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41. 发明专利

IT1262949B Catalysts for the polymerisation of olefins 未知
公开(公告)号：IT1262949B
公开(公告)日：1996-07-22
申请号：ITMI921497
申请日：1992-06-18
申请人： RESCONI LUIGI , GALIMBERTI MAURIZIO , PIEMONTESI FABRIZIO , ALBIZZATI ENRICO
发明人： RESCONI LUIGI , GALIMBERTI MAURIZIO , PIEMONTESI FABRIZIO , ALBIZZATI ENRICO
IPC分类号： C08F20060101 , C08F
摘要： Catalysts for the polymerisation of olefins comprising the product of the reaction between: a) a substituted titanium, zirconium or hafnium cyclopentadienyl compound, and b) a product of the reaction between water and an aluminium alkyl in which at least one alkyl contains at least three carbon atoms, the aluminium alkyl/water ratio being greater than 2:1.

42. 发明专利

CA2008907A1 CATALYSTS FOR THE POLYMERIZATION OF OLEFINS 未知
公开(公告)号：CA2008907A1
公开(公告)日：1990-07-31
申请号：CA2008907
申请日：1990-01-30
申请人： RESCONI LUIGI , GIANNINI UMBERTO , ALBIZZATI ENRICO
发明人： RESCONI LUIGI , GIANNINI UMBERTO , ALBIZZATI ENRICO
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
摘要： Catalysts for the polymerization of olefins, obtained from special zirconocenic compounds and from alkyl-Al compounds.

43. 发明申请

WO2013007664A1 HETEROPHASIC COPOLYMERS 审中-公开
标题翻译：异构共聚物
公开(公告)号：WO2013007664A1
公开(公告)日：2013-01-17
申请号：PCT/EP2012/063332
申请日：2012-07-06
申请人： BOREALIS AG , HAFNER, Norbert , RESCONI, Luigi , GAHLEITNER, Markus , WANG, Jimgbo , CASTRO, Pascal , KULYABIN, Pavel Sergeevich , IZMER, Vyatcheslav , VOSKOBOYNIKOV, Alexander , KONONOVICH, Dmitry , VIRKKUNEN, Ville
发明人： HAFNER, Norbert , RESCONI, Luigi , GAHLEITNER, Markus , WANG, Jimgbo , CASTRO, Pascal , KULYABIN, Pavel Sergeevich , IZMER, Vyatcheslav , VOSKOBOYNIKOV, Alexander , KONONOVICH, Dmitry , VIRKKUNEN, Ville
IPC分类号： C08L23/12 , C08F2/00
CPC分类号： C07F7/0818 , C07C13/36 , C07C13/38 , C07C13/465 , C07C41/01 , C07F17/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/12 , C08L2207/02 , C08L2314/06 , C08L23/16 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A heterophasic polypropylene resin comprising a polypropylene homopolymer matrix phase (A) and an ethylene-propylene copolymer phase (B) dispersed within the matrix, wherein the xylene soluble fraction of the heterophasic polypropylene resin is in the range 20 to less than 50 wt%; the heterophasic polypropylene resin has an MFR2 of 0.01 to 50 g/10min; the ethylene content of the xylene soluble fraction of the heterophasic polypropylene resin is in the range of at least 20 wt% to less than 50 wt%; the heterophasic polypropylene resin has a notched charpy impact strength at -20C of at least 25 kJ/m 2 , preferably at least 50 kJ/m 2 ; and wherein the MFR 2 (Matrix)/MFR 2 (XS) ≥ 5, preferably ≥10.
摘要翻译：包含分散在基质内的聚丙烯均聚物基质相（A）和乙烯 - 丙烯共聚物相（B）的多相聚丙烯树脂，其中所述多相聚丙烯树脂的二甲苯可溶部分在20至小于50重量％的范围内; 多相聚丙烯树脂的MFR 2为0.01〜50g / 10min; 多相聚丙烯树脂的二甲苯可溶部分的乙烯含量在至少20重量％至小于50重量％的范围内; 多相聚丙烯树脂在-20℃下具有至少25kJ / m 2，优选至少50kJ / m 2的缺口夏比冲击强度; 并且其中MFR 2（Matrix）/ MFR 2（XS）= 5，优选= 10。

44. 发明申请

WO2012110351A1 SEALING PROPYLENE COPOLYMER 审中-公开
标题翻译：密封丙烯共聚物
公开(公告)号：WO2012110351A1
公开(公告)日：2012-08-23
申请号：PCT/EP2012/051993
申请日：2012-02-07
申请人： BOREALIS AG , REICHELT, Kristin , RESCONI, Luigi , PAAVILAINEN, Juha
发明人： REICHELT, Kristin , RESCONI, Luigi , PAAVILAINEN, Juha
IPC分类号： C08L23/14 , C08F297/08 , C08J5/18 , C08F210/06
CPC分类号： C08L23/14 , C08F2/001 , C08F4/65912 , C08J5/18 , C08L23/142 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C09D123/14 , C09D123/142 , C08L2666/06 , C08F210/16
摘要： Propylene copolymer composition comprising a propylene copolymer (A) having a comonomer content in the range of equal or more than 0.5 to equal or below 2.0 wt.-%, the comonomers are C5 to C12 α-olefins, and a propylene copolymer (B) having a comonomer content in the range of equal or more than 4.0 to equal or below 10.0 wt.-%, the comonomers are C5 to C12 α-olefins, wherein further the propylene copolymer composition has a comonomer content in the range of equal or more than 3.5 to equal or below 7.0 wt.-%, the comonomers are C5 to C12 α-olefins, and the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is in the range of 20/80 to below 55/45.
摘要翻译：包含丙烯共聚物（A）的丙烯共聚物组合物，其共聚单体含量在等于或大于等于或小于2.0重量％的范围内，共聚单体是C 5 -C 12α-烯烃，丙烯共聚物（B）共聚单体含量在等于或大于4.0至等于或低于10.0重量％的范围内，共聚单体是C 5 -C 12α-烯烃，其中丙烯共聚物组合物的共聚单体含量在等于或更大的范围内 3.5以上7.0重量％以下，共聚单体为C 5〜C 12α-烯烃，丙烯共聚物（A）与丙烯共聚物（B）的重量比为20/80〜 55/45。

45. 发明申请

WO2012001052A3 GROUP 4 METALLOCENES USEFUL AS CATALYST FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：第4组金属有助于烯烃聚合的催化剂
公开(公告)号：WO2012001052A3
公开(公告)日：2012-03-01
申请号：PCT/EP2011060921
申请日：2011-06-29
申请人： BOREALIS AG , CASTRO PASCAL , RESCONI LUIGI , HUHTANEN LAURI
发明人： CASTRO PASCAL , RESCONI LUIGI , HUHTANEN LAURI
IPC分类号： C07F17/00 , B01J31/12
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the ß-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the ß-atom to the cyclopentadienyl ring where the ß-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 groupeach R5 is the same or different and isa C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代。R 5相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基 ; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

46. 发明申请

WO2011135005A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2011135005A2
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056673
申请日：2011-04-27
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri , HAFNER, Norbert
发明人： RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri , HAFNER, Norbert
IPC分类号： C08F4/6592 , C08F110/06
CPC分类号： C08F4/76 , C08F4/6428 , C08F4/6592 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： A polypropylene homopolymer with a melting point of less than 147°C, a percentage of 2,1 errors of at least 1% and a xylene soluble fraction of less than 0.5 wt%.
摘要翻译：熔点小于147℃的聚丙烯均聚物，2,1误差百分比至少为1％，二甲苯可溶部分小于0.5重量％。

47. 发明申请

WO2011135004A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2011135004A2
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056672
申请日：2011-04-27
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
发明人： RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A solid, particulate catalyst comprising: (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 independently is a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; T 1 and T 4 , which can be the same or different, are an OR 2 , a SR 2 , CH(R 18 ) 2 , CH 2 R 18 , aryl or heteroaryl group; each R 2 , which can be the same or different, is a C1-C20 hydrocarbyl radical; each R 18 , which can be the same or different, is a C1-C20 hydrocarbyl radical or two R 18 groups together with the carbon atom to which they are attached may form a cyclic C4-C20 hydrocarbyl group; T 2 and T 3 , which may be the same or different, are a C(R 18 ) 3 group; W 1 and W 2 , which may be the same or different, are a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group; each R 5 , which can be the same or different, is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W 1 or W 2 , optionally substituted by one or two groups R 5 ; and (ii) a cocatalyst.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是任选地含有一个或多个第14-16族的杂原子的直链或支链C 1 -C 20烃基; T1和T4可以相同或不同，是OR2，SR2，CH（R18）2，CH2R18，芳基或杂芳基; 每个R 2可以相同或不同，是C 1 -C 20烃基; 每个R 18可以相同或不同，是C1-C20烃基或两个R18基团与它们所连接的碳原子一起形成环状C 4 -C 20烃基; T2和T3可以相同或不同，是C（R18）3基团; W1和W2可以相同或不同，是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5可以相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 并且任选地两个相邻的R5基团可以形成另外的稠合成W1或W2的单环或多环，任选地被一个或两个基团R 5取代; 和（ii）助催化剂。

48. 发明申请

WO2009115395A8 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115395A8
公开(公告)日：2010-10-07
申请号：PCT/EP2009052116
申请日：2009-02-23
申请人： BASELL POLIOLEFINE SRL , RESCONI LUIGI , BALBONI DAVIDE , ESPOSITO SIMONA
发明人： RESCONI LUIGI , BALBONI DAVIDE , ESPOSITO SIMONA
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, preferably at least 1- octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C8-C12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C8-C12 alpha-olefin molar content fulfil the following relationship: 0 8-C12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at 13C NMR.
摘要翻译：含有C-C 12α-烯烃的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元，优选至少1-辛烯衍生单元的共聚物，其含有0％-2％（摩尔）丙烯或戊烯，高于0.2％且低于7.2摩尔％的α-烯烃衍生单元; 具有以下特征：a）通过DSC（TmII）和C8-C12α-烯烃摩尔含量测量的熔点满足以下关系：0 8-C12α-烯烃衍生单元和TmII是在第二次熔融转变; b）在135℃四氢萘中测得的特性粘度（Ⅳ）在0.8和5dL / g之间; 和c）高于或等于90％的全同立构五单元组mmmm; 低于4的五单元组（mmrr + mrrm），在13 C NMR下不能检测到五单元组。

49. 发明申请

WO2008025721A1 1-BUTENE PROPYLENE COPOLYMER COMPOSITIONS 审中-公开
标题翻译： 1-BOTENE丙烯共聚物组合物
公开(公告)号：WO2008025721A1
公开(公告)日：2008-03-06
申请号：PCT/EP2007/058781
申请日：2007-08-23
申请人： Basell Polyolefine GmbH , PELLEGATTI, Giampaolo , BIGIAVI, Daniele , MARTELLI, Rita , TONTI, Maria Silvia , RESCONI, Luigi , GUIDOTTI, Simona
发明人： PELLEGATTI, Giampaolo , BIGIAVI, Daniele , MARTELLI, Rita , TONTI, Maria Silvia , RESCONI, Luigi , GUIDOTTI, Simona
IPC分类号： C08L23/20 , C08F210/08
CPC分类号： C08L23/20 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F210/06 , C08F210/08 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F4/65904 , C08F2/001 , C08L2666/06 , C08L2666/04 , C08F2500/15 , C08F2500/03
摘要： A 1-butene/propylene copolymer composition having a content of propylene derived units from 4 to 10% by weight, wherein at least 50% of the polymer is present in the thermodynamically stable, trigonal form I after 100 hours at room temperature, said composition comprising: a) from 5% by weight to 95% by weight of an atactic 1-butene propylene copolymer having the following features: i) distribution of molecular weight Mw/Mn equal to or lower than 4; ii) no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); and iii) infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene propylene copolymer having the following features: i) isotactic pentads (mmmm) measured by 13 C-NMR, higher than 80%; ii) melting point (Tm(II)) higher than 70°C; and iii) distribution of molecular weight Mw/Mn equal to or lower than 4.
摘要翻译：所述丙烯衍生单元含量为4-10重量％的1-丁烯/丙烯共聚物组合物，其中至少50％的聚合物在室温下100小时后以热力学稳定的三角形I存在，所述组合物包括：a）5重量％至95重量％的具有以下特征的无规立构1-丁烯丙烯共聚物：i）分子量Mw / Mn等于或低于4的分布; ii）在差示扫描量热计（DSC）处不可检测到融合焓; 和iii）红外结晶度低于0.5％; b）5重量％至95重量％的具有以下特征的全同立构1-丁烯丙烯共聚物：i）通过13 C-NMR测量的全同立构五单元组（mmmm）高于80％ ; ii）高于70℃的熔点（Tm（II））; 和iii）等于或低于4的分子量Mw / Mn的分布。

50. 发明申请

WO2007122098A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMERS 审中-公开
标题翻译：制备乙烯共聚物的方法
公开(公告)号：WO2007122098A1
公开(公告)日：2007-11-01
申请号：PCT/EP2007/053429
申请日：2007-04-06
申请人： BASELL POLYOLEFINE GMBH , FOCANTE, Francesca , RESCONI, Luigi
发明人： FOCANTE, Francesca , RESCONI, Luigi
IPC分类号： C08F210/16 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/08 , C08F2500/17
摘要： A polymerization process comprising contacting under polymerization conditions ethylene and at least one alpha olefin of fo rmu la CH2=CHA wherein A is a C 2 -C 20 alkyl radical to obtain a copolymer containing from 95% by mol to 50% by mol of ethylene derived units in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formu la (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 -R 4 , L, M and W are described in the text.
摘要翻译：一种聚合方法，包括在聚合条件下使乙烯和至少一种其中A为C 2 -C 20烷基的α-烯烃，其中A为C 2 -C 20烷基，共聚物在催化剂体系的存在下含有95摩尔％至50摩尔％的乙烯衍生单元，所述催化剂体系可以通过以下方式获得：b）至少一种式Ia（I）的茂金属化合物：铝氧烷或能够形成烷基茂金属阳离子; 和任选地c）有机铝化合物; 其中基团R 1 -R 4，L，M和W在文中描述。

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