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    • 2. 发明申请
    • SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES
    • 包含桥接金属的固体颗粒催化剂
    • WO2011135004A3
    • 2012-10-04
    • PCT/EP2011056672
    • 2011-04-27
    • BOREALIS AGRESCONI LUIGICASTRO PASCALHUHTANEN LAURI
    • RESCONI LUIGICASTRO PASCALHUHTANEN LAURI
    • C08F10/00C08F4/6592
    • C08F4/65927C08F4/65912C08F10/00C08F110/06Y10S526/943C08F2500/12C08F2500/15C08F2500/17
    • A solid, particulate catalyst comprising: (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 independently is a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; T1 and T4, which can be the same or different, are an OR2, a SR2, CH(R18)2, CH2R18, aryl or heteroaryl group; each R2, which can be the same or different, is a C1-C20 hydrocarbyl radical; each R18, which can be the same or different, is a C1-C20 hydrocarbyl radical or two R18 groups together with the carbon atom to which they are attached may form a cyclic C4-C20 hydrocarbyl group; T2 and T3, which may be the same or different, are a C(R18 )3 group; W1 and W2, which may be the same or different, are a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5, which can be the same or different, is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W1 or W2, optionally substituted by one or two groups R5; and (ii) a cocatalyst.
    • 一种固体颗粒催化剂,其包含:(i)式(I)的络合物,其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-,-R'2C-CR'2-,-R'2Si-,-R'2Si-SiR'2-,-R'2Ge-的二价桥,其中每个R' 独立地为氢原子,C 1 -C 20烷基,三(C 1 -C 20 - 烷基)甲硅烷基,C 6 -C 20 - 芳基,C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是任选地含有一个或多个第14-16族的杂原子的直链或支链C 1 -C 20烃基; T1和T4可以相同或不同,是OR2,SR2,CH(R18)2,CH2R18,芳基或杂芳基; 每个R 2可以相同或不同,是C 1 -C 20烃基; 每个R 18可以相同或不同,是C1-C20烃基或两个R18基团与它们所连接的碳原子一起形成环状C 4 -C 20烃基; T2和T3可以相同或不同,是C(R18)3基团; W1和W2可以相同或不同,是5或6元芳基或杂芳基环,其中所述环的每个原子任选被R 5基团取代; 每个R 5可以相同或不同,是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 并且任选地两个相邻的R5基团可以形成另外的稠合成W1或W2的单环或多环,任选地被一个或两个基团R 5取代; 和(ii)助催化剂。
    • 3. 发明申请
    • CATALYSTS
    • 催化剂
    • WO2012001052A2
    • 2012-01-05
    • PCT/EP2011/060921
    • 2011-06-29
    • BOREALIS AGCASTRO, PascalRESCONI, LuigiHUHTANEN, Lauri
    • CASTRO, PascalRESCONI, LuigiHUHTANEN, Lauri
    • C07F17/00B01J31/12
    • C08F4/65912C07F17/00C08F4/65927C08F110/06Y10S526/943C08F2500/03C08F2500/12
    • A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R 18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 .
    • 式(I)的络合物:其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-,-R'2C-CR'2-,-R'2Si-,-R'2Si-SiR'2-,-R'2Ge-的二价桥,其中每个R' 独立地为氢原子,C 1 -C 20烃基,三(C 1 -C 20烷基)甲硅烷基,C 6 -C 20 - 芳基,C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基,任选地含有一个或多个属于第14-16族的杂原子,或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基 其中β原子是Si原子; n为0-3; 每个R 18相同或不同,并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环,其中所述环的每个原子任选被R 5基团取代。R 5相同或不同,是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基 ; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。
    • 5. 发明申请
    • PROCESS FOR OLEFIN POLYMERIZATION
    • 烯烃聚合方法
    • WO2011058091A1
    • 2011-05-19
    • PCT/EP2010/067268
    • 2010-11-11
    • BOREALIS AGAUMO, JeannetteMATIKAINEN, PasiBARTKE, MichaelELOVIRTA, TomVIJAY, SameerLYLYKANGAS, MikkoELO, PerttiHUHTANEN, Lauri
    • AUMO, JeannetteMATIKAINEN, PasiBARTKE, MichaelELOVIRTA, TomVIJAY, SameerLYLYKANGAS, MikkoELO, PerttiHUHTANEN, Lauri
    • C08F10/00C08F4/659
    • C08F10/00C08F110/06C08F2410/01C08F4/65912C08F4/65927C08F2/00C08F2500/12C08F4/6492
    • The present invention aims to provide a process for polymerizing at least one olefin in the presence of a polymerization catalyst comprising the steps of: (A) continuously introducing a first liquid comprising a transition metal compound, an organometallic compound of a metal of Group 13 of Periodic System of Elements and a solvent, and a second liquid which together with said first liquid is capable of forming an emulsion, into an emulsification stage to produce an emulsion comprising said first liquid dispersed in said second liquid; (B) continuously withdrawing an emulsion stream from said emulsification stage and directing it into a solidification stage to form a slurry comprising a solid polymerization catalyst component comprising said transition metal compound and said organometallic compound suspended in said second liquid; (C) continuously recovering said solid polymerization catalyst component from said solidification stage; (D) directing said solid polymerization catalyst component into a first prepolymerization stage together with a monomer and an amount of second liquid wherein the monomer is prepolymerized onto said solid polymerization catalyst component so that the ratio of the weight of the polymer to the weight of said solid polymerization catalyst component is from 0.1:1 to 20:1 to form a slurry of a prepolymerized solid polymerization catalyst component suspended in said second liquid; (E) recovering said prepolymerized solid polymerization catalyst component from said first prepolymerization stage; (F) continuously introducing said prepolymerized solid polymerization catalyst component into a second prepolymerization stage together with an olefin monomer to form a prepolymerized catalyst comprising in average 100 to 1000 g of polymer per 1 gram of said solid polymerization catalyst component; (G) continuously withdrawing said prepolymerized catalyst from said second prepolymerization stage and directing it into a subsequent polymerization stage together with at least one olefin monomer to effect polymerization of the at least one olefin monomer in the presence of said prepolymerized catalyst. The polymerization process produces polymers in high yield. The morphology of the polymer powder is good and the amount of fine particle polymer is low. The process can be operated for long a long period in a stable manner.
    • 本发明的目的在于提供一种在聚合催化剂存在下聚合至少一种烯烃的方法,包括以下步骤:(A)连续引入包含过渡金属化合物的第一液体,第13族金属的有机金属化合物 元素周期性系统和溶剂,以及与所述第一液体一起能够形成乳液的第二液体进入乳化阶段以产生包含分散在所述第二液体中的所述第一液体的乳液; (B)从所述乳化阶段连续抽出乳液流并将其导入固化阶段以形成包含悬浮在所述第二液体中的包含所述过渡金属化合物和所述有机金属化合物的固体聚合催化剂组分的浆料; (C)从所述固化阶段连续回收所述固体聚合催化剂组分; (D)将所述固体聚合催化剂组分与单体和一定量的第二液体一起引导到第一预聚合阶段,其中所述单体预聚合到所述固体聚合催化剂组分上,使得所述聚合物的重量与所述 固体聚合催化剂组分为0.1:1至20:1,以形成悬浮在所述第二液体中的预聚合固体聚合催化剂组分的浆液; (E)从所述第一预聚合阶段回收所述预聚固体聚合催化剂组分; (F)将所述预聚合的固体聚合催化剂组分连同烯烃单体一起连续引入第二预聚合阶段,以形成预聚合的催化剂,每克所述固体聚合催化剂组分平均含有100至1000克聚合物; (G)从所述第二预聚合阶段连续地抽出所述预聚合催化剂,并将其引导至随后的聚合阶段与至少一种烯烃单体,以在所述预聚合的催化剂存在下进行至少一种烯烃单体的聚合。 聚合过程以高产率生产聚合物。 聚合物粉末的形态好,微粒聚合物的量低。 该方法可以长时间稳定运行。
    • 9. 发明申请
    • GROUP 4 METALLOCENES USEFUL AS CATALYST FOR THE POLYMERIZATION OF OLEFINS
    • 第4组金属有助于烯烃聚合的催化剂
    • WO2012001052A3
    • 2012-03-01
    • PCT/EP2011060921
    • 2011-06-29
    • BOREALIS AGCASTRO PASCALRESCONI LUIGIHUHTANEN LAURI
    • CASTRO PASCALRESCONI LUIGIHUHTANEN LAURI
    • C07F17/00B01J31/12
    • C08F4/65912C07F17/00C08F4/65927C08F110/06Y10S526/943C08F2500/03C08F2500/12
    • A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R'2C-, -R'2C-CR'2-, -R'2Si-, -R'2Si-SiR'2-, -R'2Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the ß-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the ß-atom to the cyclopentadienyl ring where the ß-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 groupeach R5 is the same or different and isa C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
    • 式(I)的络合物:其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-,-R'2C-CR'2-,-R'2Si-,-R'2Si-SiR'2-,-R'2Ge-的二价桥,其中每个R' 独立地为氢原子,C 1 -C 20烃基,三(C 1 -C 20烷基)甲硅烷基,C 6 -C 20 - 芳基,C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基,任选地含有一个或多个属于第14-16族的杂原子,或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基 其中β原子是Si原子; n为0-3; 每个R 18相同或不同,并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环,其中所述环的每个原子任选被R 5基团取代。R 5相同或不同,是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基 ; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。