是氢或羟基,或者基团R 3和R 4 各自独立地为其它苯基或1-或2-萘基,该苯基或萘基各自可被1,2或3个C 1 -C 12烷基,C 1 -C 12烷氧基,氯,溴,氟,三氟甲基或氰基取代 在2或3个取代基的情况下,这些取代基相同或不同,A和B各自独立地为化学键,C 1 -C 22 - 亚烷基,亚环烷基,其中m和o分别为 1至20,R 10为氢,C 1 -C 22 - 烷基,C 5 -C 12 - 环烷基,C 7 -C 18 - 苯基烷基,苯基或C 2 -C 22 - 氰基烷基,M为式 A不仅通过氮原子而且通过碳原子,并且R 11,R 12,R 13和R 14各自独立地为C 1 -C 4 - 烷基,或者R 11和R 12和/或R 13和R 14分别为四甲基 烯或五亚甲基,R 5是氢,氰基,羟基,R 15是氢,C 1 -C 22 - 烷基,C 5 -C 12 - 环烷基,C 5 -C 16 - 苯基烷基或5-或6-元杂环 或者当n为1时,-MB-R 5为式(VI)的基团,其中R 16为C 1 -C 4 - 烷基,R 17为氢,C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基 和R18是氢或C1-C12烷基,在塑料方面具有非常好的稳定性,是无色的,与有机聚合物高度相容并且对热分解是稳定的。
    • 8. 发明授权
    • Maleimide/.alpha.-olefin copolymers and their use as light stabilizers
and stabilizers for organic material
    • 马来酰亚胺/α-烯烃共聚物及其用作有机材料的光稳定剂和稳定剂
    • US5710228A
    • 1998-01-20
    • US644123
    • 1996-05-10
    • Alfred KrauseWalter DenzingerAlbert HettcheAlexander AumuellerHubert Trauth
    • Alfred KrauseWalter DenzingerAlbert HettcheAlexander AumuellerHubert Trauth
    • C08F2/06C08F8/32C08F210/14C08F222/40C08F210/00
    • C08F8/32C08F210/14
    • Maleimide/.alpha.-olefin copolymers are composed of structural units I ##STR1## where R.sup.1 is a tetramethylpiperidinyl radical of the formula II ##STR2## R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, formyl, C.sub.2 -C.sub.6 -alkanoyl, C.sub.1 -C.sub.12 -alkoxy, C.sub.5 - or C.sub.6 -cycloalkoxy, cyanomethyl, 2-hydroxyethyl, benzyl or a radical of the formula --CR.sup.4 =CH--CO--OR.sup.5, R.sup.4 is hydrogen, C.sub.1 -C.sub.6 -alkyl or a radical of the formula --CO--OR.sup.5, and R.sup.5 is C.sub.5 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.7 -C.sub.18 -aralkyl, phenyl or tolyl, and up to 8 mol %, based on II, of R.sup.1 may furthermore be hydrogen, C.sub.1 -C.sub.22 -alkyl or C.sub.5 -C.sub.8 -cycloalkyl, and R.sup.2 is a mixture of C.sub.14 -C.sub.28 -alkyl groups, where two of these alkyl groups, which may differ by no more than two carbon atoms, each account for at least 30% of this mixture, having an average molecular weight of from 1,000 to 50,000. The copolymers described are suitable as light stabilizers and stabilizers for organic material, in particular plastics and coatings.
    • 马来酰亚胺/α-烯烃共聚物由结构单元Ⅰ(II)组成,其中R 1是式II的四甲基哌啶基,其中R 3是氢,C 1 -C 6烷基,甲酰基,C 2 -C 6 - 烷酰基,C 1 -C 12 - 烷氧基,C 5 - 或C 6 - 环烷氧基,氰基甲基,2-羟乙基,苄基或式-CR 4 = CH-CO-OR 5基团,R 4是氢,C 1 -C 6烷基或 式-CO-OR5和R5是C5-C18-烷基,C5-C8-环烷基,C7-C18-芳烷基,苯基或甲苯基,并且基于II的至多8摩尔%的R 1还可以是氢, C 1 -C 22 - 烷基或C 5 -C 8 - 环烷基,并且R 2是C 14 -C 28 - 烷基的混合物,其中两个可以不超过两个碳原子的烷基各自占据至少30% 的该混合物,其平均分子量为1,000至50,000。 所述的共聚物适合用作有机材料的光稳定剂和稳定剂,特别是塑料和涂料。
    • 9. 发明授权
    • Amino compounds as processing stabilizers for thermoplastic materials
    • 氨基化合物作为热塑性材料的加工稳定剂
    • US5496877A
    • 1996-03-05
    • US313115
    • 1994-10-12
    • Alexander AumuellerHubert Trauth
    • Alexander AumuellerHubert Trauth
    • C07D233/61C08K5/17C08K5/34C08K5/3445C08K5/3462C08L101/00C08K3/20
    • C08K5/3462C08K5/17C08K5/3445
    • Compounds of the general formula (I) or (II) ##STR1## where m is 2 or 3,n is an integer from 1 to 6,R.sup.1 and R.sup.2 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl or C.sub.5 - to C.sub.12 cycloalkyl, R.sup.4 and R.sup.5 are, independently of one another, hydrogen, C.sub.1 - to C.sub.18 -alkyl, C.sub.3 - to C.sub.8 -alkenyl, C.sub.5 - to C.sub.12 -cycloalkyl or C.sub.7 - to C.sub.12 -phenylalkyl, in which the phenyl ring may be substituted by up to 3 C.sub.1 - to C.sub.12 -alkyl or C.sub.1 - to C.sub.12 -alkoxy groups,X is oxygen or NR.sup.3,R.sup.3 is an R.sup.1 radical or a group of the formula ##STR2## B completes a 3- to 12-membered heterocycle, A when n=1 is an aliphatic radical or unsubstituted or substituted phenyl, andA when n>1 is a divalent organic radical, are used as processing stabilizers for thermoplastic materials.
    • PCT No.PCT / EP93 / 00951 Sec。 371日期:1994年10月12日 102(e)日期1994年10月12日PCT提交1993年4月20日PCT公布。 公开号WO93 / 22376 (I)或(II)的化合物其中m为2或3,n为1至6的整数,R 1和R 2为 彼此独立地为氢,C 1至C 18烷基,C 3至C 8链烯基或C 5至C 12环烷基,R 4和R 5彼此独立地为氢,C 1 -C 18 - 烷基,C 3 - C 8 - 烯基,C 5 - 至C 12 - 环烷基或C 7 - 至C 12 - 苯基烷基,其中苯环可被至多3个C 1 -C 12 - 烷基或C 1 -C 12烷氧基取代,X为氧或NR 3 R 3为R 1基团或式VIII所示基团,当n = 1是脂族基团或未取代或取代的苯基时,A完成3至12元杂环,当n> 1是二价 有机基团用作热塑性材料的加工稳定剂。