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1. 发明申请

WO2011061151A1 ETHYLENE COPOLYMERS 审中-公开
标题翻译：乙烯共聚物
公开(公告)号：WO2011061151A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067490
申请日：2010-11-15
申请人： BASELL POLYOLEFINE GMBH , PIEMONTESI, Fabrizio , ESPOSITO, Simona
发明人： PIEMONTESI, Fabrizio , ESPOSITO, Simona
IPC分类号： C08F210/02
CPC分类号： C08F210/02 , C08F4/65912 , C08F10/00 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/17 , C08F2500/25 , C08F4/65927
摘要： A process for copolymerizing ethylene, comprising the step of contacting ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical under polymerization conditions in the presence of a catalyst system obtainable by contacting: A) a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a hidrocabon group optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R 1 are C 1 -C 40 hydrocarbon radical; R 2 , and R 5 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals; R6, equal to or different from each other, are C1-C20 hydrocarbon radicals; R 3 and R 4 , form together a condensed saturated or unsaturaded C 3 -C 7 -membered ring; B) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally (C) an organo aluminum compound.
摘要翻译：一种使乙烯共聚的方法，其包括使乙烯，一种或多种非共轭环状二烯和任选的一种或多种式CH 2 = CHT的α-烯烃接触的步骤，其中T是C1-C20烷基，在聚合条件下，在催化剂体系可通过以下方式获得：A）式（I）的茂金属化合物，其中：M是钛锆或铪; X为相同或不同的氢原子，卤素原子，任选含有元素周期表第13-17族杂原子的吡啶酮基; R1是C1-C40烃基; R2和R5是氢原子或C1-C20烃基; R6相同或不同，为C1-C20烃基; R3和R4一起形成饱和或不饱和的C3-C7-元环; B）铝氧烷或能够形成烷基茂金属阳离子的化合物; 和（C）有机铝化合物。

2. 发明申请

WO2009115402A1 1-BUTENE TERPOLYMERS 审中-公开
标题翻译： 1-BOTENE TERPOLYMERS
公开(公告)号：WO2009115402A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052364
申请日：2009-02-27
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F210/14 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F210/08 , C08F210/14 , C08F2420/05 , C08F4/65927 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A terpolymer of 1-butene, ethylene and a at least a C 8 -C 12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C 8 -C 12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.
摘要翻译： 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，其含有0.1％至5％（摩尔）的乙烯衍生单元，和1％为20％（摩尔）的C 8 -C 12α-烯烃具有以下性质：i）等于或等于90％的全同立构五单元mmmm; 低于4的五元组（mmrr + mrrm）和13C NMR不能检测到的五元组。 ii）在135℃的四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI -0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是最高的熔融峰在通过DSC测量的第一熔融转变中，不能检测到熔点Tm1。

3. 发明申请

WO2009115395A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115395A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052116
申请日：2009-02-23
申请人： Basell Polyolefine Italia s.r.l. , Resconi, Luigi , Balboni, Davide , Esposito, Simona
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C 8 -C 12 alpha-olefin derived units, preferably at least 1- octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C 8 -C 12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C 8 -C 12 alpha-olefin molar content fulfil the following relationship: 0 8 -C 12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at 13 C NMR.
摘要翻译：含有C-C 12α-烯烃的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元，优选至少1-辛烯衍生单元的共聚物，其含有0％-2％（摩尔）丙烯或戊烯，高于0.2％且低于7.2摩尔％的α-烯烃衍生单元; 具有以下特征：a）通过DSC（TmII）和C8-C12α-烯烃摩尔含量测量的熔点满足以下关系：0 8-C12α-烯烃衍生单元和TmII是在第二次熔融转变; b）在135℃四氢萘中测得的特性粘度（Ⅳ）在0.8和5dL / g之间; 和c）高于或等于90％的全同立构五单元组mmmm; 低于4的五单元组（mmrr + mrrm），在13 C NMR下不能检测到五单元组。

4. 发明申请

WO2009000637A1 1-BUTENE ETHYLENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE乙烯共聚物
公开(公告)号：WO2009000637A1
公开(公告)日：2008-12-31
申请号：PCT/EP2008/057180
申请日：2008-06-09
申请人： BASELL POLYOLEFINE GMBH , PELLEGATTI, Giampaolo , SPATARO, Stefano , MARCHINI, Roberta , GUIDOTTI, Simona , ESPOSITO, Simona
发明人： PELLEGATTI, Giampaolo , SPATARO, Stefano , MARCHINI, Roberta , GUIDOTTI, Simona , ESPOSITO, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F210/16 , C08F4/65927 , C08F2500/03 , C08F2500/11 , C08F2500/20
摘要： A 1-butene ethylene copolymer having an ethylene derived units content ranging from 15.10 % by molto 18.00 % by mol having the following properties: a) distribution of molecular weight lower than 3; preferably b) hardness shore A (measured according to ISO 868) lower than 65; c) tension set lower than 30% at 100% of deformation (ISO 2285) d) no melting pointdetectable at the DSC; e) Melting enthalpy measured after 10 days of aging at room temperature comprised between 4 and 15 J/g.
摘要翻译：乙烯衍生单元含量范围为15.10摩尔％至18.00摩尔％的1-丁烯乙烯共聚物具有以下特性：a）低于3的分子量分布; 优选b）硬度岸A（根据ISO 868测量）低于65; c）100％变形时张力设定低于30％（ISO 2285）d）在DSC下无法检测到熔点; e）在室温下老化10天后测量的熔融焓在4至15J / g之间。

5. 发明申请

WO2008071208A1 TIRE AND CROSSLINKABLE ELASTOMERIC COMPOSITION 审中-公开
标题翻译：轮胎和可交联弹性体组合物
公开(公告)号：WO2008071208A1
公开(公告)日：2008-06-19
申请号：PCT/EP2006/011986
申请日：2006-12-13
申请人： PIRELLI TYRE S.p.A. , POLITECNICO DI MILANO , GALIMBERTI, Maurizio , MELILLO, Gianluca , GUGLIELMONE, Massimiliano , ESPOSITO, Simona
发明人： GALIMBERTI, Maurizio , MELILLO, Gianluca , GUGLIELMONE, Massimiliano , ESPOSITO, Simona
IPC分类号： B60C1/00 , C08K3/34 , C08L9/06
CPC分类号： C08K5/548 , B60C1/0016 , C08K3/346 , C08K3/36 , C08K9/04 , C08L21/00
摘要： Tire comprising at least one structural element including a crosslinked elastomeric material obtained by crosslinking a crosslinkable elastomeric composition comprising : (a) 100 phr of at least one elastomeric polymer; (b) from 0.1 phr to 120 phr, preferably from 20 phr to 90 phr of at least one silica reinforcing filler; (c) from 0.1 phr to 10 phr, preferably from 0.5 phr to 8 phr, of at least one coupling agent containing at least one mercapto group, (d) from 0.5 phr to 20 phr, preferably from 2 phr to 10 phr, of at least one layered material having an individual layer thickness of from 0.01 nm to 30 nm, preferably of from 0.2 nm to 15 nm, more preferably of from 0.5 nm to 2 nm. Preferably, said at least one structural element is a tread band.
摘要翻译：轮胎包括至少一种结构元件，其包括通过交联可交联弹性体组合物获得的交联弹性体材料，其包含：（a）100phr的至少一种弹性体聚合物; （b）0.1phr至120phr，优选20phr至90phr的至少一种二氧化硅增强填料; （c）0.1phr至10phr，优选0.5phr至8phr的至少一种含有至少一个巯基的偶联剂，（d）0.5phr至20phr，优选2phr至10phr的偶联剂至少一层层状材料，其单层厚度为0.01nm至30nm，优选为0.2nm至15nm，更优选为0.5nm至2nm。优选地，所述至少一个结构元件是胎面带。

6. 发明申请

WO2009115399A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115399A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052207
申请日：2009-02-25
申请人： Basell Poliolefine Italia s.r.l. , Resconi, Luigi , Balboni, Davide , Esposito, Simona
发明人： Resconi, Luigi , Balboni, Davide , Esposito, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F2420/05 , C08F4/65927 , C08F210/14 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： A copolymer of 1 -butene and at least a C 8 -C 12 alpha-olefin derived units, having a content of C 8 - C 12 alpha-olefin derived units equal to or higher than 7.2% and lower than 20.0% by mole; endowed with the following features: a) no detectable melting point TmII as the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetraline at 135°C comprised between 0.8 and 5.0 dL/g; c) isotactic pentad mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable at 13 C NMR; d) the tensile modulus (TM) measured with DMTA in MPa and the comonomer content fulfill the following relationship: TM 8 -C 12 alpha-olefin derived units; e) the tension set at 100% of deformation is lower than 55 %; and f) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfill the following relationship: TmI 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition; otherwise the melting point TmI is not detectable by DSC.
摘要翻译：具有等于或高于7.2％且低于20.0摩尔％的C 8 -C 12α-烯烃衍生单元的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元的共聚物; 具有以下特征：a）没有可检测的熔点TmII作为第二熔融转变中最高的熔融峰; b）在135℃下在四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; c）全同立构五价mmmm高于或等于90％; 低于4的五元组（mmrr + mrrm）和在13 C NMR下不能检测到的五元组; d）用DMTA测得的拉伸弹性模量（MPa）和共聚单体含量满足下列关系：TM8-C12α-烯烃衍生单元; e）100％变形时的张力设定值低于55％; 和f）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI 8-C12α-烯烃衍生单元，TmI是第一熔融转变中最高的熔融峰; 否则熔点Tm1不能通过DSC检测。

7. 发明申请

WO2012139897A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012139897A1
公开(公告)日：2012-10-18
申请号：PCT/EP2012/055593
申请日：2012-03-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
发明人： GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
IPC分类号： C08F10/06 , C08F4/651
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于： ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于，0.60。

8. 发明申请

WO2010009955A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2010009955A1
公开(公告)日：2010-01-28
申请号：PCT/EP2009/058108
申请日：2009-06-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F4/6592
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/65927 , C08F2420/05 , C08F210/14 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A crosslinked copolymer of 1-butene and 1-octene or 1-decene; containing from 3.0% to 20.0% by mole of 1-octene or 1-decene derived units;
摘要翻译： 1-丁烯和1-辛烯或1-癸烯的交联共聚物; 含有3.0％至20.0％摩尔的1-辛烯或1-癸烯衍生的单元;

9. 发明申请

WO2009115395A8 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2009115395A8
公开(公告)日：2010-10-07
申请号：PCT/EP2009052116
申请日：2009-02-23
申请人： BASELL POLIOLEFINE SRL , RESCONI LUIGI , BALBONI DAVIDE , ESPOSITO SIMONA
发明人： RESCONI LUIGI , BALBONI DAVIDE , ESPOSITO SIMONA
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F210/14 , C08F210/06 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, preferably at least 1- octene derived units, containing from 0% to 2% by mole of propylene or pentene, having a content of C8-C12 alpha-olefin derived units higher than 0.2% and lower than 7.2% by mole; endowed with the following features: a) the melting point measured by DSC (TmII) and the C8-C12 alpha-olefin molar content fulfil the following relationship: 0 8-C12 alpha-olefin derived units and TmII is the highest melting peak in the second melting transition; b) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5 dL/g; and c) isotactic pentads mmmm higher than or equal to 90 %; pentads (mmrr+mrrm) lower than 4 and pentads rmmr not detectable at 13C NMR.
摘要翻译：含有C-C 12α-烯烃的1-丁烯和至少一种C 8 -C 12α-烯烃衍生单元，优选至少1-辛烯衍生单元的共聚物，其含有0％-2％（摩尔）丙烯或戊烯，高于0.2％且低于7.2摩尔％的α-烯烃衍生单元; 具有以下特征：a）通过DSC（TmII）和C8-C12α-烯烃摩尔含量测量的熔点满足以下关系：0 8-C12α-烯烃衍生单元和TmII是在第二次熔融转变; b）在135℃四氢萘中测得的特性粘度（Ⅳ）在0.8和5dL / g之间; 和c）高于或等于90％的全同立构五单元组mmmm; 低于4的五单元组（mmrr + mrrm），在13 C NMR下不能检测到五单元组。

10. 发明申请

WO2010012587A1 ETHYLENE POLYMERS 审中-公开
标题翻译：乙烯聚合物
公开(公告)号：WO2010012587A1
公开(公告)日：2010-02-04
申请号：PCT/EP2009/058993
申请日：2009-07-14
申请人： BASELL POLYOLEFINE ITALIA S.R.L. , BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
发明人： BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC分类号： C08F210/18 , C08F4/6592
CPC分类号： C08F210/02 , C08F4/65912 , C08F210/18 , C08F4/65927 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17
摘要： A process for copolymerizing ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical comprising the step of contacting the monomers under polymerization conditions in the presence of a catalyst system comprising a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, is a hydrogen atom, a halogen atom, a R, OR, OR'O, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group wherein R is an hydrocarbon radical and R' is a C 1 -C 20 -alkylidene, C 6 -C 20 -arylidene, C 7 -C 20 -alkylarylidene, or C 7 -C 20 -arylalkylidene radical; R 1 , is a C 1 -C 20 -alkyl radical; R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals or two or more R 2 , R 3 , R 4 , and R 5 can also be joined to form a C 3 -C 10 ring; L is a divalent C 1 -C 40 hydrocarbon radical.
摘要翻译：共聚乙烯，一种或多种非共轭环状二烯和任选一种或多种式CH 2 = CHT的α-烯烃的方法，其中T是C 1 -C 20烷基，其包括在聚合条件下，在催化剂体系包含式（I）的茂金属化合物，其中：M是钛锆或铪; X，是氢原子，卤素原子，R，OR，OR'O，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R是烃基，R'是C 1 -C 20亚烷基，C 6 -C 20 亚芳基，C 7 -C 20 - 亚烷基亚芳基或C 7 -C 20 - 芳基亚烷基; R1是C1-C20烷基; R2，R3，R4，R5，R6和R7是氢原子，或C1-C20烃基或两个或更多个R2，R3，R4和R5也可以连接形成C 3 -C 10环; L是二价C1-C40烃基。

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