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1. 发明申请

WO2012001052A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2012001052A2
公开(公告)日：2012-01-05
申请号：PCT/EP2011/060921
申请日：2011-06-29
申请人： BOREALIS AG , CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
发明人： CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
IPC分类号： C07F17/00 , B01J31/12
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R 18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C 1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 .
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代。R 5相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基 ; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

2. 发明申请

WO2011135005A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2011135005A2
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056673
申请日：2011-04-27
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri , HAFNER, Norbert
发明人： RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri , HAFNER, Norbert
IPC分类号： C08F4/6592 , C08F110/06
CPC分类号： C08F4/76 , C08F4/6428 , C08F4/6592 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： A polypropylene homopolymer with a melting point of less than 147°C, a percentage of 2,1 errors of at least 1% and a xylene soluble fraction of less than 0.5 wt%.
摘要翻译：熔点小于147℃的聚丙烯均聚物，2,1误差百分比至少为1％，二甲苯可溶部分小于0.5重量％。

3. 发明申请

WO2011135004A2 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2011135004A2
公开(公告)日：2011-11-03
申请号：PCT/EP2011/056672
申请日：2011-04-27
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
发明人： RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A solid, particulate catalyst comprising: (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR' 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 independently is a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16; T 1 and T 4 , which can be the same or different, are an OR 2 , a SR 2 , CH(R 18 ) 2 , CH 2 R 18 , aryl or heteroaryl group; each R 2 , which can be the same or different, is a C1-C20 hydrocarbyl radical; each R 18 , which can be the same or different, is a C1-C20 hydrocarbyl radical or two R 18 groups together with the carbon atom to which they are attached may form a cyclic C4-C20 hydrocarbyl group; T 2 and T 3 , which may be the same or different, are a C(R 18 ) 3 group; W 1 and W 2 , which may be the same or different, are a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group; each R 5 , which can be the same or different, is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W 1 or W 2 , optionally substituted by one or two groups R 5 ; and (ii) a cocatalyst.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是任选地含有一个或多个第14-16族的杂原子的直链或支链C 1 -C 20烃基; T1和T4可以相同或不同，是OR2，SR2，CH（R18）2，CH2R18，芳基或杂芳基; 每个R 2可以相同或不同，是C 1 -C 20烃基; 每个R 18可以相同或不同，是C1-C20烃基或两个R18基团与它们所连接的碳原子一起形成环状C 4 -C 20烃基; T2和T3可以相同或不同，是C（R18）3基团; W1和W2可以相同或不同，是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5可以相同或不同，是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 并且任选地两个相邻的R5基团可以形成另外的稠合成W1或W2的单环或多环，任选地被一个或两个基团R 5取代; 和（ii）助催化剂。

4. 发明申请

WO2012001051A1 PROCESS FOR OLEFIN POLYMERISATION USING GROUP 4 METALLOCENE AS CATALYSTS 审中-公开
标题翻译：使用第4组金属催化剂进行烯烃聚合的方法
公开(公告)号：WO2012001051A1
公开(公告)日：2012-01-05
申请号：PCT/EP2011/060920
申请日：2011-06-29
申请人： BOREALIS AG , CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
发明人： CASTRO, Pascal , RESCONI, Luigi , HUHTANEN, Lauri
IPC分类号： C07F17/00 , C08F4/64 , C08F10/06
CPC分类号： C08F4/6592 , C08F4/65912 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F2500/12 , C08F2500/03 , C08F4/65927
摘要： A process for the preparation of a random propylene copolymer comprising polymerising propylene and at least one C2-10 alpha olefin (especially ethylene) in the presence of a catalyst; wherein said catalyst comprises: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R 18 is the same or different and may be a C1 -C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R 4 is a hydrogen atom or a C1-6 -hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group; each R 5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 ; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种制备无规丙烯共聚物的方法，包括在催化剂存在下聚合丙烯和至少一种C 2-10α-烯烃（特别是乙烯）; 其中所述催化剂包括：（i）式（I）的络合物：其中M是锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR2-，-R'2Ge-的二价桥，其中每个R'独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20芳基，C 7 -C 20芳基烷基或C 7 -C 20烷基芳基; 每个R 1是在β原子处与环戊二烯基环支链的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β原子处支化至环戊二烯基的C 3 -C 20烃基其中β原子是Si原子; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环稠合成可任选地被一个或两个基团R 5取代的W 1; 和（ii）包含第13族金属的有机金属化合物的助催化剂。

5. 发明申请

WO2011076780A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：WO2011076780A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/070354
申请日：2010-12-21
申请人： BOREALIS AG , RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
发明人： RESCONI, Luigi , CASTRO, Pascal , HUHTANEN, Lauri
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F2500/12 , C08F2500/15
摘要： A solid particulate catalyst free from an external carrier comprising (i) a complex of Formula (I), wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from -R' 2 C-, -R' 2 C-CR' 2 -, -R' 2 Si-, -R' 2 Si-SiR 2 -, -R' 2 Ge-, wherein each R' is independently a hydrogen atom, Cl-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R 1 independently is hydrogen or a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14- 16 of the Periodic Table of the Elements; each R 2 and R 3 taken together form a 4-7 membered ring condensed to the benzene ring of the indenyl moiety, said ring optionally containing heteroatoms from groups 14-16, each atom forming said ring being optionally substituted with at least one R 18 radical; each R 18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16 each R 4 is a hydrogen atom or a C 1 - 6 -hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each W is independently a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R 5 group; each R 5 is the same of different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R 5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R 5 ; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal, preferably aluminoxane.
摘要翻译：不含外部载体的固体颗粒催化剂，其包含（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR2-，-R'2Ge-的二价桥，其中每个R'独立地为氢原子，C 1 -C 20 - 烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是氢或任选地含有元素周期表第14-16族的一个或多个杂原子的直链或支链C 1 -C 20烃基; 每个R 2和R 3一起形成4-烯基部分的苯环稠合的4-7元环，所述环任选地含有14-16个杂原子，形成所述环的每个原子任选被至少一个R 18基团取代; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于基团14-16的杂原子的C 1 -C 20烃基，每个R 4是氢原子或任选含有一个或多个属于组14-16; 每个W独立地是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5是不同的，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环稠合成可任选地被一个或两个基团R 5取代的W 1; 和（ii）包含第13族金属的有机金属化合物，优选铝氧烷的助催化剂。

6. 发明申请

WO2011076617A1 PREPARATION OF SINGLE-SITE CATALYSTS 审中-公开
标题翻译：单壁催化剂的制备
公开(公告)号：WO2011076617A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/069633
申请日：2010-12-14
申请人： BOREALIS AG , DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
发明人： DENIFL, Peter , CASTRO, Pascal , RAUTIO, Soile , HUHTANEN, Lauri , OKSMAN, Marita , MUSTONEN, Marja
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F2410/01 , C08F4/65912
摘要： The formula (II) is (formula (II)) wherein R 1 is a semi-, highly- or perfluorinated hydrocarbon residue, and R 2 is a residue selected from the group consisting of -C(R 3 )=C(R 3' )-R 4 , wherein R 3 , R 4 , R 3' , are independently from each other selected from the group consisting of H, C 1 to C 20 alkyl, C 2 to C 20 alkenyl, C 2 to C 20 alkinyl.
摘要翻译：式（II）是（式（II）），其中R 1是半，高度或全氟化的烃残基，R 2是选自-C（R 3）= C（R 3'）-R 4 其中R3，R4，R3'彼此独立地选自H，C1至C20烷基，C2至C20烯基，C2至C20炔基。

7. 发明申请

WO2011076443A1 PREPARATION OF POLYPROPYLENE IN THE PRESENCE OF A SINGLE-SITE CATALYST 审中-公开
标题翻译：单壁催化剂存在下聚丙烯的制备
公开(公告)号：WO2011076443A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/058433
申请日：2010-06-16
申请人： BOREALIS AG , HUHTANEN, Lauri , KALLIO, Kalle , CASTRO, Pascal
发明人： HUHTANEN, Lauri , KALLIO, Kalle , CASTRO, Pascal
IPC分类号： C08F10/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65927 , C08F110/06 , C08F4/65912
摘要： Process for the preparation of a polypropylene, wherein propylene is polymerised optionally with a comonomer selected from the group consisting of ethylene, a C 4 -C 20 α-olefin and mixtures thereof, in the presence of a catalyst system comprising solid catalyst particles, wherein the solid catalyst particles (a) comprise a transition metal compound of formula (I) L m R n MX q (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), each "R" is a bridging group linking two organic ligands (L), "m" is 2 or 3, preferably 2, "n" is 0, 1 or 2, preferably 1, "q" is 1, 2 or 3, preferably 2, m+q is equal to the valency of the transition metal (M), (c) comprise a cocatalyst (Co) comprising an element (E) of group 13 of the periodic table (IUPAC), preferably a cocatalyst (Co) comprising a compound of Al, wherein further the loss of activity of the solid catalyst particles during polymerization is at most 20 %.
摘要翻译：制备聚丙烯的方法，其中在包含固体催化剂颗粒的催化剂体系的存在下，丙烯任选地与选自乙烯，C 4 -C 20α-烯烃及其混合物的共聚单体聚合，其中固体催化剂颗粒（a）包含式（I）的过渡金属化合物LmRnMXq（I）其中“M”是周期表（IUPAC）的第3至10族中的任何一个的过渡金属，每个“X”独立地为每个“L”独立地是与过渡金属（M）配位的有机配体，每个“R”是连接两个有机配体（L）的桥连基团，“m”是2或3，优选 2，“n”为0,1或2，优选为1，“q”为1,2或3，优选2，m + q等于过渡金属（M）的化合价，（c）包含助催化剂（Co），其包含元素周期表第13族元素（IUPAC），优选包含Al的化合物的助催化剂（Co），其中f 聚合过程中固体催化剂颗粒的活性降低至多20％。

8. 发明申请

WO2011058091A1 PROCESS FOR OLEFIN POLYMERIZATION 审中-公开
标题翻译：烯烃聚合方法
公开(公告)号：WO2011058091A1
公开(公告)日：2011-05-19
申请号：PCT/EP2010/067268
申请日：2010-11-11
申请人： BOREALIS AG , AUMO, Jeannette , MATIKAINEN, Pasi , BARTKE, Michael , ELOVIRTA, Tom , VIJAY, Sameer , LYLYKANGAS, Mikko , ELO, Pertti , HUHTANEN, Lauri
发明人： AUMO, Jeannette , MATIKAINEN, Pasi , BARTKE, Michael , ELOVIRTA, Tom , VIJAY, Sameer , LYLYKANGAS, Mikko , ELO, Pertti , HUHTANEN, Lauri
IPC分类号： C08F10/00 , C08F4/659
CPC分类号： C08F10/00 , C08F110/06 , C08F2410/01 , C08F4/65912 , C08F4/65927 , C08F2/00 , C08F2500/12 , C08F4/6492
摘要： The present invention aims to provide a process for polymerizing at least one olefin in the presence of a polymerization catalyst comprising the steps of: (A) continuously introducing a first liquid comprising a transition metal compound, an organometallic compound of a metal of Group 13 of Periodic System of Elements and a solvent, and a second liquid which together with said first liquid is capable of forming an emulsion, into an emulsification stage to produce an emulsion comprising said first liquid dispersed in said second liquid; (B) continuously withdrawing an emulsion stream from said emulsification stage and directing it into a solidification stage to form a slurry comprising a solid polymerization catalyst component comprising said transition metal compound and said organometallic compound suspended in said second liquid; (C) continuously recovering said solid polymerization catalyst component from said solidification stage; (D) directing said solid polymerization catalyst component into a first prepolymerization stage together with a monomer and an amount of second liquid wherein the monomer is prepolymerized onto said solid polymerization catalyst component so that the ratio of the weight of the polymer to the weight of said solid polymerization catalyst component is from 0.1:1 to 20:1 to form a slurry of a prepolymerized solid polymerization catalyst component suspended in said second liquid; (E) recovering said prepolymerized solid polymerization catalyst component from said first prepolymerization stage; (F) continuously introducing said prepolymerized solid polymerization catalyst component into a second prepolymerization stage together with an olefin monomer to form a prepolymerized catalyst comprising in average 100 to 1000 g of polymer per 1 gram of said solid polymerization catalyst component; (G) continuously withdrawing said prepolymerized catalyst from said second prepolymerization stage and directing it into a subsequent polymerization stage together with at least one olefin monomer to effect polymerization of the at least one olefin monomer in the presence of said prepolymerized catalyst. The polymerization process produces polymers in high yield. The morphology of the polymer powder is good and the amount of fine particle polymer is low. The process can be operated for long a long period in a stable manner.
摘要翻译：本发明的目的在于提供一种在聚合催化剂存在下聚合至少一种烯烃的方法，包括以下步骤：（A）连续引入包含过渡金属化合物的第一液体，第13族金属的有机金属化合物元素周期性系统和溶剂，以及与所述第一液体一起能够形成乳液的第二液体进入乳化阶段以产生包含分散在所述第二液体中的所述第一液体的乳液; （B）从所述乳化阶段连续抽出乳液流并将其导入固化阶段以形成包含悬浮在所述第二液体中的包含所述过渡金属化合物和所述有机金属化合物的固体聚合催化剂组分的浆料; （C）从所述固化阶段连续回收所述固体聚合催化剂组分; （D）将所述固体聚合催化剂组分与单体和一定量的第二液体一起引导到第一预聚合阶段，其中所述单体预聚合到所述固体聚合催化剂组分上，使得所述聚合物的重量与所述固体聚合催化剂组分为0.1:1至20:1，以形成悬浮在所述第二液体中的预聚合固体聚合催化剂组分的浆液; （E）从所述第一预聚合阶段回收所述预聚固体聚合催化剂组分; （F）将所述预聚合的固体聚合催化剂组分连同烯烃单体一起连续引入第二预聚合阶段，以形成预聚合的催化剂，每克所述固体聚合催化剂组分平均含有100至1000克聚合物; （G）从所述第二预聚合阶段连续地抽出所述预聚合催化剂，并将其引导至随后的聚合阶段与至少一种烯烃单体，以在所述预聚合的催化剂存在下进行至少一种烯烃单体的聚合。聚合过程以高产率生产聚合物。聚合物粉末的形态好，微粒聚合物的量低。该方法可以长时间稳定运行。

9. 发明申请

WO2010052263A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052263A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064669
申请日：2009-11-05
申请人： BOREALIS AG , HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
发明人： HAKALA, Kimmo , MANSNER, Erik , DENIFL, Peter , LEHTINIEMI, Ismo , KAUHANEN, Jyrki , HUHTANEN, Lauri
IPC分类号： B01J31/12 , B01J31/16 , B01J31/22 , B01J31/14 , C08F4/00
CPC分类号： B01J31/128 , B01J31/143 , B01J31/165 , B01J31/2295 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/65912 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/24
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein • the solid catalyst system (B) • has a porosity measured according to ASTM 4641 of less than 1.40 ml/g, • comprises a transition metal compound of formula (I) L m R n MX q , (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and a cocatalyst (Co) comprising a compound of A1, and • the weight ratio of the polymer matrix (A) and the catalyst system (B) [weight polymer matrix (A)/weight catalyst system (B)] in the solid catalyst composition is below 25.0.
摘要翻译：包含聚合物基体（A）并分布在其中的固体催化剂体系（B）的固体催化剂组合物，其中固体催化剂体系（B）°具有根据ASTM 4641测量的孔隙率小于1.40ml / g的固体催化剂组合物包含式（I）的过渡金属化合物LmRnMXq，（I）其中“M”是周期表（IUPAC）中3至10族中的任何一个的过渡金属，每个“X”独立地是一价阴离子S-配体，每个“L”独立地是与过渡金属（M）配位的有机配体，“R”是连接两个有机配体（L）的桥连基团，“m”是2或3，“n”是0,1或 2中，“q”为1,2或3，m + q等于过渡金属（M）的化合价，以及包含A1化合物的助催化剂（Co），以及聚合物基质的重量比 A）和固体催化剂组合物中的催化剂体系（B）[重量聚合物基质（A）/重量催化剂体系（B）]低于25.0。

10. 发明申请

WO2010052260A1 SOLID CATALYST COMPOSITION 审中-公开
标题翻译：固体催化剂组合物
公开(公告)号：WO2010052260A1
公开(公告)日：2010-05-14
申请号：PCT/EP2009/064666
申请日：2009-11-05
申请人： BOREALIS AG , HAKALA, Kimmo , MANSNER, Erik , HÄTÖNEN, Jari , HUHTANEN, Lauri , TUOMINEN, Olli , AUMO, Jeanette , LEHTINIEMI, Ismo
发明人： HAKALA, Kimmo , MANSNER, Erik , HÄTÖNEN, Jari , HUHTANEN, Lauri , TUOMINEN, Olli , AUMO, Jeanette , LEHTINIEMI, Ismo
IPC分类号： C08F4/00 , B01J31/16 , B01J31/22 , B01J31/12 , B01J31/14
CPC分类号： B01J31/2295 , B01J31/128 , B01J31/143 , B01J31/165 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F210/16 , C08F210/14
摘要： Solid catalyst composition comprising a polymer matrix (A) and distributed therein a solid catalyst system (B), wherein - the solid catalyst system (B) has a porosity measured according to ASTM 4641 of less than 1.40 ml/g, comprises a transition metal compound of formula (I), L m R n MX q (I) wherein "M" is a transition metal of anyone of the groups 3 to 10 of the periodic table (IUPAC), each "X" is independently a monovalent anionic σ-ligand, each "L" is independently an organic ligand which coordinates to the transition metal (M), "R" is a bridging group linking two organic ligands (L), said organic ligands (L) and said bridging groups (R) do not comprise polymerizable olefinic groups, "m" is 2 or 3, "n" is 0, 1 or 2, "q" is 1, 2 or 3, m+q is equal to the valency of the transition metal (M), and a cocatalyst (Co) comprising a compound of Al, and - the mol ratio of Al of the cocatalyst (Co) and the transition metal "M" of the transition metal compound [Al/M] is from 100 to 800 mol/mol.
摘要翻译：固体催化剂组合物，其包含聚合物基质（A）并在其中分布有固体催化剂体系（B），其中固体催化剂体系（B）具有根据ASTM 4641测量的小于1.40ml / g的孔隙，包含过渡金属式（I）的化合物，其中“M”是周期表（IUPAC）的3至10族中的任何一个的过渡金属的LmRnMXq（I），每个“X”独立地是一价阴离子S-配体， L“独立地是与过渡金属（M）配位的有机配体，”R“是连接两个有机配体（L）的桥连基团，所述有机配体（L）和所述桥连基团（R）不包含可聚合烯烃基团“m”为2或3，“n”为0,1或2，“q”为1,2或3，m + q等于过渡金属（M）的化合价和助催化剂 Co）和 - 助催化剂（Co）的Al与过渡金属化合物[Al / M]的过渡金属“M”的摩尔比为100〜800摩尔/摩尔的化合物。

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