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1. 发明授权

US06524560B1 Use of substituted vinyltetrahydronaphthalenes and vinyl-benzotetrahydropyrans as light protection agents 失效
标题翻译：使用取代的乙烯基四氢萘和乙烯基 - 苯并四氢吡喃作为防光剂
公开(公告)号：US06524560B1
公开(公告)日：2003-02-25
申请号：US09583760
申请日：2000-05-31
申请人： Frank Prechtl , Thorsten Habeck , Horst Westenfelder , Thomas Wünsch
发明人： Frank Prechtl , Thorsten Habeck , Horst Westenfelder , Thomas Wünsch
IPC分类号： A61K742
CPC分类号： A61K8/40 , A61K8/368 , A61K8/37 , A61K8/498 , A61K2800/52 , A61Q17/04
摘要： The invention relates to the use of compounds of the formula I in which X is the divalent radical of oxygen, a carbonyl radical, optionally aliphatically substituted imino or the radical ═CR9R10, Y is a carbonyl group or the radical ═CR9R10, R1 and R2 are identical or different electron-withdrawing radicals, chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl, optionally substituted aminocarbonyl, alkyl- or arylsulfinyl, alkyl- or arylsulfonyl and optionally substituted aminosulfonyl, R3 is a hydrogen atom, a cyano, hydroxyl, carboxyl or aminocarbonyl group or a C5-C20-aryl radical or C1-C20-alkylradical optionally bonded via an oxygen bridge, an aminocarbonyl bridge or oxycarbonyl bridge, R4 is a hydrogen atom, a hydroxyl group, an amino group, or a C5-C20-aryl radical or C1-C20-alkyl radical optionally bonded via an oxygen bridge, and R5 to R10 independently of one another are hydrogen or C1-C20-alkyl radicals and where in addition R7 and R8 together with the chain carbon atom are a carbonyl group, as photostable UV filters in cosmetic and pharmaceutical preparations for protecting human skin and human hair from solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：本发明涉及式Iin化合物的用途，其中X是氧的二价基团，羰基，任选地是脂族取代的亚氨基或基团= CR 9 R 10，Y是羰基或基团= CR 9 R 10，R 1和R 2相同或不同的吸电子基团，其选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基，任选取代的氨基羰基，烷基 - 或芳基亚磺酰基，烷基 - 或芳基磺酰基和任选取代的氨基磺酰基，R 3是氢原子，氰基，羟基，羧基或氨基羰基或C 5 -C 20 - 芳基或任选经由氧桥，氨基羰基桥或氧羰基桥键合的C 1 -C 20烷基取代基，R 4是氢原子，羟基，氨基，或通过氧桥任选键合的C 5 -C 20芳基或C 1 -C 20烷基，R 5至R 10彼此独立地为氢或C 1 -C 20 - 烷基，并且其中R 7和R 8为具有链状碳原子的碳原子是羰基，作为用于保护人类皮肤和人类头发免受太阳光线影响的化妆品和药物制剂中的光稳定性紫外线过滤器，单独或与在UV区域吸收的化合物一起，并且本身已被用于化妆品和药物制剂。

2. 发明授权

US06409995B1 Use of amino-substituted hydroxybenzophenones as photostable UV filters in cosmetic and pharmaceutical preparations 有权
标题翻译：在化妆品和药物制剂中使用氨基取代的羟基二苯甲酮作为光稳定的紫外线过滤器
公开(公告)号：US06409995B1
公开(公告)日：2002-06-25
申请号：US09553897
申请日：2000-04-20
申请人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder , Sylke Haremza , Thorsten Bach , Anja Spiegel
发明人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder , Sylke Haremza , Thorsten Bach , Anja Spiegel
IPC分类号： C07D49310
CPC分类号： C07D295/112 , A61K8/411 , A61K8/445 , A61K8/4913 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C225/22 , C07C229/52 , C07C2601/14
摘要： Use of amino-substituted hydroxybenzophenones of the formula I in which the variables have the meanings explained in the description, as photostable UV filters in cosmetic and pharmaceutical preparations for protecting human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用式Iin的氨基取代的羟基二苯甲酮，其变量具有在说明书中解释的含义，作为用于保护人类皮肤或人类头发免受太阳光线的化妆品和药物制剂中的光稳定性UV过滤器，单独或与吸收的化合物一起使用 UV区域，并且本身已知化妆品和药物制剂。

3. 发明授权

US06238649B1 Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
标题翻译：含有光稳定紫外线过滤器的化妆品和药物制剂
公开(公告)号：US06238649B1
公开(公告)日：2001-05-29
申请号：US09133173
申请日：1998-08-13
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
IPC分类号： A61K742
CPC分类号： C07C235/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/42 , A61K31/12 , A61K31/122 , A61K31/216 , A61K31/277 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C69/618 , C07C233/11
摘要： 4,4-Diarylbutadienes of the formula I, where the variables have the meanings explained in the description, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：式I中的4,4-二芳基丁二烯，其中变量具有说明书中解释的含义，用作化妆品和药物制剂中的光稳定性UV过滤器，以单独或与化合物一起保护人皮肤或人类头发免受太阳光线其在UV区域中吸收并且本身已知化妆品和药物制剂。

4. 发明授权

US06407247B1 Photo-stable cosmetic and pharmaceutical formulations containing UV-filters 失效
标题翻译：光稳定的化妆品和药物配方含有紫外线过滤器
公开(公告)号：US06407247B1
公开(公告)日：2002-06-18
申请号：US09494474
申请日：2000-01-31
申请人： Thorsten Habeck , Alexander Aumüller , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch
发明人： Thorsten Habeck , Alexander Aumüller , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch
IPC分类号： C07D22102
CPC分类号： C07D275/03 , A61K8/411 , A61K8/42 , A61K8/466 , A61K8/49 , A61K8/498 , A61K8/4986 , A61Q1/04 , A61Q17/04 , C07C229/56 , C07C229/60 , C07C255/30 , C07C255/58 , C07C309/46 , C07D319/06 , C07D333/38
摘要： A method of using compounds of formula I in which the C═C double bond is present in E and/or Z configuration and the variables have the following meanings: R1 denotes COOR5, COR5, CONR5R6, CN, O═S(—R5)═O, O═S(═OR5)═O, R7O—P(—OR8)═O; R2 denotes COOR6, COR6, CONR5R6, CN, O═S(—R6)═O, O═S(═OR6)═O, R7O—P(—OR8)═O; R3 denotes hydrogen, an optionally substituted aliphatic, cycloaliphatic, araliphatic or aromatic radical having in each case up to 18 carbon atoms; R4 denotes an optionally substituted aromatic or heteroaromatic radical containing from 5 to 12 ring atoms; R5 to R8 independently denote hydrogen, an open-chain or branched-chain aliphatic, araliphatic, cycloaliphatic or optionally substituted aromatic radical containing in each case up to 18 carbon atoms, where the variables R3 to R8 may also form, together with the carbon atoms to which they are attached, a 5-membered or 6-membered ring, which may be anellated if desired, as UV filters, particularly UV-A filters, in cosmetic and pharmaceutical formulations for the protection of the human skin or human hair from solar radiation, alone or together with compounds known per se in cosmetic and pharmaceutical formulations and capable of absorbing radiation in the UV range.
摘要翻译：在E和/或Z构型中使用存在C = C双键的式Iin化合物的方法，并且变量具有以下含义：R 1表示COOR 5，COR 5，CONR 5 R 6，CN，O = S（-R 5）= O = S（= OR5）= O，R7O-P（-OR8）= O; R2表示COOR6，COR6，CONR5R6，CN，O = S（-R6）= O，O = S（= OR6）= O，R7O-P（-OR8）= O; R3表示氢，任选取代的脂族，脂环族，芳脂族或芳族基团，其中每种情况下最多可达18个碳原子; R4表示任选取代的芳族或杂芳族基团， 12个环原子; R5至R8独立地表示氢，开链或支链脂族，芳脂族，脂环族或任选取代的芳族基团，其中每种情况最多可包含18个碳原子，其中变量R3至R8也可以形成，它们所连接的碳原子，5元或6元环，如果需要，可以将其作为UV滤光器，特别是UV-A滤光器，在化妆品和药物中用于保护人类皮肤或人类头发免受太阳辐射，单独或与化妆品和药物制剂中本身已知的化合物一起并且能够吸收UV范围内的辐射。

5. 发明授权

US06191301B1 4,4-diarylbutadienes as water-soluble photostable UV filters for cosmetic and pharmaceutical preparation 失效
标题翻译：作为用于化妆品和药物制备的水溶性光稳定紫外线过滤剂
公开(公告)号：US06191301B1
公开(公告)日：2001-02-20
申请号：US09526528
申请日：2000-03-16
申请人： Thorsten Habeck , Horst Westenfelder , Thomas Wünsch
发明人： Thorsten Habeck , Horst Westenfelder , Thomas Wünsch
IPC分类号： C07C25506
CPC分类号： A61K8/466 , A61K8/37 , A61K8/42 , A61K2800/52 , A61Q17/04 , C07C69/618 , C07C69/738 , C07C233/40 , C07C309/58 , C07C309/59
摘要： Use of 4,4-diarylbutadienes of the formula I, where the variables have the meanings explained in the description, as water-soluble photostable UV filters in cosmetic and pharmaceutical preparations for protecting the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用式I的4,4-二芳基丁二烯，其中变量具有在说明书中解释的含义，作为用于保护人类皮肤或人类头发免受太阳光线的化妆品和药物制剂中的水溶性光稳定紫外线过滤器，单独或以及在UV区域吸收的化合物和本身已知的用于化妆品和药物制剂的化合物。

6. 发明授权

US06603014B1 Use of cyclic enamines as light protection agents 失效
标题翻译：使用环状烯胺作为防晒剂
公开(公告)号：US06603014B1
公开(公告)日：2003-08-05
申请号：US10053323
申请日：2002-01-23
申请人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
发明人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
IPC分类号： C07D27764
CPC分类号： A61K8/4946 , A61K8/49 , A61K8/494 , A61K2800/52 , A61Q1/04 , A61Q17/04
摘要： The use of compounds of the formula I in which R1 and R2 are identical or different, electron-withdrawing radicals chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl and optionally substituted aminocarbonyl, R3 is a hydrogen atom, a C1-C20-alkyl radical or a C3-C20-cycloalkyl radical or a radical of the formula —CH2—CH2—SO3—M+, where M+ is a cation, X is the divalent radical of oxygen, sulfur or the radical where R3 is as defined above, is the divalent radical of the formula II or III, which forms a fused system with the radical of the formula I where R4 can be bonded one or more times to the benzylidene ring I or naphthylidene ring II, and is hydrogen, alkyl, cycloalkyl, alkyloxy, cycloalkyloxy, alkoxycarbonyl, mono- or dialkylaminocarbonyl, alkylamino, dialkylamino, each having up to 20 carbon atoms, and also cyano, amino and SO3—M+, where M+ is a cation, as photostable UV filters in cosmetic and pharmaceutical preparations to protect human skin and human hair against solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用其中R 1和R 2相同或不同的式Iin化合物，选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基和任选取代的氨基羰基的吸电子基，R 3是氢原子，C 1 -C 20 - 烷基或C 3 -C 20环烷基或式-CH 2 -CH 2 -SO 3 -M +的基团，其中M +是阳离子，X是氧，硫或基团的二价基团，其中R3如所定义是式II或III的二价基团，其与式I的基团形成稠合体系，其中R 4可以与亚苄基环I或亚萘基环II键合一次或多次，并且是氢，烷基，环烷基，烷氧基，环烷氧基，烷氧基羰基，单或二烷基氨基羰基，烷基氨基，二烷基氨基，各自具有至多20个碳原子，以及氰基，氨基和SO3-M +，其中M +是阳离子，作为化妆品和药物制剂中的光稳定性UV过滤剂保护人体皮肤a 将人类头发抵抗太阳光线，单独或与在UV区域吸收的化合物一起，并且本身已知用于化妆品和药物制剂。

7. 发明授权

US06541032B1 Use of finely divided dye-containing polymers PD as color-imparting constituent in cosmetic compositions 失效
标题翻译：在化妆品组合物中使用细分散的含染料的聚合物PD作为赋色成分
公开(公告)号：US06541032B1
公开(公告)日：2003-04-01
申请号：US09677864
申请日：2000-10-03
申请人： Monika Medelnick , Ellen Pfrommer , Thorsten Clemens , Peter Erk , Arno Böhm , Sabine Kielhorn-Bayer , Helmut Witteler , Wilma M. Dausch , Horst Westenfelder , Thomas Wünsch , Klemens Mathauer , Thorsten Habeck , Takahiro Ikeda , Hideyuki Ichihara
发明人： Monika Medelnick , Ellen Pfrommer , Thorsten Clemens , Peter Erk , Arno Böhm , Sabine Kielhorn-Bayer , Helmut Witteler , Wilma M. Dausch , Horst Westenfelder , Thomas Wünsch , Klemens Mathauer , Thorsten Habeck , Takahiro Ikeda , Hideyuki Ichihara
IPC分类号： A61K914
CPC分类号： A61Q5/06 , A61K8/046 , A61K8/8152 , A61K8/8158 , A61Q1/02 , A61Q1/06 , A61Q1/08 , A61Q1/10 , A61Q3/02 , A61Q5/00 , A61Q17/04 , Y10S514/844 , Y10S514/937
摘要： The present invention describes the use of finely divided dye-containing polymers PD in the form of an aqueous polymer dispersion or a polymer powder obtainable therefrom, the polymer matrix of which comprises at least one organic dye D in homogeneously dispersed form, as color-imparting constituent in cosmetic compositions. The present invention also describes cosmetic compositions which comprise a color-containing polymer in an amount of from 0.1 to 50% by weight, based on the total weight of the cosmetic composition, and additives customary for cosmetic compositions.
摘要翻译：本发明描述了使用细分散的含染料的聚合物PD，其形式为聚合物水分散体或由其获得的聚合物粉末，其聚合物基质包含至少一种均匀分散形式的有机染料D，作为赋色剂化妆品组合物中的成分。本发明还描述了化妆品组合物，其包含基于化妆品组合物的总重量为0.1-50重量％的含颜色聚合物和用于化妆品组合物的添加剂。

8. 发明授权

US06545174B2 Cosmetic and pharmaceutical preparations containing photostable UV filters 有权
标题翻译：含有光稳定紫外线过滤器的化妆品和药物制剂
公开(公告)号：US06545174B2
公开(公告)日：2003-04-08
申请号：US09765624
申请日：2001-01-22
申请人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
发明人： Thorsten Habeck , Sylke Haremza , Volker Schehlmann , Horst Westenfelder , Thomas Wünsch , Michael Drögemüller , Volker Bomm
IPC分类号： C07C6976
CPC分类号： C07C235/34 , A61K8/35 , A61K8/37 , A61K8/40 , A61K8/42 , A61K31/12 , A61K31/122 , A61K31/216 , A61K31/277 , A61K2800/52 , A61Q1/04 , A61Q17/04 , C07C69/618 , C07C233/11
摘要： 4,4-Diarylbutadienes of the formula I, where the diene system has the Z,Z; Z,E; E,Z or E,E configuration or a mixture thereof, and where the variables independently of one another have the following meanings: R1 and R2 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C3-C10-cycloalkenyl, C1-C12-alkoxy, C1-C20-alkoxycarbonyl, C1-C12-alkylamino, C1-C12-dialkylamino, aryl, hetaryl, unsubstituted or substituted, substituents which confer solubility in water and are selected from the group consisting of carboxylate, sulfonate, or ammonium residues; R3 is COOR5, CONR5R6; R4 is COOR6, CONR5R6; R5 and R6 are hydrogen, C1-C20-alkyl, C2-C10-alkenyl, C3-C10-cycloalkyl, C7-C10-bicycloalkyl, C3-C10-cycloalkenyl, C7-C10-bicycloalkenyl, aryl, hetaryl, unsubstituted or substituted; n is 1 to 3; and R3 and R4 are not COOCH3 when R1 and R2 are hydrogen, are used as photostable UV filters in cosmetic and pharmaceutical preparations to protect the human skin or human hair from the sun's rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：式I的4,4-二芳基丁二烯，其中二烯体系具有Z，Z; Z，E; E，Z或E，E构型或其混合物，其中彼此独立的变量具有以下含义：R 1和R 2为氢，C 1 -C 20 - 烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基， C 3 -C 10 - 环烯基，C 1 -C 12 - 烷氧基，C 1 -C 20烷氧基羰基，C 1 -C 12 - 烷基氨基，C 1 -C 12 - 二烷基氨基，芳基，杂芳基，未取代或取代的取代基，其赋予在水中的溶解性并且选自由羧酸盐，磺酸盐或铵残基组成; R3为COOR5，CONR5R6; R4是COOR6，CONR5R6; R 5和R 6是氢，C 1 -C 20烷基，C 2 -C 10 - 烯基，C 3 -C 10 - 环烷基，C 7 -C 10 - 双环烷基，C 3 -C 10 - 环烯基，C 7 -C 10 - 双环烯基，芳基，杂芳基，未取代或取代的; n为1〜3; 当R 1和R 2为氢时，R 3和R 4不是COOCH 3，用作化妆品和药物制剂中的光稳定性UV过滤剂，以保护人皮肤或人类头发免受太阳光线的影响，单独或与在UV区域吸收的化合物一起，本身就是化妆品和药物制剂。

9. 发明授权

US06436373B1 Oligomeric diarylbutadienes 失效
标题翻译：低聚二芳基丁二烯
公开(公告)号：US06436373B1
公开(公告)日：2002-08-20
申请号：US09455484
申请日：1999-12-06
申请人： Thorsten Habeck , Thomas Wünsch , Horst Westenfelder
发明人： Thorsten Habeck , Thomas Wünsch , Horst Westenfelder
IPC分类号： A61K742
CPC分类号： A61Q17/04 , A61K8/40 , C07C69/618 , C07C255/41
摘要： Oligomeric 4,4-diarylbutadienecarboxylates and -carboxamides of the formula I in which R1 and R2 independently of one another are hydrogen, an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical or substituents which confer solubility in water, chosen from the group consisting of carboxylate, sulfonate or ammonium radicals; R3 is an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical or a radical which is bonded by a carbonyl, sulfonyl or a phosphonyl group, or is a carboxylate or a cyano group; Y is the group; in which R4 is hydrogen, an aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic radical and m is from 2 to 10, n is from 1 to 3, and x is the m-valent radical of a polyol having from 2 to 10 hydroxyl groups.
摘要翻译：式Iin的低聚4,4'-二芳基丁二羧酸酯和羧酰胺，其中R 1和R 2彼此独立地是氢，脂族，脂环族，芳族，芳脂族或杂环基或其在水中赋予溶解性的取代基，其选自羧酸酯，磺酰基或铵基; R 3是脂族，脂环族，芳族，芳脂族或杂环基或通过羰基，磺酰基或膦酰基键合或者是羧酸酯或氰基键合的基团; Y是基团;其中R 4 是氢，脂族，脂环族，芳族，芳脂族或杂环基团，且m为2至10，n为1至3，x为具有2至10个羟基的多元醇的m价基团。

10. 发明授权

US06413503B1 Use of cyclic enamines as light protection agents 失效
标题翻译：使用环状烯胺作为防晒剂
公开(公告)号：US06413503B1
公开(公告)日：2002-07-02
申请号：US09583288
申请日：2000-05-31
申请人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
发明人： Thorsten Habeck , Frank Prechtl , Thomas Wünsch , Horst Westenfelder
IPC分类号： A61K742
CPC分类号： A61K8/4946 , A61K8/49 , A61K8/494 , A61K2800/52 , A61Q1/04 , A61Q17/04
摘要： The use of compounds of the formula I in which R1 and R2 are identical or different, electron-withdrawing radicals chosen from the group consisting of cyano, alkyl- or arylcarbonyl, alkyloxy- or aryloxycarbonyl and optionally substituted aminocarbonyl, R3 is a hydrogen atom, a C1-C20-alkyl radical or a C3-C20-cycloalkyl radical or a radical of the formula —CH2-CH2—SO3—M+, where M+ is a cation, X is the divalent radical of oxygen, sulfur or the radical where R3 is as defined above, Z is the divalent radical of the formula II or III, which forms a fused system with the radical of the formula I where R4 can be bonded one or more times to the benzylidene ring I or naphthylidene ring II, and is hydrogen, alkyl, cycloalkyl, alkyloxy, cycloalkyloxy, alkoxycarbonyl, mono- or dialkylaminocarbonyl, alkylamino, dialkylamino, each having up to 20 carbon atoms, and also cyano, amino and SO3—M+, where M+ is a cation, as photostable UV filters in cosmetic and pharmaceutical preparations to protect human skin and human hair against solar rays, alone or together with compounds which absorb in the UV region and are known per se for cosmetic and pharmaceutical preparations.
摘要翻译：使用其中R 1和R 2相同或不同的式Iin化合物，选自氰基，烷基 - 或芳基羰基，烷氧基 - 或芳氧基羰基和任选取代的氨基羰基的吸电子基，R 3是氢原子，C 1 -C 20 - 烷基或C 3 -C 20环烷基或式-CH 2 -CH 2 -SO 3 -M +的基团，其中M +是阳离子，X是氧，硫或R3的二价基团，其中R 3为 Z是式II或III的二价基团，其与式I基团形成稠合体系，其中R4可以与亚苄基环I或亚萘基环II键合一次或多次，并且是氢，烷基，环烷基，烷氧基，环烷氧基，烷氧基羰基，单或二烷基氨基羰基，烷基氨基，二烷基氨基，各自具有至多20个碳原子，以及氰基，氨基和SO3-M +，其中M +是阳离子，作为化妆品中的光稳定性紫外线过滤器药物制剂保护人类亲和人类头发对抗太阳光线，单独或与在UV区域吸收的化合物一起，并且本身已知用于化妆品和药物制剂。

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