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1. 发明申请

WO2007116034A1 METALLOCENE COMPOUNDS 审中-公开
标题翻译：金属化合物
公开(公告)号：WO2007116034A1
公开(公告)日：2007-10-18
申请号：PCT/EP2007/053422
申请日：2007-04-06
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , FOCANTE, Francesca , BALBONI, Davide , NIFANT'EV, Ilya E. , IVCHENKO, Pavel V. , BAGROV, Vladimir
发明人： RESCONI, Luigi , FOCANTE, Francesca , BALBONI, Davide , NIFANT'EV, Ilya E. , IVCHENKO, Pavel V. , BAGROV, Vladimir
IPC分类号： C07F17/00 , C07F7/08 , C08F10/00 , C08F4/64
CPC分类号： C07F17/00 , C07F7/0812 , C07F7/0818 , C08F4/65912 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65927 , C08F210/16 , C08F2500/15 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F210/14 , C08F210/08
摘要： A bridged metallocene compound of formula (I) wherein: M is a transition metal; X, is a hydrogen atom, a halogen atom, or a hydrocarbon group optionally containing heteroatoms; L is a divalent bridging group; R 1 is a linear C 1 -C 40 hydrocarbon radical optionally containing heteroatoms; T 1 and T 4 are a oxygen, sulfur atom or a C(R 18 ) 3 group; wherein R 18 , are hydrogen atoms or a C 1 -C 40 hydrocarbon radical; T 3 and T 4 are C 1 -C 40 hydrocarbon radicals; R 4 is a hydrogen atom or a C 1 -C 40 hydrocarbon radical; W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥连茂金属化合物，其中：M是过渡金属; X是氢原子，卤原子或任选含有杂原子的烃基; L是二价桥基; R 1是任选地含有杂原子的直链C 1 -C 40烃基; T 1和T 4是氧，硫原子或C（R 18）3 N 3基团; 其中R 18是氢原子或C 1 -C 40烃基; T 3和T 4是C 1 -C 40烃基; R 4是氢原子或C 1 -C 40烃基; W是芳族5或6元环。

2. 发明申请

WO2006134046A1 PROCESS FOR THE COPOLYMERIZATION OF PROPYLENE 审中-公开
标题翻译：丙烯共聚方法
公开(公告)号：WO2006134046A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/062964
申请日：2006-06-07
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , CIACCIA, Eleonora , FOCANTE, Francesca
发明人： RESCONI, Luigi , CIACCIA, Eleonora , FOCANTE, Francesca
IPC分类号： C08F210/06 , C08F4/6592
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F210/06 , C08F2/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A solution polymerization process comprising contacting under polymerization conditions propylene and at least ethylene or an alpha olefin of formula CH 2 =CHT wherein T is a C 2 -C 20 alkyl radical, in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 R 4 , L, M and W are described in the text.
摘要翻译：一种溶液聚合方法，包括在聚合条件下接触丙烯和至少乙烯或式CH 2 CH 2的α烯烃，其中T是C 2 -C 20 在通过使b）至少一种式（I）的茂金属化合物b）铝氧烷或能够形成烷基金属茂阳离子的化合物可以得到的催化剂体系的存在下，和任选地c）有机铝化合物; 其中基团R 1，R 4，L，M和W在文中描述。

3. 发明申请

WO2007122098A1 PROCESS FOR THE PREPARATION OF ETHYLENE COPOLYMERS 审中-公开
标题翻译：制备乙烯共聚物的方法
公开(公告)号：WO2007122098A1
公开(公告)日：2007-11-01
申请号：PCT/EP2007/053429
申请日：2007-04-06
申请人： BASELL POLYOLEFINE GMBH , FOCANTE, Francesca , RESCONI, Luigi
发明人： FOCANTE, Francesca , RESCONI, Luigi
IPC分类号： C08F210/16 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/08 , C08F2500/17
摘要： A polymerization process comprising contacting under polymerization conditions ethylene and at least one alpha olefin of fo rmu la CH2=CHA wherein A is a C 2 -C 20 alkyl radical to obtain a copolymer containing from 95% by mol to 50% by mol of ethylene derived units in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formu la (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 -R 4 , L, M and W are described in the text.
摘要翻译：一种聚合方法，包括在聚合条件下使乙烯和至少一种其中A为C 2 -C 20烷基的α-烯烃，其中A为C 2 -C 20烷基，共聚物在催化剂体系的存在下含有95摩尔％至50摩尔％的乙烯衍生单元，所述催化剂体系可以通过以下方式获得：b）至少一种式Ia（I）的茂金属化合物：铝氧烷或能够形成烷基茂金属阳离子; 和任选地c）有机铝化合物; 其中基团R 1 -R 4，L，M和W在文中描述。

4. 发明申请

WO2007122097A1 PROCESS FOR THE PREPARATION OF ETHYLENE PROPYLENE COPOLYMERS 审中-公开
标题翻译：制备乙烯丙烯共聚物的方法
公开(公告)号：WO2007122097A1
公开(公告)日：2007-11-01
申请号：PCT/EP2007/053424
申请日：2007-04-06
申请人： Basell Polyolefine GmbH , RESCONI, Luigi , FOCANTE, Francesca
发明人： RESCONI, Luigi , FOCANTE, Francesca
IPC分类号： C08F210/06 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/06 , C08F2500/17
摘要： A polymerization process comprising contacting under polymerization conditions ethylene and at least propylene to obtain a copolymer containing from 96% by mol to 71% by mol of ethylene derived units, in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I), b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R 1 -R 4 , L, M and W are described in the text.
摘要翻译：一种聚合方法，包括在聚合条件下使乙烯和至少丙烯接触，以获得含有衍生自乙烯的单元的96摩尔％至71摩尔％的乙烯衍生单元的共聚物，所述催化剂体系可以通过以下方式获得：b）至少一种茂金属式（I）化合物，b）铝氧烷或能够形成烷基金属茂阳离子的化合物; 和任选地c）有机铝化合物; 其中基团R 1 -R 4，L，M和W在文中描述。

5. 发明申请

WO2007107448A1 METALLOCENE COMPOUNDS 审中-公开
标题翻译：金属化合物
公开(公告)号：WO2007107448A1
公开(公告)日：2007-09-27
申请号：PCT/EP2007/052056
申请日：2007-03-05
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , NIFANT'EV, Ilya E. , IVCHENKO, Pavel V. , BAGROV, Vladimir , FOCANTE, Francesca , MOSCARDI, Gilberto
发明人： RESCONI, Luigi , NIFANT'EV, Ilya E. , IVCHENKO, Pavel V. , BAGROV, Vladimir , FOCANTE, Francesca , MOSCARDI, Gilberto
IPC分类号： C07F17/00 , C07F7/08 , C08F10/00 , C08F4/62
CPC分类号： C07F17/00 , C07F7/0859 , C07F7/0861 , C08F4/65912 , C08F10/00 , C08F210/06 , C08F4/65927 , C08F210/16 , C08F2500/17
摘要： A bridged metallocene compound of formula (I) wherein: M is an atom of a transition metal selected from those belonging to group 3, 4, or to the lanthanide or actinide groups in the Periodic Table of the Elements; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group; L is a divalent bridging group; R 1 and R 2 , equal to each other, are C 1 -C 40 h ydrocarbon radical; R3 is hydrogen o r a are C 1 -C 40 hydrocarbon radical and W is an aromatic 5 or 6 membered ring.
摘要翻译：式（I）的桥接金属茂化合物，其中：M是选自族3,4中的过渡金属的原子，或元素周期表中的镧系元素或锕系元素基团; X，相同或不同的是氢原子，卤素原子，R，OR，OSO 2，CF 3，OCOR，SR，NR _{2 或PR <2> 组; L是二价桥基; R 1和R 2彼此相同，为C 1 -C 40烷基; R 3是氢，a是C 1 -C 40烃基，W是芳族5或6元环。}

6. 发明申请

WO2004005360A2 CATALYST SYSTEM FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2004005360A2
公开(公告)日：2004-01-15
申请号：PCT/EP2003/007485
申请日：2003-07-09
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , FOCANTE, Francesca , CAMURATI, Isabella , GUIDOTTI, Simona
发明人： RESCONI, Luigi , FOCANTE, Francesca , CAMURATI, Isabella , GUIDOTTI, Simona
IPC分类号： C08F10/00
CPC分类号： C07F5/027 , C08F4/65912 , C08F4/65925 , C08F10/00 , C08F110/02 , C08F4/65908
摘要： An organometallic compound obtainable by contacting: a compound having the following formula (I), wherein: R a is a hydrocarbon radical; R b , R ° and R d , are hydrogen atoms, halogen atoms, or hydrocarbon radicals; with a Lewis acid of formula (II) MtR 1 3 (II) wherein Mt is a metal belonging to Group 13 of the Periodic Table of the Elements; R l are selected from the group consisting of halogen atoms, halogenated C 6- C 20 aryl and halogenated C 7 -C 20 alkylaryl groups.
摘要翻译：通过使具有下式（I）的化合物接触而获得的有机金属化合物，其中：R a是烃基; R b，R o和R d分别是氢原子，卤素原子或烃基; 与式（II）的路易斯酸MtR 1（II）其中Mt是属于元素周期表第13族的金属; R 1选自卤素原子，卤代C 6 -C 20芳基和卤代C 7 -C 20烷基芳基。

7. 发明申请

WO2006117285A1 PROCESS FOR THE POLYMERIZATION OF ALPHA OLEFINS 审中-公开
标题翻译： ALPHA OLEFINS聚合方法
公开(公告)号：WO2006117285A1
公开(公告)日：2006-11-09
申请号：PCT/EP2006/061545
申请日：2006-04-12
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
发明人： RESCONI, Luigi , GUIDOTTI, Simona , SANTORIELLO, Iolanda
IPC分类号： C08F10/00 , C08F4/6592 , C07F17/00 , C07F7/08
CPC分类号： C07F7/0818 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/06 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2/02 , C08F2500/17 , C08F210/16
摘要： A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CHT 2 =CHT wherein T is a C 3 -C 10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a a hydrocarbon radical, optionally containing heteroatoms; R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , R 11 , R 12 and R 13 are hydrogen atoms, or C 1 -C 4O hydrocarbon radicals optionally containing heteroatoms; R 1 , R 2 and R 3 , are linear or branched, C 1 -C 2o -alkyl radicals, optionally containing heteroatoms; B) a Jumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.
摘要翻译：一种制备1-丁烯聚合物的方法，包括将1-丁烯或1-丁烯与乙烯，丙烯或式CHT 2 CH = CHT的α-烯烃聚合，其中T是C 3 在可以通过下述方法获得的催化剂体系存在下进行：A）属于式（I）的茂金属化合物：其中M是锆钛或铪; X，彼此相同或不同，是氢原子，卤素原子，烃基，任选地含有杂原子; R 4，R 5，R 6，R 7，R 8， R 9，R 10，R 11，R 12和R 13是氢原子或任选含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的C 1 -C 2 O 任选地含有杂原子的烷基; B）可以形成烷基茂金属阳离子的Jumoxane或化合物; 和任选的C）有机铝化合物。

8. 发明申请

WO2006005648A1 METALLOCENE COMPOUNDS, LIGANDS USED IN THEIR PREPARATION, PREPARATION OF 1-BUTENE POLYMERS AND 1-BUTENE POLYMERS THEREFROM 审中-公开
标题翻译：金属化合物，其制备中使用的配体，1-丁烯聚合物的制备和其中的1-保加利亚聚合物
公开(公告)号：WO2006005648A1
公开(公告)日：2006-01-19
申请号：PCT/EP2005/052486
申请日：2005-05-31
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , MORHARD, Friederike
发明人： RESCONI, Luigi , MORHARD, Friederike
IPC分类号： C08F10/08
CPC分类号： C07D495/04 , C07D333/78 , C07F7/08 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/08 , C08F210/08 , C08F2420/06 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F210/16 , C08F210/06 , C08F210/14
摘要： A process for preparing 1-butene polymers comprising polymerizing 1-butene and optionally ethylene, propylene or higher alpha-olefin, in the présence of a catalyst system obtainable by contacting: a) metallocene compound of formula (I): wherein: M is a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent CI - C40 hydrocarbon radical; R 1 is a C 1 -C 40 hydrocarbon radical; T', is a moiety of formula (Ha) or (IIb): wherein R 2 and R 3 , are C 1 -C 40 hydrocarbon radicals or they can form together a C 3 -C 7 membered ring; R 4 is C 1 -C 40 hydrocarbon radicals; T 2 and T 3 , are a moiety of formula (IIla) wherein R 6 and R 7 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a hydrogen atom or a C 1 -C 40 hydrocarbon radicals; with the proviso that if T 1 is a moiety of formula (Ila) at least one between T 2 and T 3 is a moiety of formula (I1Tb), and if T 1 is a moiety of formula (IIb) at least one between T 2 and T 3 is a moiety of formula (IIIa); b) at least an alumoxane or a compound able to form an alkylmetallocene cation
摘要翻译：一种制备1-丁烯聚合物的方法，其包括聚合1-丁烯和任选的乙烯，丙烯或更高级的α-烯烃，催化剂体系可通过使下列物质接触而获得：a）式（I）的茂金属化合物：其中：M为过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是二价Cl

9. 发明申请

WO2005105865A1 PROCESS FOR THE PREPARATION OF ATACTIC 1-BUTENE POLYMERS 审中-公开
标题翻译：制备单层1-丁烯聚合物的方法
公开(公告)号：WO2005105865A1
公开(公告)日：2005-11-10
申请号：PCT/EP2005/004506
申请日：2005-04-25
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi , GUIDOTTI, Simona
发明人： RESCONI, Luigi , GUIDOTTI, Simona
IPC分类号： C08F10/08
CPC分类号： C08F10/08 , C08F4/65912 , C08F110/08 , C08F210/02 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F210/06 , C08F210/16
摘要： A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2=CHR, wherein R is a linear or branched C3-C 20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C 1 -C 40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R' and R 2 , are C 1 -C 40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (Ilb) wherein R 3 is a C I -C 40 hydrocarbon radical; R 4 and R 6 , are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; R 5 is a C I -C 40 hydrocarbon radical; R 7 and R 8 , equal to or different from each other, are hydrogen atoms or C 1 -C 40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：获得任选含有选自乙烯，丙烯或式CH 2 = CHR的α-烯烃的至少一种共聚单体的无规性1-丁烯聚合物的方法，其中R是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃在催化剂体系的存在下，可通过以下步骤获得： - ）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R'和R 2是C1-C40烃基; T为相同或不同的式（IIa）或（IIb）的部分，其中R 3为C 1 -C 40烃基; R 4和R 6是氢原子或C 1 -C 40烃基; R 5是C 1 -C 40烃基; R 7和R 8彼此相同或不同，是氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

10. 发明申请

WO2002100908A1 PROCESS FOR THE POLYMERIZATION OF 1-BUTENE 审中-公开
标题翻译： 1-BOTENE聚合方法
公开(公告)号：WO2002100908A1
公开(公告)日：2002-12-19
申请号：PCT/EP2002/006574
申请日：2002-06-11
申请人： BASELL POLYOLEFINE GMBH , RESCONI, Luigi
发明人： RESCONI, Luigi
IPC分类号： C08F10/08
CPC分类号： C08F110/08 , C08F4/65912 , C08F10/08 , C08F210/08 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/17 , C08F2500/12 , C08F2500/15 , C08F2500/20 , C08F2500/03 , C08F210/16
摘要： A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridget metallocene compound of formula (I) wherein R 1 and R 2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 , wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxigen (O) or sulphur (S) atom or a CH 2 group; and R 3 and R 4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminium compound.
摘要翻译：一种聚合1-丁烯的方法，包括在聚合条件下使1-丁烯和任选的0至20摩尔％的α-烯烃与可通过使式（I）的桥连金属茂化合物（其中R 1， 1>和R 2是烃基A是碳原子，锗原子或硅原子; m为1,2; M是元素周期表第4族的金属; X是氢，卤素原子或基团R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2，其中取代基R是烃基; L是式（IIa）或（IIb）的部分，其中T是氧原子（O）或硫（S）原子或CH 2基团; R 3和R 4是氢原子或烃基; 一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物; 和任选的有机铝化合物。

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